Search

Copyright of China Rubber Industry is the property of Editorial Office of China Rubber Industry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Summary: The physical, chemical, phenolic constituents, fatty acids and mineral contents of the breads produced from wheat flour and turpentine paste at different concentrations were analysed by chromatographic and spectrophotometric methods. L*, a* and b* results of the breads were equal to 49.28–74.51, 0.90–6.55 and 13.45–20.19, respectively. Total phenolic and flavonoid quantities of the breads prepared by adding turpentine fruit paste at different concentrations were depicted to be between 26.15 (control) and 222.66 mg GAE/100 g (20%) to 74.52 (control) and 389.29 mg/100 g (20% turpentine fruit paste), respectively. Also, antioxidant activities of breads with turpentine paste were assigned to be between 2.44 (control) and 7.29 mmol kg−1 (20% turpentine paste). Gallic acid amounts of the breads were specified to be between 3.51 (control) and 16.98 mg/100 g (20% turpentine paste). Oleic and linoleic acid values of the bread oils were depicted to be between 45.34 (control) and 53.66% (3%) to 23.66 (3%) and 26.35% (control), respectively. K, P, S, Ca and Mg were the most abundant elements of bread samples. The changes in physical, chemical, phenolic components, fatty acids and mineral contents and sensory properties of the breads produced with turpentine paste added to wheat flour at different concentrations were determined. [ABSTRACT FROM AUTHOR]

The importance of protecting valuable phenolic compounds causes the need for coatings with greater resistance, for which chemical modification is used. Encapsulation of jujube extract in sodium alginate/whey protein isolate (WPI) and modified sodium alginate/whey protein isolate beads (modified with Octenyl Succinic Anhydride (OSA)) was studied. Total phenolic compounds of the jujube extract, some physical and structural properties of the beads were measured. The highest content of total phenol in modified beads at ambient temperature was 91.2 mg/l (first day). The highest efficiency was observed in the alginate/WPI beads stored at ambient temperature on the 14th day which was 14.91%. The hardness of the beads was also affected by the modification (from 0.99 to 1.26 N). The higher Tg which ensures higher stability in thermal procedure was revealed in the modified beads (77.23°C). FTIR revealed hydroxyl groups related to the jujube extract, gum and whey protein-induced intramolecular beta-sheets. These results are very important in the construction of protective systems and delivery of biological compounds of jujube extract for use in the production of novel functional foods and beverages. [ABSTRACT FROM AUTHOR]

Renewable, green, and safe natural biopolymer-derived materials are highly desired for the purification of pollutants, but significantly improving their performance without the introduction of additional harmful chemicals remains a huge challenge. Based on the concept of "structure optimization design", environment-friendly composite beads (named SA/PASP/RE) with excellent adsorption performance and recyclability were rationally constructed through a green ionic crosslinking route, using the completely green biopolymer sodium alginate (SA), sodium salt of polyaspartic acid (PASP), and the natural nanoclay rectorite (RE) as starting materials. The nano-layered RE was embedded in the polymer matrix to prevent the polymer chain from becoming over-entangled so that more adsorption sites inside the polymer network were exposed, which effectively improved the mass transfer efficiency of the adsorbent and the removal rate of contaminants. The composite beads embedded with 0.6% RE showed high adsorption capacities of 211.78, 197.13, and 195.69 mg/g for Pb(II) and 643.00, 577.80, and 567.10 mg/g for methylene blue (MB) in Yellow River water, Yangtze River water, and tap water, respectively. And the beads embedded with 43% RE could efficiently adsorb Pb(II) and MB with high capacities of 187.78 mg/g and 586.46 mg/g, respectively. This study provides a new route to design and develop a green, cost-effective, and efficient adsorbent for the decontamination of wastewater. [ABSTRACT FROM AUTHOR]

The pomelo-doped zinc oxide beads (PZB), pomelo-doped titanium dioxide beads (PTB), and pomelo-doped zinc oxide and titanium dioxide beads (PZTB) were synthesized for sorbing methylene blue (MB) dye. Their characterizations were explored by X-Ray Diffractometer (XRD), Field Emission Scanning Electron Microscopy and Focus Ion Beam (FESEM-FIB), Energy Dispersive X-Ray Spectrometer (EDX), and Fourier Transform Infrared Spectroscopy (FT-IR). In addition, their sorbent efficiencies for sorbing MB dye were investigated through batch experiments, sorbent reusability studies, sorption isotherms, kinetics, and thermodynamic studies. They were crystalline phases presenting the specific peaks of zinc oxide (ZnO) or titanium dioxide (TiO2). Their surfaces had lamella structures with coarse surfaces, and they also found specific structures of ZnO or TiO2 on the surfaces. Zn–O or Ti–O–Ti was also detected in PZB or PTB or, PZTB depending upon metal oxide types added into pomelo beaded sorbents. For batch experiments, they could adsorb MB dye of more than 86%, and PZTB showed the highest MB dye removal efficiency. In addition, they could be reused for more than three cycles with high MB dye sorptions of more than 72%. They corresponded to Freundlich and pseudo-second-order kinetic models. Moreover, the increasing temperature affected their decreasing MB dye sorptions which were exothermic processes. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Shanghai University of Engineering Science / Shanghai Gongcheng Jishu Daxue Xuebao is the property of Journal of Shanghai University of Engineering Science Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Twin tungsten electrode – wire electrode indirect arc welding (TTW IAW) was a novel welding method. In this paper, the wettability and spreading of weld bead of TTW IAW were investigated by comparing with single tungsten electrode – wire electrode indirect arc welding (STW IAW). Results showed that compared to STW IAW, TTW IAW possessed larger arc width and greater arc heat distribution range with smaller variation gradient, due to the lower velocity of charged particles toward the arc center, caused by the smaller electromagnetic force acting on the arc plasma. So did the temperature distribution of weld pool of TTW IAW. Moreover, the process stability of TTW IAW was better. Besides, at the molten pool front, the transverse convection of the melted metal of TTW IAW was adequate, because of the superior wettability and long flow duration of the melted metal; at the molten pool rear, the inward convection of the melted metal of TTW IAW was weak mainly owing to the low Marangoni force. Therefore, the weld bead width of TTW IAW increased by about 25.0% and the wetting angle of the weld bead decreased by about 25.7% compared to STW IAW, which indicated that the weld bead spreading of TTW IAW was better. [ABSTRACT FROM AUTHOR]

Copyright of International Journal of Nautical Archaeology is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

BACKGROUND: This research was aimed at the fabrication of jujube extract (JE)‐loaded beads by extrusion, using whey protein isolate (WPI), chickpea protein concentrate (PPC) and a combination of two types of hydrocolloid insoluble fraction of Persian gum (IFPG) and sodium alginate (Al). RESULTS: JE‐loaded beads with the highest encapsulation efficiency (10.87%) and polyphenol content (120.8 mg L−1 gallic acid) were obtained using Al‐IFPG/PPC at 4 °C. The Al‐IFPG, Al‐IFPG/WPI and Al‐IFPG/PPC beads revealed 5.66, 6.85 and 5.76 mm bead size, respectively, and almost all of them demonstrated a homogeneous and spherical structure. Fourier transform infrared spectroscopy data proved that the stable structure of the Al‐IFPG beads was due to hydrogen bonding and electrostatic interactions. The thermostability of beads loaded with JE based on Al‐IFPG/WPI was significantly enhanced compared to pure Al‐IFPG. Texture evaluation of JE‐loaded beads based on Al‐IFPG incorporation with WPI revealed an increment in the hardness of beads. CONCLUSION: This study confirmed the potential of Al‐IFPG complex beads for the effective delivery of jujube extract via incorporation into pea and whey proteins and for the expansion of its use in products. © 2023 Society of Chemical Industry. [ABSTRACT FROM AUTHOR]

Electricity generation using nuclear power has various advantages, such as carbon reduction, but the treatment of nuclear waste is emerging as a big issue in many countries. The development of technology that can selectively remove radionuclides from liquid radioactive waste is one of the ways to reduce nuclear waste. Here, we assessed a new way of removing radioactive cobalt from a liquid using an aptamer. Aptamers specifically binding cobalt ions were selected through systematic evolution of ligands by exponential enrichment (SELEX). Their binding strength and stability of their complexes with cobalt were analyzed through surface plasmon resonance assay and 2D program Mfold, respectively. The optimal aptamer/bead conjugate conditions for binding cobalt were established using an FA-C1 aptamer with the strongest binding to cobalt. Under these conditions, more than 80% of radioactive cobalt was removed, and more than 99.95% of removed cobalt was recovered. These results proved that radioactive cobalt removal using this aptamer can effectively reduce liquid radioactive waste. This means that the aptamer/bead complex can be utilized to remove various radioactive metal ions. [ABSTRACT FROM AUTHOR]

A unique methodology has been developed with the compilation of two magnets to produce the double axial magnetic field, and the effect on the arc shape and the bead characteristics in the gas tungsten arc welding (GTAW) process have been investigated. The load-carrying capacity of the joint depends upon the bead geometry. The developed methodology is capable of altering the arc shape and consequently the bead geometry of weld as per the requirement. Experimental results show that the double axial magnetic field changes the arc shape from a conical to constricted conical. It is further observed that magnetic configurations North-South-South-North (N-S-S-N) and Zero-Zero-South-North (0-0-S-N) provided better results than other configurations. The North-South-South-North (N-S-S-N) configuration produced a minimum penetration (0.98 mm) and a maximum shape factor (7.81), along with good appearance of weld beads. This configuration is suitable for cladding and hardfacing applications. The increased penetration (3.03 mm) was achieved with the Zero-Zero-South-North (0-0-S-N) configuration compared with conventional welding (2.20 mm). Similarly, this configuration yielded a higher bead width (8.13 mm) than conventional welding (5.90 mm). This configuration is suggested for the single-pass welding operation. [ABSTRACT FROM AUTHOR]

Single-cell sequencing (SCS) is an evolutionary technique for conducting life science research, providing the highest genome-sale throughput and single-cell resolution and unprecedented capabilities in addressing mechanistic and operational questions. Unfortunately, the current SCS pipeline cannot be directly applied to algal research as algal cells have cell walls, which makes RNA extraction hard for the current SCS platforms. Fortunately, effective methods are available for producing algal protoplasts (cells without cell walls), which can be directly fed into current SCS pipelines. In this review, we first summarize the cell wall structure and chemical composition of algal cell walls, particularly in Chlorophyta, then summarize the advances made in preparing algal protoplasts using physical, chemical, and biological methods, followed by specific cases of algal protoplast production in some commonly used eukaryotic algae. This review provides a timely primer to those interested in applying SCS in eukaryotic algal research. [ABSTRACT FROM AUTHOR]

Structural fires globally have a catastrophic impact on loss of life, property damage, and socioeconomic factors. Forensic scientists, engineers, and/or fire investigators — often working together as fire investigation practitioners — are commonly tasked with determining both the area of fire origin and its cause. During the course of a fire investigation, a fire investigation practitioner may implement an origin determination methodology termed “arc mapping” or an “arc survey.” The correct application of an arc survey as a fire origin determination method is dependent on the fire investigation practitioner’s ability to distinguish and characterize features observed on post-fire damage electrical wiring and equipment. Experiments were conducted to generate a dataset of post-fire damaged electrical conductor artifacts. Generated artifacts were visually examined, compared, and characterized by X-ray examination. The research results produced a validated, novel, non-destructive methodology for utilizing X-ray imagery to reliably distinguish and characterize electrical conductor damage features for forensic investigations. [ABSTRACT FROM AUTHOR]

The stabilizer link, also known as the anti-roll bar link or anti-roll bar link, is an important component of a vehicle's suspension. It plays a major role in keeping the vehicle stable during cornering and reducing unwanted vehicle movement. The main function of the anti-roll bar is to reduce body roll during cornering, i.e. when the vehicle turns, the weight is transferred from one wheel to the other on the same axle and this can lead to body roll. The stabiliser linkage provides an inertial link between the two suspension axles and prevents lateral roll. Stopping the roll phenomenon contributes to better vehicle handling and to maintaining optimal contact of the wheels with the road surface. This paper presents studies on a stabilizer bar linkage made of a polymer often used in the automotive industry, namely acrylonitrile butadiene styrene (ABS). This research will show by finite element method the limit values supported in tension for each end with ball joints and identify the areas where concentrated loads are found. The study also uses the application of reverse engineering by scanning a stabilizer bar linkage in the vehicle suspension subassembly. [ABSTRACT FROM AUTHOR]

This technique report describes an alternative method to stabilize surgical templates throughout full‐arch static computer‐assisted implant surgery (FA s‐CAIS). In FA s‐CAIS, remaining teeth, mucosa, existing implants, custom occlusal device, bone, or any combination thereof, could be used as an initial positioning mechanism to position surgical templates. Different anchoring mechanisms are then used to stabilize the surgical templates during surgery. In this report, a novel design of surgical templates using remaining dentition and opposing occlusal surfaces as initial positioning mechanism followed by the combination of bone block fixation screw and stainless‐steel beads as secondary anchoring mechanisms is described. The advantages, limitations, and comparisons with surgical templates using other anchoring mechanisms are also discussed. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Natural Fibers is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Lead contamination in the industrial wastewater is a major concern because of human health effects, so wastewater treatment is required before uses. Adsorption is an effective method with a reasonable cost, and natural wastes are an interesting choice as low-cost adsorbent. Lemon peels were chosen with their proper chemical properties for lead removal. This study is aimed at synthesizing lemon peel adsorbents; analyzing adsorbent characterizations; investigating affecting factors on dose, contact time, pH, and concentration; examining adsorption isotherms and kinetics; and exploring desorption experiments and fixed-bed column experiments. This study was successful synthesized adsorbents of lemon peel powder (LP) and beads (LPB) and was characterized through XRD, FESEM-FIB, EDS, BET, and FTIR. The optimum conditions of LP and LPB of 50 mg L−1 lead concentration were 4 g, 6 h, and pH 5 and 3 g, 5 h, and pH 5, respectively. Both adsorbents were corresponded to Freundlich and pseudo-second-order kinetic model. Fixed-bed column experiments which represented LPB had high lead removal efficiency with the adsorption capacity of 1.67 mg g−1, and it was also a good reusability more than 2 cycles. Therefore, LPB is a potential adsorbent to possibly apply for wastewater treatment. [ABSTRACT FROM AUTHOR]

Objective(s): Early, specific, and sensitive detection methods of COVID-19 are essential for force stopping its worldwide infection. Although CT images of the lung and/or viral RNA extraction followed by real-time reverse-transcriptase-polymerase chain reaction (rRT-PCR) are widely used; they have some limitations. Here, we developed a highly sensitive magnetic bead-based viral RNA extraction assay followed by rRT-PCR. Materials and Methods: Case group included oropharyngeal/nasopharyngeal and blood samples from 30 patients diagnosed positive by PCR test for COVID-19 and control group included 30 same samples from COVID-19 negative PCR test individuals. RNA was extracted, using viral RNA extraction kit as well as using our hand-made capture bead-based technique. A one-step cDNA synthesis and Real Time PCR was conducted. A two-step comparison of the different viral RNA extraction methods for oropharyngeal/nasopharyngeal and blood samples was performed. Student t-test was applied with a P<0.05 considered statistically significant. Results: In the case group, all 30 mucosal samples extracted either with viral RNA extraction kit or with beads-based assay were COVID-19 positive although in the latter category, Cqs were much lower. Although 43% of plasma samples extracted by bead-based method were found to be positive but no plasma samples extracted with column-based kit were detected positive by Real Time PCR. Conclusion: Bead-based RNA extraction method can reduce RNA loss by its single-tube performance and enhance the test sensitivity. It is also more sensitive to lower viral loads as shown in the detection of blood samples and the lower Cqs of mucosal samples. [ABSTRACT FROM AUTHOR]

In the present investigation, stability of weld morphology was investigated in case of electrolytic tough pitch copper (12 mm thickness) processed by Hot Wire Gas Tungsten Arc Welding (HW GTAW) using CuNi filler wire with variations of processing conditions, using different combination of hot wire's parameters such as feed rate and current. The assessment of weld bead geometry was performed using visual examination (during and after welding), and macrographic dimensional measurements of weld bead geometry such as depth of penetration and depth to width ratio. In addition to the stability of weld bead geometries, microstructural variations and weld quality assessments were studied using optical microscopy, scanning electron microscopy, energy dispersive x-ray spectroscopy, and micro-hardness measurements in case of processed sample observed with most uniform weld bead geometry. The results revealed that minimum dimensional variations of weld bead geometry throughout the processed length was obtained with 5.42 mm bead width, 1.2 mm bead height, 1.8 mm penetration, and 0.36 depth to width ratio when hot wire's parameters were 0.6 m/min wire feed rate and 90 amps hot wire current. The bridging mode of metal transfer helps to receive more stable weld bead geometry with minimum dimensional variations. Ni filler wire of HW GTAW improves the hardness in the Heat affected zone (70 HV0.3) and weld zone (80 HV0.3), which were 33% and 17% higher of base material. The weld zone was consisting of mixed mode of grains such as dendrites just above the fusion line and cellular grains further above dendrites in case of processed sample of minimum dimensional variations of weld bead geometry throughout the processed length. [ABSTRACT FROM AUTHOR]

Confined crystallization behavior of poly(ethylene oxide) (PEO) was studied in electrospun core-shell nanofibers and beads, respectively, using DSC. The core-shell structure consisted of PEO core and polystyrene (PS) shell. It was observed that the morphology of PEO core changed from continuous to discrete domains when the core spinning solvent was switched from water to chloroform. This significantly influenced the crystallization behavior of PEO such that whereas the crystallization nucleation mechanism was heterogeneous for nanofibers with continuous PEO core, it became fractionated for nanofibers with discontinuous PEO core. The relaxation of the PEO domains, in the nanofibers with discontinuous core, via thermal annealing above the glass transition temperature of PS shell, markedly increased homogenous nucleation contribution in the crystallization. This plausibly was due to relaxation of PEO domains through domain breakup and coalescence process resulting in higher fraction of nanosized PEO domains. [ABSTRACT FROM AUTHOR]

Functional nanomaterials (NM) of different size, shape, chemical composition, and surface chemistry are of increasing relevance for many key technologies of the twenty-first century. This includes polymer and silica or silica-coated nanoparticles (NP) with covalently bound surface groups, semiconductor quantum dots (QD), metal and metal oxide NP, and lanthanide-based NP with coordinatively or electrostatically bound ligands, as well as surface-coated nanostructures like micellar encapsulated NP. The surface chemistry can significantly affect the physicochemical properties of NM, their charge, their processability and performance, as well as their impact on human health and the environment. Thus, analytical methods for the characterization of NM surface chemistry regarding chemical identification, quantification, and accessibility of functional groups (FG) and surface ligands bearing such FG are of increasing importance for quality control of NM synthesis up to nanosafety. Here, we provide an overview of analytical methods for FG analysis and quantification with special emphasis on bioanalytically relevant FG broadly utilized for the covalent attachment of biomolecules like proteins, peptides, and oligonucleotides and address method- and material-related challenges and limitations. Analytical techniques reviewed include electrochemical titration methods, optical assays, nuclear magnetic resonance and vibrational spectroscopy, as well as X-ray based and thermal analysis methods, covering the last 5–10 years. Criteria for method classification and evaluation include the need for a signal-generating label, provision of either the total or derivatizable number of FG, need for expensive instrumentation, and suitability for process and production control during NM synthesis and functionalization. [ABSTRACT FROM AUTHOR]

Ever-growing needs in pipeline welding relating to quality, frequent usage of advanced, heat-sensitive, and corrosion-resistant materials alongside high production costs encourage the evaluation of a welding process thoroughly. The only way to overcome those problems is the adaptation of technically evolved welding methods that combine the goodness of cutting-edge power supply sources and advanced software configuration. One such technique is Regulated Metal Deposition (RMDTM) welding. In this context, the current study explores the influence of the regulated metal deposition (RMDTM) welding variables on ASME SA387-11-2 steels. Current (A), voltage (V), and gas flow rate (GFR) are preferred regulated metal deposition (RMD™) welding variables, and at the same time the depth of penetration (DOP), heat-affected zone (HAZ), bead height (BH), and bead width (BW) are incorporated as performance evaluation attributes. Furthermore, the exploration of Rao algorithms is presented to evaluate the optimal welding settings. The obtained optimal welding settings is current = 92 A, voltage = 13 V, and gas flow rate = 21 litre/min. The results are also compared with the JAYA, and teaching learning-based optimization (TLBO) approaches to show the efficacy of the intended approach. [ABSTRACT FROM AUTHOR]

Copyright of TÜBA-AR: Turkish Academy of Sciences, Journal of Archaeology is the property of Turkish Academy of Sciences and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

IThis article deals with development of contactless measuring device for measurement of geometric and qualitative parameters of semi product for tire - bead. Due to the current measurement and evaluation methods in series production, this equipment represents a technical and technological improvement in the tire manufacturing process. This solution excludes potential influence of process or operator during measurement or evaluation parameters. The device uses the latest knowledge and components used in industry, automation and electrical engineering as well. The designed device is immediately applicable globally as an autonomous device. Its modification also enables integration into a fully automatic process of production of tire semi-product - bead by manipulation devices. The measured parameters allow iteration and necessary set up between production process and measuring device in the future. [ABSTRACT FROM AUTHOR]

Stainless steel is a widely used material in various industries such as aerospace, chemical processing and transportation. Tungsten Inert Gas (TIG) or Gas Tungsten Arc Welding (GTAW) process is extensively used for joining thin sections of stainless steel. However, it is not useful in joining thick sections in a single pass. Activated TIG (A-TIG) significantly increases weld penetration up to 1.5– 4 times in a single pass. Because of its deep penetration ability, A-TIG is the focus of research amongst the researchers. This article reports the mechanisms associated with A-TIG, effects of various weld parameters on weld bead geometry and optimization techniques to optimize the process variable of the A-TIG welding process. The present work also analyzes the consequence of activated fluxes on microstructure and mechanical properties of A-TIG weld metal. Along with this, recent developments in the TIG welding process have been discussed. The study concludes that the A-TIG welding process enhances the weld penetration to a great extent, but a high amount of slug gets deposited on the weld surface. This drawback can be overcome by novel variants of the A-TIG welding process such as Flux Bounded TIG (FB-TIG) and Flux Zone TIG (FZ-TIG) welding processes which enhance the future scope of research. [ABSTRACT FROM AUTHOR]

Copyright of Folklor / Edebiyat is the property of Cyprus International University and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

In this paper, a novel adsorbent which used polyvinyl alcohol, alginate and biochar was successfully made and been used to remove lead from aqueous solutions. Batch experiments were carried out to evaluate the adsorption capacities of Pb (II) on this bead. Experimental data were analysed by the model equations like Langmuir and Freundlich and adsorption kinetic constants were determined using pseudo-first-order (PFO) and pseudo-second-order (PSO). In this study, the adsorption characteristics of Pb (II) were well fitted by the Langmuir isotherm model and pseudo-second-order (PSO) kinetic model. The adsorption of Pb (II) onto PVA-biochar beads are spontaneous and exothermic at 303–333 K by the evidence of the changes in standard Gibbs free energy, standard enthalpy and standard entropy. The maximum adsorption capacity for Pb (II) was estimated to be 176.40 mg/g, which is comparable with other adsorbents. While the maximum adsorption increased varying the pH of initial solution from 2 to 6, the effect on the adsorption amount by the sodium ion concentration is not very large. The results of EDS spectra indicated that the existence of lead in polyvinyl alcohol (PVA)-biochar bead after adsorption, which proving the adsorption of lead. In XPS spectrum, the observed Pb elements also demonstrated that the lead was adsorbed by PVA-biochar bead. [ABSTRACT FROM AUTHOR]

Keyhole gas tungsten arc welding (K-GTAW) was applied to characterize the weld bead geometry in case of the 6 mm thick electrolytic tough pitch copper. Various conditions of welding speeds and preheating on the bead geometry were studied for its uniformity. Visual examination, macro bead dimensional analysis, microhardness profile across the transverse section, microstructural analyses were performed to investigate the K-GTAW on electrolytic tough pitch copper. The results revealed that full penetration of 6 mm can be obtained in a single pass using keyhole mode in GTAW. Keyhole length and width were majorly affected by the welding speed and preheating temperature. Significant variations in weld bead geometry were observed even when high heat input conditions were applied without preheating. Uniform weld bead geometry of 5 mm bead width and depth to width ratio of 0.42 was obtained for a length of 80 mm using appropriate preheating of 300°C and heat input condition of 1.37 kJ/mm (resulted from 300 amperes welding current, 120 mm/min welding speed, and 15.3 volts voltage). In the uniform weld bead geometry, the weld and heat affected zones were consisted of coarse grains relative to base material, wherein the micro hardness variations were observed. [ABSTRACT FROM AUTHOR]

The two neighboring late prehistoric/protohistoric sites of Aw Gyi and Maliwan, located in the southernmost part of Myanmar in the Isthmus of Kra, yielded large quantities of glass beads and wastes. The measurement of 61 glass compositions from these sites using laser ablation-inductively coupled plasma-mass spectrometry has revealed two different patterns. At Aw Gyi, a combination of potash and m-Na-Ca-Al glasses, also noticed at Arikamedu, India (1st c. BC and onward), and Phu Khao Thong, Thailand (2nd c. BC–4th c. AD), two ports facing the Bay of Bengal, suggests the existence of a “Bay of Bengal” network, active from the 2nd–1st c. BC. At Maliwan, the glass types are more diversified with some of them found generally during the 4th to 2nd c. BC period. This is in line with the radiocarbon dating of the site that shows an occupation from the 4th to the 1st c. BC. However, Maliwan has little in common in terms of glass typology with other early and contemporary sites along the Isthmus of Kra indicating that they were not part of the same network. At Aw Gyi and Maliwan, evidence would suggest bead making, but the craft areas where such an activity would have taken place remains to be found. Despite this caveat, the difference in glass composition and typology between these close-by sites draws perhaps a more complex economic and political situation than expected with different networks at early periods on the east and west side of the Isthmus of Kra. [ABSTRACT FROM AUTHOR]

An axe head and a round bead were found at the burial site of an adult male (dated at 3770 ± 90 14C years BP) at Amboy, Córdoba (central Argentina). These artifacts were studied using electron microprobe, scanning electron microscopy and X-ray diffraction, for a complete characterization of the materials and to infer the source. The axe head is carved from very fine-grained tonalite (composed dominantly of zoned plagioclase, quartz, potassic feldspar, chlorite, magnesiohornblende, titanite and magnetite) with microporphyritic texture. The bead is mainly composed of muscovite, an amorphous Cu–Al hydrated silicate (similar to chrysocolla) and malachite. Based on the coincidence between textures, mineralogy and chemical compositions, the most likely source of the axe is dykes of metaluminous tonalite scattered in the Sierras Chicas Range. The provenance of the bead could not be ascertained, but it is probable that it was carved from material collected from a very localized outcrop. These artifacts associated with a funerary context represent one of the oldest evidences of such materials for hunter–gatherer groups in central Argentina. [ABSTRACT FROM AUTHOR]

In the present study, the effect of process parameters in Wire Arc Additive Manufacturing (WAAM) of Stainless Steel 304 as filler wire and mild steel as a substrate has been investigated. The deposition was made by using the Cold Metal Transfer (CMT) process. Single-pass beads are most useful for remanufacturing and repairing purposes. The quality of cladding for additive manufacturing predominantly depends on bead geometry. Hence, it is required to have an optimum range of bead parameters to ensure the desired mechanical properties. Response surface methodology and ANOVA were used to estimate the effects of current, weld speed, standoff distance on bead characteristics. Multiple regression models were developed to relate process parameters to bead quality. [ABSTRACT FROM AUTHOR]

Indus Valley Civilization flourished in India and Pakistan owing to its technological advancements dating back to the 3rd millennium BC. The present paper aims to trace the emergence of pyrotechnology through documenting the industrial settlements that have been excavated in recent years, as well as locating the potential trading network for the craft items being produced at these small settlements on the outskirts of major Harappan cities such as Harappa, Mohenjo-daro and others. The paper focuses on the excavated Harappan sites with special reference to the site of Binjor - 4MSR in India's Ghaggar riverbed region. The reconstruction of kilns and furnaces based on the excavated remains was considered through the experimental study, such as wheel motion and the quantification of fuel consumption in the production of pottery, including terracotta figurines, bead and metal objects. During the research, the author has documented more than 50 furnaces, attempting to find parallels between Harappan heat treatment and modern potters and smiths located on ancient mounds. The ethnographic similarities between Harappans and the contemporary villagers who continue to inhabit the archaeological mound have been emphasised. The research also examines whether the technology utilised by the Harappans has changed or not, ranging from pottery manufacture to metal smelting, and what can be deduced from these experimental approaches to comprehend the technological prowess of their artisans. [ABSTRACT FROM AUTHOR]

Montmorillonite/alginate composite beads have been studied for adsorption of brilliant green dye in batch experiments. The geometry and features of this clay/polymer composite, in combination with the strong color of the dye, were very useful to apply and test in a simple way the shrinking core model (SCM). This model is very popular for describing adsorption in porous systems, but not in clay/polymer composite beads. The SCM describes the adsorption as a diffusion process of the adsorbate through a spherical shell. The great advantage of using the clay and the dye is that they allow observing with the naked eye or through digital photographs the progress of the front of adsorption (penetration radius) as the reaction takes place. This was never informed in the literature. The experimental changes in penetration radius and dye concentration with time were compared with SCM predictions at different initial concentrations of brilliant green. There was an excellent agreement between theory and experiments, and thus the kinetics of the process could be thoroughly evaluated. The estimated values of the parameters liquid phase mass transfer coefficient and effective diffusion coefficient in the adsorbent are kf > 0.00008 m s−1 and Dp = 5 × 10−10 m2 s−1 respectively. [ABSTRACT FROM AUTHOR]

Background: Multiplex bead assays, also known as addressable laser bead immunoassays (ALBIA) or Luminex® technology, have provided an alternative to enzyme-linked immunoassay, which is still the most widely utilized routine immunoassay for detection of specific autoantibodies. Our laboratory adopted the ALBIA technology early into its routine service. Methods: We report the performance and utility of measurement of three different autoantibody types tested using the FIDIS (BMD, Marne La Vallee, France) ALBIA system. The analytes discussed are thyroid antibodies (thyroglobulin [TG], thyroid peroxidase [TPO]), anti-neutrophil cytoplasmic antibodies (ANCA), and ribonucleoprotein (RNP) antibodies. Results: In single antibody analysis, TPO antibody testing was superior to TG antibody in identifying patients with Graves' disease and Hashimoto's thyroiditis. However, testing only TPO antibody would result in missing 8.6% of Graves' and 11.9% of Hashimoto's thyroiditis patients, hence demonstrating an advantage for the multiplex TG plus TPO assay. With respect to ANCA, the FIDIS ALBIA produced an overall similar level of performance to our comparator method, the Phadia fluorescent enzyme linked immunoassay. Sensitivity of the ALBIA for RNP antibodies was low in comparison to countercurrent immunoelectrophoresis, but performance was improved by altering the cutoff value for the assay. Conclusions: ALBIA technology has many potential advantages in the routine laboratory, but as with any new assay, evaluation must be thorough and ongoing to ensure satisfactory clinical performance is obtained. Both false positive and false negative results have been reported in ALBIA studies. It may be necessary to re-evaluate assay performance and cutoff and consider further clinical correlation. [ABSTRACT FROM AUTHOR]

BACKGROUND: The aim of this work was to develop a cheap and easy method for the synthesis of porous iron oxide/iron silicate composite materials in the form of spheres to replace their corresponding counterparts in powder form. Macrospheres with diameters in the range 1.2–1.3 mm were prepared by the spray‐gelling technique using the multi‐templating method. Iron nitrate and tetraethyl orthosilicate were used as iron and silica sources respectively. Chitosan played a dual role (pore‐ and shape‐generating agent), while other inexpensive and easily accessible biomaterials including yeast and gelatin were used as pore generators. By this technique can be obtained metallosilicates or metal oxides/metallosilicates containing high amounts of metal incorporated within the silica framework. RESULTS: The iron oxide/iron silicate composite beads were characterized by nitrogen sorption, scanning electron microscopy (SEM), energy‐dispersive X‐ray (EDX), Fourier transform infrared (FTIR), Raman, X‐ray diffraction (XRD), diffuse reflectance (DR) ultraviolet (UV)–visible and X‐ray photoelectron spectroscopy (XPS) analyses. Wide angle XRD indicated the presence of iron oxides on the surface of sample. XPS, FTIR, Raman and UV–visible analyses showed that the samples contained both intra‐framework as well as extra‐framework iron species. SEM images indicated that the macrospheres were endowed with large pores. The iron oxide/iron silicate beads exhibited good catalytic activity in the hydroxylation reaction of phenol with hydrogen peroxide. CONCLUSION: This synthesis method allowed the obtaining of spherical shaped particles with large pores which exhibited good mechanical, thermal and chemical stability. Owing to their size, hardness and shape, these materials can be easily handled, recovered and reused. © 2019 Society of Chemical Industry [ABSTRACT FROM AUTHOR]

The present work investigates the effect of dynamic correction (DC) and the arc length correction (ALC) parameters on the deposition of Stellite 6 filler wire on AISI H13 steel by Cold Metal Transfer (CMT) welding. The changes in the current and voltage waveforms were studied along with high-speed camera imaging of the process during single bead deposition. The effect of the arc correction parameters on the area and volumetric dilution, bead geometry, microstructure, and hardness are presented. The DC parameter influences the current waveform whereas the ALC parameter affects the voltage waveform and duration of the CMT cycle. It is shown that the ALC parameter has a strong effect on the dilution as compared to DC parameter. A wide scatter in the dilution values with similar heat input for different arc correction parameters was observed. Lower heat-input results in lower dilution and finer microstructure resulting in high hardness of the bead. [ABSTRACT FROM AUTHOR]

Chitosan–tripolyphosphate beads are a highly stable and biocompatible polymer-network with versatile applications. In this study, we relate the main synthesis parameters of these particles using a design of experiments and a multivariate calibration to understand how some structural characteristics (mass, diameter and water retention capacity) of these spherical hydrogels are achieved from the point of view of the ionotropic association between chitosan chains and tripolyphosphate molecules. The results conduct to a better conceptualization of the crosslinking process, establish the ranges where particles with different structural characteristic can be obtained and a better understanding of how the physicochemical behavior of the chitosan and the tripolyphosphate affect the structural parameters of the chitosan–tripolyphosphate beads. As a novelty, we propose a refined 3D junction zone for the interaction between the raw molecules that allows to conclude that one TPP molecule can associate with up to three amino groups as a maximum. [ABSTRACT FROM AUTHOR]

In attempt to enlighten the debate on the Middle to Upper Palaeolithic transition, this work contributes new data from a yet unpublished site, Riparo Broion in the north-east of Italy. Studies confirm the presence of the Uluzzian technocomplex embedded in an archaeological sequence which includes Mousterian, Gravettian and Epigravettian. These layers have yielded finds of bone and lithic technology, shell beads, engraved portable art and the use of red mineral pigments, which make this archive a unique case for evaluating the implications of cultural dynamics in Northern Italy 44.0–42.4 ky BP. The diversity of the faunal assemblage recovered in layers 1f and 1g is representative of the different environments surrounding the site, with ungulates being targeted for hunting and consumption. The lithic assemblage records a high fragmentation rate due to the extensive use of the bipolar knapping technique, responsible for a large variety of splintered pieces and associated chips which also affected the backed pieces, lunates and end-scrapers. The features of the bone tools, as well as those of the marine and freshwater beads, echo the technique used in the Uluzzian in the south of Italy, confirming the geographic spread of this technocomplex in the North Adriatic region, as previously envisaged at Grotta Fumane. However, comparisons between these two sites stimulate a discussion around the possible driving forces responsible for the differences observed in technological, typological and structural lithic assemblages. A definitive scenario for the Middle Palaeolithic–Upper Palaeolithic transition in this region of Southern Europe is ongoing and Riparo Broion is adding key contributions. [ABSTRACT FROM AUTHOR]

This paper describes the burials of Mugan plain of Azerbaijan. As a result of archaeological exploration of the territory, it was revealed that the region belongs to one of the oldest populations of farmers and herdsmen in the Caucasus. One of the interesting sides of the culture, discovered through examination of these monuments are burials. These burials were completed by inhabitants and belonged to various building horizons. The age composition of dead men varies from infants to full grown men. [ABSTRACT FROM AUTHOR]

Load-carrying capacity of weld joints could be identified by its shape and size where weld bead geometry and shape relationship parameters are of utmost importance. Heat input and preheating temperature together can control the cooling time of weld, which in turn determines the weld microstructure and its mechanical properties. To control the shape and geometry of weld bead, it is necessary to understand its relationship with cooling time. In present work, preheating temperature is used as process variable along with heat input varying parameters for understanding their effects on weld bead geometry and shape relationship parameters using submerged arc welding process on high-strength low alloy pipeline steel. The experimental investigation was then analyzed by using the mathematical modeling in context with response surface methodology. The mathematical model predicts the influential dependency of cooling time on the preheating temperature than the other weld process parameters. The associated effects in relation to the process parameters have been discussed and analyzed in the present study. [ABSTRACT FROM AUTHOR]

The working properties of glass used in Early Medieval England - Glass made during the Romano British period was recycled throughout the Late Roman and Early Medieval periods. Studies have shown that British beadmakers of the fifth and early sixth centuries AD made a large proportion of their beads using Roman period glass (Peake, 2013). To study fully the techniques of glass workers in early Anglo-Saxon times, it is important to be sure the modern glass used to recreate ancient beads and other glass objects is similar in properties to the ancient glass used to make the originals. Glass with very different working properties could affect the techniques used. This study explains the importance of glass properties such as viscosity, temperature working range and softening point when studying ancient techniques of glass working. A quantity of Roman glass cullet, supplied by the Museum of London Archaeology, has been put to a range of tests, including beadmaking, to investigate the behaviour of the glass in the flame. The results show that the thermal expansion and viscosity of the ancient glass samples place them well within the range of modern artisan glasses used for beadmaking and glass fusing. The tests also revealed a wide variety of working properties in the samples, but the glass was all easily workable with more favourable properties than some modern glasses (See Figure 1). [ABSTRACT FROM AUTHOR]

Förster resonance energy transfer (FRET) is extremely sensitive to the separation distance between the donor and the acceptor which is ideal for probing such biological phenomena. Also, FRET-based probes have been developing for detecting an unamplified, low-abundance of target DNA. Here we describe the development of FRET based DNA sensor based on an accumulated QD system for detecting KRAS G12D mutation which is the most common mutation in cancer. The accumulated QD system consists of the polystyrene beads which surface is modified with carboxyl modified QDs. The QDs are sandwich-hybridized with DNA of a capture probe, a reporter probe with Texas-red, and a target DNA by EDC-NHS coupling. Because the carboxyl modified QDs are located closely to each other in the accumulated QDs, these neighboring QDs are enough to transfer the energy to the acceptor dyes. Therefore the FRET factor in the bead system is enhancing by the additional increase of 29.2% as compared to that in a single QD system. These results suggest that the accumulated nanobead probe with conjugated QDs can be used as ultrasensitive DNA nanosensors detecting the mutation in the various cancers. [ABSTRACT FROM AUTHOR]

This paper presents a study of the influence of MIG welding process parameters on the weld bead geometry of 6063-T5 aluminium alloy. The welded profile is a longitudinally cut tubular profile that has been joined by a weld bead to make a butt joint. The influence of the electrical parameters employed, welding speed, power, and separation between edges is relevant to determine the influence of the electrical parameters of welding in each of the pieces that configure the weld. The analysed parts of the weld bead include bead height, root width, penetration, over-thickness (face), over-thickness (root), perimeter, and area of filler material. Studying the geometry of the bead weld is of great importance because the shape can condition other factors such as stress concentrators and fatigue behaviour. [ABSTRACT FROM AUTHOR]

Abstract: The diffusion of glucose and sucrose was investigated in membrane and bead experiments. Concentration‐dependent diffusion coefficients of pure glucose and sucrose were determined in precipitated chitosan membranes of varying thickness using diffusion cell experiments. Contrary to fructose, the resulting diffusion coefficients of glucose and sucrose did not reach their free diffusion coefficients at infinite dilution suggesting additional interactions between chitosan and these two sugars. Counter‐diffusion in bead experiments showed a good agreement between predicted and measured data allowing the inclusion of the diffusion data in the simulation of the proposed production process for laminaribiose. In conclusion, the encapsulation in chitosan presented a good trade‐off between increased mass transfer resistance as evaluated by the Thiele modulus and improved thermal stability and antibacterial activity. [ABSTRACT FROM AUTHOR]

Electrospun scaffolds consist of micro-scale or nano-scale porous fibrous networks. These electrospun scaffolds had become increasingly popular in tissue engineering filed as it could provide nano-environment for cell culture and produced by using biodegrable polymer. One of the important key to provide such environment for cell culture is the porosity of the electrospun scaffolds as it is highly related with the cell-cell interaction. The porosity of the electrospun scaffolds could be affected by bead formation which is one of the common problems faced in electrospinning process. However, the formation of beads are difficult to be controlled as it depends on environmental factors such as humidity and operating temperature. Controlling these two environmental factors normally requires an expensive control system. This paper aims to solve the problem of bead formation by adjusting material concentration and process parameters without controlling the environmental factors. The parameters studied in this paper include polymer concentration, flow rate, distance between the syringe needle tip and collector and applied voltage. The microstructure of the electrospun scaffolds produced were visualised using scanning electron microscopy (SEM) and were analysed in terms of bead formation and fiber diameter. This study shows that polymer concentration is the best strategy to prevent bead formation in gelatin scaffolds while other process parameters such as applied voltage, distance between the syringe needle tip and the collector as well as flow rate can be used to control the fiber diameter. An understanding of the effects of each parameter provides a guideline to control microstructure morphology by producing bead-free electrospun gelatin scaffolds. [ABSTRACT FROM AUTHOR]

In this article, effects of advanced submerged arc welding process parameters on weld bead geometry have been investigated. A novel water-cooled torch has been developed which allow a use of higher preheat current values for a continuous advanced submerged arc welding (ASAW) operation. Weld beads have been deposited on AISI 1023 steel plates by varying open circuit voltage, wire feed rate, welding speed, nozzle to plate distance, and preheat current as per central composite design. The relationships between welding parameters and weldment characteristics namely bead width, penetration, reinforcement, and dilution have been developed using multiple linear regression. The effects of individual process parameters and their interactions on response parameters were examined. Finally, single and multiobjective optimization of process parameters were performed using desirability approach and Jaya algorithm. The results reveal that a smaller bead width and lower dilution can be achieved with the developed torch by allowing the use of higher preheat current values. [ABSTRACT FROM PUBLISHER]

There is an increasing need to explore effective and clean approaches for hazardous contamination removal from wastewaters. In this work, a novel bead adsorbent, polyvinyl alcohol-graphene oxide (PVA-GO) macroporous hydrogel bead was prepared as filter media for p-nitrophenol (PNP), dye methylene blue (MB), and heavy metal U(VI) removal from aqueous solution. Batch and fixed-bed column experiments were carried out to evaluate the adsorption capacities of PNP, MB, and U(VI) on this bead. From batch experiments, the maximum adsorption capacities of PNP, MB, and U(VI) reached 347.87, 422.90, and 327.55 mg/g. From the fixed-bed column experiments, the adsorption capacities of PNP, MB, and U(VI) decreased with initial concentration increasing from 100 to 400 mg/L. The adsorption capacities of PNP, MB, and U(VI) decreased with increasing flow rate. Also, the maximum adsorption capacity of PNP decreased as pH increased from 3 to 9, while MB and U(VI) presented opposite tendencies. Furthermore, the bed depth service Time (BDST) model showed good linear relationships for the three ions' adsorption processes in this fixed-bed column, which indicated that the BDST model effectively evaluated and optimized the adsorption process of PVA-GO macroporous hydrogel bead in fixed-bed columns for hazardous contaminant removal from wastewaters. [ABSTRACT FROM AUTHOR]