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1. Rigid pillars and double walls in a porous metal-organic framework: single-crystal to single-crystal, controlled uptake and release of iodine and electrical conductivity

Author

Ming-Hua Zeng, Qiang-Xin Wang, Yan-Xi Tan, Sheng Hu, Hai-Xia Zhao, La-Sheng Long, and Kurmoo, Mohamedally

Subjects
Electrical conductivity -- Analysis, Iodine -- Chemical properties, Organometallic compounds -- Structure, Organometallic compounds -- Chemical properties, Organometallic compounds -- Electric properties, Zinc -- Chemical properties, Chemistry
Abstract

A highly stable pillared and double-walled zinc(II) metal-organic framework with regular nanochannels has exhibited single-crystal to single-crystal transformation upon desolvation and a large quantity of iodine uptake, controlled release and electrical conductivity elevation because of synergy between the iodine guests and the host framework.

Published
2010

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