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Large volumes of water containing tritium are generated during the operation, decommissioning, and incident-management of nuclear installations and related facilities, and are expected to increase with the ongoing expansion of nuclear power generation. If released into the environment, this water could pose a substantial environmental threat to living organisms. However, conventional isotope separation techniques, such as cryogenic distillation and catalytic exchange, are inadequate for efficiently isolating significant quantities of low-level tritiated water because of the complex machinery and excessive energy required, and the potential for hydrogen-gas detonation. In contrast, water distillation (WD), as a traditional technology, has the unique advantages of simple operation, no corrosive and toxic substances, and no hydrogen explosion risk, but problems of small separation coefficient and low efficiency always exist in this technique. However, the separation effect of WD can be effectively improved by improving the process variables in the process of WD, such as temperature, distillation column diameter, and packing dimensions, so as to adapt WD to the separation of industrial tritiated water. This study provides a thorough exposition of the basic principles and distinctive features of water distillation and examines the effect of various operational parameters on separation efficiency to adapt the process for the industrial separation of tritiated water. The impact of various process variables on the separation efficiency of tritiated water via distillation was investigated, and results show that optimizing these variables can markedly improve the separation efficiency of water distillation. In particular, decreasing the dimensions of the packing material or altering its properties can lead to higher separation factors and lower residual tritiated water concentration. These findings suggest that water distillation can be used for the separation of tritiated water. By optimizing its operational parameters, water distillation can become a viable method for the industrial separation of tritiated water and is expected to play a significant role in this field in the future.