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In this paper, phenolic resin hollow microspheres (PHM) were prepared using in-situ polymerization and used as flame-retardants for TPU. The structure and composition of PHM were characterized by Scanning Electron Microscope (SEM). The potential of PHM as flame retardant was verified by thermogravimetric analysis (TG). Then, the flame retardancy and toxicity reduction of PHM in TPU/PHM composites were verified by cone calorimeter test (CCT) and Thermogravimetric Analysis-infrared Spectrometry (TG-IR). It has been found that comparing TPU/PHM-4 sample containing 4.0 wt% PHM with pure TPU, the peak heat release rate (pHRR) was reduced by 61.6%, the total smoke release (TSR) by 23.2%, and the CO production by 86.2%, respectively. The SEM, Laser Raman Spectroscopy Test (LRS), and other tests were carried out to test the char residues after CCT, and the mechanism of PHM in the process of flame retardant TPU was reasonably deduced. In a word, PHM is very effective as a flame retardant of TPU.

Abstract The focal plane camera is the core component of the Wide Field-of-view Cherenkov/fluorescence Telescope Array (WFCTA) of the Large High-Altitude Air Shower Observatory (LHAASO). Because of the capability of working under moonlight without aging, silicon photomultipliers (SiPM) have been proven to be not only an alternative but also an improvement to conventional photomultiplier tubes (PMT) in this application. Eighteen SiPM-based cameras with square light funnels have been built for WFCTA. The telescopes have collected more than 100 million cosmic ray events and preliminary results indicate that these cameras are capable of working under moonlight. The characteristics of the light funnels and SiPMs pose challenges (e.g. dynamic range, dark count rate, assembly techniques). In this paper, we present the design features, manufacturing techniques and performances of these cameras. Finally, the test facilities, the test methods and results of SiPMs in the cameras are reported here.

In this work, nickel citrate (NC) was combined with ammonium polyphosphate (APP) to improve the flame retardance of thermoplastic polyurethane (TPU). And, the influence of nickel citrate on the flame retardance of TPU/APP composites was investigated by cone calorimeter test (CCT), thermogravimetric analysis/infrared spectrometry (TG-IR), scanning electron microscope (SEM), gas chromatography/mass spectrometry (GC-Ms), and X-ray photoelectron spectrometer (XPS), respectively. It has been found the combination of NC and APP improved the flame retardancy and reduced the total heat release (THR) of TPU composites. The THR value of TPU/APP/NC0.5 was reduced by 20.7% at 750 s compared with that of TPU/APP. The flame retardancy of TPU composites and the graphitization degree of char residue from TPU composites were improved by the combination of both NC and APP. This work provided a new way to improve the flame retardancy of polymer composites.

The omphalocele-exstrophy-imperforate anus-spinal defects (OEIS) complex represents severe midline abdominal and pelvic defects of unknown etiology. This complex is rare, affecting 1 in 200,000 to 400,000 pregnancies and is extremely rare in twin or triplet gestations. Here, we report the OEIS complex in a spontaneous monozygotic twin pregnancy and previously reported OEIS complex in twin or triplet pregnancy are reviewed. Spontaneous pregnancy and unremarkable family history, but concordance of monozygotic twins for the defect may support the theory that early malformation complexes, e.g., OEIS, may be related to errors in monozygotic splitting in early blastogenesis.

The Advanced Himawari Imager (AHI) onboard Himawari-8, a next-generation geostationary meteorological satellite, provided firstly the full-disk aerosol observations every 10 min at sub-kilometer spatial resolution(5 km). This is responsible for retrieving the ground-level particulate matter of fewer than 2.5 micrometers and improving assimilation model. However, the representativeness of AHI L3 hourly Aerosol Optical Thickness (AOT) products remains unclear under different air quality conditions, Especially, over frequently polluted urban areas that feature complex surface characteristics and aerosol models. In this study, One-to-one comprehensive comparisons were conducted to evaluate the performance of three types of AHI L3 AOT products (version 3.0) based on the Aerosol Robotic NETwork (AERONET) aerosol measurements over Beijing. The overall comparisons of AHI and ground AOTs show the AHI merged AOT perform best, which the R is 0.87, RMSE is 0.25 and 52.5% of retrievals fall within the envelope of Expect Error (EE, ±(0.05 + 0.2 * AOTground)). For the different primary pollutants, the results suggested the three types AHI hourly AOT products are more suitable for the fine particulate matters (PM2.5) retrievals, especially the merged AOT with 0.87 of R, 0.29 of RMSE and 58.8% of within EE. Furthermore, when the slight and moderate pollution happened over Beijing, the AHI hourly AOT products perform well. And when the heavy pollution happened, the performance of the AHI merge AOT and L2 mean AOT is better. a case during low to high pollution suggested that AHI merged AOT can capture the similar spatial pattern to the MODIS (Deep Blue) DB or (Dark Target) DTDB merged AOT and has good consistency with ground-based air quality monitoring. These results demonstrate the AHI hourly merged AOT is a promising aerosol retrieval for air quality.

Abstract In China, irrigation is widespread in 40.7% cropland to sustain crop yields. By its action on water cycle, irrigation affects water resources and local climate. In this study, a new irrigation module, including flood and paddy irrigation technologies, was developed in the ORCHIDEE‐CROP land surface model which describes crop phenology and growth in order to estimate irrigation demands over China from 1982 to 2014. Three simulations were performed including NI (no irrigation), IR (with irrigation limited by local water resources), and FI (with irrigation demand fulfilled). Observations and census data were used to validate the simulations. Results showed that the estimated irrigation water withdrawal ( W) based on IR and FI scenarios bracket statistical W with fair spatial agreements ( r=0.68±0.07; p

Emergent phenomena often appear in crystals in the two-dimensional limit but are rare in bulky compounds. Here, Guo et al. report a quasi-two-dimensional superconductivity in a bulk material AuTe2Se4/3 at 2.85 K, potentially owing to a topological transition.

The 3 August 2014 Ludian, China, Ms = 6.5 earthquake caused many large landslides. The biggest occurred at Hongshiyan near the epicenter, had a volume of 1.0 × 107 m3 and dammed the Niulanjiang River, creating a large lake. Post-event field investigations yielded detailed data on the following aspects: rock structure of the landslide, the local lithology and geometry of the area around the landslide dam and composition and grain sizes of the debris avalanche. Based on these data, this work analyzes the geology and topography of the Hongshiyan area, and explores reasons for the occurrence of an unusually large landslide at this location. Our analysis suggests the following conditions are responsible for this catastrophic event. (1) Due to recent crustal deformation, intense incision on the river increased topographic relief with steep slopes and scarps. (2) Combined structures, including unloading fissures, high-angle joints and low-angle beds along the river, as well as an upper-strong and lower-weak interlayer structure on the slope, especially the existence of weak layers in the slope, are important factors that contribute to this large failure. (3) Hongshiyan lies near an active fault, where intense crustal deformation has resulted in rock fractures and weathering, and frequent earthquakes may progressively reduce the strength of the slope. (4) During the Ms = 6.5 earthquake, the terrain and site conditions led to abnormally strong ground shaking. The combined impacts of these factors triggered a very large landslide during a moderate-sized earthquake.

Earthquake-triggered landslides have drawn much attention around the world because of the severe hazards they pose. The 20 April 2013 Ms = 7.0 Lushan Earthquake, which occurred in the Longmen Shan region in Sichuan province, China, triggered more than 1000 landslides throughout an area of about 2200 km2, and completely blocked many roads and exacerbated overall transportation problems in the mountainous terrain. Preliminary landslide inventory is complied immediately following the earthquake, mainly based on the high-resolution remote sensing images. At the same time, the distribution of these landslides is statistically investigated to determine how the occurrence of landslides correlates with distance from the earthquake epicenter, slope steepness, seismic intensity and rock type. Statistic analysis is conducted using landslide point density (LPD), which is defined as the number of landslides per square kilometer. It is found that LPD has a strong positive correlation with slope gradients and a negative-exponential decline with the distance from the epicenter. The higher LPD values occur in younger strata systems like Quaternary and Tertiary sediments in the study area. Spatially, the triggered landslides are controlled by the causative faults and mainly concentrated around the epicenter. All the landslides are located within the area with seismic intensity ≥ VII and in line with seismic intensity. Generally, LPD value decreases with increasing distance from the epicenter, and sometimes landslides are densely distributed along the roads in the mountainous region. Also, this study reveals that the empirical relationship between distance and seismic magnitude is more suitable for estimating the landslide concentration area during the Lushan earthquake compared to other methods.

During the 12 May 2008, Wenchuan earthquake in China, more than 15 000 landslides were triggered by the earthquake. Among these landslides, there were 112 large landslides generated with a plane area greater than 50 000 m2. These large landslides were markedly distributed closely along the surface rupture zone in a narrow belt and were mainly located on the hanging wall side. More than 85% of the large landslides are presented within the range of 10 km from the rupture. Statistical analysis shows that more than 50% of large landslides occurred in the hard rock and second-hard rock, like migmatized metamorphic rock and carbonate rock, which crop out in the south part of the damaged area with higher elevation and steeper landform in comparison with the northeast part of the damaged area. All large landslides occurred in the region with seismic intensity ≥ X except a few of landslides in the Qingchuan region with seismic intensity IX. Spatially, the large landslides can be centred into four segments, namely the Yingxiu, the Gaochuan, the Beichuan and the Qingchuan segments, from southwest to northeast along the surface rupture. This is in good accordance with coseismic displacements. With the change of fault type from reverse-dominated slip to dextral slip from southwest to northeast, the largest distance between the triggered large landslides and the rupture decreases from 15 km to 5 km. The critical acceleration ac for four typical large landslides in these four different segments were estimated by the Newmark model in this paper. Our results demonstrate that, given the same strength values and slope angles, the characteristics of slope mass are important for slope stability and deeper landslides are less stable than shallower landslides. Comprehensive analysis reveals that the large catastrophic landslides could be specifically tied to a particular geological setting where fault type and geometry change abruptly. This feature may dominate the occurrence of large landslides. The results will be useful for improving reliable assessments of earthquake-induced landslide susceptibility, especially for large landslides which may result in serious damages.

Southwest China is located in the southeastern margin of the Tibetan Plateau and it is a region of high seismic activity. Historically, strong earthquakes that occurred here usually generated lots of landslides and brought destructive damages. This paper introduces several earthquake-triggered landslide events in this region and describes their characteristics. Also, the historical data of earthquakes with a magnitude of 7.0 or greater, having occurred in this region, is collected and the relationship between the affected area of landslides and earthquake magnitude is analysed. Based on the study, it can be concluded that strong earthquakes, steep topography as well as fragile geological environment, are the main reasons responsible for serious landslides in southwest China. At the same time, it is found that the relationship between the area affected by landslides and the earthquake magnitude in this region are consistent with what has been obtained worldwide. Moreover, in this paper, it is seen that the size of the areas affected by landslides change enormously even under the same earthquake magnitude in the study region. While at the same tectonic place or fault belt, areas affected by landslides presented similar outline and size. This means that local geological conditions and historical earthquake background have an important influence on landslides distribution, and they should be considered when assessing earthquake-triggered landslide hazards at Grade 1 according to ISSMGE.

Due to its harsh natural conditions, there had not been any intensive radiosonde observations over the Tibetan Plateau (TP) before the year 2008, when a regional radiosonde observation network was implemented through a Sino-Japan joint cooperation project. This paper reports, on the basis of these observations, on an analysis of the structure of upper troposphere and lower stratosphere (UTLS) and provides observations of stratosphere and troposphere exchange (STE) over the TP. Due to sparseness of high resolution radiosonde data, many previous studies assumed that there was only one thermal tropopause over the TP. Actually, the radiosonde temperature profiles in winter time over the TP often exhibit a multiple tropopause (MT). The MT occurs in winter with a high frequency over the Plateau. MT events during this time are associated with tropopause folds near the subtropical westerly jet. The MT consistently varied with the movement of the jet. The MT becomes a single tropopause with the development of the monsoon. The detailed analyses of MT characteristics are reported in this paper. Earlier analyses of global MT events (with data based on GPS radio occultation, ERA-40 data and Integrated Global Radiosonde Archive database) resulted in a climatic frequency of MT occurrences in the winter season over the Plateau is not more than 40 %. Based on high resolution data of intensive radiosonde observations, our estimations of MT occurrence over the Plateau can be as high as 80 % during certain winters. This reminds us to pay more attention to the MT events above the Plateau. The influence of the coarse vertical resolution and other effects on the estimation of MT occurrence frequency are also discussed. The stratospheric intruding episodes are generally associated with the presence of subtropical jet stream over the Plateau. The complex structure of dynamic tropopause folding over the Plateau have been reflected by the thermal MT events observed by radiosondes. The intrusion of air masses from the stratosphere may contribute to a higher upper tropospheric ozone concentration in winter than in summer above the plateau.