1. Processing optimization: A way to improve the ionic conductivity and dielectric loss of electroactive polymers.
- Author
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Pedroli, Francesco, Marrani, Alessio, Le, Minh‐Quyen, Froidefond, Cédric, Cottinet, Pierre‐Jean, and Capsal, Jean‐Fabien
- Subjects
IONIC conductivity ,DIELECTRIC loss ,CONDUCTING polymers ,ACTUATORS ,DIELECTRIC strength ,STRAINS & stresses (Mechanics) - Abstract
ABSTRACT: Electro‐active polymers (EAPs) such as P(VDF‐TrFE‐CTFE) are greatly promising in the field of flexible sensors and actuators, but their low dielectric strength driven by ionic conductivity is a main concern for achieving high electrostrictive performance. It is well known that there is a quadratic dependence of the strain response and mechanical energy density on the applied electric field. This dependence highlights the importance of improving the electrical breakdown EAPs while reducing the dielectric losses. This article demonstrates that it is possible to dramatically increase the electrical breakdown and decrease the dielectric losses by controlling processing parameters of the polymer synthesis and fabrication procedure. As a result, an enhancement of around 70% is achieved in both the strain and blocking force. The effects on the dielectric losses of the polymer crystallinity, molecular weight, solvent purity, and crystallization temperature are also investigated. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 1164–1173 [ABSTRACT FROM AUTHOR]
- Published
- 2018
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