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We study the luminosity line ratio in a sample of nearby (z < 0.05) galaxies: 25 star-forming galaxies (SFGs) from the xCOLD GASS survey, 36 hard X-ray-selected active galactic nucleus (AGN) host galaxies from the BAT AGN Spectroscopic Survey, and 37 infrared-luminous galaxies from the SCUBA Local Universe Galaxy Survey. We find a trend for r31 to increase with star formation efficiency (SFE). We model r31 using the UCL-PDR code and find that the gas density is the main parameter responsible for the variation of r31, while the interstellar radiation field and cosmic-ray ionization rate play only a minor role. We interpret these results to indicate a relation between SFE and gas density. We do not find a difference in the r31 value of SFGs and AGN host galaxies, when the galaxies are matched in SSFR (〈r31〉 = 0.52 ± 0.04 for SFGs and 〈r31〉 = 0.53 ± 0.06 for AGN hosts). According to the results of the UCL-PDR models, the X-rays can contribute to the enhancement of the CO line ratio, but only for strong X-ray fluxes and for high gas density (nH > 104 cm−3). We find a mild tightening of the Kennicutt–Schmidt relation when we use the molecular gas mass surface density traced by CO(3–2) (Pearson correlation coefficient R = 0.83), instead of the molecular gas mass surface density traced by CO(1–0) (R = 0.78), but the increase in correlation is not statistically significant (p-value = 0.06). This suggests that the CO(3–2) line can be reliably used to study the relation between SFR and molecular gas for normal SFGs at high redshift and to compare it with studies of low-redshift galaxies, as is common practice. [ABSTRACT FROM AUTHOR]

IRAM 30 m Observations toward eight protostellar outflow sources were taken in the 96–176 GHz range. Transitions of CH3OH and CH3CHO were detected in seven of them. The integrated emissions of the transitions of each species that fell into the observed frequency range were measured and fit using RADEX and LTE models. Column densities and gas properties inferred from this fitting are presented. The ratio of the A and E-type isomers of CH3OH indicates that the methanol observed in these outflows was formed on the grain surface. Both species demonstrate a reduction of terminal velocity in their line profiles in faster outflows, indicating destruction in the post-shock gas phase. This destruction, and a near constant ratio of the CH3OH and CH3CHO column densities, imply it is most likely that CH3CHO also forms on the grain surface. [ABSTRACT FROM AUTHOR]

The main carrier of sulfur in dense clouds, where it is depleted from the gas phase, remains a mystery. Shock waves in young molecular outflows disrupt the ice mantles and allow us to directly probe the material that is ejected into the gas phase. A comprehensive study of sulfur-bearing species toward L1157-B1, a shocked region along a protostellar outflow, has been carried out as part of the IRAM-30 m large program ASAI. The data set contains over 100 lines of CCS, H2CS, OCS, SO, SO2, and isotopologues. The results of these observations are presented, complementing previous studies of sulfur-bearing species in the region. The column densities and fractional abundances of these species are measured and together these species account for 10% of the cosmic sulfur abundance in the region. The gas properties derived from the observations are also presented, demonstrating that sulfur bearing species trace a wide range of different gas conditions in the region. [ABSTRACT FROM AUTHOR]

Many species of complex organic molecules (COMs) have been observed in several astrophysical environments but it is not clear how they are produced, particularly in cold, quiescent regions. One process that has been proposed as a means to enhance the chemical complexity of the gas phase in such regions is the explosion of the ice mantles of dust grains. In this process, a build up of chemical energy in the ice is released, sublimating the ices and producing a short lived phase of high density, high temperature gas. The gas–grain chemical code UCLCHEM has been modified to treat these explosions in order to model the observed abundances of COMs toward the TMC-1 region. It is found that, based on our current understanding of the explosion mechanism and chemical pathways, the inclusion of explosions in chemical models is not warranted at this time. Explosions are not shown to improve the model’s match to the observed abundances of simple species in TMC-1. Further, neither the inclusion of surface diffusion chemistry, nor explosions, results in the production of COMs with observationally inferred abundances. [ABSTRACT FROM AUTHOR]

For decades, the detection of phosphorus-bearing molecules in the interstellar medium was restricted to high-mass star-forming regions (e.g., SgrB2 and Orion KL) and the circumstellar envelopes of evolved stars. However, recent higher-sensitivity observations have revealed that molecules such as PN and PO are present not only toward cold massive cores and low-mass star-forming regions with PO/PN ratios ≥1 but also toward the giant molecular clouds in the Galactic center known to be exposed to highly energetic phenomena such as intense UV radiation fields, shock waves, and cosmic rays. In this paper, we carry out a comprehensive study of the chemistry of phosphorus-bearing molecules across different astrophysical environments that cover a range of physical conditions (cold molecular dark clouds, warm clouds, and hot cores/hot corinos) and are exposed to different physical processes and energetic phenomena (proto-stellar heating, shock waves, intense UV radiation, and cosmic rays). We show how the measured PO/PN ratio (either ≥1, as in, e.g., hot molecular cores, or ≤1, as in UV strongly illuminated environments) can provide constraints on the physical conditions and energetic processing of the source. We propose that the reaction P + OH → PO + H, not included in previous works, could be an efficient gas-phase PO formation route in shocks. Our modeling provides a template with which to study the detectability of P-bearing species not only in regions in our own Galaxy but also in extragalactic sources. [ABSTRACT FROM AUTHOR]

Toward the prestellar core L1544, the methanol (CH3OH) emission forms an asymmetric ring around the core center, where CH3OH is mostly in solid form, with a clear peak at 4000 au to the northeast of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH3OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2 km s−1 and the velocity dispersion increases from subsonic to transonic toward the central zone of the core, where the velocity field also shows complex structure. This could be an indication of gentle accretion of material onto the core or the interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH3OH column density, Ntot(CH3OH), profile has been derived with non-LTE radiative transfer modeling and compared with chemical models of a static core. The measured Ntot(CH3OH) profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunneling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance. [ABSTRACT FROM AUTHOR]

Previous work by various authors has suggested that the detection by Herschel/HIFI of nitrogen hydrides along the low-density lines of sight toward G10.6-0.4 (W31C) cannot be accounted for by gas-phase chemical models. In this paper we investigate the role of surface reactions on dust grains in diffuse regions, and we find that formation of the hydrides by surface reactions on dust grains with efficiency comparable to that for H2 formation reconciles models with observations of nitrogen hydrides. However, similar surface reactions do not contribute significantly to the hydrides of O+ ions detected by Herschel/HIFI that are present along many sight lines in the Galaxy. The O+ hydrides can be accounted for by conventional gas-phase chemistry either in diffuse clouds of very low density with normal cosmic-ray fluxes or in somewhat denser diffuse clouds with high cosmic-ray fluxes. Hydride chemistry in dense dark clouds appears to be dominated by gas-phase ion–molecule reactions. [ABSTRACT FROM AUTHOR]

We report on the effects of cosmic rays (CRs) on the abundance of CO in H2 clouds under conditions typical for star-forming galaxies in the universe. We discover that this most important molecule for tracing H2 gas is very effectively destroyed in ISM environments with CR energy densities , a range expected in numerous star-forming systems throughout the universe. This density-dependent effect operates volumetrically rather than only on molecular cloud surfaces (i.e., unlike FUV radiation that also destroys CO), and is facilitated by (a) the direct destruction of CO by CRs and (b) a reaction channel activated by CR-produced He+. The effect we uncover is strong enough to render Milky-Way-type Giant Molecular Clouds very CO-poor (and thus CO-untraceable), even in ISM environments with rather modestly enhanced average CR energy densities of . We conclude that the CR-induced destruction of CO in molecular clouds, unhindered by dust absorption, is perhaps the single most important factor controlling the CO-visibility of molecular gas in vigorously star-forming galaxies. We anticipate that a second-order effect of this CO destruction mechanism will be to make the H2 distribution in the gas-rich disks of such galaxies appear much clumpier in CO J = 1–0, 2–1 line emission than it actually is. Finally we give an analytical approximation of the CO/H2 abundance ratio as a function of gas density and CR energy density for use in galaxy-size or cosmological hydrodynamical simulations, and propose some key observational tests. [ABSTRACT FROM AUTHOR]