1. COMPARISON OF SOIL PHOSPHORUS MEASUREMENTS.
- Author
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Kweon, G., Lund, E. D., Maxton, C., Lee, W. S., and Mengel, D. B.
- Subjects
PHOSPHORUS in soils ,CALIBRATION ,DETECTORS ,FILTERS & filtration ,COLORIMETRIC analysis - Abstract
This study evaluated four sensor technologies (near-infrared (NIR), Raman spectroscopy, electro-chemical, and colorimetry) to determine a feasible approach for an in-field soil phosphorus (available P) measurement system. The dataset consisted of 12 North American Proficiency Testing Program (NAPT) soils and 12 wet Kansas soils (P range of 5 to 156.0 mg kg
-1 ). An NIR spectrometer showed an R² ≥ 0.43 and a ratio of prediction to deviation (RPD) of 1.372, which did not reach the goal (RPD = 2 and R² ≥ 0.70). For a Raman spectrometer, a partial least squares (PLS) regression and a simple linear regression method of calibration were tested; however, both methods showed poor results (RPD = 1.21 and R² = 0.27 or lower). Customized cobalt ion-selective electrodes were tested in Mehlich 3 extraction solutions and resulted in poor results (R² = 0.44 and RPD = 1.33) for NAPT soils. A rapid colorimetric method was developed consisting of a shortened extraction (1 min), rapid filtration (syringe filter), and rapid color development (1 min with stirring at 50°C), which had an excellent R² of 0.98 for each change independently. The rapid colorimetric method was compared to the standard colorimetric analysis. This test resulted in an R² of 0.85 and an RPD of 1.94 for all NAPT samples, and soils with P < 80 mg kg-1 had an R² of 0.95 and an RPD of 4.74. For field soils, the R² was 0.85 and the RPD was 1.91 for all ranges, and an R² of 0.83 and an RPD of 2.12 was found for soils with P < 80 mg kg-1 . Considering that it is not necessary to measure soil P contents precisely in areas where fertilizer does not need to be applied, this rapid colorimetric method would be used for in-field soil P measurement systems. [ABSTRACT FROM AUTHOR]- Published
- 2015
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