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Start Over Author "Dubois, Lionel" Journal journal of physical chemistry b Database Gale General OneFile
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1. Dynamics of xenon inside hydrophobic cavities as probed by NMR relaxation of dissolved laser-polarized xenon

Author

Dubois, Lionel, Parres, Sandra, Huber, J.Gaspard, Berthault, Patrick, and Desvaux, Herve

Subjects
Chemistry, Physical and theoretical -- Research, Hydrophobic effect -- Research, Xenon -- Magnetic properties, Xenon -- Research, Xenon -- Chemical properties, Chemicals, plastics and rubber industries
Abstract

Longitudinal relaxation times T(sub 1) of laser-polarized xenon in water solutions containing alpha-cylodextrin and wheat nonspecific lipid transfer protein are measured. It reveals that even with an atom of high polarizability, such as xenon, the van der Waals energy is not sufficiently predominant to avoid large amplitude motions of an apolar guest around its average sites.

Published
2004

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