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Microbially mediated NO3−-N and Cr(VI) reduction is being recognized as an eco-friendly and cost-effective remediation strategy. Iron sulfide mineral, as a natural inorganic electron donor, has a strong influence on NO3−-N and Cr(VI) transformation, respectively. However, little is known about the simultaneous nitrate and chromium removal performance and underlying mechanism in an iron sulfide mineral-involved mixotrophic biofilter. This study demonstrated that the NO3−-N and Cr(VI) removal efficiencies were stable at 62 ± 8% and 56 ± 10%, and most of them were eliminated in the 0–100-mm region of the biofilter. Cr(VI) was reduced to insoluble Cr(III) via microbial and chemical pathways, which was confirmed by the SEM–EDS morphology and the XPS spectra of biofilm and pyrite particles. SO42− was as a main byproduct of pyrite oxidation; however, the bacterial SO42− reduction synchronously occurred, evidenced by the variations of TOC and SO42− concentrations. These results suggested that there were complicated and intertwined biochemical relations between NO3−-N/Cr(VI)/SO42−/DO (electron acceptors) and pyrite/organics (electron donors). Further investigation indicated that both the maximal biomass and greatest denitrifiers' relative abundances in microbial sample S1 well explained why the pollutants were removed in the 0–100-mm region. A variety of denitrifiers such as Pseudoxanthomona, Acidovorax, and Simplicispira were enriched, which probably were responsible for both NO3−-N and Cr(VI) removal. Our findings advance the understanding of simultaneous nitrate and chromium removal in pyrite-involved mixotrophic systems and facilitate the new strategy development for nitrate and chromium remediation. [ABSTRACT FROM AUTHOR]

The urgent need to address the severe issue of nitrogen pollution has prompted the search for a functional and easy recycling material. In this study, manganese oxides (MnOx) were loaded on activated carbon (AC), resulting in a composite known as AC-MnOx, for efficient ammonium removal from aqueous solutions. The results indicated a remarkable 15.6-fold increase in ammonium removal efficiency and a fivefold enhancement in removal capacity for AC-MnOx (3.20 mg/g) compared to AC. Under specific conditions (initial NH4+-N concentration of 15 mg/L, adsorbent dose of 2.5 g, pH of 6.5, and temperature of 35 ℃), the highest achieved ammonium removal efficiency reached 94.6%. Furthermore, the study distinguishes the contributions of catalytic oxidation and adsorption in the removal process. The adsorption process was effectively modeled using pseudo-second-order kinetics and Langmuir isotherm models. Interestingly, the amount of oxidation conversion (Ntur) exhibited a linear relationship with the dosage when the initial ammonium concentration was sufficiently high, while the relationship between initial ammonium concentration and the ratio of Ntur to adsorption capacity (Nsur) followed a negative exponential trend. The removal mechanisms involved electrostatic interaction between ammonium and the negatively charged dehydrogenated hydroxyl groups (− OHsur) or cation tunnel in crystal structures of MnOx, ion exchange adsorption, and the oxidation impact of MnOx. This research provides valuable insights into the application of immobilized MnOx media for ammonium removal. Moreover, filling AC-MnOx into constructed wetlands (CW) proved to be an effective method for reducing ammonium pollution, demonstrating its potential in the field of engineering wastewater treatment. [ABSTRACT FROM AUTHOR]

The urgent need to address the severe issue of nitrogen pollution has prompted the search for a functional and easy recycling material. In this study, manganese oxides (MnOx) were loaded on activated carbon (AC), resulting in a composite known as AC-MnOx, for efficient ammonium removal from aqueous solutions. The results indicated a remarkable 15.6-fold increase in ammonium removal efficiency and a fivefold enhancement in removal capacity for AC-MnOx (3.20 mg/g) compared to AC. Under specific conditions (initial NH4+-N concentration of 15 mg/L, adsorbent dose of 2.5 g, pH of 6.5, and temperature of 35 ℃), the highest achieved ammonium removal efficiency reached 94.6%. Furthermore, the study distinguishes the contributions of catalytic oxidation and adsorption in the removal process. The adsorption process was effectively modeled using pseudo-second-order kinetics and Langmuir isotherm models. Interestingly, the amount of oxidation conversion (Ntur) exhibited a linear relationship with the dosage when the initial ammonium concentration was sufficiently high, while the relationship between initial ammonium concentration and the ratio of Ntur to adsorption capacity (Nsur) followed a negative exponential trend. The removal mechanisms involved electrostatic interaction between ammonium and the negatively charged dehydrogenated hydroxyl groups (− OHsur) or cation tunnel in crystal structures of MnOx, ion exchange adsorption, and the oxidation impact of MnOx. This research provides valuable insights into the application of immobilized MnOx media for ammonium removal. Moreover, filling AC-MnOx into constructed wetlands (CW) proved to be an effective method for reducing ammonium pollution, demonstrating its potential in the field of engineering wastewater treatment. [ABSTRACT FROM AUTHOR]

Considerable advances have been made in the substrate design and operation strategies of constructed wetlands to facilitate nitrogen elimination. However, few studies examined the complicated interaction between solid organic substrates and limited aeration on nitrogen removal. A vertical flow constructed wetlands in gradient distribution of inorganic and solid organic substrates (polycaprolactone/PCL) (P-VFCW) and a controlled vertical flow constructed wetland without PCL (C-VFCW) were developed for the tertiary treatment of municipal tailwater. Results indicated that ammonia was nearly converted to nitrate, while the total nitrogen removal efficiencies (TNREs) in C-VFCW were negligible. In P-VFCW, however, optimal TNREs approached 95% with an aeration rate of 0.06 mL·min−1 and hydraulic retention time (HRT) of 24 h, and simultaneous nitrification and denitrification process (SND) in aerobic conditions was confirmed. As for the spatial microbial community structure evolution, Comamonas, which is associated with heterotrophic nitrification and anoxic/aerobic denitrification, was enriched along the vertical profiles of P-VFCW. Autotrophic nitrifier (Nitrospira), aerobic denitrifier (Bradyrhizobium and Azospira), and anoxic denitrifier (Ignavibacterium and Methyloversatilis) were dominated in different depths of P-VFCW, respectively. Besides, Canna indica biomass in P-VFCW was significantly larger than that in C-VFCW, which was attributed to the plant adaption response to diverse nitrogen. The P-VFCW in gradient distribution of inorganic and solid carbon sources under limited aeration is a promising technology for advanced nitrogen removal. [ABSTRACT FROM AUTHOR]

Phosphorus pollution has the potential to cause both aquatic eutrophication and global phosphorus scarcity. Fe-based layered double hydroxides (LDHs) have received much attention due to their high phosphorus adsorption and recovery. The composition of Fe-based LDHs is an important factor in determining their adsorption performance. However, the mechanism by which single component regulation of Fe-based LDHs affects phosphorus adsorption performance remains unknown. In this study, two typical types of Fe-based LDHs were prepared: Mg/Fe LDH and Zn/Fe LDH. Results showed that the equilibrium adsorption capacity of Zn/Fe LDH was much greater than that of Mg/Fe LDH, reaching 65.85 mg/g with a phosphorus concentration of 150 mg/L. Calcination facilitated a substantial increase of adsorption capacity for Mg/Fe LDH rather than Zn/Fe LDH. Meanwhile, the phosphorus removal efficiency of Fe-based LDHs both exceeded 90% with an initial pH of 3.0, but it decreased as pH increased, and pH inhibition was relatively weaker for Zn/Fe LDH than Mg/Fe LDH. The common coexisting anions caused a phosphorus adsorption loss, with SO42− possessing the most competition with phosphorus. Combined with FTIR, XRD, XPS, and BET analyses, a superior adsorption performance of Zn/Fe-LDH over Mg/Fe-LDH was probably attributed to a higher surface complexation and larger specific surface area. It was also concluded that Fe-based LDHs are a promising method for removing phosphorus from recirculating aquaculture wastewater. [ABSTRACT FROM AUTHOR]

The functionalized biochar was assembled on modified zeolite to synthesize a novel modified composite adsorbent. The latter was applied to simultaneous adsorption of ammonium and nitrate. The Box–Behnken design (BBD) in response surface methodology (RSM) was applied to optimize the parameters, which included ratio of raw materials, adsorbent dose, pH, and temperature. The chemical functional groups were determined by Fourier transform infrared adsorption (FT-IR). Stronger absorption peaks of amine groups indicated that the functionalized adsorbent could enhance the adsorption of contaminants. The composite adsorbent effectively increased NH4+ and NO3− adsorption capacity by porous structure recombination, change of surface morphology and further exposure of surface functional groups. The kinetic results indicate that the adsorption of both NH4+ and NO3− follows a pseudo-second-order nonlinear model. The Langmuir isotherm model fitted well the experimental data with a maximum adsorption capacity of 24.45 mg/g for nitrate and 24.63 mg/g for ammonium at 25°C. Nitrate was absorbed by electrostatic interactions with grafted amine groups and, in contrast, the ammonium adsorption was mainly related to ion exchange with Na+. The adsorption process of both nitrate and ammonium were spontaneous and exothermic. The adsorbents can be regenerated effectively in NaCl and NaOH mixed solutions, and the desorbed adsorbents are of high reusability and can be applied effectively at least for five cycles. Therefore, it has a great potential for nitrate and ammonium simultaneous removal from water environment. [ABSTRACT FROM AUTHOR]

In this study, a poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/poly(lactic acid) (PHBV/PLA)–supported denitrification system was built to remove nitrogen from municipal wastewater treatment plant secondary effluent, and the influence of operating temperature on nitrogen removal was further investigated. Results indicated that a PHBV/PLA-supported denitrification system could effectively fulfill the tertiary nitrogen removal. The nitrogen removal efficiency gradually declined with the operating temperature decreasing, and the denitrification rate at 30 °C was 5 times higher than that at 10 °C. Meanwhile, it was found that a slight TOC accumulation only occurred at 30 °C (with an average of 2.03 mg/L) and was avoided at 10~20 °C. The reason for effluent TOC variation was further explained through the consumption and generation pathways of TOC in this system. Furthermore, the temperature coefficient was about 0.02919, indicating that the PHBV/PLA-supported denitrification system was a little sensitive to temperature. A better knowledge of the effect of operating temperature will be significant for the practical application of the solid-phase denitrification system. [ABSTRACT FROM AUTHOR]

Enhanced understanding of non-aqueous phase liquid (NAPL) infiltration into porous media is important for the effective design of remediation strategies. Six model multi-flow experiments in two-dimensional polymethyl methacrylate tank were carried out to verify the influences of soil initial water content, local low permeability lens, lithologic sharp interface and leakage position on light non-aqueous phase liquid (LNAPL) and dense on non-aqueous phase liquid (DNAPL) transport velocities in soil, with diesel and perchlorethylene as LNAPL and DNAPL, respectively. The evolutions of the plume were recorded through the transparent side of the tank by CCD camera and the contaminant fronts were traced using gel pen on a plastic film coated on tank wall at appropriate intervals. The controlling factors of free NAPL migration paths and speeds were analyzed thoroughly, and capillary pressure equilibrium models of NAPL-water/NAPL-air interface and the partition movement theory were put forward. Results show that the effect of NAPL types: soil initial water content, local low permeability lens, leakage position and lithologic sharp interface on NAPL migration paths and velocities are diverse. The NAPL movement principles should be presented in accordance with partitions as related to the initial water content namely dry soil area, capillary zone and water-saturated zone. The vertical movement and lateral extension of NAPL are interdependent, and the vertical migration is dominant in initial leakage stage. The vertical migration is hindered by lateral growth when meeting with local low permeability lens, lithologic sharp interface or capillary fringe. Vertical migration rate reduction is mainly caused by the pore resistance, NAPL residual and lateral spreading and the causes of corresponding increase of horizontal expansion speed are the decrease of vertical velocity and the increase of buoyancy. The sufficiently short time allows to neglect chemical reactions, dissolution and sorption of NAPL and heterogeneous porous media. [ABSTRACT FROM AUTHOR]