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Hybrid laser-arc welding (HLAW) was carried out on high strength thermo-mechanical controlled process (TMCP) steel of 14 mm thickness using single-pass welding (SPW) and multi-pass welding (MPW) processes. Well-formed weld joints with good performance were successfully obtained. The results showed that the microstructure of weld was pre-eutectoid ferrite, acicular ferrite and some granular bainite. There were mainly lath bainite, granular bainite and acicular ferrite in the heat-affected zone. The grain sizes of SPW were thicker than MPW, and the bainite content of MPW was higher than SPW. The average hardness value of the fusion zone was lower than that of the Heat affected zone, but higher than that of the base material. The weld was divided into upper arc domain zone (ADZ) and lower laser domain zone (LDZ). The ADZ was harder than the LDZ. The average absorbed energy of SPW and MPW in the fusion zone at −40 ∘ C was 125.5 and 92 J/cm2, respectively. The influences of microstructure on impact toughness were summarized by analyzing the hardness distribution and microstructure of the welded joint. The brittle transition temperatures of the two processes obtained by the energy criterion and the morphology criterion were close to each other. [ABSTRACT FROM AUTHOR]