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Objective: The aim of this study was to evaluate the roughness, hardness, and color change of pit and fissure sealants of two commercial brands (Fluroshield ™ and Ultraseal XT ™) incorporated with nanostructured silver vanadate nanomaterial decorated with silver nanoparticles (β-AgVO3) in concentrations (0% - control, 2.5% and 5%). Material and methods: Two commercial brands Fluroshield TM and Ultraseal XT ™ were used to make the samples with dimensions of 6 × 6 × 4 mm. The control group was made according to the manufacturer's instructions and in the groups with the addition of β-AgVO3, the nanomaterial was added proportionally by mass at percentages of 2.5% and 5%. Roughness properties were evaluated using a 3D Laser Confocal Microscope (n = 10), Knoop microhardness by Microdurometer (n = 10), and color change by Portable Color Spectrophotometer on the CIEDE2000 system (n = 10). Data were evaluated by one-way ANOVA with Bonferroni adjustment and Tukey's mean comparison test at a 5% significance level. Results: Ultraseal XT ™ sealant roughness showed a significant difference between concentrations with the highest mean for the 5% group (P = 0.010). Regarding the hardness, both sealants showed no significant difference between the groups. Fluroshield ™ sealant showed a significant difference in ΔE00 between the control-2.5% 24.93 (3.49) and control-5% 28.41 (2.58). Conclusion: It may be concluded that the incorporation of β-AgVO3 influenced the increase in roughness for Ultraseal XT ™ pit and fissure sealant, did not interfere with the microhardness of both sealants, and promoted a change in the color of Fluroshield ™ sealant within clinically acceptable limits.

In this work a colloidal approach to synthesize water-soluble CdSe quantum dots (QDs) bearing a surface ligand, such as thioglycolic acid (TGA), 3-mercaptopropionic acid (MPA), glutathione (GSH), or thioglycerol (TGH) was applied. The synthesized material was characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), UV-visible spectroscopy (UV-Vis), and fluorescence spectroscopy (PL). Additionally, a comparative study of the optical properties of different CdSe QDs was performed, demonstrating how the surface ligand affected crystal growth. The particles sizes were calculated from a polynomial function that correlates the particle size with the maximum fluorescence position. Curve resolution methods (EFA and MCR-ALS) were employed to decompose a series of fluorescence spectra to investigate the CdSe QDs size distribution and determine the number of fraction with different particle size. The results for the MPA-capped CdSe sample showed only two main fraction with different particle sizes with maximum emission at 642 and 686 nm. The calculated diameters from these maximum emission were, respectively, 2.74 and 3.05 nm.

This work reports a simple and reproducible method for silica-coated multiwalled carbon nanotubes (MWCNTs) nanostructures by the sol-gel method using tetraethoxysilane and 3-aminopropyltriethoxysilane as organosilicon precursors of silica. The synthetic method is based on a noncovalent functionalization of the MWCNTs by the adsorption of the monolayers of different polyelectrolytes, such as poly(allylamine hydrochloride) and poly(sodium 4-styrene sulfonate), which are positively and negatively charged, respectively. The role of these polyelectrolytes is the dispersion and interaction with both the nanotubes and the silicon precursors, influencing directly the silica shell growth. Two different morphology types of the silica-coated multiwalled carbon nanotubes composites were obtained on multiwalled carbon nanotubes. In both case the samples displayed uniformity in the silica layer. Finally, the investigation of the photoluminescence spectra of the samples suggested the presence of some incorrect oxygen bond, or vacancy of oxygen or even presence of nitrogen in the network, which is a typical feature of materials prepared by the sol-gel process at room temperature.

The work described in this paper is related to the effect of adding carbon nanotubes (CNT) on the mechanical properties of polymer-cement composites. A full factorial design has been performed on 160 samples to identify the contribution provided by the following factors: polymeric phase addition, CNT weight addition and water/cement ratio. The response parameters of the full factorial design were the bulk density, apparent porosity, compressive strength and elastic modulus of the polymer-cement-based nanocomposites. All the factors considered in this analysis affected significantly the bulk density and apparent porosity of the composites. The compressive strength and elastic modulus were affected primarily by the cross-interactions between polymeric phase and CNT additions, and the water/cement ratio with polymeric phase factors.

The post-preparative size-selective precipitation technique was applied in CdTe and CdSe semiconductor nanocrystals prepared via colloidal route in water. The synthesis of CdTe and CdSe nanoparticles and the effect of the post-preparative size-selective precipitation have been characterized mainly by mean of ultraviolet and visible absorption spectroscopy (UV-Vis). It was demonstrated that the size-selective precipitation are able to isolate particles of different sizes and purify the nanoparticles as well.

Mineral rock wastes are being widely investigated due to possible damage to the environment when discarded indiscriminately in the nature, but also because of their great potential as ceramic raw materials. This work aims to study the effect of steatite particle additions on the mechanical properties of clay composites. A comprehensive series of experiments have been conducted to assess the influence of: steatite particle size, steatite fraction and compacting pressure on the performance of clay composites. The composite of superior properties was manufactured with 20 wt. (%) of steatite, 100-200 US-Tyler of steatite particle size and 30 MPa of compacting pressure.

Colloidal semiconductor nanocrystals, also known as quantum dots, have attracted great attention since they have interesting size-dependent properties due to the quantum confinement effect. These nanoparticles are highly luminescent and have potential applications in different technological areas, including biological labeling, light-emitting diodes and photovoltaic devices. The synthetic methods of semiconductor nanocrystals have progressed in the last 30 years, and several protocols were developed to synthesize monodisperse nanocrystals with good optical properties, different compositions and morphologies. This review describes the main methods used to synthesize nanocrystals in the II-VI and III-V systems, and the recent approaches in this field of research.

Ceramic matrix composites (CMCs), constituted of a silicon boron oxycarbide (SiBCO) matrix and unidirectional carbon fiber rods as a reinforcement phase, were prepared by pyrolysis of carbon fiber rods wrapped in polysiloxane (PS) or poly(borosiloxane) (PBS) matrices. The preparation of the polymeric precursors involved hydrolysis/condensation reactions of alkoxysilanes in the presence and absence of boric acid, with B/Si atomic ratios of 0.2 and 0.5. Infrared spectra of PBS showed evidence of Si-O-B bonds at 880 cm-1, due to the incorporation of the crosslinker trigonal units of BO3 in the polymeric network. X ray diffraction analyses exhibited an amorphous character of the resulting polymer-derived ceramics obtained by pyrolysis up to 1000 °C under inert atmosphere. The C/SiBCO composites showed better thermal stability than the C/SiOC materials. In addition, good adhesion between the carbon fiber and the ceramic phase was observed by SEM microscopy

Quantum dot solar cells (QDSC) have been subject of extensive research in recent years. QDSC, as a promising alternative to existing solar cells, are among the candidates for next-generation photovoltaic devices that require low cost, high efficiency, so that quantum dots stand out for their unique features and versatile desirable on photovoltaic systems. The rapid development of QDSC provided a significant increase in energy conversion efficiency, which was certified for the first time in 2010 as 2% then being currently as 11.3%, according to the National Renewable Energy Laboratory (NREL). This paper presents a review of the quantum dot-sensitized solar cells and the major advances reported concerning these cells, besides other types of cell architectures involving quantum dots.

Solar energy has been considered as an important source of clean and safe energy to overcome the problems associate to the burn of fossil fuels (e.g. climate changes, pollution, health problems, etc.). In the area of photovoltaics, devices that convert solar energy into electricity, perovskites solar cells (PSC) have attracted great attention due to their rapid development, high energy conversion efficiency, diversification of the processing methods and different materials. The fantastic properties of the hybrid perovskite materials, such as high absorption coefficient, direct and tunable bandgap, ambipolar charge carrier, simple preparation, etc., have quoted this technology as one the most important in this century. The rapid development of PSC has provided a significant increase in energy conversion efficiency, which was first reported, in 2009, as 3.8% and now reaches up to 22.10%, according to the National Laboratory of Renewable Energy (NREL). Many studies have been carried out to further increase the efficiency of devices and solve problems as the instability of the material, and the presence of lead, so that the PSC can be applied commercially. This paper presents a review on PSC and the major advances reported in device’s architecture, preparation methods, novel materials and interface engineering.