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Rechargeable sodium-chlorine (Na-Cl2) batteries show high theoretical specific energy density and excellent adaptability for extreme environmental applications. However, the reported cycle life is mostly less than 500 cycles, and the understanding of battery failure mechanisms is quite limited. In this work, we demonstrate that the substantially increased voltage polarization plays a critical role in the battery failure. Typically, the passivation on the porous cathode caused by the deposition of insulated sodium chloride (NaCl) is a crucial factor, significantly influencing the three-phase chlorine (NaCl/Na+, Cl-/Cl2) conversion kinetics. Here, a self-depassivation strategy enabled by iodine anion (I-)-tuned NaCl deposition was implemented to enhance the chlorine reversibility. The nucleation and growth of NaCl crystals are well balanced through strong coordination of the NaI deposition-dissolution process, achieving depassivation on the cathode and improving the reoxidation efficiency of solid NaCl. Consequently, the resultant Na-Cl2 battery delivers a super-long cycle life up to 2000 cycles. An iodine-induced self-depassivation strategy extends Na-Cl2 battery life to 2000 cycles by forming high-reactivity NaCl and lowering the chlorine conversion polarization, which successfully solves a key failure mechanism for superior reversibility. [ABSTRACT FROM AUTHOR]

A fundamental challenge in soil macroecology is to understand how microbial community structure shapes ecosystem function along environmental gradients of the land surface at broad spatial scales (i.e. the horizontal dimension). However, little is known about microbial community structure–function relationships in extreme environments along environmental gradients of soil depth at finer spatial scales (i.e. the vertical dimension). Here, we propose a general spatial dimension partitioning approach for assessing the patterns and drivers of soil microbial community structure–function relationships across horizontal and vertical spatial gradients simultaneously. We leveraged a 200‐km desert soil salinity gradient created by a 12‐year saline‐water irrigation in the Tarim basin of Taklamakan Desert. Specifically, using a general linear model, hierarchical variance partitioning, and a path model, we assessed the patterns and key ecological processes controlling spatial turnover in microbial community structure (i.e. β‐diversity) and enzymatic activity relevant to carbon, nitrogen, and phosphorus cycling along soil salinity gradients across study sites (horizontal dimension) and soil depths (vertical dimension). We found a decoupled relationship between soil microbial β‐diversity and enzymatic activity. Differences in soil depth (on the scale of meters) were as important as geographic distance (on the scale of kilometers) in shaping bacterial and fungal β‐diversity. However, the vertical and horizontal turnover in enzymatic activity was largely attributed to an increase in the heterogeneity of soil properties, such as soil texture, water content, and pH. Our findings suggest that dispersal limitation controls microbial community β‐diversity and that environmental heterogeneity, rather than soil salinization, controls enzymatic activity. Taken together, this work highlights that in the face of ongoing environmental alterations, soil depth is an under‐explored spatial dimension that must be considered in soil conservation efforts as a critical factor in determining microbial community structure and function in extreme environments. [ABSTRACT FROM AUTHOR]

Consumers usually endorse tourism products differently when sharing positive electronic word-of-mouth (eWOM). This research examines the relative persuasiveness of two endorsement styles, that is, explicit endorsement (e.g., "I recommend it") and implicit endorsement (e.g., "I love it"). Drawing on the persuasion knowledge model, we propose that explicit endorsements are less persuasive than implicit endorsements because the former trigger stronger persuasion knowledge. We further argue that source trustworthiness mitigates the persuasion effect difference between the two endorsement styles. This article assesses these hypotheses across different sources (anonymous reviewers, friends, influencers), channels (online community, social commerce platform, social networking app), and products (hotels, restaurants) using secondary data analysis and two experiments. Three studies provide support for our hypotheses. By revealing the relationship between endorsement styles and eWOM persuasiveness, this article provides important implications for implementing effective product endorsement. [ABSTRACT FROM AUTHOR]

A novel multi-combined-step-size normalized subband adaptive filtering algorithm is proposed. Different from the traditional combined-step-size method, by employing a variable mixing parameter on each subband, our designed algorithm is able to combine a large step size with a small one more effectively for each subband. The subband mixing parameters are derived from the variance of the noise-free a priori subband error signals. In this design, a noniterative shrinkage strategy is also utilized to estimate the noise-free a priori subband error signals. Moreover, the mean-square and steady-state performances of the proposed algorithm are studied. Simulation results illustrate that the proposed algorithm outperforms other algorithms mentioned in this paper in terms of tracking capability, convergence speed and steady-state error. [ABSTRACT FROM AUTHOR]

Purpose: Building on the theory of brand psychological ownership, this paper aims to explore the mediating role of brand psychological ownership in the relationship between brand personality (innocence/coolness) and consumers' preferences, as well as identify the boundary conditions of this relationship. Design/methodology/approach: To test the hypotheses, a series of four experiments were conducted in Wuhan, a city in southern China, using questionnaires administered at two universities and two supermarkets. Hypotheses were tested using PLS-SEM in SmartPLS 4. Findings: The results indicate that brand personality, specifically the dimensions of innocence and coolness, has a significant impact on consumers' brand preferences. Brands with a cool personality are preferred over those with an innocent personality. Moreover, the relationship between brand personality and consumers' brand preferences is moderated by power motivation and identity centrality. Originality/value: This study contributes to the literature by differentiating between brand personality of innocence and coolness as two separate constructs and proposing brand psychological ownership as a mechanism through which brand personality affects brand preferences. The study's samples were drawn from universities and supermarkets in southern China, providing evidence for the significant moderating effects of power motivation and identity centrality on consumers' brand preferences. [ABSTRACT FROM AUTHOR]

This study used a mixed method to investigate the dual effects of the flow experience provided by tourism live streaming (TLS) on tourists' travel intentions and how such effects vary across different types of destinations. The results reveal that, in contrast to managers' predictions, while flow experience from TLS may boost offline travel through inspiration, it can also increase tourists' concern for substitutability and thereby reduce their travel intentions. Live streamers' expertise positively moderates the positive effect of flow experience on inspiration. Furthermore, the negative impacts are more salient in highly reputable cultural destinations and natural destinations with limited reputation. [ABSTRACT FROM AUTHOR]

Designing Pt-based electrocatalysts with high catalytic activity and CO tolerance is challenging but extremely desirable for alkaline hydrogen oxidation reaction. Herein we report the design of a series of single-atom lanthanide (La, Ce, Pr, Nd, and Lu)-embedded ultrasmall Pt nanoclusters for efficient alkaline hydrogen electro-oxidation catalysis based on vapor filling and spatially confined reduction/growth of metal species. Mechanism studies reveal that oxophilic single-atom lanthanide species in Pt nanoclusters can serve as the Lewis acid site for selective OH- adsorption and regulate the binding strength of intermediates on Pt sites, which promotes the kinetics of hydrogen oxidation and CO oxidation by accelerating the combination of OH− and *H/*CO in kinetics and thermodynamics, endowing the electrocatalyst with up to 14.3-times higher mass activity than commercial Pt/C and enhanced CO tolerance. This work may shed light on the design of metal nanocluster-based electrocatalysts for energy conversion. Exploring enhanced catalysts for alkaline hydrogen oxidation with high catalytic activity and CO tolerance is highly desired yet challenging. Here, the authors report single-atom lanthanide embedded Pt nanoclusters with high activities and durability. [ABSTRACT FROM AUTHOR]

A brand series employs various letters which make such variations in brand names relatively comparable. However, scant attention has been paid to the influence of alphabetic order in a brand series on consumers' preferences(liking). This research aims to investigate the influence of alphabetic order in a brand series on consumers' preferences(liking) based on space–time congruity theory. With 4 experiments, this paper examines how the alphabetic order in a brand series influences consumers' preferences(liking) and uncovers the underlying psychological mechanism that connects alphabetic order in a brand series and consumers' preferences(liking). The findings indicate that a brand series employing a late letter receives more favors than a comparatively early letter. Newness perception mediates the effect of alphabetic order in brands on consumers' preferences(liking). For the products which accord with "new means advantages" (the time value for these products is "new means more advantages and better performances than old"), a brand series employing a late letter receives more favors than a comparatively early letter. However, for the products which accord with "old means advantages" (the time value for these products is "old means more advantages and better performances than new"), this effect is the opposite. The effect of alphabetic order in a brand series on consumers' preferences(liking) is only significant when consumers are in high involvement condition. The paper provides new insight into the influence of alphabetic order in a brand series on consumers' preferences. [ABSTRACT FROM AUTHOR]

Since the rapid development of network technology, the rise of livestreaming shopping platforms has followed. Some streamers influence consumers' preferences for products through their gender role attributes, thus generating great commercial value. Based on attachment theory and using an experimental approach, this study explored the impact of streamers' gender roles (single gender/androgyny) on consumers' preferences through 2 studies. Study 1 shows the androgynous streamer elicits a higher product preference than the single-gender (masculine and feminine) streamer. Study 2 demonstrates the moderating effect of gender stereotypes through 2 experiments to construct clear boundary conditions for the main effect and the results show that regardless of whether the streamer is male or female when individuals have a high gender stereotype, the single-gender streamer leads to a higher product preference than the androgynous streamer. When individuals have a low gender stereotype, the androgynous streamer promotes a higher product preference than the single-gender streamer. [ABSTRACT FROM AUTHOR]

The color of green product advertisements is an important factor affecting consumers' preferences. Based on the theory of the self-control system, this paper explores the influence mechanism and boundary conditions of green product ad color on consumers' preferences through three experiments. Experiment 1 tested the effect of advertisement color type (green/color) on consumers' preferences for green products. The results show that color ad can promote consumers' preferences for green products compared with green ad. Experiment 1 also analyzed the mediating role of the self-control system between advertisement color type (green/color) and consumers' preferences. Experiment 2 further clarified the boundary of the main effect. The effect of ad color (green/color) on consumers' preferences was only effective in the context of green products. Experiment 3 explored the moderating effect of green product type (egoistic/altruistic) on the main effect. The results show that only when the green product type is altruistic, the ad color type (green/color) can significantly affect consumers' preferences. This study is the first to link the ad color of green products with consumers' preferences. The findings confirm that the use of color ad for green products can elicit higher consumers' preferences than pure green ad, which enriches the research on the color of green product advertisements. [ABSTRACT FROM AUTHOR]

The color of green product advertisements is an important factor affecting consumers’ preferences. Based on the theory of the self-control system, this paper explores the influence mechanism and boundary conditions of green product ad color on consumers’ preferences through three experiments. Experiment 1 tested the effect of advertisement color type (green/color) on consumers’ preferences for green products. The results show that color ad can promote consumers’ preferences for green products compared with green ad. Experiment 1 also analyzed the mediating role of the self-control system between advertisement color type (green/color) and consumers’ preferences. Experiment 2 further clarified the boundary of the main effect. The effect of ad color (green/color) on consumers’ preferences was only effective in the context of green products. Experiment 3 explored the moderating effect of green product type (egoistic/altruistic) on the main effect. The results show that only when the green product type is altruistic, the ad color type (green/ color) can significantly affect consumers’ preferences. This study is the first to link the ad color of green products with consumers’ preferences. The findings confirm that the use of color ad for green products can elicit higher consumers’ preferences than pure green ad, which enriches the research on the color of green product advertisements. [ABSTRACT FROM AUTHOR]

This study employs morality preference theory to explore how acknowledgment type (self- vs. other-focused) influences donors' subsequent donation desires. The current research consists of 3 studies. Study 1 finds that an other-focused acknowledgment letter elicits higher subsequent donation desires than a self-focused letter. Study 2 testifies to the mediating role of morality preference between the relationship of acknowledgment type and subsequent donation desires. Study 3 manipulates the moral value on "what is the morally right thing of donation" and developed a new scale to measure morality preference. Study 4 excludes the influence of language structure and tests the main effect in a real donation behavior context. [ABSTRACT FROM AUTHOR]

Taking the Giant Panda National Park as an example, this paper uses factor analysis to measure residents' financial awareness and mediating effect models to investigate the influence paths of community governance, financial awareness, and residents' willingness to participate in the construction and development of national parks. Finally, it suggests potential solutions for national park development and biodiversity conservation. The results indicated that financial awareness and community governance levels had a positive effect on residents' willingness to participate, and satisfaction with community governance played a significant partially mediating role in their financial awareness, which in turn influenced their level of willingness. [ABSTRACT FROM AUTHOR]

Soil is the largest terrestrial reservoir of organic carbon and is central for climate change mitigation and carbon-climate feedbacks. Chemical and physical associations of soil carbon with minerals play a critical role in carbon storage, but the amount and global capacity for storage in this form remain unquantified. Here, we produce spatially-resolved global estimates of mineral-associated organic carbon stocks and carbon-storage capacity by analyzing 1144 globally-distributed soil profiles. We show that current stocks total 899 Pg C to a depth of 1 m in non-permafrost mineral soils. Although this constitutes 66% and 70% of soil carbon in surface and deeper layers, respectively, it is only 42% and 21% of the mineralogical capacity. Regions under agricultural management and deeper soil layers show the largest undersaturation of mineral-associated carbon. Critically, the degree of undersaturation indicates sequestration efficiency over years to decades. We show that, across 103 carbon-accrual measurements spanning management interventions globally, soils furthest from their mineralogical capacity are more effective at accruing carbon; sequestration rates average 3-times higher in soils at one tenth of their capacity compared to soils at one half of their capacity. Our findings provide insights into the world's soils, their capacity to store carbon, and priority regions and actions for soil carbon management. Mineral-organic associations play a key role in soil carbon preservation. Here, Georgiou et al. produce global estimates of mineral-associated soil carbon, providing insight into the world's soils and their capacity to store carbon [ABSTRACT FROM AUTHOR]

Purpose: The purpose of this research is to explore how experienced scarcity affects home country consumers' attitudes toward the firm engaging in cross-border philanthropy by analyzing perceived distributive justice as a mediating variable. This research also investigates the moderating factor of this effect to identify practical strategies for managers. Design/methodology/approach: This research conducted one survey (Study 1) and three experiments (Studies 2–4) by manipulating scarcity to provide robust evidence for the influence of experienced scarcity on consumer perception of the company conducting cross-border philanthropy. Findings: This paper provides empirical insights about the significant negative effect of experienced scarcity on consumer attitudes toward the firm engaging in cross-border philanthropy. It proposes that home country consumers with high versus low experienced scarcity show lower perceived distributive justice for cross-border philanthropy, which generates less favorable attitudes toward the firm. To alleviate the negative impact of experienced scarcity on consumers' perceptions of corporate reputation, providing donation amount comparisons between home and foreign countries has a significant moderating effect. Practical implications: This paper provides several suggestions for marketers seeking cross-border philanthropy to improve consumers' attitudes toward the firm. Originality/value: This paper enriches the literature on corporate social responsibility in the domain of cross-border philanthropy and explains contradictory findings on consumers' attitudes toward corporate cross-border philanthropy. Moreover, this study makes meaningful contributions to the scarcity and justice literature. [ABSTRACT FROM AUTHOR]

Soils are important carbon (C) reservoirs and play a critical role in regulating the global C cycle. Soil water potential (SWP) measures the energy with which water is retained in the soil and is one of the most vital factors that constrain the decomposition of soil organic C (SOC). The measurements for soil water retention curve (SWRC), on which the estimation of SWP depends, are usually carried out above −1.5 MPa (i.e., the wilting point for many plants). However, the average moisture threshold at which soil microbial activity ceases is usually below −10 MPa in mineral soils. Beyond the measurement range, the SWP estimation has to be derived from extrapolating the SWRC, which violates the statistical principle, resulting in possibly inaccurate SWP estimations. To date, it is unclear to what extent the extrapolated SWP estimation deviates from the "true value" and how it impacts the modeling of SOC decomposition. This study combined SWRC measurements down to −43.7 MPa, a 72‐day soil incubation experiment with four moisture levels, and an SOC decomposition model. In addition to the complete SWRC (SWRCall), we fitted two more SWRCs by using measurements above −0.5 MPa (SWRC0.5) and −1.7 MPa (SWRC1.7), respectively, to quantify the deviations of extrapolated SWPs from the complete SWRC. Results showed that extrapolating the SWRC beyond its measurement range significantly underestimated the SWP. Incorporating the extrapolated SWP in the model significantly underestimated the SOC decomposition under relatively dry conditions. With the extrapolated SWP, the model predicted no SOC decomposition in the driest treatment, while the experiment observed a significant CO2 emission. The results emphasize that accurate SWP estimations beyond the wilting point are critically needed to improve the modeling of SOC decomposition. [ABSTRACT FROM AUTHOR]

Salinization poses great threats to soil fungal communities that would cause the losses of ecosystems services. Soil fungal communities are composed of different functional guilds such as saprotrophic, symbiotrophic, and pathotrophic fungi, and each guild includes many rare taxa and a few abundant taxa. Despite of low abundance, rare taxa may be crucial in determining the responses of entire soil fungal communities to salinization. However, it remains poorly understood how rare taxa mediate the impacts of soil salinization on soil fungal community structure. Here, we took advantage of a salinity gradient in a desert ecosystem ranging from 0.60 to 31.09 g kg−1 that was created by a 12-year saline-water irrigation and assessed how the rare vs. abundant taxa of soil saprotrophic, symbiotrophic, and pathotrophic fungi respond to soil salinization through changes in the community biodiversity and composition. We found that the rare taxa of soil saprotrophic, symbiotrophic, and pathographic fungi were more sensitive to changes in soil salinity compared to the abundant taxa. In addition, the community composition of rare taxa of the saprotrophic and pathotrophic fungi not the symbiotrophic fungi was positively associated with soil salinity change. However, the symbiotrophic fungi showed greater variations in the species richness along the salinity gradient. These findings highlight the importance to differentiate rare taxa in predicting how the biodiversity and functional groups of soil fungal communities respond to soil salinization. [ABSTRACT FROM AUTHOR]

The rationally structural engineering is an efficient strategy to improve the comprehensive performance of potassium‐ion storage anode materials. In this paper, a hybrid with hollow FeS2 nanoparticles anchored into the 3D carbon skeleton (labeled as H‐FeS2@3DCS) is successfully constructed through two critical steps of in situ chemical deposition and anion‐exchange reaction strategies. In the former, the water‐soluble Na2CO3 crystals are used as hard templates for the preparation of 3DCS, while Fe3+‐containing aqueous solutions are utilized to remove the Na2CO3 templates. Interestingly, the intense collision between Fe3+ and CO32‐ in aqueous solution produces nanoscale Fe(OH)3 colloidal particles, which are firmly anchored into the pores of the carbon skeleton to form a "lotus‐seed"‐like nanostructure. In the latter case, a central void space is created inside the FeS2 nanoparticles due to the different diffusion rates of S‐anions and Fe‐cations during the subsequent sulfidation process. Thanks to this unique composition model, the H‐FeS2@3DCS hybrid not only alleviates the volume expansion efficiently by rationally hollow structure design, but also provides spacious "roads" (3D carbon skeleton) and "houses" (hollow FeS2 nanoparticles) for fast K‐ion transition and storage. As the anode of PIBs and PIHCs, the resultant H‐FeS2@3DCS electrode delivers an obviously enhanced K‐ions storage performance over state‐of‐the‐art. [ABSTRACT FROM AUTHOR]

We study a parallel multi-access edge computing (MEC) system in this work and investigate its energy-efficient resources management. Particularly, the MEC system consists of an edge node and a number of mobile users, where each user has an inelastic computing task with nonnegligible duration of task execution and nonnegligible size of task result. In addition, the MEC system operates in orthogonal frequency division multiple access (OFDMA) wireless networks and can support the transmission as well as the execution of different tasks in parallel. On this basis, we build a nonconvex mixed-integer nonlinear programming (MINLP) problem aiming to minimize the energy consumed by the system. By using the McCormick method and exploring the problem's structural properties, we first equivalently transform it to a manageable convex MINLP problem, and then devise two low-complexity suboptimal algorithms. Finally, numerical results are presented to show the effectiveness of our proposed algorithms. [ABSTRACT FROM AUTHOR]

Both happy and sad facial expressions of recipients are frequently used in charity advertisements. However, the relative effectiveness of these two types of facial expressions has been found paradoxical in the past. In this study, we examine when happy facial expression can more effectively increase donation intentions of consumers and when vice versa. Specially, we propose that eye contact between a donor and a potential recipient may moderate the relative effectiveness of happy and sad facial expressions, and further explain the interaction effect from the perspective of emotional intensity. Results from two experiments suggest that, when donor-recipient eye contact is present, consumers tend to have stronger emotional intensity, and, in turn, show higher donation intentions when the recipient is with a happy rather than sad facial expression. In contrast, when the eye contact is absent, consumers may show stronger emotional intensity and donation intentions toward the charity advertisement with a recipient showing sad rather than happy expression. [ABSTRACT FROM AUTHOR]

Quantifying the upper limit of stable soil carbon storage is essential for guiding policies to increase soil carbon storage. One pool of carbon considered particularly stable across climate zones and soil types is formed when dissolved organic carbon sorbs to minerals. We quantified, for the first time, the potential of mineral soils to sorb additional dissolved organic carbon (DOC) for six soil orders. We compiled 402 laboratory sorption experiments to estimate the additional DOC sorption potential, that is the potential of excess DOC sorption in addition to the existing background level already sorbed in each soil sample. We estimated this potential using gridded climate and soil geochemical variables within a machine learning model. We find that mid- and low-latitude soils and subsoils have a greater capacity to store DOC by sorption compared to high-latitude soils and topsoils. The global additional DOC sorption potential for six soil orders is estimated to be 107 ± 13 Pg C to 1 m depth. If this potential was realized, it would represent a 7% increase in the existing total carbon stock. [ABSTRACT FROM AUTHOR]

Template‐assistant design and fabrication of porous carbon electrode materials has experienced great progress throughout the past decades and yielded lots of successes via various gas or solid state templates. Nevertheless, liquid‐state templates are rather rare in preparing porous carbon materials to date. In this work, melting B2O3 beads are used as both templates and a B dopant, leading to unique B, N co‐doping hierarchically porous carbons containing a "bubble pool"‐like skeleton built of interconnected carbon nanobubbles. Notably, an interesting amending effect of doped B atoms on the N‐doped carbon network can be identified for the first time, which creates a "paddy field"‐like hybrid microstructure with the co‐existence of sp2 short‐range order and sp3 defective areas, leading to an ideal model of carbon materials with both good conductivity and high capacity. Together with the rich ion diffusing pathways and the structural integrity of the "bubble pool"‐like skeleton, the resultant electrode delivers a comprehensive K‐ion storage performance. Therefore, the findings demonstrate the unique pore‐making merits of liquid state templates, which may open the door for exploring porous carbons with more innovations of microstructures and functionalities for applications in energy storage and other fields. [ABSTRACT FROM AUTHOR]

Many studies highlight the merits of positive reviews on social networking sites (SNSs), suggesting that consumers tend to consider these to be trustworthy recommendations. This study draws attention to the potential negative effects of luxury hotels' positive reviews on SNSs. We propose that positive reviews may encourage social comparison and trigger feelings of malicious envy, thereby negatively influencing purchase intentions. Results from two experiments show that high similarity between the review writer and readers increases readers' social comparison tendency, which induces malicious envy when the writer is considered undeserving of luxury hotel consumption. This leads to decreased purchase intentions toward the hotel brand mentioned in the review and increased purchase intentions toward competing hotel brands. The findings have implications for buzz marketing strategies seeking to mitigate the risk of eliciting malicious envy on SNSs. [ABSTRACT FROM AUTHOR]

Purpose: This study aims to investigate the impact of cross-border charitable activities on host- and home-country consumers based on the social identity theory. Design/methodology/approach: Through an extensive literature review and two experimental designs, this study establishes the research framework and hypothesises the relationships between the constructs. Findings: National power moderates the impact of cross-border charitable activities on host- and home-country consumers. In particular, compared to countries with high national power, countries with low national power undertaking cross-border charitable activities will receive more positive reactions from the host-country consumers, and, conversely, more negative reactions from the home-country consumers. Research limitations/implications: From the consumer perspective, this study finds that brand cross-border charitable activities have different influences on consumers in different countries because of an identity transformation mechanism that exists between the "insiders" and the "outsiders", which is different from the assumptions of western theories. Practical implications: The findings provide insights for undertaking brand cross-border charitable activities. Originality/value: Previous studies, which are based on social identity categorisation, assume that cross-border charitable activities have a more positive impact on home-country consumers than host-country consumers. However, this study adopts the research paradigm of social identity relationisation and draws an opposite conclusion, which not only expands the theory of local intergroup interaction, but also clarifies how brand cross-border charitable activities influence Chinese consumers. [ABSTRACT FROM AUTHOR]

The large volume expansion induced by K+ intercalation is always a big challenge for designing high‐performance electrode materials in potassium‐ion storage system. Based on the idea that large‐sized ions should accommodate big "houses," a facile‐induced growth strategy is proposed to achieve the self‐loading of MoS2 clusters inside a hollow tubular carbon skeleton (HTCS). Meantime, a step‐by‐step intercalation technology is employed to tune the interlayer distance and the layer number of MoS2. Based on the above, the ED‐MoS2@CT hybrids are achieved by self‐loading and anchoring the well‐dispersed ultrathin MoS2 nanosheets on the inner surface of HTCSs. This unique compositing model not only alleviates the mechanical strain efficiently, but also provides spacious "roads" (hollow tubular carbon skeleton) and "houses" (interlayer expanded ultrathin MoS2 sheets) for fast K+ transition and storage. As an anode of potassium‐ion batteries, the resultant ED‐MoS2@CT electrode delivers a high specific capacity of 148.5 mAh g−1 at 2 A g−1 after 10 000 cycles with only 0.002% fading per cycle. The assembled ED‐MoS2@CT//PC potassium‐ion hybrid supercapacitor device shows a high energy density of 148 Wh kg−1 at a power density of 965 W kg−1, which is comparable to that of lithium‐ion hybrid supercapacitors. [ABSTRACT FROM AUTHOR]

Purpose: Extreme online reviews can have great impacts on consumers' purchase decisions. The purpose of this paper is to investigate when users are more likely to provide extreme ratings. The study draws inference from attitude certainty theory and proposes that review extremity is influenced by the interaction of evaluation duration and product/service types: for hedonic products/services, shorter evaluation duration can foster attitude certainty, leading to higher review extremity; in contrast, for utilitarian products/services, longer evaluation duration can increase attitude certainty, resulting in more extreme reviews. Design/methodology/approach: Three studies were conducted to test the hypotheses: Study 1 is an empirical analysis of 3,000 reviews from an online retailing website; Studies 2 and 3 are two between-subject experiments. Findings: Results from three studies confirm the hypotheses. Study 1 provides preliminary evidence on how review extremity varies in evaluations of different durations and product/service types. Results from Studies 2 and 3 show that for hedonic products/services, the shorter the evaluation duration, the more likely users are to give extreme ratings; however, for utilitarian products/service, the longer the evaluation duration, the more likely users are to give extreme reviews; and attitude certainty plays a mediating role between evaluation duration and review extremity. Originality/value: Findings from this study provide understandings on when a fast rather than a slow evaluation can lead to more extreme reviews. The results also highlight the role of users' attitude certainty in the underlying mechanism. [ABSTRACT FROM AUTHOR]

With the rapid development of artificial intelligence, information system, and mobile technologies, some companies (e.g. airlines) consider fully replacing service employees with self-service technologies (SSTs) to cut down costs and to increase efficiency. However, replacing full services with SSTs sometimes fail to deliver the benefits companies have hoped for: users may feel that they are being forced to use SSTs and show resistance to the new technologies. To investigate why users show resistance, we draw inferences from psychological reactance theory and argue that users may perceive the forced adoption as a threat, which leads to resistance of SSTs. A conceptual model was developed and an empirical study was conducted. The results show that, under a forced situation, users are likely to perceive the forced adoption as a threat to their freedom, causing them to have negative emotions and perceptions towards the SSTs, and, in turn, their adoption intention decreases and switch intention increases. The findings provide insights on why users show resistance to SSTs and highlight the impacts of the motivational state of psychological reactance. [ABSTRACT FROM AUTHOR]

The roles of soil fungal diversity and community composition in regulating soil respiration when above‐ and below‐ground plant carbon (C) inputs are excluded remain unclear. In the present study, we aimed to examine the following. (a) How does the exclusion of above‐ and below‐ground plant C inputs affect soil respiration and soil fungi singly and in combination? (b) Are changes in soil fungal diversity aligned with changes in soil respiration? A field experiment with manipulation of plant C inputs was established in a subtropical forest in southwest China in 2004 with litter removal and tree stem‐girdling to exclude inputs of the above‐ and below‐ground plant C, respectively. In 2009, we measured the rates of soil respiration with an infrared gas analyser and soil fungal community structure using Illumina sequencing. We found that the rates of soil respiration were reduced significantly by litter removal and girdling, by similar magnitudes. However, they were not decreased further by the combination of these two treatments compared to either treatment alone. In contrast, litter removal increased the diversity of soil fungal communities, whereas girdling decreased the abundance of symbiotrophic fungi but increased the abundance of saptrotrophic and pathotrophic fungi. These changes in soil fungal community might initiate CO2 emission from soil C decomposition, offsetting further decline in soil respiration when plant C inputs are excluded. These results revealed that the exclusion of the above‐ and below‐ground plant C inputs led to contrasting soil fungal communities but similar soil function. Our findings suggest that both above‐ and below‐ground plant C are important in regulating soil respiration in subtropical forests, by limiting substrates for soil fungal growth and altering the diversity and composition of the soil fungal community. Highlights: Litter removal and girdling decreased soil respiration by similar magnitudesThe combination of litter removal and girdling did not further decrease soil respirationLitter removal significantly increased species richness of soil fungal communitiesGirdling changed the abundance of functional guilds of soil fungal communities [ABSTRACT FROM AUTHOR]

Whether the dryland to cropland conversation in arid regions could lead to a decrease in soil carbon (C) and land degradation remains unclear. In this study, we investigated the vertical patterns of soil C change with different lengths of land use history in the arid regions of China and explored the controls and mechanisms of these changes. One native desert grassland and six croplands with similar management but different cultivation times (i.e., 1, 3, 5, 15, 30, and 50 years) and were selected in Xinjiang, Northwest China. We measured both soil organic and inorganic C concentrations and soil properties (e.g., total nitrogen [N], NO3−‐N, NH4+‐N, pH, and electrical conductivity) with a 20‐cm depth interval down to 2 m in all croplands. The results showed that soil organic carbon (SOC) stocks increased with cultivation year for the topsoils (0–120 cm), which could be a result of higher plant C inputs and decreased soil pH in cropland than in the native desert. Soil pH explained the largest variation (45%) of SOC concentration. Soil inorganic C (SIC) stocks decreased with cultivation year in topsoils layers (0–40 cm) but increased in deep soil layers (120–200 cm), resulting in the net increment of SIC to the depth of 200 cm. This pattern might be caused by changes in soil pH in the cropland. Overall, this study demonstrated that, instead of reducing soil C, proper management of the desert ecosystem can enhance soil C sequestration in the arid regions. [ABSTRACT FROM AUTHOR]

Agroforestry (AF) has the potential to restore degraded lands, provide a broader range of ecosystem goods and services such as carbon (C) sequestration and high biodiversity, and increase soil fertility and ecosystem stability through additional C input from trees, erosion prevention, and microclimate improvement. Advantages and processes for global C sequestration in AF are unknown. We used a meta‐analysis of 427 soil C stock data pairs grouped into four main AF systems—alley cropping, windbreaks, silvopastures, and homegardens—and evaluated changes in AF and adjacent control cropland or pasture. Mean soil C stocks in AF (1‐m depth) were 126 Mg C·ha−1, which is 19% more than that in cropland or pasture. The highest C stocks in soil were in subtropical homegardens, AF with younger trees, and topsoil (0–20 cm). Increased soil C stocks in AF were lower than aboveground C stocks in most AF systems, except alley cropping. Homegardens stored the highest C in both aboveground and belowground, especially in the subsoil (20–100 cm). Advantages of AF ecosystem services focusing on mechanisms of belowground C sequestration were analyzed. AF could store 5.3 × 109 Mg additional C in soil on 944 Mha globally, with most in the tropics and subtropics. AF systems could greatly contribute to global soil C sequestration if used in larger areas. Future investigations of AF should include (a) mechanistic‐ and process‐based studies (instead of common monitoring and inventories), (b) models linking forest and crop growth with soil water and C and nutrient cycling, and (c) accurate assessments of the AF area worldwide based on the remote sensing approaches. [ABSTRACT FROM AUTHOR]

Aims: This study aimed to evaluate the associations between types of night shift work and different indices of obesity using the baseline information from a prospective cohort study of night shift workers in China. Methods: A total of 3,871 workers from five companies were recruited from the baseline survey. A structured self-administered questionnaire was employed to collect the participants’ demographic information, lifetime working history, and lifestyle habits. Participants were grouped into rotating, permanent and irregular night shift work groups. Anthropometric parameters were assessed by healthcare professionals. Multiple logistic regression models were used to evaluate the associations between night shift work and different indices of obesity. Results: Night shift workers had increased risk of overweight and obesity, and odds ratios (ORs) were 1.17 (95% CI, 0.97–1.41) and 1.27 (95% CI, 0.74–2.18), respectively. Abdominal obesity had a significant but marginal association with night shift work (OR = 1.20, 95% CI, 1.01–1.43). A positive gradient between the number of years of night shift work and overweight or abdominal obesity was observed. Permanent night shift work showed the highest odds of being overweight (OR = 3.94, 95% CI, 1.40–11.03) and having increased abdominal obesity (OR = 3.34, 95% CI, 1.19–9.37). Irregular night shift work was also significantly associated with overweight (OR = 1.56, 95% CI, 1.13–2.14), but its association with abdominal obesity was borderline (OR = 1.26, 95% CI, 0.94–1.69). By contrast, the association between rotating night shift work and these parameters was not significant. Conclusion: Permanent and irregular night shift work were more likely to be associated with overweight or abdominal obesity than rotating night shift work. These associations need to be verified in prospective cohort studies. [ABSTRACT FROM AUTHOR]

Soil organic carbon (SOC) can be defined by measurable chemical and physical pools, such as mineral-associated carbon, carbon physically entrapped in aggregates, dissolved carbon, and fragments of plant detritus. Yet, most soil models use conceptual rather than measurable SOC pools. What would the traditional pool-based soil model look like if it were built today, reflecting the latest understanding of biological, chemical, and physical transformations in soils? We propose a conceptual model-the Millennial model-that defines pools as measurable entities. First, we discuss relevant pool definitions conceptually and in terms of the measurements that can be used to quantify pool size, formation, and destabilization. Then, we develop a numerical model following the Millennial model conceptual framework to evaluate against the Century model, a widely-used standard for estimating SOC stocks across space and through time. The Millennial model predicts qualitatively similar changes in total SOC in response to single factor perturbations when compared to Century, but different responses to multiple factor perturbations. We review important conceptual and behavioral differences between the Millennial and Century modeling approaches, and the field and lab measurements needed to constrain parameter values. We propose the Millennial model as a simple but comprehensive framework to model SOC pools and guide measurements for further model development. [ABSTRACT FROM AUTHOR]

Quantifying soil organic carbon ( SOC) decomposition under warming is critical to predict carbon-climate feedbacks. According to the substrate regulating principle, SOC decomposition would decrease as labile SOC declines under field warming, but observations of SOC decomposition under warming do not always support this prediction. This discrepancy could result from varying changes in SOC components and soil microbial communities under warming. This study aimed to determine the decomposition of SOC components with different turnover times after subjected to long-term field warming and/or root exclusion to limit C input, and to test whether SOC decomposition is driven by substrate lability under warming. Taking advantage of a 12-year field warming experiment in a prairie, we assessed the decomposition of SOC components by incubating soils from control and warmed plots, with and without root exclusion for 3 years. We assayed SOC decomposition from these incubations by combining inverse modeling and microbial functional genes during decomposition with a metagenomic technique (GeoChip). The decomposition of SOC components with turnover times of years and decades, which contributed to 95% of total cumulative CO2 respiration, was greater in soils from warmed plots. But the decomposition of labile SOC was similar in warmed plots compared to the control. The diversity of C-degradation microbial genes generally declined with time during the incubation in all treatments, suggesting shifts of microbial functional groups as substrate composition was changing. Compared to the control, soils from warmed plots showed significant increase in the signal intensities of microbial genes involved in degrading complex organic compounds, implying enhanced potential abilities of microbial catabolism. These are likely responsible for accelerated decomposition of SOC components with slow turnover rates. Overall, the shifted microbial community induced by long-term warming accelerates the decomposition of SOC components with slow turnover rates and thus amplify the positive feedback to climate change. [ABSTRACT FROM AUTHOR]

Soil organic carbon ( SOC) dynamics are regulated by the complex interplay of climatic, edaphic and biotic conditions. However, the interrelation of SOC and these drivers and their potential connection networks are rarely assessed quantitatively. Using observations of SOC dynamics with detailed soil properties from 90 field trials at 28 sites under different agroecosystems across the Australian cropping regions, we investigated the direct and indirect effects of climate, soil properties, carbon (C) inputs and soil C pools (a total of 17 variables) on SOC change rate ( r C, Mg C ha−1 yr−1). Among these variables, we found that the most influential variables on r C were the average C input amount and annual precipitation, and the total SOC stock at the beginning of the trials. Overall, C inputs (including C input amount and pasture frequency in the crop rotation system) accounted for 27% of the relative influence on r C, followed by climate 25% (including precipitation and temperature), soil C pools 24% (including pool size and composition) and soil properties (such as cation exchange capacity, clay content, bulk density) 24%. Path analysis identified a network of intercorrelations of climate, soil properties, C inputs and soil C pools in determining r C. The direct correlation of r C with climate was significantly weakened if removing the effects of soil properties and C pools, and vice versa. These results reveal the relative importance of climate, soil properties, C inputs and C pools and their complex interconnections in regulating SOC dynamics. Ignorance of the impact of changes in soil properties, C pool composition and C input (quantity and quality) on SOC dynamics is likely one of the main sources of uncertainty in SOC predictions from the process-based SOC models. [ABSTRACT FROM AUTHOR]

Introduction: To generate information for the effective management of soil organic carbon (SOC) sequestration in Chinese croplands, we compared the additional organic carbon (C) that can be stabilized by fine soil particles (<20 µm) with typical fertilization practices across soil types and climate zones. Using data from 30 long-term experimental study sites across the major agricultural zones in China, we estimated stable SOC saturation deficit (SOCdeficit) under no fertilization (CK), chemical fertilization (CF), straw plus CF (S + CF), and manure plus CF (M + CF). Stable SOCdeficit was defined as the difference between potential and current SOC stabilized by fine soil particles. Outcomes: Stable SOCdeficit values varied from 51% to 82%. Soils dominated by 2:1 clay minerals showed larger stable SOCdeficit than soils dominated by 1:1 clay minerals under each treatment. For soils dominated by 2:1 clay minerals, stable SOCdeficit was significantly lower under M + CF (69%) than under CK, CF, and S + CF (78-82%) treatments, and it increased with increasing mean annual temperature (<10°C). In soils dominated by 1:1 clay minerals, stable SOCdeficit was considerably lower in paddy and paddy-upland than in upland soils, suggesting that paddies effectively stabilize C inputs. Discussion: Agricultural soils in China have considerable C sequestration potential, despite decades of fertilization practices. To manage soil C sequestration and model soil C dynamics effectively, factors such as soil mineral types, fertilization, and cropland use should be considered. Conclusion: Our results demonstrated that manure addition was the best fertilization method for improving soil fertility, whereas straw return in Chinese croplands should take into account climate mitigation in future. [ABSTRACT FROM AUTHOR]

Unprecedented levels of nitrogen (N) have been deposited in ecosystems over the past century, which is expected to have cascading effects on microbially mediated soil respiration ( SR). Extracellular enzymes play critical roles on the degradation of soil organic matter, and measurements of their activities are potentially useful indicators of SR. The links between soil extracellular enzymatic activities ( EEAs) and SR under N addition, however, have not been established. We therefore conducted a meta-analysis from 62 publications to synthesize the responses of soil EEAs and SR to elevated N. Nitrogen addition significantly increased glycosidase activity ( GA) by 13.0%, α-1,4-glucosidase ( AG) by 19.6%, β-1,4-glucosidase ( BG) by 11.1%, β-1,4-xylosidase ( BX) by 21.9% and β-D-cellobiosidase ( CBH) by 12.6%. Increases in GA were more evident for long duration, high rate, organic and mixed N addition (combination of organic and inorganic N addition), as well as for studies from farmland. The response ratios ( RRs) of GA were positively correlated with the SR- RRs, even when evaluated individually for AG, BG, BX and CBH. This positive correlation between GA- RR and SR- RR was maintained for most types of vegetation and soil as well as for different methods of N addition. Our results provide the first evidence that GA is linked to SR under N addition over a range of ecosystems and highlight the need for further studies on the response of other soil EEAs to various global change factors and their implications for ecosystem functions. [ABSTRACT FROM AUTHOR]

Purpose: Little is known about the biogeochemical properties of millennia-old soil organic matter (SOM) in boreal forest paleosols and whether these properties contribute to the persistence of several millennia-old SOM. In this study, we assessed the physicochemical properties of a well-drained paleosol and looked for links between these properties and the mineralizable carbon (C) fraction. Materials and methods: We studied a well-drained paleosol located under a typical forest podzol in Northern Sweden, in which up to 7-kyr-old SOM was preserved according to C dating. We assessed the elemental compositions of the outermost 2-μm and 10-nm soil particle surfaces by using energy-dispersive X-ray scanning electron microscopy and X-ray photoelectron spectroscopy, respectively. We also conducted a 5-week laboratory incubation of samples from both the paleosol and the podzol to quantify their mineralizable C fractions and analyzed the thermal stability of soil samples before and after incubation by using temperature-programmed desorption coupled with mass spectrometry techniques. Results and discussion: Proxies for weathering (i.e., total mineral surface area and Al/Si and Fe/Si ratios of particle surfaces) suggested that the paleosol was at the same weathering stage as the contemporary forming podzol. Mineral soil particle surfaces of both the paleosol and podzol were dominated by aliphatic and ether/alcohol C functional groups. The incubation and thermal analysis showed that the mineralizable C fraction of the paleosol was smaller than that of the podzol, and losses of thermally labile SOM due to microbial degradation during the incubations were only detected in the mineral free O horizon of the podzol. Moreover, the mineralizable C fraction of the sampled podzol-paleosol sequence was correlated to the proportion of ether/alcohol C functional groups at the outermost 10-nm soil particle surfaces. Conclusions: Based on the links between microbial decomposition and the chemistry of soil particle surfaces and the thermal stability difference between organic and mineral soils induced by microbial decomposition, we conclude that the intrinsic chemical properties of SOM and its chemical surroundings is important for SOM preservation over a millennia timescale in the studied soil. [ABSTRACT FROM AUTHOR]

Organic carbon (C) associated with fine soil particles (<20 μm) is relatively stable and accounts for a large proportion of total soil organic C (SOC). The soil C saturation concept proposes a maximal amount of SOC that can be stabilized in the fine soil fraction, and the soil C saturation deficit (i.e., the difference between current SOC and the maximal amount) is presumed to affect the capacity, magnitude, and rate of SOC storage. In this study, we argue that predictions using current models underestimate maximal organic C stabilization of fine soil particles due to fundamental limitations of using least-squares linear regression. The objective was to improve predictions of maximal organic C stabilization by using two alternative approaches; one mechanistic, based on organic C loadings, and one statistical, based on boundary line analysis. We collected 342 data points on the organic C content of fine soil particles, fine particle mass proportions in bulk soil, dominant soil mineral types, and land use types from 32 studies. Predictions of maximal organic C stabilization using linear regression models are questionable because of the use of data from soils that may not be saturated in SOC and because of the nature of regression itself, resulting in a high proportion of presumed over-saturated samples. Predictions of maximal organic C stabilization using the organic C loading approach fit the data for soils dominated by 2:1 minerals well, but not soils dominated by 1:1 minerals; suggesting that the use of a single value for specific surface area, and therefore a single organic C loading, to represent a large dataset is problematic. In boundary line analysis, only data representing soils having reached the maximal amount (upper tenth percentile) were used. The boundary line analysis estimate of maximal organic C stabilization (78 ± 4 g C kg fraction) was more than double the estimate by the linear regression approach (33 ± 1 g C kg fraction). These results show that linear regression models do not adequately predict maximal organic C stabilization. Soil properties associated with soil mineralogy, such as specific surface area and organic C loading, should be incorporated to generate more mechanistic models for predicting soil C saturation, but in their absence, statistical models should represent the upper envelope rather than the average value. [ABSTRACT FROM AUTHOR]

Labile organic carbon (LOC) is a critical component of soil organic carbon (C) because of its intimate association with soil heterotrophic respiration and role in the decomposition of resistant soil organic matter. In a subtropical moist evergreen broad-leaved forest of southwest China, we examined changes of LOC and its potential turnover time, microbial biomass C (MBC), and soil microbial activity of the organic and the 0-10 cm mineral soil layers with aboveground plant litter and belowground root treatments. In February of 2004, removal of organic layer, root-trenching, and tree-girdling treatments were applied alone and in combination to manipulate plant-C inputs. In 2006, root-trenching and tree-girdling treatments did not significantly change LOC in the organic layer. In the 0-10 cm mineral soil layer, LOC increased substantially due to tree-girdling treatment, especially in the plots of tree-girdling and the combinations of three treatments, but this increase was absent in 2007. Soil MBC in these two layers generally did not change markedly after plant-C inputs manipulations except significant increase under tree-girdling treatment in 2006. The potential turnover times of LOC increased in all plots with the plant-C inputs manipulations. The lack of influence of plant-C inputs manipulations on LOC pools is likely due to high total soil organic C here, while insignificant changes of MBC suggest the soil microbes are not C limited in this forest. The changes of the potential turnover time of LOC imply that the sources of LOC have been shifted from fresh plant litter or root exudates to old soil organic C. Our results suggest that LOC recently derived from plants is preferred by microbes when available, but microbes can also use LOC from soil organic matter when fresh plant C is not available. [ABSTRACT FROM AUTHOR]