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2. Coordination-induced gelation of an l-glutamic acid Schiff base derivative: the anion effect and cyanide-specific selectivity.

Author

Sun, Jinguo, Liu, Yucun, Jin, Longyi, Chen, Tie, and Yin, Bingzhu

Subjects
GELATION, SCHIFF bases, GLUTAMIC acid, ZINC compounds, COPPER compounds
Abstract

By rational assembly of Zn2+ and Cu2+ with G, three metallogels (ZnG, CuG and Zn-CuG) were prepared. The gelation was controlled by the presence of specific anions, with their efficacy linked to the Hofmeister series. Zn-CuG could fluorescently detect CN− with specific selectivity over S2− and Cys through the competitive coordination of CN− and G with Cu2+. [ABSTRACT FROM AUTHOR]

Published
2016
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