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Introduction: On intensive grassland dairy farms in high rainfall areas with poorly drained soils, networks of open drainage channels linked to in-field drainage systems are needed to enable farm operations. Nitrogen and phosphorus point and diffuse sources may be connected to this open drainage channel network along surface and subsurface pathways, with negative impacts upon delivery to the downstream aquatic system. Methods: This study developed a semi-quantitative risk assessment model by: (1) selecting parameters (categorical or continuous) representing the nutrient transfer continuum and (2) scoring (relative magnitude and impact) the risk of nutrient source connectivity and delivery for every open drainage channel section across seven dairy farms. Results and Discussion: A Risk Index Classification System consisting of low, medium, high, or very high-risk class was developed, with high or above requiring a mitigation plan. Results showed that 23%, 68%, 9% and 0% of all open drainage channels on study farms were identified as low, moderate, high and very highrisk, respectively. A range from 2% to 25% per farm of the open drainage channels was classified as high-risk that potentially needed mitigation, although none was identified as very high-risk. Two-thirds of the high-risk open drainage channels were connected to the farmyards, with potential for high nutrient loss from point sources. A combined approach of source management and targeted breaking of the pathway (e.g., in-channel filters, water diversion bars) may help minimise nutrient losses from high risk open drainage channels on poorly draining soils. [ABSTRACT FROM AUTHOR]

Introduction: On intensive grassland dairy farms in high rainfall areas with poorly drained soils, networks of open drainage channels linked to in-field drainage systems are needed to enable farm operations. Nitrogen and phosphorus point and diffuse sources may be connected to this open drainage channel network along surface and subsurface pathways, with negative impacts upon delivery to the downstream aquatic system. Methods: This study developed a semi-quantitative risk assessment model by: (1) selecting parameters (categorical or continuous) representing the nutrient transfer continuum and (2) scoring (relative magnitude and impact) the risk of nutrient source connectivity and delivery for every open drainage channel section across seven dairy farms. Results and Discussion: A Risk Index Classification System consisting of low, medium, high, or very high-risk class was developed, with high or above requiring a mitigation plan. Results showed that 23%, 68%, 9% and 0% of all open drainage channels on study farms were identified as low, moderate, high and very highrisk, respectively. A range from 2% to 25% per farm of the open drainage channels was classified as high-risk that potentially needed mitigation, although none was identified as very high-risk. Two-thirds of the high-risk open drainage channels were connected to the farmyards, with potential for high nutrient loss from point sources. A combined approach of source management and targeted breaking of the pathway (e.g., in-channel filters, water diversion bars) may help minimise nutrient losses from high risk open drainage channels on poorly draining soils. [ABSTRACT FROM AUTHOR]

Introduction: On intensive grassland dairy farms in high rainfall areas with poorly drained soils, networks of open drainage channels linked to in-field drainage systems are needed to enable farm operations. Nitrogen and phosphorus point and diffuse sources may be connected to this open drainage channel network along surface and subsurface pathways, with negative impacts upon delivery to the downstream aquatic system. Methods: This study developed a semi-quantitative risk assessment model by: (1) selecting parameters (categorical or continuous) representing the nutrient transfer continuum and (2) scoring (relative magnitude and impact) the risk of nutrient source connectivity and delivery for every open drainage channel section across seven dairy farms. Results and Discussion: A Risk Index Classification System consisting of low, medium, high, or very high-risk class was developed, with high or above requiring a mitigation plan. Results showed that 23%, 68%, 9% and 0% of all open drainage channels on study farms were identified as low, moderate, high and very highrisk, respectively. A range from 2% to 25% per farm of the open drainage channels was classified as high-risk that potentially needed mitigation, although none was identified as very high-risk. Two-thirds of the high-risk open drainage channels were connected to the farmyards, with potential for high nutrient loss from point sources. A combined approach of source management and targeted breaking of the pathway (e.g., in-channel filters, water diversion bars) may help minimise nutrient losses from high risk open drainage channels on poorly draining soils. [ABSTRACT FROM AUTHOR]

Installation of shallow drainage systems (mole drainage, gravel mole drainage, and subsoiling connected to an underlying tile drainage system) is common in fine-textured grassland soils. The performance and efficiency of these systems are known to vary, and a greater understanding of these criteria is needed. This study analyzed shallow drainage systems installed on four sites in southwest Ireland, namely Doonbeg (DG), Athea (AA), Castleisland 1 (C1), and Castleisland 2 (C2), across two high-rainfall periods (8 months in 2015–2016 and 5 months in 2017). Discharge characteristics in terms of peak flow rate, total discharge, and discharge hydrographs were analyzed. All drainage systems were responsive to rainfall events, but efficiency varied both temporally and between systems. [ABSTRACT FROM AUTHOR]

Runoff from farm roadways within farm boundaries are acknowledged as a year-round source of pollutants discharging to surface water, particularly during the main grazing season (Feb-Nov) when their usage is high. These losses are considered to be a significant catchment scale pressure and have led to recent legislation in Ireland to prohibit direct runoff from farm roadways to waters with similar guidance in the UK and New Zealand. However, roadway runoff (RR) remains an undocumented and understudied part of the transfer continuum where knowledge gaps remain in relation to its quantity and composition and in relation to the impacts of RR management options on adjacent surface waters. Indeed some information on mitigation measure design and efficacy is only available from non-agriculture land uses e.g. forestry and needs to be presented in a farm specific context. The present review brings together knowledge on RR in terms of content on- or off-roadway management options and proposes alternative mitigation measures that may require pilot scale testing. Studies show that RR contains a mix of legacy (surface materials) and incidental (fresh urine and faeces) constituents such as phosphorus (P), Escherichia coli (E. Coli) and sediment which become temporarily mobilised during rainfall events. Once mobilised, the roadway network can quickly transport pollutants providing connectivity between farmyards, hard standings, underpasses where attached to a watercourse, fields and even public roadways to watercourses. Its contents are not dissimilar to dilute slurry or dairy soiled water with loads being highest where animals congregate (within 100 m of the farmyard or where roadway configuration or quality impedes stock movement along the network). On-roadway management options include regularly spaced diversion structures that divert runoff for passive treatment in a field or drainage ditch or the application of chemical amendments to roadway surfaces. Off-roadway options can include natural or enhanced features, which attenuate flow leading to settlement of suspended sediment and in some cases treatment of a percentage of the load before delivery to a watercourse. It should be noted that the options presented in this review need to be retrofitted to site specific conditions. Therefore, a number of factors, including their effectiveness, cost and management needs on a particular farm, as well as local regulation requirements will need to be considered prior to implementation. Therefore, only the measures that divert RR away from waters are applicable to Ireland. Future research should develop and validate a farm roadway risk assessment tool to identify vulnerable roadway sections that need management and/or re-design, and identify means of incorporating RR into catchment scale risk assessment models. In addition, design of on- and off-RR management options should consider the wide variations in farm configuration and management with regard to size, topography, soil type/drainage class, enterprise, intensity, scale, stage of development and the potential impacts of climate change. [ABSTRACT FROM AUTHOR]

Dairy processing wastewater treatment sludge (DPWTS) is applied to grassland to recycle valuable nutrients and organic matter. Until recently the chemical composition of the dominant DPWTS types (calcium, aluminium or iron rich) was unknown, but the latest study (Ashekuzzaman et al. in J Clean Prod 230:1266–1275, 2019) indicates that DPWTS has high nitrogen (N) and phosphorus (P) content and their inherent chemical properties may influence their availability and losses. Herein for the first time edge of field-losses and plant-available P changes are simulated in an agitator test 48 h after application. In terms of overall losses, metals are not of concern across treatment types, iron-rich DPWTS has the highest losses in terms of concentration of ammonium-N and carbon, whereas calcium-rich DPWTS has the highest dissolved reactive P (DRP) losses but lowest losses of ammonium-N and carbon. The loss of DRP was found to be strongly positively associated with the increase in water-extractable P, degree of P saturation, Morgan's and Mehlich-3 extractable phosphorus (Pm, M3-P), respectively. Runoff concentrations presented here represent edge of field-losses and may not represent final concentrations entering a surface waterbody. In terms of plant-available P, there were no negative effects with Pm exhibiting a positive trend across DPWTS types and soils. In particular, a significant increase was found for the calcium-rich DPWTS across all soils (average increase in Pm by fivefold). As applying DPWTS to grassland is an understudied area, further field trials should focus on emissions to air and water and examine the fertilizer value from N and P perspectives. Thus a better management of DPWTS as fertiliser can be maintained from an agronomic and environmental context. [ABSTRACT FROM AUTHOR]

The quality of a soil is its ability to deliver functions providing ecosystem services, human health and well-being. Soil physical quality (SPQ) values use different parts of the soil water retention curve (SWRC) to calculate SPQ. For example, the plant available water capacity (PAWC) method is the difference in water content between permanent wilting point and field capacity. The S-index uses the slope of the SWRC at its inflection point and the relative air-water energy (AWr) is the integral of "dry" divided by the "wet" area of the SWRC. Increasing demand for soil monitoring policies calls for reliable and sensitive soil quality indicators (SQIs). The objectives of the study were to assess the sensitivity and applicability of SPQ indicators using direct and indirect data inputs. The indirect approach provided sufficient data complexity for the PAWC and S-index values, but the more complex AWr required the direct approach. PAWC and S-index values were identified as static SPQ indicators. The values obtained from these approaches should be used to form baseline static datasets and therefore have an indicative role only. The AW value was identified as a dynamic SPQ indicator and provided required sensitivity to pick up temporal changes in SPQ. This indicator could be used at multiple scales and could even guide grassland management in terms of SPQ. Higher SWRC data resolution will require more complex hydraulic models to fit and will ultimately improve the accuracy of soil hydraulic data and improve the sensitivity of AWr as a SPQ indicator. [ABSTRACT FROM AUTHOR]

Abstract: Visual evaluation of soil structure (VESS) is used for assessing arable management impact on soil quality. When used on pastures, operators have identified limitations because VESS does not consider a surface root‐mat typical of managed grassland. The structure of the root‐mat may be indicative of nutrient use efficiency, pollution potential and subsurface compaction. The objectives of this research were to develop GrassVESS for grassland soil management, to compare it with VESS and quantitative physical indicators and to assess its utility for soil management. GrassVESS maintained the methodological strengths of VESS, but uses a flow chart, grassland images and a new root‐mat score. A focus group found GrassVESS to be quicker, dealt better with technical information and made root‐mat evaluation easier. The range of structural quality scores assigned by the focus group for a site was less for GrassVESS than VESS, suggesting the procedure is more reproducible, thus suitable for use by a range of stakeholders. GrassVESS was also deployed at 30 grassland sites across Ireland. Results indicated that GrassVESS generated the same overall diagnoses as VESS, but the GrassVESS root‐mat structural quality score was better related to bulk density, total porosity at 5–10 cm and a visual estimation of damaged sward area. It was concluded that GrassVESS has improved the VESS method for the specific assessment of grassland soil structural quality and could be used in real‐time farm management decision support. [ABSTRACT FROM AUTHOR]

Abstract: Cost‐effective strategies for using chemically amended organic fertilizers need to be developed to minimize nutrient losses in surface and groundwater. Coupling specific soil physical and chemical characteristics with amendment type could increase their effectiveness. This study investigated how water‐extractable phosphorus (P) was affected by chemical amendments added to pig slurry and how this effect varied with soil properties. A 3‐month incubation study was conducted on 18 different mineral soils, stored at 10 °C and 75% humidity and treated with unamended and amended slurry which was incorporated at a rate equivalent to 19 kg total P (TP)/ha. The amendments examined were commercial‐grade liquid alum, applied at a rate of 0.88:1 [Al:TP], and commercial‐grade liquid poly‐aluminium chloride (PAC), applied at a rate of 0.72:1 [Al:TP]. These amendments were previously identified by the authors as being effective in reducing incidental losses of P. The efficacy of the amendments varied with the soil test P, the degree of P saturation (DPS) and the Mehlich aluminium, iron and calcium, but not soil texture. Chemical amendments were most effective in soils with DPS over approximately 20%. Due to their high cost, the incorporation of amendments into existing management practices can only be justified as part of a holistic management plan where soils have high DPS. [ABSTRACT FROM AUTHOR]

Soil structure forms a key component of soil quality, and its assessment by semi-quantitative visual soil evaluation ( VSE) techniques can help scientists, advisors and farmers make decisions regarding sampling and soil management. VSE techniques require inexpensive equipment and generate immediate results that correlate well with quantitative measurements of physical and biochemical properties, highlighting their potential utility. We reviewed published VSE techniques and found that soils of certain textures present problems and a lack of research into the influence of soil moisture content on VSE criteria. Generally, profile methods evaluate process interactions at specific locations within a field, exploring both intrinsic aspects and anthropogenic impacts. Spade methods focus on anthropogenic characteristics, providing rapid synopses of soil structure over wider areas. Despite a focus on structural form, some methods include criteria related to stability and resiliency. Further work is needed to improve existing methods regarding texture influences, on-farm sampling procedures and more holistic assessments of soil structure. [ABSTRACT FROM AUTHOR]

The removal efficiency of carbon (C) and nitrogen (N) in constructed wetlands (CWs) is very inconsistent and frequently does not reveal whether the removal processes are due to physical attenuation or whether the different species have been transformed to other reactive forms. Previous research on nutrient removal in CWs did not consider the dynamics of pollution swapping (the increase of one pollutant as a result of a measure introduced to reduce a different pollutant) driven by transformational processes within and around the system. This paper aims to address this knowledge gap by reviewing the biogeochemical dynamics and fate of C and N in CWs and their potential impact on the environment, and by presenting novel ways in which these knowledge gaps may be eliminated. Nutrient removal in CWs varies with the type of CW, vegetation, climate, season, geographical region, and management practices. Horizontal flow CWs tend to have good nitrate (NO3-) removal, as they provide good conditions for denitrification, but cannot remove ammonium (NH4+) due to limited ability to nitrify NH4+. Vertical flow CWs have good NH4+ removal, but their denitrification ability is low. Surface flow CWs decrease nitrous oxide (N2O) emissions but increase methane (CH4) emissions; subsurface flow CWs increase N2O and carbon dioxide (CO2) emissions, but decrease CH4 emissions. Mixed species of vegetation perform better than monocultures in increasing C and N removal and decreasing greenhouse gas (GHG) emissions, but empirical evidence is still scarce. Lower hydraulic loadings with higher hydraulic retention times enhance nutrient removal, but more empirical evidence is required to determine an optimum design. A conceptual model highlighting the current state of knowledge is presented and experimental work that should be undertaken to address knowledge gaps across CWs, vegetation and wastewater types, hydraulic loading rates and regimes, and retention times, is suggested. We recommend that further research on process-based C and N removal and on the balancing of end products into reactive and benign forms is critical to the assessment of the environmental performance of CWs. [ABSTRACT FROM AUTHOR]

There is little empirical evidence to indicate that dairy cow live weight affects the extent of soil damage at the hoof-soil interface during grazing on poorly drained permanent grassland. In the present study the impact of Holstein-Friesian (HF) dairy cows with a mean (±standard deviation) live weight of 570 (±61) kg were compared with Jersey × Holstein-Friesian (JX) with a mean live weight of 499 (±52) kg each at two stocking densities: mean 2·42 ± (0·062) and 2·66 (±0·079) cows/ha. Soil physical properties (bulk density, macroporosity, gravimetric water content, air-filled porosity, penetration resistance and shear strength), poaching damage (post-grazing soil surface deformation and hoof-print depth), herbage yield and milk production were measured throughout 2011 and 2012. Soil physical properties, post-grazing soil surface deformation and herbage production were not affected by dairy cow breed or by interactions between breed and stocking density. Hoof-print depth was higher in the HF treatments (39 v. 37 mm, s.e. 0·5 mm). Loading pressure imposed at the soil surface was the same for both breeds due to a direct correlation between live weight and hoof size. Poaching damage was greater at higher stocking density. Using the lighter JX cow offered little advantage in terms of lowering the negative impact of treading on soil physical properties or reducing poaching damage and no advantage in terms of herbage or milk production compared with the heavier HF cow. [ABSTRACT FROM PUBLISHER]

Soil erosion and suspended sediment (SS) pose risks to chemical and ecological water quality. Agricultural activities may accelerate erosional fluxes from bare, poached or compacted soils, and enhance connectivity through modified channels and artificial drainage networks. Storm-event fluxes dominate SS transport in agricultural catchments; therefore, high temporal-resolution monitoring approaches are required, but can be expensive and technically challenging. Here, the performance of in situ turbidity sensors, conventionally installed submerged at the river bankside, is compared with installations where river water is delivered to sensors ex situ, i.e. within instrument kiosks on the riverbank, at two experimental catchments (Grassland B and Arable B). The in situ and ex situ installations gave comparable results when calibrated against storm-period, depth-integrated SS data, with total loads at Grassland B estimated at 12 800 and 15 400 t, and 22 600 and 24 900 t at Arable B, respectively. The absence of spurious turbidity readings relating to bankside debris around the in situ sensor and its greater security make the ex situ sensor more robust. The ex situ approach was then used to characterise SS dynamics and fluxes in five intensively managed agricultural catchments in Ireland which feature a range of landscape characteristics and land use pressures. Average annual suspended sediment concentration (SSC) was below the Freshwater Fish Directive (78/659/EEC) guideline of 25mg L-1, and the continuous hourly record demonstrated that exceedance occurred less than 12% of the observation year. Soil drainage class and proportion of arable land were key controls determining flux rates, but all catchments reported a high degree of inter-annual variability associated with variable precipitation patterns compared to the long-term average. Poorly drained soils had greater sensitivity to runoff and soil erosion, particularly in catchments with periods of bare soils. Well drained soils were less sensitive to erosion even on arable land; however, under extreme rainfall conditions, all bare soils remain a high sediment loss risk. Analysis of storm-period and seasonal dynamics (over the long term) using high-resolution monitoring would be beneficial to further explore the impact of landscape, climate and land use characteristics on SS export. [ABSTRACT FROM AUTHOR]

Two different in situ spectrophotometers are compared that were used in the field to determine nitrate-nitrogen (NO3-N) concentrations at two distinct spring discharge sites. One sensor was a double wavelength spectrophotometer (DWS) and the other a multiple wavelength spectrophotometer (MWS). The objective of the study was to review the hardware options, determine ease of calibration, accuracy, influence of additional substances and to assess positive and negative aspects of the two sensors as well as troubleshooting and trade-offs. Both sensors are sufficient to monitor highly time-resolved NO3-N concentrations in emergent groundwater. However, the chosen path length of the sensors had a significant influence on the sensitivity and the range of detectable NO3-N. The accuracy of the calculated NO3-N concentrations of the sensors can be affected if the content of additional substances such as turbidity, organic matter, nitrite or hydrogen carbonate significantly varies after the sensors have been calibrated to a particular water matrix. The MWS offers more possibilities for calibration and error detection but requires more expertise compared with the DWS. [ABSTRACT FROM AUTHOR]

Soil erosion and suspended sediment (SS) pose risks to chemical and ecological water quality. Agricultural activities may accelerate erosional fluxes from bare, poached or compacted soils, and enhance connectivity through modified channels and artificial drainage networks. Storm-event fluxes dominate SS transport in agricultural catchments; therefore, high temporal-resolution monitoring approaches are required but can be expensive and technically challenging. Here, the performance of in situ turbidity sensors, conventionally installed submerged at the river bankside, is compared with installations where river water is delivered to sensors ex situ, i.e. within instrument kiosks on the riverbank, at two experimental catchments (Grassland B and Arable B). Calibrated against storm-period depth-integrated SS data, both systems gave comparable results; using the ex situ and in situ methods respectively, total load at Grassland B was estimated at 128±28 and 154±35, and 225±54 and 248±52 t at Arable B. The absence of spurious turbidity peaks relating to bankside debris around the in situ sensor and its greater security, make the ex situ sensor more robust. The ex situ approach was then used to characterise SS dynamics and fluxes in five intensively managed agricultural catchments in Ireland which feature a range of landscape characteristics and land use pressures. Average annual suspended sediment concentration (SSC) was below the Freshwater Fish Directive (FFD) guideline of 25mgL-1, and the continuous hourly record demonstrated that exceedance occurred less than 12% of the observation year. Soil drainage class and proportion of arable land were key controls determining flux rates, but all catchments reported a high degree of inter-annual variability associated with variable precipitation patterns compared to the long-term average. Poorly-drained soils had greater sensitivity to runoff and soil erosion, particularly in catchments with periods of bare soils. Well drained soils were less sensitive to erosion even on arable land; however, under extreme rainfall conditions, all bare soils remain a high sediment loss risk. Analysis of storm-period and seasonal dynamics (over the long term) using high resolution monitoring would be beneficial to further explore the impact of landscape, climate and land use characteristics on SS export. [ABSTRACT FROM AUTHOR]

Engineered remediation technologies such as denitrifying bioreactors target single contaminants along a nutrient transfer continuum. However, mixed contaminant discharges to a water body are more common from agricultural systems. Indeed, evidence presented herein indicates that pollution swapping within denitrifying bioreactor systems adds to such deleterious discharges. The present paper proposes a more holistic approach to contaminant remediation on farms, moving from the use of ‘denitrifying bioreactors’ to the concept of a ‘permeable reactive interceptor’ (PRI). Besides management changes, a PRI should contain additional remediation cells for specific contaminants in the form of solutes, particles or gases. Balance equations and case studies representing different geographic areas are presented and used to create weighting factors. Results showed that national legislation with respect to water and gaseous emissions will inform the eventual PRI design. As it will be expensive to monitor a system continuously in a holistic manner, it is suggested that developments in the field of molecular microbial ecology are essential to provide further insight in terms of element dynamics and the environmental controls on biotransformation and retention processes within PRIs. In turn, microbial and molecular fingerprinting could be used as an in-situ cost-effective tool to assess nutrient and gas balances during the operational phases of a PRI. [ABSTRACT FROM PUBLISHER]

A 9-month incubation study was conducted to investigate the effectiveness of amending dairy cattle slurry with either alum, lime, poly-aluminum chloride (PAC), or ferric chloride (FeCl3) in reducing water-extractable P (WEP) levels in five soils (four mineral and one organic). Alum, lime, and PAC were the most effective amendments in decreasing WEP (compared to a slurry-control) for the four mineral soils (by an average of 47% at the end the 9-month incubation period). In comparison, FeCl3increased WEP (compared to the slurry-control) by an average of 35% at the end the study. None of the amendments examined effectively reduced WEP of the organic soil. No amendment reduced soil-test P [(Morgan’s P (Pm) and Mehlich 3 P (M3P)] compared to the soil-only treatment. Alum maintained the greatest levels of M3P across the four mineral soils with the least risk of P loss to overlying water. [ABSTRACT FROM PUBLISHER]

The nitrogen (N) removal efficiency of constructed wetlands (CWs) is very inconsistent and does not alone explain if the removed species are reduced by physical attenuation or if they are transformed to other reactive forms (pollution swapping). There are many pathways for the removed N to remain in the system: accumulation in the sediments, leaching to groundwater (nitrate-NO3- and ammonium-NH4+), emission to atmosphere via nitrous oxide- N2O and ammonia and/or conversion to N2 gas and adsorption to sediments. The kinetics of these pathways/processes varies with CWs management and therefore needs to be studied quantitatively for the sustainable use of CWs. For example, the quality of groundwater underlying CWs with regards to the reactive N (Nr) species is largely unknown. Equally, there is a dearth of information on the extent of Nr accumulation in soils and discharge to surface waters and air. Moreover, CWs are rich in dissolved organic carbon (DOC) and produce substantial amounts of CO2 and CH4. These dissolved carbon (C) species drain out to ground and surface waters and emit to the atmosphere. The dynamics of dissolved N2O, CO2 and CH4 in CWs is a key "missing piece" in our understanding of global greenhouse gas budgets. In this review we provide an overview of the current knowledge and discussion about the dynamics of C and N in CWs and their likely impacts on aquatic and atmospheric environments. We suggest that the fate of various N species in CWs and their surface emissions and subsurface drainage fluxes need to be evaluated in a holistic way to better understand their potential for pollution swapping. Research on the process based N removal and balancing the end products into reactive and benign forms are critical to assess environmental impacts of CWs. Thus we strongly suggest that in situ N transformation and fate of the transformation products with regards to pollution swapping requires further detailed examination. [ABSTRACT FROM AUTHOR]

Land application of dairy slurry can result in incidental losses of phosphorus (P) to runoff in addition to increased loss of P from soil as a result of a buildup in soil test P (STP). An agitator test was used to identify the most effective amendments to reduce dissolved reactive phosphorus (DRP) loss from the soil surface after land application of chemically amended dairy cattle slurry. This test involved adding slurry mixed with various amendments (mixed in a beaker using a jar test flocculator at 100 rpm), to intact soil samples at approximate field capacity. Slurry/amended slurry was applied with a spatula, submerged with overlying water and then mixed to simulate overland flow. In order of effectiveness, at optimum application rates, ferric chloride (FeCl) reduced the DRP in overlying water by 88%, aluminium chloride (AlCl) by 87%, alum (Al(SO)·nHO) by 83%, lime by 81%, aluminium water treatment residuals (Al-WTR; sieved to <2 mm) by 77%, flyash by 72%, flue gas desulphurization by-product by 72% and Al-WTR sludge by 71%. Ferric chloride (€4.82/m treated slurry) was the most cost-effective chemical amendment. However, Al compounds are preferred owing to stability of Al-P compared with Fe-P bonds. Alum is less expensive than AlCl (€6.67/m), but the risk of effervescence needs further investigation at field-scale. Phosphorus sorbing materials (PSM) were not as efficient as chemicals in reducing DRP in overlying water. The amendments all reduced P loss from dairy slurry, but the feasibility of these amendments may be limited because of the cost of treatment. [ABSTRACT FROM AUTHOR]

The main threats to soils outlined in the pending Soil Framework Directive (SFD) are: contamination, loss of organic matter, erosion, compaction, sealing, salinization and desertification. The first four threats are pertinent to agricultural systems in Atlantic Europe, but vary in their extent between countries depending on the spatial soil distribution. Loss of soil biodiversity has not been included as a potential threat in the SFD due to lack of information that is currently available both spatially and temporally to facilitate any legislation to protect it. This paper gives emphasis to the four main threats outlined above associated with Agricultural systems in Atlantic Europe. Each soil threat is discussed in relation to the agricultural management calendar for cultivated and grazed grassland soils. The paper discusses current soil protection policies and possible changes to such legislation with the adoption of the SFD by member states. [ABSTRACT FROM AUTHOR]

This study examined the quantity of mineral N in soil and nitrate-N losses to groundwater from grassland-based dairy production in 2001 and 2002. There were four treatments with different inputs of N, through fertilizers, concentrates and biological fixation, and four associated stocking densities. Nitrogen inputs were 205, 230, 300 and 400 kg ha−1, respectively, and annual stocking densities were 1·75, 2·10, 2·50 and 2·50 cows ha−1. There were 18 cows per treatment. Grazed herbage accounted for 0·64, grass-silage for 0·26 and concentrates 0·10 of annual DM consumed by the cows. Quantities of mineral N (nitrate-N and ammonium-N) in soil were measured, following extraction in 2 M KCl (1:2 w/v) shaken continuously for 2 h, on three occasions between late September and early February each winter. Concentrations of nitrate-N in groundwater from wells inserted vertically to a depth of 1 m were determined throughout both winters. Quantities of mineral N in the soil increased ( P < 0·001) with higher N inputs and declined ( P < 0·001) with later sampling date. There were no relationships between nitrate-N concentrations in groundwater and N inputs, N surpluses, deposition of excreta-N at the soil surface and soil mineral N during both winters. Low losses of nitrate-N to groundwater were primarily attributed to high rates of denitrification associated with a heavy soil texture, wet anaerobic soil conditions, relatively high organic carbon contents throughout the soil profile and mild soil temperatures throughout the year. Uptake of N by herbage made an important contribution to low N losses over the winter. [ABSTRACT FROM AUTHOR]

In adult rabbits, an experimentally transected digital extensor tendon was repaired. The technique employed a tongue, created from the proximal tendon, folded over to bridge the transection and reattached distally. Animals were allowed immediate post-operative mobilisation. Tendon material, 14–120 days post-operatively, was examined ultrastructurally in control and experimental animals from four different zones within the repaired tendon. The operation was well tolerated and adhesion free. Associated with the repair, two types of collagen fibril populations were observed. Firstly, in areas where tendon tissue had been removed, there was a population of fibrils with a narrow range of diameters. Secondly, in areas where tendon tissue was subjected to an increased level of stress per unit cross-sectional area, a population of fibrils with a range of diameters similar to that of controls but with a marked increase in the percentage of small diameter fibrils. The relevance of these observations to human tendon repair is discussed. [ABSTRACT FROM PUBLISHER]

Organic sorbents alter physicochemical soil properties and mitigate heavy metal (HM) bioavailability. However, some sorbents are labile and, therefore, introduce the risk of HM release into soil after mineralisation. Before field application, new stable organic sorbents such as woodchip biochar (BIO) and brown coal waste (BCW) need to be tested and compared with standard organic amendments like farmyard manure (FYM). An incubated pot experiment was conducted to investigate the efficacy of FYM, BIO and BCW (added to soil in pots at 5 and 10% w/w) to alter soil physicochemical properties and mitigate bioavailability of Cd, Pb and Zn spiked in treatments at different doses (in mg kg−1); 0 (not spiked), 1 (1 Cd, 70 Pb, 100 Zn) and 2 (3 Cd, 500 Pb, 700 Zn), and incubated for 9 weeks. At the end of the experiment, the EDTA-extractable HM fractions, pH, cation exchange capacity (CEC) and specific surface area (SSA, to check trends) were determined in all treated soils. Results showed that FYM, BCW and BIO generally improved all soil properties (except reduced pH from BCW and apparent SSA reduction from FYM) and accounted for respective maximum abatements of Cd (50.2, 69.9 and 25.5%), Pb (34.2, 64.3 and 17.4%) and Zn (14.9, 17.7 and 11.8%) bioavailability in soil. FYM and BCW were more effective at 10% w/w especially in the low contaminated soil, whereas the highest efficacy for BIO was at 5% w/w and in the high contaminated soil. The efficacies of sorption by the organic sorbents varied for different HMs and were in the orders: BCW > FYM > BIO for Cd, FYM > BCW > BIO for Pb and BIO > BCW > FYM for Zn. Soil pH and CEC were strongly correlated with HM bioavailability in all treatments and implied that immobilisation of HMs occurred via complex formation, ion exchange and pH-dependent specific adsorption. All three sorbents were beneficial as soil amendments, and in terms of HM mitigation, BCW had the highest efficacy, followed by FYM and then BIO. Considering the documented high soil stability of BCW and BIO, these results are promising for further trialling at field scale. [ABSTRACT FROM AUTHOR]

Two patients with haemoperitoneum due to spontaneous haemorrhage near the tail of the pancreas are described. One patient presented acutely with epigastric pain and was found to be bleeding from the main trunk of the splenic artery. The other presented with a prolonged history of epigastric pain culminating in a haematemesis and was found to have a partially organized haematoma in the tail of the pancreas. In both cases the bleeding was proximal to the splenic pedicle, and distal pancreatectomy with splenectomy was necessary to achieve haemostasis. [ABSTRACT FROM PUBLISHER]

Background: Grazed grassland management regimes can have various effects on soil fauna. For example, effects on earthworms can be negative through compaction induced by grazing animals, or positive mediated by increases in sward productivity and cattle dung pats providing a food source. Knowledge gaps exist in relation to the behaviour of different earthworm species i.e. their movement towards and aggregation under dung pats, the legacy effects of pats and the spatial area of recruitment. The present study addressed these knowledge gaps in field experiments, over 2 years, using natural and simulated dung pats on two permanent, intensively grazed pastures in Ireland. Results: Dung pats strongly affected spatial earthworm distribution, with up to four times more earthworms aggregating beneath pats, than in the control locations away from pats. In these earthworm communities comprising 11 species, temporally different aggregation and dispersal patterns were observed, including absence of individual species from control locations, but no clear successional responses. Epigeic species in general, but also certain species of the anecic and endogeic groups were aggregating under dung. Sampling after complete dung pat disappearance (27 weeks after application) suggested an absence of a dung pat legacy effect on earthworm communities. Based on species distributions, the maximum size of the recruitment area from which earthworms moved to pats was estimated to be 3.8 m2 per dung pat. Since actual grazing over 6 weeks would result in the deposition of about 300 dung pats per ha, it is estimated that a surface area of 1140 m2 or about 11% of the total grazing area can be influenced by dung pats in a given grazing period. Conclusions: This study showed that the presence of dung pats in pastures creates temporary hot spots in spatial earthworm species distribution, which changes over time. The findings highlight the importance of considering dung pats, temporally and spatially, when sampling earthworms in grazed pastures. Published comparisons of grazed and cut grasslands probably reached incorrect conclusions by ignoring or deliberately avoiding dung pats. Furthermore, the observed intense aggregation of earthworms beneath dung pats suggests that earthworm functions need to be assessed separately at these hot spots. [ABSTRACT FROM AUTHOR]