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The most extensive carbon reservoir system on Earth is found in the vegetation and soil in terrestrial ecosystems, which are essential to preserving the stability of ecosystems. Land use/cover change (LUCC) patterns in terrestrial ecosystems significantly impact carbon storage (CS). Therefore, it is imperative to investigate the relationship between LUCC and CS to coordinate regional ecological conservation and industrial development. In this study, the characteristics of spatial and temporal changes in land use and CS in the Yanqi Basin from 2000 to 2020 were revealed using the PLUS (patch-generating land use simulation) model and the CS module of the InVEST (Integrated Valuation of Ecosystem Services and Tradeoffs) model. This study also predicted the spatial and temporal evolution of CS and the response mechanism of the Yanqi Basin from four scenarios—natural development scenario (NDS), ecological protection scenario (EPS), cropland protection scenario (CPS), and urban development scenario (UDS) for the years 2030, 2040, and 2050. This study shows the following: (1) Between 2000 and 2020, the Yanqi Basin witnessed an expansion in cropland and construction land, the order of the land use dynamic degree which is as follows: construction land > cropland > woodland > unused land > water > grassland. At the same time, the CS exhibited a trend of growth that was followed by a decline, a cumulative decrease of 3.61 Tg. (2) Between 2020 and 2050, woodland, grassland, and unused land decreased under the NDS and UDS. Meanwhile, grassland and woodland showed an expanding trend, and there was a decrease in cropland and construction land under the EPS; the CPS projected an increase in cropland to 3258.06 km2 by 2050. (3) CS under the UDS is always the lowest, and CS under the EPS is the highest; moreover, by 2050, CS under the EPS is projected to increase by 1.18 Tg compared with that under the UDS. The spatial distribution of CS shows a high value in the western part of the region and a low value in the eastern part of the region, which is more in line with the historical spatial distribution. (4) The development of land by human activities is one of the major factors leading to the change of CS. The direct cause of the decrease in CS is the transformation of large areas of cropland and woodland into construction land. Therefore, woodlands must be protected to improve CS and prevent ecological degradation. At the same time, future land use planning in the Yanqi Basin needs to limit the conversion rate of various types of land, control the construction land, optimize the urban pattern, improve the regional CS level, adhere to the concept of striving to achieve carbon neutrality, and realize the sustainable development of the region to provide scientific suggestions for carrying out macro-decision making regarding land use planning in arid areas. [ABSTRACT FROM AUTHOR]

Electroreduction of carbon dioxide (CO2) to chemicals is a promising route to convert and utilize CO2 under atmospheric conditions. However, the relative poor reaction efficiency seriously hinders the practical applications of this route. In this work, flowerlike In2S3 assembled by nanoflakes was synthesized via ionothermal method and exhibited a high Faradaic efficiency (FE) of 86 % with excellent formate formation rate of 478 μmol h−1 cm−2 in ionic liquid (IL) electrolyte. Flowerlike structure can provide large electrochemically active surface area and enhance mass transfer rate. Additionally, density functional theory (DFT) calculations reveal that the origin of the improved performance can be attributed to the large adsorption energy of CO2* and OCHO* intermediate on the (440) facet which is the main exposed crystal facet of flowerlike In2S3.[f1] [ABSTRACT FROM AUTHOR]

Abstract: Electroreduction of carbon dioxide (CO2) into high value‐added products is a potential solution to a reduction in CO2 levels and its utilization. One major challenge is the lack of an efficient system that can highly selectively reduce CO2 into desirable products with low energy consumption. Ionic liquids (ILs) have been used as electrolytes for the electroreduction of CO2, and it has been proven that the CO2–cation complex results in a low‐energy pathway. In this work, an ionic microhabitat (IMH) has been built for CO2 electroreduction, and a novel anion‐functionalized IL, 1‐butyl‐3‐methylimidazolium 1,2,4triazolide ([Bmim][124Triz]), has been designed as the reaction medium. The results showed that the IMH played a key role in enhancing the performance of CO2 electroreduction, especially in dominating the product selectivity, which is recognized to be a great challenge in an electroreduction process. New insights into the role of the IMH in higher CO2 solubility, bending linear CO2 by forming the [124Triz]–CO2− adduct, and transferring activated CO2 into the cathode surface easily were revealed. The Faradaic efficiency for formic acid is as high as 95.2 %, with a current density reaching 24.5 mA cm−2. This work provides a promising way for the design of robust and highly efficient ILs for CO2 electroreduction. [ABSTRACT FROM AUTHOR]

Ammonia (NH3) emissions have caused a wide range of environmental problems and serious harm to human health. However, efficiently separating NH3 and simultaneously recovering high purity NH3 easily remains a great challenge. A new strategy to design transition metal ionic liquids (MILs) by combining specific metal centers and ligands with ILs was proposed for efficient and reversible absorption of NH3. Not only exceptional NH3 absorption capacity and high NH3/CO2 selectivity, but also excellent recyclability were achieved by cobalt ILs [Cnmim]2[Co(NCS)4]. The maximal capacity of NH3 is up to 6.09 mol NH3 mol IL−1 at 30 °C and 0.10 MPa, which is much higher than all reported ILs to date, and is over 30 times higher than the conventional ILs [Cnmim][SCN]. The superior NH3 capacity and desorption performance originate from the moderate Lewis acid–base and cooperative hydrogen bond interactions between the metal center-ligands and NH3. [ABSTRACT FROM AUTHOR]

We previously reported a symmetric monocarbonyl analog of curcumin ( MACs), C66, which demonstrated potential anti-inflammatory activity and low toxicity. In continuation of our ongoing research, we designed and synthesized 34 asymmetric MACs based on C66 as a lead molecule. A majority of the C66 analogs effectively inhibited LPS induction of TNF- α and IL-6 expression. Additionally, a preliminary SAR was conducted. Furthermore, active compounds 4a11 and 4a16 were found to effectively reduce the W/D ratio in the lungs and the protein concentration in the bronchoalveolar lavage fluid ( BALF). Meanwhile, a histopathological examination indicated that these two analogs significantly attenuate tissue injury in the lungs with LPS-induced ALI rats. 4a11 and 4a16 also inhibited mRNA expression of several inflammatory cytokines, including TNF- α, IL-6, IL-1 β, COX-2, ICAM-1 and VCAM-1, in the Beas-2B cells after LPS challenge. Altogether, the data exhibit a series of new C66 analogs as promising anti-inflammatory agents for the treatment of LPS-induced ALI. [ABSTRACT FROM AUTHOR]

Abstract: The increasing emission of carbon dioxide (CO2) caused by the unrestrained consumption of fossil fuels in recent hundreds of years, has caused global environmental and social problems. Meanwhile, CO2 is a cheap, abundant and renewable C1‐feedstock, which can be converted into alcohols, ethers, acids and other value‐added chemicals. Compared with the thermal reactions, electrochemical reduction of CO2 is more attractive because of its advantages by using the seasonal, geographical and intermittent energy (tide, wind and solar) under mild conditions. In recent years, taking ionic liquids (ILs) as electrolytes in the CO2 electrochemical reduction reaction has been paid much more attention due to the advantages of lowering the overpotential of CO2 electroreduction and improving the Faradaic efficiency. In this paper, we summarized the recent progresses of electrochemical reduction of CO2 in ILs electrolytes, and analyzed the reaction mechanism of CO2 reaction in the electrode‐electrolyte interface region by experimental and simulation methods. Finally, the research which needs to be highlighted in this area was proposed. [ABSTRACT FROM AUTHOR]