Search

We have calculated the electric dipole (E1) oscillator strengths and spontaneous decay rates for 12 spin-changing P-D transitions of atomic helium. We included the effects of the finite nuclear mass and the anomalous magnetic moment of the electron. The specific transitions for [sup.4]He are [n.sup.1][P.sup.o.sub.1] - [n'.sup.3] [D.sub.1,2] and [n.sup.3][P.sup.o.sub.2] - [n'.sup.1][D.sub.2] with n = 2, 3, 4 and n' = 3, 4. To include the effects of intermediate coupling between pure LS and jj, we used the Breit formulation for the spin-orbit and spin-other-orbit operators and combined the results of the exact diagonalization of the 2x2 energy matrix with pseudostate expansions to perform the perturbation sums over intermediate states. We calculated both the length and velocity gauges as a check on numerical accuracy and the validity of the transition operators. Key words: helium, atomic spectra, transition probabilities, nuclear mass, relativistic effects. Nous calculons les forces d'oscillateur dipolaires electriques (E1) et les taux de disintegration spontanee pour 12 transitions P-D a variation de spin de l'atome d'helium. Nous incluons les effets de la masse nucleaire finie et le moment magnetique anomal de l'electron. Specifiquement, les transitions etudiees dans [sup.4]He are [n.sup.1][P.sup.o.sub.1] - [n'.sup.3] [D.sub.1,2] and [n.sup.3][P.sup.o.sub.2] - [n'.sup.1][D.sub.2] with n = 2, 3, 4 and n' = 3, 4. Afin d'inclure les effets du couplage intermediate entre LS et jj purs, nous utilisons la formulation de Breit pour les operateurs de spin-orbite et de spin-autre-orbite et combinons les resultats de la diagonalisation exacte des matrices d'energie 2x2, avec expansion en pseudo-etats pour reussir les sommes de perturbation sur les etats intermediates. Nous calculons les jauges longueur et vitesse pour verifier la precision numerique et la validite des operateurs de transition. [Traduit par la Redaction] Mots-cles: helium, spectres atomiques, probabilites de transition, masse nucleaire, effets relativistes., 1. Introduction With this paper we wish to extend our previous calculations of spin-changing radiative transitions in neutral helium to P-D transitions and include the effects of the finite nuclear [...]

The relativistic corrections to the theoretical oscillator strengths of light elements such as helium are typically less than 0.1% and usually are ignored. However, they can be important for comparisons with the most accurate experiments, and they rapidly increase in magnitude with increasing nuclear charge. We have begun with the spin-forbidden electric-dipole transitions of neutral helium, using calculations consisting of (1) extremely accurate wave functions without relativistic corrections for both infinite and finite nuclear mass, (2) spin-changing matrix elements through the perturbations of the wave functions by the spin-orbit and spin-other-orbit Breit operators, (3) the use of pseudostates in the sums over all the intermediate states including the continuum, and (4) the inclusion as perturbers of the 1S0 and 3S1 states the pseudostates corresponding to the doubly excited npn'p ³[P.sup.e.sub.0] and npn'p ¹[P.sup.e.sub.1] terms, respectively. As examples of these calculations, we present oscillator strengths for the transitions 1 ¹[S.sub.0]-2 ³[P.sub.1], 2 ¹[S.sub.0]-2 ³[P.sub.1], 2 ³[S.sub.1]-2 ¹[P.sub.1], 2 ¹[P.sub.1-3] ³[D.sub.1,2], and 2 ³[P.sub.1,2]-3 ¹[D.sub.2]. PACS No: 32.70.Cs Les corrections relativistes aux forces d'oscillateur theeoriques d'eleements legers comme l'heelium sont typiquement plus petites que 0.1% et sont generalement ignorees. Cependant, elles peuvent etre importantes pour comparer avec les valeurs experimentales les plus precises et elles augmentent rapidement avec la charge nucleeaire. Nous deebutons avec les transitions dipolaires electriques spin interdites dans l'heelium neutre, a l'aide de calculs qui reposent sur, (1) des fonctions d'onde extrismement precises sans correction relativiste pour des masses nucleaires infinies et finies, (2) des elements de matrice de changements de spin via les perturbations de la fonction d'onde causees par les operateurs de Breit de spinorbite et de spin-autre orbite, (3) l'utilisation de pseudo etats dans la somme sur tous les etats intermediaries, incluant le continuum et (4) l'introduction, comme agents perturbant les etats ¹[S.sub.0] et ³[S.sub.1], des pseudo etats correspondant aux termes doublement excites npn'p ³[P.sup.e.sub.0] et npn'p ³[P.sup.e.sub.1] respectivement. Comme exemples de nos calculs, nous presenteras les forces d'oscillateur pour les transitions 1 ¹[S.sub.0]-2 ³[P.sub.1], 2 ¹-2 ³[P.sub.1], 2 ³[S.sub.1]-2 ¹[P.sub.1], 2 ¹pP.sub.1]-3 3 [D.sub.1,2] et 2 ³[P.sub.1,2]-3 ¹[D.sub.2]. [Traduit par la Redaction], 1. Introduction Although a three-body atomic system cannot be solved in closed analytical form, current computational techniques provide remarkable accuracies in the determination of energy levels, wave functions, and transition [...]

Abstract: This paper presents a review of recent progress in high-precision calculations for the ground state and low-lying excited states of helium, including the nonrelativistic energy, relativistic corrections of [α.sup.2] [...]

Abstract: We calculate very accurate ab initio ionization energies for both [sup.4]He I and ³He I as well as the isotope shifts for n = 1 to 10, L = [...]