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The problem of using natural building materials in low-rise construction lies in ensuring their durability during operation in conditions of atmospheric fluctuations, as well as in ensuring their thermal insulation properties. The purpose of this study is to find the thermal insulation properties of materials, namely thermally modified common hornbeam wood (the outer surface of the building), common pine wood (the inner surface of the building) and a thermal insulation layer of reeds, which allow justifying the effectiveness of their use in construction. The study uses a comprehensive research method, which included figuring out the thermal insulation properties of materials and justifying their feasibility in construction. The thermal insulation properties of wood and reed materials were calculated based on thermophysical dependences. The coefficient of thermal conductivity for wood reaches 0.0082 W/(m∙K), and for reed – 0.0022 W/(m∙K). Therewith, the thermal conductivity is no more than 0.19·10-6 m²/s, the heat capacity of wood is within 70÷90 kJ/(kg·K), and the heat capacity of a reed product is 337.2 kJ/(kg·K) respectively, which refers them to thermal-insulating materials. The practical value of this study lies in the substantiation of the method of establishing thermal insulation characteristics of building materials by finding their physical and thermophysical properties. The obtained results also expand the scope of application of products and building structures made of wood and reed. [ABSTRACT FROM AUTHOR]

Thermally modified wood is becoming an increasingly popular material for different applications in buildings. Laboratory tests indicated a positive effect of thermal modification on durability, dimensional stability and thermal conductivity of wood. Therefore, windows and facade elements made of thermally modified Norway spruce and non-modified Norway spruce were tested in the field and installed in different test objects which were exposed at five locations in Europe (Slovenia, Germany, Sweden, and Spain). Results from monitoring showed that elements and windows made of thermally modified spruce (TMS) had considerably lower wood moisture content compared to the ones made of non-modified spruce and that wax further positively influenced moisture performance. Colour changes of TMS were more intensive compared to non-modified spruce but were successfully retarded by adding pigments to the wax. Mould and stain growth was largely dependent on the location, amount of precipitation and relative humidity. [ABSTRACT FROM AUTHOR]

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The load-carrying capacity of a timber structure is highly dependent on the strength of its connections. Very limited information exists on the thermal degradation, or the properties at elevated temperatures, of such connections. This insufficient information is one of the major impediments for modeling elevated temperature performance for wood-frame structures. The objective of this study was to characterize thermal degradation of yield load capacity of single-shear nailed connections between wood and oriented strand board (OSB) as a function of time and temperature. The mechanism of degradation was explained using first order kinetics. Using the principles of time–temperature superposition (TTS), predictive models for connection capacity degradation were developed. A total of 450 wood-to-OSB connections were tested laterally after exposure to nine different elevated temperature regimes. The degradation of yield load strength over time occurred at a constant linear rate. Temperature dependence of this rate was modeled using the Arrhenius activation energy theory. Using Arrhenius activation energy theory and principles of TTS, a master curve was developed to predict the performance of connections after exposure to a temperature of 150°C. The predictions matched well with independent experimental observations. The master curve developed using TTS provides predictive estimates of residual capacity in a connection as well as its failure times. [ABSTRACT FROM PUBLISHER]

The present work studied the numerical modelling of heat transfer in a pile of Pinus radiata samples of a square cross-section by using radio frequency heating. More precisely, the study focused on the effects of the energy transferred to a dielectric material (wood) from an electromagnetic field, which required the calculation of the dielectric loss factor and its correlation with conservative equations. In this way, the temperature distribution across Pinus radiata samples was obtained through the integration of the energy equation using the finite volume method. The numerical results were compared to experimental data obtained from three experiments of radio-frequency heating of wood samples of a crosssectional area of 4 in × 4 in, 3.1-m-long, and 20 cm of separation between plates. According to the observed linear behavior of the heat transfer process, the numerical results of the transient variation of temperature were in agreement with the experimental data. [ABSTRACT FROM AUTHOR]

Five types of alternative sandwich composite structures designed for building walls were investigated in this study using various core materials such as wood shavings, recycled acrylonitrile butadiene styrene panels, and rock wool. The sandwich structures were designed for exterior walls with a thickness of 175 mm. The experiment simulated the conditions for inside and outside temperatures during winter and summer seasons. The thermal conductivity coefficient associated with winter was lower by about 55% than those registered for summer. Wood shavings and one ABS panel as core components led to the most thermally stable structure. The best insulation solutions were the rock wool core structures with a mean thermal conductivity coefficient between 0.0564 W/mK and 0.0605 W/mK for the entire testing cycle. The two ABS panels from the core configurations had a negative impact on the thermal performance. The lowest thermal performance was recorded by the pure wood shavings core structure, with a maximum value of thermal conductivity coefficient of 0.150 W/mK. Compressed wood shaving core structures can compete with rock wool as thermal insulation solution. [ABSTRACT FROM AUTHOR]

The contribution aims to design, deliver and debate on thermal degradation and thermal stability of several wood/PP composite materials. The wood polymer-based composites (n. WPCs) were manufactured through injection moulding by deploying various wood species under 10% and 40% weight fraction within the thermoplastic matrix. Thermal degradation of WPC specimens revealed similarities in characteristics, small discrepancies in the degradation temperatures but higher contents in the char formation, between 10% to 35% with wood content increase. [ABSTRACT FROM AUTHOR]

This paper deals with the results of a study of the thermodestruction of the earlywood and latewood in the 1988-1998 growth rings of Gmelin larch ( Larix gmelinii (Rupr.) Rupr.) trees growing along the polar tree line (7052′53″N, 102°58′26″E, Taimyr Peninsula). The study used methods of thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC). Thermogravimetric data obtained were analyzed by Ozawa-Flynn-Wall kinetic model. We determined macrokinetic parameters of thermodestruction. Earlywood and latewood showed no significant difference in cellulose/hemicellulose/lignin ratio, whereas they differed significantly in destruction average value of activation energy (197.55 and 55.90 kJ mol, respectively). Our analysis of the correlation of thermodestruction values with mean monthly air temperature and precipitation revealed that component composition of both earlywood and latewood was influenced more by the weather conditions at the beginning of the growing season (April-June). Air temperature had markable influence on the wood component composition during cell wall synthesis only in latewood, whereas precipitation influenced the composition in both latewood and earlywood. TG/DTG and DSC methods were found to be promising for developing information on biochemical composition of early and latewood tracheids in stems and for identifying the extent of the influence of climatic changes on cell wall synthesis. [ABSTRACT FROM AUTHOR]

The feasibility of using rattan canes (Laccosperma secundiflorum and Eremospatha macrocarpa) as reinforced fillers for high density polyethylene based plastic composite production was investigated. Extruded composites were tested for water sorption, tensile and thermal properties. The results obtained indicated that the rattan composites were dimensionally (water absorption: 2,2-21,4% thickness swell: 0,9-5,3%) and thermally stable (Tc: 116,8-118,2°C) and possessed adequate tensile properties (7,3-21,7 MPa). Composites made from L. secundiflorum had higher strength and thermal properties but lower sorption values compared to those of E. macrocarpa. Differences in the densities of the composites and the anatomical structures of the rattans seemed to influence properties of the composites. [ABSTRACT FROM AUTHOR]

The cross-section design of wood/polyvinyl chloride composite log-wall panels was studied for effects on compressive load, thermal and acoustic properties. Variation in the slenderness ratio (2, 4, 8, 10 and 12) on compressive load was also included. Two parameters of log-wall cross sections consisting of web thickness (3.5, 7.0 and 10.0 mm) and flange spacing (45, 60 and 90 mm) were also investigated. Experimental results indicated that higher web thickness and lower flange spacing of wood/polyvinyl chloride composite log-wall cross sections increased the ultimate compressive load and noise reduction. However, lateral deflection and thermal resistance decreased. Increasing the slenderness ratio of the log-wall panels resulted in lower ultimate compressive load and higher lateral deflection. Empirical equations for predicting the ultimate compressive load of wood/polyvinyl chloride composite log-wall panels in practical uses were proposed regarding web thickness, flange spacing and slenderness ratio. [ABSTRACT FROM AUTHOR]

This article deals with the characterization of biomass pellets using Differential Scanning Calorimetry. We used three types of industrially produced and commercially available pellets as samples: wood pellets containing grass, wood pellet containing bark and wood pellets without bark. Each of the samples were examined using the DSC method. Based on the measurements in atmosphere of air and nitrogen temperature, the changes caused by thermal degradation of various kinds of test fuels were observed. Subsequently, limits of exothermic processes, reaction enthalpy changes and the temperature at which exothermic reactions reached peaks were determined. [ABSTRACT FROM AUTHOR]

In this study, silica sol (SiO sol) and KCO were used as flame retardants for wood. The synergistic effect of SiO sol and KCO on the flame retardancy, leaching resistance, and thermal properties of wood was investigated. The limiting oxygen index results revealed a significant improvement in the flame retardancy and leaching resistance of the wood sample treated with KCO and SiO sol using the double bath technique. The thermal analysis results showed that the synergistic effect of KCO and the SiO sol effectively prolonged the degradation of the wood sample during the charring stage and improved the stability of the char residue. The thermogravimetry-mass spectrometry analysis and scanning electron microscopy results showed that KCO catalyzed the degradation reaction of the wood sample at lower temperatures resulting in an increase in the water and carbon dioxide output, and the SiO sol formed a compact and melted barrier on the surface of the char residue, which hindered the transfer of heat and combustible gases in the condensed phase. Thus, the combination of KCO and SiO sol proves to be a promising flame-retardant system for wood. [ABSTRACT FROM AUTHOR]

Wood modification is an efficient method to improve wood performance and expand the applications of wood material. In this study, a combination modification method of aluminum sol-gel and furfurylation was developed to improve the performance of poplar wood. Wood samples were characterized by Fourier transform infrared spectroscopy and field emission scanning electron microscopy. The properties of the treated wood, including thermal stability, water uptake, dimensional stability, and dynamic wettability were also evaluated. The thermogravimetric analysis results indicated that the incorporation of an aluminum-based gel could prevent furfurylated wood from thermal degradation by converting the gel into nano-Al2O3. The aluminum-based sol-gel apparently hindered furfuryl alcohol polymerization and reduced the weight percent gain of the samples; the anti-swelling efficiency of the treated wood was over 57% (with little decrease) due to crosslinking between the wood and aluminum-based gel. The water uptake and hydrophobicity of the modified samples were improved significantly in comparison to the control samples. [ABSTRACT FROM AUTHOR]

The aim of this paper was to determine the moisture desorption isotherms and essentials thermodynamic properties of two Oak wood varieties. Desorption isotherms were measured using a static gravimetric method at 50, 60, 70 and 80 °C within the range of 5-90 % relative humidity. The equilibrium moisture content decreased with increasing temperature and decreased with decreasing relative humidity at a constant temperature. The 'Thermodynamic' sorption equation was found to be the best for describing the experimental moisture sorption isotherms of woods within the range of temperature and water activity investigated. The Fiber saturation point, deduced from the 'Thermodynamic' model parameters, depends on the temperature and varying from 22.6 to 54.4 (% kg water/kg dry matter). Isosteric heat of desorption and differential entropy were calculated by applying Clausius-Clapeyron equation to the desorption data fitted by the 'Thermodynamic' model. The isosteric heat of desorption and the differential entropy decreased with increasing moisture content according to an exponential law equation and varying from 2.03 to 31.14 kJ/mol and from 73.98 to 4.34 J/(mol K), respectively. The linear relationship between differential enthalpy and entropy satisfied the enthalpy-entropy compensation theory. The sign of Gibbs free energy was found to be positive (+283 J/mol) and (+97 J/mol) for Quercus robur and Quercus canariensis, respectively. The isokinetic temperature was found to be greater than the harmonic temperature. Based on the enthalpy-entropy compensation theory, it could be concluded that the moisture desorption isotherm of Oak wood is a non-spontaneous and enthalpy-controlled process. [ABSTRACT FROM AUTHOR]

This study examines the dynamic compression and thermo-physical properties of some wood particles obtained from Akure, south local government area, Ondo State, South Western Nigeria. These wood particles are of the species of Celtis zenkeri and Celtis philippensis of the Ulmaceae family. The samples were possessed into different particle sizes (300, 600 and 850 μm) and subjected to varied compacting pressures (2.60-3.0 MPa). The density and specific heat capacity of the wood samples were determined using weighing displacement methods and temperature dependent model while the thermal diffusivity was estimated from other thermal properties. The results revealed significant variation in the values of the specific heat capacity as a result of change in pressure for all the wood samples considered. The density of wood samples lies between 4.51×102 -7.32×102 kg/m3 and the specific heat capacity values obtained for the samples fall within the range of 1.28×103-1.33×103 J/kg/K. It was also noted that the thermal diffusivity obtained falls within the range of 1.37×10-7-2.10×10-7 m2/s for the wood materials considered. However, the values of the densities, specific heat capacities and thermal diffusivities of the samples were found to change as the compacting pressure increased due to decreased in porosity. The implication of the study is that the materials have potential for use in polymer applications and the fabrication of film based photographic devices. [ABSTRACT FROM AUTHOR]

BACKGROUND The solubilisation of hardwood glucuronoxylan using hot, compressed water is an environmentally friendly technology for biorefineries. Upon processing, most cellulose and lignin remain in the solid phase and can be further separated, enabling the integral benefit of the feedstock. RESULTS The combined effects of time and temperature on the aqueous, non-isothermal processing of Betula alba wood have been assessed in selected experiments. Operating at temperatures within the range 190-230 °C, sugars and higher saccharides derived from glucuronoxylan were the major reaction products, whereas cellulose and lignin were scarcely affected. Refining treatments by membranes and ion-exchange resulted in mixtures of partially acetylated, acidic oligo- and polysaccharides made up of xylose. CONCLUSION The processing scheme proposed in this work enabled the production of separate streams containing substituted hemicellulosic saccharides with different average polymerisation degrees, which show potential as co-products for biorefineries. © 2016 Society of Chemical Industry [ABSTRACT FROM AUTHOR]

Aims Analyse the controversial relationship existing between wood density, precipitation, temperature and aridity, and its importance in shaping forest communities facing drought. Location New Caledonia (SW Pacific). Methods We sampled wood density in 1580 trees belonging to 175 species across nine sites (eight 1-ha plots) located in dry, mesic and humid forests. We tested whether wood density varied across species, communities and habitats, and depended on mean annual precipitation (MAP), mean annual temperature (MAT) and an aridity index (AI). We also tested whether the variations observed in community mean wood density (WDmean) and in wood density standard deviation differed from those obtained by a randomized species distribution across communities. We constructed a phylogenetic supertree at genus level and tested for the non-random distribution of WDmean. Results We found that WDmean tended to increase with increasing aridity (i.e. decreasing MAP and increasing MAT) and was significantly higher than expected under randomized species distribution at the dry forest site only. However, some species with low wood density grew well at these dry sites. At genus level, wood density was not random within the phylogenetic supertree. Some lineages exhibiting higher wood density than expected by randomization were also the most represented at the dry sites. Conclusions Although we did not observe an environmental filter sensu stricto, aridity associated with a low MAP and a high MAT at the dry and mesic forest sites was likely to favour species with a high wood density. Our phylogenetic results suggested that species belonging to a few lineages exhibiting high wood density were likely to be adapted to drought, hence favoured by increasing drought. [ABSTRACT FROM AUTHOR]

Thermal modification is the most important commercial modification procedure. Thermally modified (TM) wood has improved durability, but its performance does not meet expectations predominately under moist conditions. To reduce water uptake of TM wood, Norway spruce specimens were treated with suspensions of a natural wax by dipping impregnation (DipI) or by vacuum-pressure impregnation (VPI). Wax-treated specimens were subsequently TM at 185, 200, 215, and 230°C. Control specimens were heated up to 100°C only. Contact angle (CA), short-term and long-term water uptake, bending strength, and performance against wood decay fungi of the resulting material were determined. The results show that a combination of wax treatment and thermal modification have a synergistic effect that considerably improves hydrophobicity, reduces liquid water uptake, slows down water vapor uptake, and improves the resistance against fungal decay of the treated material. [ABSTRACT FROM AUTHOR]

Thermally modified (TM) wood production has significantly increased in the last decade. The trend for TM wood residues should be similar – rapidly increasing, which has prompted this research on the possible efficient uses of these residues, such as sawdust. One of the possibilities could be the production of wood plastic composites (WPCs). In this work, three different hydrothermal modification regimes were used to modify birch boards. Modified and unmodified birch boards were milled to obtain sawdust. WPCs were made with a two-roll mill, and they consisted of 50 wt-% wood fibres + 50 wt-% polypropylene. Melt flow index (MFI), flexural properties, impact strength, microhardness water absorption and dimensional stability were tested. WPCs with TM wood showed improvement in flexural properties, MFI and other properties, however there was a decrease in impact strength. Scanning electron microscopy pictures of impact strength samples fracture surfaces were taken. [ABSTRACT FROM AUTHOR]

The major aim of this study was to create a numerical model of thermal bridges in a wooden structure and to discover differences between factual values of linear thermal transmittance utilized in the finite-element (FE) modelling and values given by the European normative method (EN ISO 14683). Thermal bridges of wooden structures were detected using thermocamera FLIR S65 for infrared detection. These measurements allow displaying the temperature distribution of the thermal scan and proving the positive correlation between heat flux and change in the evaluated temperatures of a thermal bridge. A three-dimensional FE model of the structure was prepared for the thermal analysis using the engineering software ANSYS Workbench 13. The transmission heat loss coefficients of a prefabricated wooden house were established based on the Czech normative method (ČSN 730540-4). Linear thermal transmittance values calculated from the thermal analysis and the normative method given by EN ISO 10211 were compared. The results show that even if the transmission heat loss coefficients meet the requirements designated by standards, the real heat losses are increased by thermal bridges involved in the construction. Their influence is determined by the linear transmittance value which is usually not exactly established. [ABSTRACT FROM PUBLISHER]

Sisal-carbon hybrid composites were produced from mixtures having different weight ratios of sisal, carbon fibers and recycled polypropylene. All formulations were tested and evaluated for tensile and flexural properties. In addition, the thermal stability of the sisal-carbon hybrid composites were examined via thermogravimetric analysis and decay tests were conducted to determine the degradation of the hybrid composites. Results showed that the biological durability and mechanical and thermal properties improved with the increasing weight ratios of carbon fiber in the hybrid composites. According to the mechanical tests, the optimum hybrid composite formulation was found to be 12% sisal fiber + 28% carbon fiber + 60% rPP. [ABSTRACT FROM AUTHOR]

Mechanical parameters of ash wood (Fraxinus excelsior) subjected to compression in radial direction, before and after its thermal modification and measured at moisture content close to the equilibrium moisture content of wood exposed in and outside (4 and 12%) were compared. Thermal modification of wood was performed at 190°C or 200°C for 2 h in industrial conditions. During the measurements, the moisture content of the modified and control samples was identical. The parameters compared included: modulus of elasticity, stress at proportionality limit, relative linear strain at proportionality limit and accumulated elastic energy. Changes in the mechanical parameters of wood induced by its thermal modification were found to depend on the modification temperature and wood moisture content. [ABSTRACT FROM AUTHOR]

High-temperature heat treatment (HTHT) is an effective method for improving the wood dimensional stability and biological durability at present. However, the quantitative control of the wood color during the HTHT has been a more difficult problem for a long time. To solve the problem of quantitative control of wood color under the thermo-vacuum treatment (TVT) process, the mathematical model of heat and moisture transfer in alder birch wood (Betula alnoides) during the TVT process was built, and its application in the quantitative control of the wood color was also studied. (1) The experimental values and the model values of heat and moisture transfer in wood were found to be in good agreement. (2) The changes of wood temperature and moisture content (MC) were influenced obviously by the heat treatment temperature, the initial MC, and the thickness of specimen as well. The higher the heat treatment temperature was, the more rapid was the rise in the wood temperature and the drop in MC. The higher the initial MC of the wood was and the thicker the wood got, the slower the rise in wood temperature and the drop in MC. (3) Based on the mathematical model of heat and moisture transfer during the TVT process and the wood color index difference regression equations in the function of the temperature and time, the quantitative control of alder birch wood color during the TVT process was achieved. Therefore, it is feasible that heat and mass transfer principle applied during the TVT process guided the wood color quantitative control. [ABSTRACT FROM PUBLISHER]

Key message : Increasing environmental pressures appearing over the last few years have led to important changes in the field of wood protection. In this context, new technologies, based either on thermal or chemical modifications, suggest increasing interest in prospect of programmed ban of biocide products. • Context : The evolution of the regulations on the use of biocide products has led to important changes in the field of wood preservation, leading to an increasing interest for non-biocide treatments like thermal or chemical modifications to face to the programmed ban of biocide products. • Aims : The paper reviews the different non-biocide alternatives developed currently on an industrial scale, highlighting their main characteristics and applications. • Results : Different treatments have been developed on an industrial scale involving mainly thermal modifications and acetylation, furfurylation and DMDHEU constituting already available solutions. • Conclusion : Different non-biocide alternatives already exist and will become more important in the next decades due to the increasing legislative pressure driven by environmental considerations. [ABSTRACT FROM AUTHOR]

Key message: An efficient use of thermal treatment of wood requires a depth understanding of the chemical modifications induced. This is a prerequisite to avoid problems of process control, and to provide high quality treated wood with accurately assessed properties to the market. Properties and structural anatomy of thermally modified woods are slightly different than un-processed woods from a same wood species. So it is necessary to create or adapt new analytical methods to control their quality. Context: Heat treatment as a wood modification process is based on chemical degradation of wood polymer by heat transfer. It improves mainly the resistance of wood to decay and provides dimensional stability. These improvements, which come at the expense of a weakening of mechanical properties, have been extensively studied. Since a decade, researches focused mainly on the understanding of wood thermal degradation, on modelling, on quality prediction and quality control. Aims: We aimed at reviewing the recent advances about (i) the analytical methods used to control thermal treatment; (ii) the effects on wood decay resistance and (iii) the advantages and drawbacks of a potential industrial use of wood heating. Methods: We carried out a literature review of the main industrial methods used to evaluate the conferred wood properties, by thermal treatment. We used papers and reports published between 1970 and 2015, identified in the web of science data base.. Results: Approximately 100 papers mostly published after 2000 were retrieved. They concentrated on: (i) wood mass loss due to thermal degradation determination, (ii) spectroscopic analyses of wood properties, (iii) colour measurements, (iv) chemical composition, (v) non-destructive mechanical assessments and (vi) use of industrial data. Conclusions: One of most interesting property of heat-treated wood remains its decay resistance. Durability test with modified wood in laboratory are expensive and time-consuming. This review displays data from different analytical methods, such as spectroscopy, thermogravimetry, chemical analyses or mechanical tests that have the potential to be valuable indicators to assess the durability of heat treated wood at industrial scale. However, each method has its limits and drawbacks, such as the required investment for the equipment, reliability and accuracy of the results and ease of use at industrial scale. [ABSTRACT FROM AUTHOR]

Tracking the changes of cellulose crystallites upon thermo-hygro-mechanical treatment is essential to understand the response of wood cell walls to steam and compression. In this paper the influence of Compression combined with Steam (CS) treatment on wood cellulose crystallites and pores structure of Chinese fir ( Cunninghamia lanceolata) was studied under different steaming temperatures and compression ratios. Small-angle X-ray scattering and wide-angle X-ray scattering were used to investigate the changes of cellulose crystallites dimension, aspect ratio, fibril diameter distribution, non-crystalline fraction, the number of chains in each microfibril, as well as the fractal dimension and size of pores in response to CS treatment conditions. Results indicate that the crystallinity increased due to CS treatment, but did not show alteration with varying CS treatment conditions, i.e. seemed nearly unaffected by higher temperatures or compression ratio, both for earlywood and latewood. The cellulose crystallite diameter depended on processing parameters: it increased with increasing treatment temperature. No considerable differences were found for earlywood and latewood. We interpret our findings as a rearrangement of adjacent cellulose chains towards higher crystalline perfection attributing to the increase in crystallinity. The same effect allows a larger coherence length of crystalline order and therefore features an increasing cross-sectional dimension. In general we can state that the CS treatment leads to higher crystallinity and more perfectly arranged cellulose crystals, while it does not greatly affect the microfibril diameter but rather the amorphous regions of the microfibrils and the surrounding hemicellulose and lignin. [ABSTRACT FROM AUTHOR]

The influence of the burning temperature was evaluated for the nonvolatile combustible content of wood and bark of plantation-grown trees, at temperature intervals ranging from 500 °C to 1000 °C relative to ash production and the concentration of Ca, Mg, K, Mn, Zn, and Fe in ash, thermal properties, and ash fusibility. Production of ash from combustion of juvenile wood at t = 500 °C was Ad = 0.74% and juvenile bark Ad = 6.88%. Ash production decreased with increasing burning temperature. This was attributed to the chemical diversity of minerals contained in the wood and bark and their slow decomposition. Analyses of the presence of inorganic substances in ash from wood and bark revealed the highest presence of Ca. The concentration of calcium in ash from wood was Ca = 189 ± 46 g.kg-1 and in bark Ca = 278 ± 25g.kg-1. The ratio of processed calcium, potassium, magnesium, zinc, manganese, and iron in ash from wood at a burning temperature of t = 500 °C was Ca:K:Mg:Zn:Mn:Fe = 1:0.58:0.13:0.04:0.03:0.02 and from bark Ca:K:Mg:Zn:Mn:Fe = 1:0.41:0.07:0.01:0.01:0.003, respectively. The influence of the burning temperature non-volatile combustible was reflected in the concentration of each elements in ash and was contradictory. While concentration of Ca, Mg, Mn, and Fe in ash from wood and bark increased, concentration K and Zn in ash decreased. The decrease in concentration K, had a positive influence upon the thermal characteristics of the ash and the creation of ash in the form of loose matter. [ABSTRACT FROM AUTHOR]

To improve the thermal properties of softwood soda lignin, we studied a method of lignin modification using black liquor powder and polyethylene glycol (PEG). In this process, the black liquor powder was directly treated with PEG under alkaline conditions to produce a thermal melting material (alkaline PEG treatment). A model experiment was performed to determine the reaction of the lignin. The lignin in the black liquor powder consisted of 62.16% acid-insoluble lignin (purified lignin) and 37.84% acid-soluble lignin. After alkaline PEG treatment using purified lignin, the samples exhibited weak thermal melting during softening point analysis but did not exhibit appropriate thermal melting during thermal mechanical analysis (TMA). Nuclear magnetic resonance (NMR) data suggest that there was no linkage between lignin and PEG in the alkaline PEG-treated lignin prepared from the purified lignin. On the other hand, when using acidsoluble lignin, NMR data suggest that PEG was introduced to the lignin at its a-carbon position. Acid-soluble lignin PEG derivatives could work as plasticizers to induce the thermal melting of the alkaline PEG-treated lignin prepared from black liquor powder. [ABSTRACT FROM AUTHOR]

Ensuring reliability of data on thermal properties of wood-based panels is important for manufacturing processes, especially when it is recommended to shorten the cooling phase and stack the panels in hot conditions. Prediction of the heat transfer during cooling phase and normal or hot stacking based on accurate data is essentially important for attaining panels of required properties. The thermal properties are also required when designing houses, especially low-energy or passive ones. Therefore, a water calorimeter was adequately designed and constructed to ensure improvement in the accuracy of the specific heat measurements. The calorimeter was used to determine the specific heat. The attained accuracy estimated by the relative error was significantly increased, and the error values were less than 2 % for all types of the investigated particleboard and OSB. In case of low-density fiberboard (LDF), the maximum value of the relative error did not exceed 4 %. It was also shown that high accuracy required for the specific heat measurements was achieved for experiments in which high-mass samples were used, in contrast to measurements for such samples in traditional DSC systems. The results for the specific heat were within the range from 1420 to 1450 J/kg K for LDF and all types of particleboard. The effect of the investigated material density on the specific heat was not found. The only exception was in case of OSB for which the specific heat was ca. 1550 J/kg K, and it was approximately 100 J/kg K higher when compared to other panels. [ABSTRACT FROM AUTHOR]

The objective of this study was to investigate the color and chemical changes of thermo-vacuum treated larch wood. Specimens were heat treated in a vacuum at various temperatures for 4 h. The color parameters of untreated and heat-treated samples were measured using the CIELab color system. Changes in the chemistry of larch wood were investigated using X-ray photoelectron spectroscopy (XPS), electron spin resonance (ESR) spectroscopy, and UV-Vis spectroscopy. The results showed that the color of larch wood became darker at higher treatment temperatures. The O/C ratio decreased with an increase in treatment temperature. The C1 peaks showed that there was an elevated content of lignin and extractives on the wood surface after heat treatment. There were more free radicals for thermally treated wood samples, as demonstrated by the increase in the intensities of the ESR signals. Some groups of lignin that contribute to the darkness of the wood increased after thermo-vacuum treatment. Changes in surface chemistry may be the cause of discolorations that occurred during thermo-vacuum treatment. [ABSTRACT FROM AUTHOR]

An asymmetrical two-layer laminated densified wood product is prone to cupping when it is placed in a fluctuating moisture environment. This study was aimed at developing a 2D finite element (FE) model to simulate this situation. Two types of specimens with two thickness ratios of 0.18 (type I) and 0.58 (type II) were prepared. A 6-week moisture and temperature treatment was conducted. The cupping value of deformed specimens was measured for verification. The major results were: (1) The cupping value of type I specimens experimentally measured and predicted was 0.307 and 0.327 mm, respectively, while that of type II specimens was 0.440 and 0.396 mm, respectively; (2) FE and experimental results were in good agreement since the FE results lied in the 95 % confidence interval of the experimental results. The developed FE model can be used to predict the moisture-induced cupping of a two-layer laminated wood product. [ABSTRACT FROM AUTHOR]

Cupping is a critical issue that affects the performance of a two-layer laminated densified wood product in service. Many parameters including material properties and product geometry can influence the cupping. It is more efficient to study the influence of these parameters on cupping using a model than by testing. A model sensitivity analysis is helpful in identifying key parameters so that product design can be optimized. This paper expanded the discussion on the finite element model developed and its application. It was found that (1) swelling/shrinkage coefficient and modulus of elasticity in the tangential direction and equilibrium moisture content were three key material parameters; (2) increasing the modulus of elasticity could offset part of cupping; (3) thickness ratio of two wood layers, as a key geometry parameter, was independent of three key material parameters; and (4) the optimal thickness ratio of two wood layers was 0.12. [ABSTRACT FROM AUTHOR]

To clarify the decay resistance effects of wood treated with different preservatives, the thermal behavior of treated samples was investigated. A thermal dynamic model was established using a mathematical method. The results showed that untreated Pinus massoniana had maximum mass loss, and the decay resistance effects of this species treated with different preservatives improved with an increase in the largest mass loss of pyrolysis. The pyrolysis can be divided into primary pyrolysis and secondary pyrolysis reactions in the lower and higher temperature regions, respectively. The activation energy represents a different degree of reduction from the primary pyrolysis reaction to the secondary pyrolysis reaction. The higher the retained cellulose content, the higher the activation energy. The sample's activation energy in the primary pyrolysis reaction can represent the decay resistance effects of wood treated with different preservatives. [ABSTRACT FROM AUTHOR]

Thermally modified wood is widely used in cladding, decking, and other construction projects that are meant for outdoor exposure. The purpose of this study was to investigate changes in the color, microstructure, and chemical composition of heat-treated, Larix spp. wood that was exposed to artificial weathering. In this study, accelerated weathering tests (UV and moisture) were conducted over a period of 3000 h. Photodegradation of both heat-treated and untreated wood was evaluated in terms of color, microstructure, and chemical changes that were characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy. Ultra-violet radiation caused the degradation of lignin and extractives of wood, resulting in an immediate color change of the wood. The SEM observation of the heat-treated wood showed deformations and cracks in both treated and untreated samples. Irradiation resulted in a pronounced reduction in the absorption intensity and broadening of the FTIR spectra. It was found that the industrial heattreatment of wood products resulted in more color stability than untreated wood during the early stages of weathering. Thermal modification was found, however, was ineffective in improving the UV resistance wood over long-term photodegradation conditions. [ABSTRACT FROM AUTHOR]

This article focuses on the plane milling of thermally modified birch wood while taking into account technological parameters that have substantial effects on the processed wood surface's arithmetic mean deviation of the waviness profile (Wa). The milling process was affected by the cutting speed, which varied from 20 to 60 m/s, with a feed rate of 4, 8, and 11 m/min. The results obtained on the set of thermally modified test specimens, were compared with the results obtained on test specimens without heat treatment. The surface finish was measured using various milling parameters. The material removal was 1 mm per pass. The results indicate that the thermal modification of wood did not significantly influence the arithmetic mean deviation of the waviness profile (Wa). Cutting speed and feed rate had the most significant effects among the monitored factors. The lowest arithmetic mean deviation of the waviness profile (Wa) was determined at a feed rate of 4 m/min and cutting speed of 40 m/s. An increase in cutting speed led to a decrease in the average roughness, while increased feed rate had the opposite effect. [ABSTRACT FROM AUTHOR]

Wood-based materials are used to manufacture various types of panels, including particleboard, fiberboard, and plywood, and they can also be used to manufacture furniture as well as interior and exterior building materials. However, wood-based materials exhibit a number of problems, including the emission of indoor air pollutants from adhesives used during production and their inherent fire risk. To date, a number of studies have investigated the emission of indoor air pollutants, and in recent years, there has been an increasing amount of interest in the flame-retardant performance of wood-based materials. In this study, the use of carbon materials was studied to improve the flame-retardant performance of wood-based materials. A comparison was made with various methods that are currently in use. The thermal conductivity was measured by the TCi method developed by C-Therm Technologies Ltd to evaluate the energy characteristics of wood-based materials that are used as interior materials. [ABSTRACT FROM AUTHOR]

Thermally-modified wood (TMW) has enhanced properties and its production does not involve the use of chemicals. However, the adoption of TMW in the marketplace has been limited in the U.S. for reasons that have not yet been clearly established. In this study, the marketing practices of U.S. producers and distributors of TMW were investigated, by conducting semi-structured interviews. Topics included major products and species, markets, distribution channels, promotional strategies, perceived barriers to adoption, and the outlook for TMW markets. Results show that TMW producers in general export a significant percent of their production; that TMW is considered a high-end product; and that customers are not as sensitive to prices as in other mainstream markets. Common products sold include siding, decking, flooring, millwork, and components for musical instruments. Respondents believe that the low awareness of TMW among the American public is a major barrier to wider adoption of TMW. However, companies envision a bright future for TMW as sales and inquiries have increased at a fast rate during the last few years. [ABSTRACT FROM AUTHOR]

Quercus pubescens Willd. is a common oak species in the Mediterranean area, where it is currently exploited mainly for purposes such as firewood. To improve the technological properties of its wood, various steaming and/or heat treatments were applied to 160 wood samples from a southern Italian stand, cut from either sapwood or heartwood, while 20 samples served as controls. Steaming was carried out in an autoclave at 120 °C, whereas heat treatments were performed in an oven at 150 or 200 °C for 3 or 6 h. The equilibrium moisture content, swelling, mass loss, wood density, compression strength, color variation, and lignin content of the samples were measured and compared among treatments. The swelling and water adsorption of wood samples decreased due to the hydrothermal treatments. The mass loss was strictly related to the temperature and duration of the heat treatments, whereas it was not influenced by the steaming treatment. The average axial compression strength value was positively influenced by the combination of steaming and heat treatments. A significant and general darkening of color was also observed for the harshest treatments, while an increase of lignin content was detected mainly in the sapwood. Thus, pubescent oak wood subjected to steaming and heat treatments may acquire useful characteristics suitable for its industrial use. [ABSTRACT FROM AUTHOR]

Casuarina equisetifolia wood is extensively used as fire wood and is also being used extensively in gassifiers. Drying is an important procedure which has to be carried out before the wood is burnt. Experiments on Casuarina wood chips of dimension 5.08 cm × 5.08 cm with 2.54 cm thickness were carried out between 80°C to 100°C in a tray drier using air flow velocity of 0.5m/s. Initial moisture content was found to be 48% on dry basis. The experimental drying curves showed only the falling rate period. Eleven thin-layer drying kinetic models were fitted with the experimental drying kinetics values and individual model constants were found. These models were compared using statistical measures like correlation coefficient, root mean square error, mean bias error and reduced chi-square to estimate the best model that would fit for the experiment. The drying rate and effective diffusion coefficient (Deff) were found to increase with temperature. [ABSTRACT FROM AUTHOR]

To upgrade the utilization of kraft lignin (KL) for high-performance lignin-based materials (e.g., carbon fiber), the purity, molecular mass distribution (MMD), and thermal properties need to be improved and adjusted to target values. Therefore, different methods, such as ultrasonic extraction (UE), solvent extraction, dialysis, and hot water treatment (HWT), were applied for the purification of KL. The chemical and thermal properties of purified lignin have been characterized by nuclear magnetic resonance, Fourier transform infrared, gel permeation chromatography, elemental analysis, differential scanning calorimetry, and thermogravimetric analysis. The lignin fractions obtained by UE with ethanol/acetone (E/A) mixture (9:1) revealed a very narrow MMD and were nearly free of inorganic compounds and carbohydrates. Further, the E/A-extracted lignin showed a lower glass transition temperature ( Tg) and a clearly detectable melting temperature ( Tm). Dialysis followed by HWT at 220°C is an efficient method for the removal of inorganics and carbohydrates; however, lignin was partly forming condensed structures during the treatment. [ABSTRACT FROM AUTHOR]

This article reports a study of flame retardancy and thermal and mechanical properties of wood-plastic composites (WPCs) based on high-density polyethylene and pine flour. The study shows that sample composition plays an important role in WPCs' properties. The influence of additives like fillers (SiO2or CaCO3) and flame retardants ammonium polyphosphate (APP) and pentaerythritol (PER) on WPCs' properties has been considered. The best properties are shown in samples using SiO2as filler and treated with the intumescent fire retardant APP/PER. Such samples have excellent fire retardancy with V-0 rating (UL-94 test) and imply that APP/PER fire retardant ensures effective fire retardancy for WPCs. [ABSTRACT FROM AUTHOR]

Thermally modified wood has high dimensional stability and biological durability. But if the process parameters of thermal modification are not appropriate, then there will be a decline in the physical properties of wood.A neural network algorithm was employed in this study to establish the relationship between the process parameters of high-temperature and high-pressure thermal modification and the mechanical properties of the wood. Three important parameters: temperature, relative humidity, and treatment time, were considered as the inputs to the neural network. Back propagation (BP) neural network and radial basis function (RBF) neural network models for prediction were built and compared. The comparison showed that the RBF neural network model had advantages in network structure, convergence speed, and generalization capacity. On this basis, the inverse model, reflecting the relationship between the process parameters and the mechanical properties of wood, was established. Given the desired mechanical properties of the wood, the thermal modification process parameters could be inversely optimized and predicted. The results indicated that the model has good learning ability and generalization capacity. This is of great importance for the theoretical and applicational studies of the thermal modification of wood. [ABSTRACT FROM AUTHOR]

This paper deals with the determination of the surface quality of both thermally treated and thermally untreated wood after the plane milling process. The milled surface quality was evaluated on the basis of the arithmetical mean deviation of the assessed profile, Ra. Surface quality measurements were carried out for various milling process parameters, such as tool clearance angles of 15°, 20°, and 25°, cutting speeds of 20, 30, and 40 m/s, and feed speeds of 4, 8, and 11 m/min. A splinter with a uniform thickness of 1 mm was removed from the wood through milling. Based on the results, it can be stated that thermal treatment of wood has no statistically significant impact on roughness. The most significant impact of the monitored factors were associated with feed speed, clearance angle, and cutting speed. The lowest average roughness values were found at 20° clearance angles, a feed speed of 4 m/min, and a cutting speed of 40 m/s. Increases in cutting speed led to a decrease in average roughness, while an increase in feed speed had the opposite effect. [ABSTRACT FROM AUTHOR]

The objective of this study was to assess the influence of varying temperature on the strength characteristics of joints bonded using three types of one-component PVAc adhesives (i.e., Rakoll Express D3, Titebond II Premium, and Rhenocoll 3W, 4B Plus) that belong to the group of thermoplastic wood adhesives intended for non-construction bonding applications. The measuring procedure was a transverse tensile test for estimation of joint strength. As documented by the test results, a higher joint strength achieved at a higher temperature was achieved again after a gradual increase in the joint temperature from 20 °C to 140 °C and subsequent cooling to the starting temperature. After cooling the joint to the starting temperature, all tested adhesives complied with the minimum strength, namely 10 MPa. The results obtained in this study indicated that the resistance and thus the strength of joints bonded using contemporary PVAc adhesives increases with time. [ABSTRACT FROM AUTHOR]

In the Great East Japan Earthquake on March 11, 2011, large amounts of disaster waste were generated by the earthquake and subsequent tsunami. Much of the mixed wood waste was stored in a temporary storage facility for an extended period of time, and fire broke out due to spontaneous ignition. Consequently, it is now the practice that when a metropolitan epicentral earthquake occurs, disaster waste will be generated and stored locally. Fire caused by the same type of spontaneous ignition is a grave cause for concern. Thus, in order to prevent such fires, we evaluated the thermal behavior of the oxidation heat of the wood that was believed to be the cause of the heat generation in disaster waste. As a result of studies using TG-DTA and TAM, it was revealed that the thermal danger of wood increases due to increases in the temperature and in the concentration of unsaturated fatty acids in the wood. It is thought that the oxidation heat of the unsaturated fatty acids contained in the waste wood contributed to heat generation near 70 °C after heat generation by fermentative bacteria. [ABSTRACT FROM AUTHOR]

The aim of this study was to enhance the water repellency and dimensional stability of thermally modified wood by combining the preimpregnation of paraffin wax emulsion. To achieve this, Southern pine (SP; Pinus spp.) samples were first impregnated with paraffin wax emulsion (with 2.0% solid content) and then subjected to thermal modification (TM) in an oven at 180°C and 220°C for 4 and 8 h. The contact angle (CA), surface free energy, water absorption rate (WAR), anti-swelling efficiency (ASE), and bending properties of the control and modified samples were investigated. Moreover, the chemical and morphological alterations were analyzed by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Both the wax impregnation and TM decreased the surface wettability, water absorption, and tangential swelling, while the combination of wax and thermal treatment exhibited the best water repellency and dimensional stability, indicating the synergism between the two procedures. However, the wax preimpregnation did not affect the mechanical properties of thermally modified wood. The FTIR, SEM, and XPS analyses confirmed that the synergistic effect is mainly due to the redistribution of the paraffin wax during TM rather than its impact on the chemical changes caused by thermal degradation. [ABSTRACT FROM AUTHOR]

We analyzed the effects of heat treatment on the chemical structure of wood from narrow-leafed Ash (Fraxinus angustifolia), a fast-growing and economically valuable species. We also analyzed the effects of heat treatment on the wood's resistance to four decay fungi. Narrow-leafed Ash wood samples were heated with saturated steam to 140, 180, 200, and 220°C for 2, 4, and 6 h. The relative contents of extractable components were analyzed, as well as the levels of holocellulose, cellulose, and lignin. In addition, the density, equilibrium moisture content, and pH of the samples were measured. To determine the effects of heat treatment on resistance to decay fungi, the samples were exposed to the white rot fungus Trametes versicolor, dry rot fungus Serpula lacrymans, and the brown rot fungi Coniophoraputearía and Gloeophyllum trabeum. Changes in the chemical composition of the wood due to heat treatment were correlated with increased resistance to fungal decay. While the hemicellulose content was dramatically reduced with increasing temperature and treatment duration, the lignin content increased proportionately. Thus, heat treatment is an environmentally friendly method of preserving narrow-leafed Ash wood against various decay fungi. [ABSTRACT FROM AUTHOR]

Wood heat treatment is an attractive alternative to improve decay resistance of wood species with low natural durability. However, this improvement of durability is realized at the expense of the mechanical resistance. Decay resistance and mechanical properties are strongly correlated to thermal degradation of wood cells wall components. Mass loss resulting from this degradation is a good indicator of treatment intensity and final treated wood properties. However, the introduction of a fast and accurate system for measuring this mass loss on an industrial scale is very difficult. Nowadays, many studies are conducted on the determination of control parameters which could be correlated with the treatment conditions and final heat treated wood quality such as decay resistance. The aim of this study is to investigate the relations between kinetics of temperature used during thermal treatment process representing heat treatment intensity, mass losses due to thermal degradation and conferred properties to heat treated wood. It might appear that relative area of treatment temperature curves is a good indicator of treatment intensity. Heat treatment with different treatment conditions (temperature-time) have been performed under vacuum, on four wood species (one hardwood and three softwoods) in order to obtain thermal degradation mass loses of 8, 10 and 12%. For each experiment, relative areas corresponding to temperature kinetics, mass loss, decay resistance and mechanical properties have been determined. Results highlight the statement that the temperature curves' area constitutes a good indicator in the prediction of needed treatment intensity, to obtain required wood durability and mechanical properties such as bending resistance and Brinell hardness. [ABSTRACT FROM AUTHOR]