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1. Novel acetate polyoxomolybdate 'host' a zigzag-chainlike 'guest' of five edge-shared sodium cations: Na (sub)21 {[Na (sub)5 (H (sub)2 O) (sub)14] (is contained in) [Mo (sub)46 O (sub)134 (OH) (sub)10 (mu-CH (sub)3 COO) (sub)4]}.CH (sub)3 COONa. (approximately equals) 95H (sub)2 O

Author

Wenbin Yang, Chanzhong Lu, Xiang Lin, and Honghui Zhuang

Subjects
Chemistry, Inorganic -- Research, Acetates -- Physiological aspects, Polymers -- Physiological aspects, Sodium -- Physiological aspects, Cations -- Physiological aspects, Carbon -- Physiological aspects, Oxygen -- Physiological aspects, Hydrogen -- Physiological aspects, Molybdenum -- Physiological aspects, Acids -- Physiological aspects, Chemistry
Abstract

Research has been conducted on the inorganic 'host-guest' polyoxometalate complexes which contain 'guest' cations, anions, molecules or cation/anion aggregates. The effect of acidity on the equilibria among different species in one reaction pot has been investigated and the results are reported.

Published
2002

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