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3. TBHP/I2-Promoted Oxidative Coupling of Azoles with Benzyl Compounds via Cleavage of Nonactivated C(sp³)-H Bonds under Solvent-Free Conditions.

Author

Xiang Liu, Guiqin Yu, Jihui Li, Dong Wang, Yongxin Chen, Keqin Shi, and Baohua Chen

Subjects
AZOLES, OXIDATIVE coupling, BENZYL compounds, CATALYSTS, SOLVENTS
Abstract

A novel and efficient TBHP/I2-promoted oxidative coupling of azoles with benzyl compounds via cleavage of nonactivated C(sp³)-H bonds under metal-free, base-free, and solvent-free conditions for the synthesis of N-alkylated azoles has been developed. The procedure, using I2 as the catalyst, is a simple, economical, and environmentally friendly protocol, which could be applied to various available substrates in moderate to good yields. [ABSTRACT FROM AUTHOR]

Published
2013
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