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Context. The interaction between dust, ice, and gas during the formation of stars produces complex organic molecules. While observations indicate that several species are formed on ice-covered dust grains and are released into the gas phase, the exact chemical interplay between solid and gas phases and their relative importance remain unclear. Aims. Our goal is to study the interplay between dust, ice, and gas in regions of low-mass star formation through ice- and gas-mapping and by directly measuring gas-to-ice ratios. This provides constraints on the routes that lead to the chemical complexity that is observed in solid and gas phases. Methods. We present observations of gas-phase methanol (CH3OH) and carbon monoxide (13CO and C18O) at 1.3 mm towards ten low-mass young protostars in the Serpens SVS 4 cluster from the SubMillimeter Array (SMA) and the Atacama Pathfinder EXperiment (APEX) telescope. We used archival data from the Very Large Telescope (VLT) to derive abundances of ice H2O, CO, and CH3OH towards the same region. Finally, we constructed gas-ice maps of SVS 4 and directly measured CO and CH3OH gas-to-ice ratios. Results. The SVS 4 cluster is characterised by a global temperature of 15 ± 5 K. At this temperature, the chemical behaviours of CH3OH and CO are anti-correlated: larger variations are observed for CH3OH gas than for CH3OH ice, whereas the opposite is seen for CO. The gas-to-ice ratios (Ngas/Nice) range from 1–6 for CO and 1.4 × 10−4–3.7 × 10−3 for CH3OH. The CO gas-maps trace an extended gaseous component that is not sensitive to the effect of freeze-out. Because of temperature variations and dust heating around 20 K, the frozen CO is efficiently desorbed. The CH3OH gas-maps, in contrast, probe regions where methanol is predominantly formed and present in ices and is released into the gas phase through non-thermal desorption mechanisms. Conclusions. Combining gas- and ice-mapping techniques, we measure gas-to-ice ratios of CO and CH3OH in the SVS 4 cluster. The CH3OH gas-to-ice ratio agrees with values that were previously reported for embedded Class 0/I low-mass protostars. We find that there is no straightforward correlation between CO and CH3OH gas with their ice counterparts in the cluster. This is likely related to the complex morphology of SVS 4: the Class 0 protostar SMM 4 and its envelope lie in the vicinity, and the outflow associated with SMM 4 intersects the cluster. This study serves as a pathfinder for future observations with ALMA and the James Webb Space Telescope (JWST) that will provide high-sensitivity gas-ice maps of molecules more complex than methanol. Such comparative maps will be essential to constrain the chemical routes that regulate the chemical complexity in star-forming regions. [ABSTRACT FROM AUTHOR]

We report on the discovery of correlations between dust and CO gas tracers of the 0.1-10 au region in planet-forming disks around young intermediate-mass stars. The abundance of refractory elements on stellar photospheres decreases as the location of hot CO gas emission recedes to larger disk radii, and as the near-infrared excess emission from hot dust in the inner disk decreases. The linked behavior between these observables demonstrates that the recession of infrared CO emission to larger disk radii traces an inner disk region where dust is being depleted. We also find that Herbig disk cavities have either low (~5-10%) or high (~20-35%) near-infrared excess, a dichotomy that has not been captured by the classic definition of "pre-transitional" disks. [ABSTRACT FROM AUTHOR]

Context. The presence or absence of ice in protoplanetary disks is of great importance to the formation of planets. By enhancing solid surface density and increasing sticking effciency, ice catalyzes the rapid formation of planetesimals and decreases the timescale of giant planet core accretion. Aims. In this paper, we analyze the composition of the outer disk around the Herbig star HD 142527. We focus on the composition of water ice, but also analyze the abundances of previously proposed minerals. Methods.We present new Herschel far-infrared spectra and a re-reduction of archival data from the Infrared Space Observatory (ISO). We modeled the disk using full 3D radiative transfer to obtain the disk structure. Also, we used an optically thin analysis of the outer disk spectrum to obtain firm constraints on the composition of the dust component. Results. The water ice in the disk around HD 142527 contains a large reservoir of crystalline water ice. We determine the local abundance of water ice in the outer disk (i.e., beyond 130AU). The re-reduced ISO spectrum di ers significantly from that previously published, but matches the new Herschel spectrum at their common wavelength range. In particular, we do not detect any significant contribution from carbonates or hydrous silicates, in contrast to earlier claims. Conclusions. The amount of water ice detected in the outer disk requires ~80% of oxygen atoms. This is comparable to the water ice abundance in the outer solar system, comets, and dense interstellar clouds. The water ice is highly crystalline while the temperatures where we detect it are too low to crystallize the water on relevant timescales. We discuss the implications of this finding. [ABSTRACT FROM AUTHOR]

Some protoplanetary disks show evidence of inner dust cavities. Recent observations of gas and dust of these so-called transition disks support the hypothesis that these cavities originate from particle trapping in pressure bumps. We present new Atacama Large Millimeter/submillimeter Array (ALMA) continuum observations at 336 GHz of two transition disks, SR21 and HD 135344B. In combination with previous ALMA observations from Cycle 0 at 689 GHz, we compare the visibility profiles at the two frequencies and calculate the spectral index (αmm). The observations of SR 21 show a clear shift in the visibility nulls, indicating radial variations of the inner edge of the cavity at the two wavelengths. Notable radial variations of the spectral index are also detected for SR 21 with values of αmm ~ 3:8-4:2 in the inner region (r ≲ 35 AU) and αmm ~ 2:6-3:0 outside. An axisymmetric ring (which we call the ring model) or a ring with the addition of an azimuthal Gaussian profile, for mimicking a vortex structure (which we call the vortex model), is assumed for fitting the disk morphology. For SR 21, the ring model better fits the emission at 336 GHz, conversely the vortex model better fits the 689 GHz emission. For HD 135344B, neither a significant shift in the null of the visibilities nor radial variations of αmm are detected. Furthermore, for HD 135344B, the vortex model fits both frequencies better than the ring model. However, the azimuthal extent of the vortex increases with wavelength, contrary to model predictions for particle trapping by anticyclonic vortices. For both disks, the azimuthal variations of αmm remain uncertain to confirm azimuthal trapping. The comparison of the current data with a generic model of dust evolution that includes planet-disk interaction suggests that particles in the outer disk of SR 21 have grown to millimetre sizes and have accumulated in a radial pressure bump, whereas with the current resolution there is not clear evidence of radial trapping in HD 135344B, although it cannot be excluded either. [ABSTRACT FROM AUTHOR]

The prominent infrared absorption band of solid CO - commonly observed towards young stellar objects (YSOs) - consists of three empirically determined components. The broad 'red component' (2136 cm-1, 4.681 µm) is generally attributed to solid CO mixed in a hydrogen-bonded environment. Usually, CO embedded in the abundantly present water is considered. However, CO:H2O mixtures cannot reproduce the width and position of the observed red component without producing a shoulder at 2152 cm-1, which is not observed in astronomical spectra. Cuppen et al. showed that CO:CH3OH mixtures do not suffer from this problem. Here, this proposition is expanded by comparing literature laboratory spectra of different CO-containing ice mixtures to high-resolution (R = λ/Δλ = 25 000) spectra of the massive YSO AFGL 7009S and of the low-mass YSO L1489 IRS. The previously unpublished spectrum of AFGL 7009S shows a wide band of solid 13CO, the first detection of 13CO ice in the polar phase. In this source, both the 12CO and 13CO ice bands are well fitted with CO:CH3OH mixtures, while respecting the profiles and depths of the methanol bands at other wavelengths, whereas mixtures with H2O cannot. The presence of a gradient in the CO:CH3OH mixing ratio in the grain mantles is also suggested. Towards L1489 IRS, the profile of the 12CO band is also better fitted with CH3OH-containing ices, although the CH3OH abundance needed is a factor of 2.4 above previous measurements. Overall, however, the results are reasonably consistent with models and experiments about formation of CH3OH by the hydrogenation of CO ices. [ABSTRACT FROM AUTHOR]

Molecular gas constitutes the dominant mass component of protoplanetary discs. To date, these sources have not been studied comprehensively at the longest far-infrared and shortest submillimetre wavelengths. This paper presents Herschel SPIRE FTS spectroscopic observations towards 18 protoplanetary discs, covering the entire 450–1540 GHz (666–195 μm) range at ν/Δν ≈ 400–1300. The spectra reveal clear detections of the dust continuum and, in six targets, a significant amount of spectral line emission primarily attributable to 12CO rotational lines. Other targets exhibit little to no detectable spectral lines. Low signal-to-noise detections also include signatures from 13CO, [C i] and HCN. For completeness, we present upper limits of non-detected lines in all targets, including low-energy transitions of H2O and CH+ molecules. The 10 12CO lines that fall within the SPIRE FTS bands trace energy levels of ∼50–500 K. Combined with lower and higher energy lines from the literature, we compare the CO rotational line energy distribution with detailed physical–chemical models, for sources where these are available and published. Our 13CO line detections in the disc around Herbig Be star HD 100546 exceed, by factors of ∼10–30, the values predicted by a model that matches a wealth of other observational constraints, including the SPIRE 12CO ladder. To explain the observed 12CO/13CO ratio, it may be necessary to consider the combined effects of optical depth and isotope selective (photo)chemical processes. Considering the full sample of 18 objects, we find that the strongest line emission is observed in discs around Herbig Ae/Be stars, although not all show line emission. In addition, two of the six T Tauri objects exhibit detectable 12CO lines in the SPIRE range. [ABSTRACT FROM AUTHOR]

Young stars are known to show variability due to non-steady mass accretion rate from their circumstellar disks. Accretion flares can produce strong energetic irradiation and heating that may affect the disk in the planet formation region, close to the central star. During an extreme accretion outburst in the young star EX Lupi, the prototype of EXor variables, remarkable changes in molecular gas emission from ∼1 AU in the disk have recently been observed. Here, we focus on water vapor and explore how it is affected by variable accretion luminosity in T Tauri stars. We monitored a young highly variable solar-mass star, DR Tau, using simultaneously two high/medium-resolution spectrographs at the European Southern Observatory Very Large Telescope: VISIR at 12.4 μm to observe water lines from the disk and X-shooter covering from 0.3 to 2.5 μm to constrain the stellar accretion. Three epochs spanning timescales from several days to several weeks were obtained. The accretion luminosity was estimated to change within a factor of ∼2 and no change in water emission was detected at a significant level. In comparison with EX Lupi and EXor outbursts, DR Tau suggests that the less long-lived and weaker variability phenomena typical of T Tauri stars may leave water at planet-forming radii in the disk mostly unaffected. We propose that these systems may provide evidence for two processes that act over different timescales: ultraviolet photochemistry in the disk atmosphere (faster) and heating of the deeper disk layers (slower). [ABSTRACT FROM AUTHOR]

We present near-infrared spectroscopic observations of 19 molecular clouds made using the AKARI satellite, and the data reduction pipeline written to analyze those observations. The 2.5-5 μm spectra of 30 objects—22 field stars behind quiescent molecular clouds and 8 low-mass young stellar objects in cores—were successfully extracted using the pipeline. Those spectra are further analyzed to calculate the column densities of key solid phase molecular species, including H2O, CO2, CO, and OCN–. The profile of the H2O ice band is seen to vary across the objects observed and we suggest that the extended red wing may be an evolutionary indicator of both dust and ice mantle properties. The observation of 22 spectra with fluxes as low as < 5 mJy toward background stars, including 15 where the column densities of H2O, CO, and CO2 were calculated, provides valuable data that could help to benchmark the initial conditions in star-forming regions prior to the onset of star formation. [ABSTRACT FROM AUTHOR]

We present a large, comprehensive survey of rovibrational CO line emission at 4.7μm from 69 protoplanetary disks, obtained with CRIRES on the ESO Very Large Telescope at the highest available spectral resolving power (R = 95,000, Δv = 3.2 km s-1). The CO fundamental band (Δv = 1) is a well-known tracer of warm gas in the inner, planet-forming regions of gas-rich disks around young stars, with the lines formed in the super-heated surfaces of the disks at radii of 0.1-10 AU. Consistent with earlier studies, the presence of 100-1000 K CO is found to be ubiquitous around young stars which still retain disks. Our high spectral resolution data provide new insight into the kinematics of the inner disk gas. The observed line profiles are complex and reveal several different components. Pure double-peaked Keplerian profiles are surprisingly uncommon in our sample, beyond the frequency expected based on disk inclination. The majority of the profiles are consistent with emission from a disk plus a slow (few km s-1) molecular disk wind. This is evidenced by analysis of different classes as well as an overall tendency for line profiles to have excess emission on their blue side. The data support the notion that thermal molecular winds are common for young disks. Thanks to the high spectral resolution, narrow absorption lines and weak emission lines from isotopologues and from vibrationally excited levels are readily detected. In general, 13CO lines trace cooler gas than the bulk 12CO emission and may arise from further out in the disk, as indicated by narrower line profiles. A high fraction of the sources show vibrationally excited emission (~50%) which is correlated with accretion luminosity, consistent with ultraviolet fluorescent excitation. Disks around early-type Herbig AeBe stars have narrower line profiles, on average, than their lower-mass late-type counterparts, due to their increased luminosity. Evolutionary changes in CO are also seen. Removal of the protostellar envelope between class I and II results in the disappearance of the strong absorption lines and CO ice feature characteristic of class I spectra. However, CO emission from class I and II objects are similar in detection frequency, excitation, and line shape, indicating that inner disk characteristics are established early. [ABSTRACT FROM AUTHOR]

We present an observational reconstruction of the radial water vapor content near the surface of the TW Hya transitional protoplanetary disk, and report the first localization of the snow line during this phase of disk evolution. The observations are comprised of Spitzer-IRS, Herschel-PACS, and Herschel-HIFI archival spectra. The abundance structure is retrieved by fitting a two-dimensional disk model to the available star + disk photometry and all observed H2O lines, using a simple step-function parameterization of the water vapor content near the disk surface. We find that water vapor is abundant (∼10-4per H2) in a narrow ring, located at the disk transition radius some 4 AU from the central star, but drops rapidly by several orders of magnitude beyond 4.2 AU over a scale length of no more than 0.5 AU. The inner disk (0.5-4 AU) is also dry, with an upper limit on the vertically averaged water abundance of 10-6 per H2. The water vapor peak occurs at a radius significantly more distant than that expected for a passive continuous disk around a 0.6 M☉star, representing a volatile distribution in the TW Hya disk that bears strong similarities to that of the solar system. This is observational evidence for a snow line that moves outward with time in passive disks, with a dry inner disk that results either from gas giant formation or gas dissipation and a significant ice reservoir at large radii. The amount of water present near the snow line is sufficient to potentially catalyze the (further) formation of planetesimals and planets at distances beyond a few AU. [ABSTRACT FROM AUTHOR]

Context. Circumstellar disks and envelopes of low-mass young stellar objects (YSOs) contain significant amounts of ice. Such icy material will evolve to become volatile components of planetary systems, such as comets in our solar system. Aims. To investigate the composition and evolution of circumstellar ice around low-mass young stellar objects (YSOs), we observed ice absorption bands in the near infrared (NIR) towards eight YSOs ranging from class 0 to class II, among which seven are associated with edge-on disks. Methods. We performed slit-less spectroscopic observations using the grism mode of the InfraRed Camera (IRC) on board AKARI, which enables us to obtain full NIR spectra from 2.5 μm to 5 μm, including the CO2 band and the blue wing of the H2O band, which are inaccessible from the ground. We developed procedures to carefully process the spectra of targets with nebulosity. The spectra were fitted with polynomial baselines to derive the absorption spectra. The molecular absorption bands were then fitted with the laboratory database of ice absorption bands, considering the instrumental line profile and the spectral resolution of the grism dispersion element. Results. Towards the class 0-I sources (L1527, IRC-L1041-2, and IRAS 04302), absorption bands of H2O, CO2, CO, and XCN are clearly detected. Column density ratios of CO2 ice and CO ice relative to H2O ice are 21-28% and 1346%, respectively. If XCN is OCN, its column density is as high as 2-6% relative to H2O ice. The HDO ice feature at 4.1 μm is tentatively detected towards the class 0-I sources and HV Tau. Non-detections of the CH-stretching mode features around 3.5 μm provide upper limits to the CH3OH abundance of 26% (L1527) and 42% (IRAS 04302) relative to H2O. We tentatively detect OCS ice absorption towards IRC-L1041-2. Towards class 0-I sources, the detected features should mostly originate in the cold envelope, while CO gas and OCN- could originate in the region close to the protostar, where there are warm temperatures and UV radiation. We detect H2O ice band towards ASR41 and 2MASSJ 1628137-243139, which are edge-on class II disks. We also detect H2O ice and CO2 ice towards HV Tau, HK Tau, and UY Aur, and tentatively detect CO gas features towards HK Tau and UY Aur [ABSTRACT FROM AUTHOR]

The physical processes leading to the disappearance of disks around young stars are not well understood. A subclass of transitional disks, the so-called cold disks with large inner dust holes, provides a crucial laboratory for studying disk dissipation processes. IRS 48 has a 30 AU radius hole previously measured from dust continuum imaging at 18.7 µm. Using new optical spectra, we determine that IRS 48 is a pre-main-sequence A0 star. In order to characterize this disk's gas distribution, we obtained AO-assisted Very Large Telescope CRIRES high-resolution (R ~ 100,000) spectra of the CO fundamental rovibrational band at 4.7 µm. All CO emission, including that from isotopologues and vibrationally excited molecules, is off-source and peaks at 30 AU. The gas is thermally excited to a rotational temperature of 260 K and is also strongly UV pumped, showing a vibrational excitation temperature of ~5000 K. We model the kinematics and excitation of the gas and posit that the CO emission arises from the dust hole wall. Prior imaging of UV-excited polycyclic aromatic hydrocarbon molecules, usually a gas tracer, within the hole makes the large CO hole even more unexpected. [ABSTRACT FROM AUTHOR]

We present a -band spectrum of LLN 19 (IRAS 08470 4321), a heavily embedded intermediate-mass young stellar object located in the Vela molecular cloud, obtained with the Very Large Telescope (VLT)-Infrared Spectrometer And Array Camera (ISAAC). The data were fitted by a two-slab cold-hot model and a wind model. The spectrum exhibits deep broad ro-vibrational absorption lines of CO and CO . A weak CO ice feature at 4.67 μm is also detected. Differences in velocity indicate that the warm gas is distinct from the cold millimetre emitting gas, which may be associated with the absorption by cooler gas (45 K). The outflowing warm gas at 300–400 K and with a mass-loss rate varying between 0.48 × 10 and 4.2 × 10 M yr can explain most of the absorption. Several absorption lines were spectrally resolved in subsequent spectra obtained with the VLT-Cryogenic Infrared Echelle Spectrograph (CRIRES) instrument. Multiple absorption substructures in the high-resolution ( ) spectra indicate that the mass-loss is episodic with at least two major events that occurred recently ( 28 yr). The discrete mass-loss events together with the large turbulent width of the gas ( = 10–12 km s ) are consistent with the predictions of the jet-bow shock outflow and the wide-angle wind model. The CO gas/solid column density ratio of 20–100 in the line of sight confirms that the circumstellar environment of LLN 19 is warm. We also derive a C/ C ratio of 67 ± 3, consistent with previous measurements in local molecular clouds but not with the higher ratios found in the envelope of other young stellar objects. [ABSTRACT FROM AUTHOR]

We present data from our ice mapping program IMAPE on the AKARI satellite. Initial results show a correlation between the abundance of CO2(s) and H2O(s), consistent with previous studies. We can trace abundances of molecules across a core using a single observation. [ABSTRACT FROM PUBLISHER]