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Most climatic changes are not just the result of human activity, but also of business models that harm the environment. An attempt to attain an ecological balance is an answer to the challenge posed by this situation. The combustion of liquid fuels results in the atmospheric emissions of pollutants, such as nitrogen oxides (NOx), sulfur dioxide and hydrocarbons. To reduce emissions of these pollutants and at the same time attain an ecological balance, specific modifiers are applied. This paper presents an analysis of the energy efficiency and ecological efficiency of fuel oil combustion in power plant boilers based on the results of tests carried out by the present authors, in which a Fe/Mg/Ce modifier was used. The tests were carried out for system capacities ranging from 1 to 5 MW. It was found that savings on fuel, which resulted from the implementation of a system for the control and supervision of power plant operation, were in the range of 4 to 6%, and those resulting from the use of the combustion modifier were from 2 to 4%. Moreover, it was found that the system designed to improve efficiency also provided the extra result of reducing CO2 emission and equivalent emission (SO2, NO2, and particulate matter). [ABSTRACT FROM AUTHOR]

Experimental results of the solubilization of olefins in hydroformylation model systems, comprising 1-dodecene and 1-tridecanal or 1-tetradecene and 1-pentadecanal, water, butanol, sodium dodecylsulfate (SDS), sodium dodecylbenzenesulfonate (SDBS), and/or tri(m-sulfofenyl)phosphine trisodium salt (TPPTS-Na) are presented. The selected systems were used for the hydroformylation of 1-dodecene and 1-tetradecene whereby high yields of aldehydes were obtained. After the reaction, the mixture spontaneously separated into an organic phase with the reaction products and an aqueous phase comprising the catalyst and excess phosphine ligand. [ABSTRACT FROM AUTHOR]

Hard coal is widely used as a source of energy, and a number of catalysts have been developed to minimize the noxious impact of this fuel on combustion. This paper presents the cost-efficiency analysis of a system for improving the combustion of solid fuels, especially fine coal, in power boilers. The system is provided with a control and supervision device. It has been designed for better accuracy in controlling the boiler operating parameters, with a view to improving combustion efficiency due to the use of catalysts. The tests were carried out for system capacities ranging from 3 to 100 MW. It was found that, depending on the size of the system in the range of 3–100 MW, savings in the fuel consumption ranged from 2% to 8% due to the implementation of novel solutions in the boiler plant operation and from 2 to 6% due to the use of the combustion catalysts. Apart from boosting energy efficiency, the use of catalysts and the efficiency-boosting system resulted in the costs of overhauls being cut by about 20%. The payback time depends on system capacities, and it is between 6.75 and 1.74 years for capacities ranging from 3 to 75 MW and 2.0 years for a 100 MW plant. [ABSTRACT FROM AUTHOR]

This paper presents the result of the investigation of organically modified silica (ORMOSIL)-zirconia coatings used to enhance their protective properties, namely corrosion and scratch resistance. Two different materials, i.e., SiO2/ZrO2 and SiO2/GPTMS/ZrO2, were synthesized, measured, and analyzed to find the difference in the used organosilane precursor (dimethyldiethoxysilane and (3-glycidoxypropyl)trimethoxysilane, respectively). SiO2/ZrO2 coatings showed higher hardness than SiO2/GPTMS/ZrO2. Moreover, the value of polarization resistance (Rp) for SiO2/GPTMS/ZrO2 coated 316L steel relative to the uncoated one was obtained. It was nearly 84 times higher. The coating delamination was observed with load 16N. Additionally, the corrosion mitigation for 316L coated by SiO2/GPTMS/ZrO2 was observed even after extended exposure to corrosion agents. [ABSTRACT FROM AUTHOR]

This research work presents the results of studies on the effect of modifiers comprising the salts CuSO4·2H2O, NaCl, NH4Cl, MgSO4·7H2O, CaCl2, and urea at various concentrations on the combustion of fine coal. The tests were carried out in a 12-kW laboratory boiler equipped with a rotary-grate retort furnace. The emission levels and concentrations of CO, CO2, SO2, NOx, and TOC in the flue gas were measured using analyzers. A modifier composed of 350 ppm Cu, Na, Mg, NH4+, Ca, and urea showed particularly high activity in the combustion of fine coal. The flue-gas levels of CO, NOx, and SO2 were reduced by approximately 9%, 12%, and 10%, respectively, in comparison with the modifier-free sample. In this case, the boiler efficiency also increased from 65% in the tests with no modifier to 76% in the tests with the modifier. The proprietary application system, enabling the modifier to be added in exact amounts to the variable flow of fine coal, is also described. It was found that the use of the modifier in coal combustion tests results in lower emissions of harmful fuel components, a higher amount of heat obtained from the fuel unit mass, lower corrosive impact of the fuels, lower boiler maintenance costs, and extended service life. [ABSTRACT FROM AUTHOR]

This study proposes an innovative installation concept for the sustainable utilization of sewage sludge. The aim of the study is to prove that existing devices and technologies allow construction of such an installation by integration of a dryer, torrefaction reactor and gasifier with engine, thus maximizing recovery of the waste heat by the installation. This study also presents the results of drying tests, performed at a commercial scale paddle dryer as well as detailed analysis of the torrefaction process of dried sewage sludge. Both tests aim to identify potential problems that could occur during the operation. The scarce literature studies published so far on the torrefaction of sewage sludge presents results from batch reactors, thus giving very limited data of the composition of the torgas. This study aims to cover that gap by presenting results from the torrefaction of sewage sludge in a continuously working, laboratory scale, isothermal rotary reactor. The study confirmed the feasibility of a self-sustaining installation of thermal utilization of sewage sludge using low quality heat. Performed study pointed out the most favorable way to use limited amounts of high temperature heat. Plasma gasification of the torrefied sewage sludge has been identified that requires further studies. [ABSTRACT FROM AUTHOR]