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1. Investigation of the properties of 4,5-dialkylated N-heterocyclic carbenesElectronic supplementary information (ESI) available: Further experimental details and spectra. CCDC reference numbers 730784–730785. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b908981k

3. Organocatalyzed Conjugate Umpolung of α,β-Unsaturated Aldehydes for the Synthesis of γ-ButyrolactonesWe thank Prof. A. Fürstner for generous support and the Deutsche Forschungsgemeinschaft, the BMBF and the Fonds der Chemischen Industrie (Liebig scholarship to F.G.) for financial support. We also thank Dr. C. W. Lehmann for the X-ray analyses, Dr. D. Belder, A. Deege, and H. Hinrichs for separations by HPLC, Dr. R. J. Mynott for help with the NMR spectroscopy analysis, and S. Holle, F. Schroer, and M. Rusek for experimental contributions.

5. Effiziente asymmetrische Hydrierung von Pyridinen ( Wir danken Prof. A. Fürstner für seine großzügige Unterstützung, dem Bundesministerium für Bildung und Forschung und dem Fonds der chemischen Industrie für finanzielle Förderung (Liebig-Stipendium für F.G.), S. Ruthe, F. Kohler und Dr. D. Belder für zahlreiche ee-Bestimmungen sowie Merck KGaA und Heraeus für Chemikalienspenden. )

8. Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction.

11. Efficient Asymmetric Hydrogenation of Pyridines ( We thank Prof. A. Fürstner for generous support and constant encouragement, the Bundesministerium für Bildung und Forschung and the Fonds der Chemischen Industrie for financial support (Liebig scholarship to F.G.), and S. Ruthe, F. Kohler, and Dr. D. Belder for numerous ee determinations. Donations of chemicals by Merck KGaA and Heraeus are also gratefully acknowledged. )

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