1. High field phase transition of cathode material Li2MnSiO4 for lithium-ion battery
- Author
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Feng Yang, Zhengcai Xia, Sha Huang, Xiaoxing Zhang, Yujie Song, Guiling Xiao, Gangqin Shao, Yong Liu, Han Deng, Dequan Jiang, and Zhongwen Ouyang
- Subjects
Li2MnSiO4 ,cathode ,magnetization ,high magnetic field ,Materials of engineering and construction. Mechanics of materials ,TA401-492 ,Chemical technology ,TP1-1185 - Abstract
The magnetic properties of the candidate lithium-ion battery cathode materials Li _2 MnSiO _4 have been studied experimentally using static and pulsed high magnetic fields. A field-induced magnetic transition is observed in low temperature region, in which a saturation magnetization is observed above 27 T which confirms that the Mn-ion has a dominant low spin state with a saturated magnetic moment of ∼3.1 μ _B /Mn. With the change of temperature and magnetic field, the Li _2 MnSiO _4 shows a complex magnetic phase transition. Considering to the coupling between spin, charge and orbital, the field-induced magnetic transition may affect the charge-discharge behavior of the cathode material, thus, the study is expected to explore the possibility and stability of the candidate lithium-ion battery cathode materials used in the low temperature and high magnetic field circumstance and its performance degradation.
- Published
- 2020
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