1. Hierarchical nanoporous intermetallic compounds with self-grown transition-metal hydroxides as bifunctional catalysts for the alkaline hydrogen evolution reaction.
- Author
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Li-Ping Han, Rui-Qi Yao, Wu-Bin Wan, Hang Shi, Zi Wen, Xing-You Lang, and Qing Jiang
- Abstract
The hydrogen evolution reaction (HER) is a crucial step in alkaline water electrolysis, but suffers from sluggish reaction kinetics, which calls for the development of active and robust catalysts for the highly efficient production of high-purity hydrogen. Here, we report hierarchical nanoporous (NP) transition-metal (TM = Fe, Co)-doped Pt
3 Al intermetallic compounds, which are composed of surface alloys of Pt and TMs with in situ self-grown TM hydroxides in an alkaline environment, NP (Pt1-x TMx )3 Al/Pt-TM(OH), as highly efficient bifunctional catalysts for the HER. By virtue of the constituent Co(OH)2 having moderate hydroxyl adsorption to accelerate water dissociation and the Pt atoms facilitating the adsorption/desorption of reactive hydrogen intermediates, the NP (Pt1-x Cox )3 Al/Pt-Co(OH)2 exhibits superior HER activity in 0.1 M KOH, with a low Tafel slope of 48 mV dec-1 and an overpotential of ~43 mV at 10 mA cm-2 , as well as exceptional durability due to its unique nanoporous structure with stable intermetallic bonds. These electrocatalytic properties outperform state-of-the-art Pt-based catalysts, suggesting that multi-site design is suitable for producing highly efficient catalysts towards the HER in alkaline environments. [ABSTRACT FROM AUTHOR]- Published
- 2019
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