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Please clickhereto download the map associated with this article. The late Miocene-Pliocene sedimentary fill of the Siena Basin (Tuscany, Italy) consists dominantly of clastics and has internal architecture that reflects the interplay of tectonics, relative sea-level changes and climate variations. Pliocene sediments are extensively exposed and overlay both late Miocene deposits and pre-Neogene bedrock. Specifically, Pliocene basin margin sediments consist largely of sand with gravel and mud intercalations, deposited mainly in nearshore settings with minor fluvial depositional episodes. They grade basinward to dominantly offshore fines with intervening turbiditic sand bodies. New fieldwork revealed that basin margin deposits, notwithstanding lithologically rather homogeneous, are made of a variety of sedimentary facies and bear several unconformities. They have been traditionally described and mapped using lithostratigraphic criteria, that have proven to be unfit to represent such complex stratigraphic architectures. The aim of this paper is to describe the allostratigraphic architecture of the Pliocene deposits exposed in a marginal key-area (45 km) of the northern Siena Basin by means of a 1:10,000 scale geological map. The recognized succession of allostratigraphic units and their bounding discontinuities, along with new biostratigraphic data from calcareous plankton, provides new insights into the geological history of the Siena Basin and represents valuable constraints for long-distance correlation. [ABSTRACT FROM PUBLISHER]

The performances of a gas-solid two-dimensional fluidized bed reactor in photocatalytic selective oxidation reactions, irradiated with traditional UV lamps or with a microscale illumination system based on UV emitting diodes (UVA-LEDs), have been compared. In the photocatalytic oxidative dehydrogenation of cyclohexane to benzene on MoOx/TiO2-A12O3 catalyst the use of UVA-LEDs modules allowed to achieve a cyclohexane conversion and benzene yield higher than those obtained with traditional UV lamps. The better performances with UVA-LEDs are due to the UVA-LEDs small dimensions and small-angle emittance, which allow photons beam be directed towards the photoreactor windows, reducing the dispersion outside of photoreactor or the optical path length. As a consequence, the effectively illuminated mass of catalyst is greater. We have found that this illumination system is efficient for photo-oxidative dehydrogenation of cyclohexane to cyclohexene on sulphated MoOx/γ-A12O3 and ethanol to acetaldehyde on VOx/TiO2. [ABSTRACT FROM AUTHOR]