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1. Ternary metal(II) complexes with tyrosine-containing dipeptides: structures of copper(II) and palladium(II) complexes involving L-tyrosylglycine and stabilization of copper(II) complexes due to intramolecular aromatic ring stacking

Author

Tamotsu Sugimori, Kimio Shibakawa, Hideki Masuda, Akira Odani, and Osamu Yamauchi

Subjects
Coordination compounds -- Research, Peptides -- Analysis, Copper compounds -- Observations, Palladium -- Observations, Ring formation (Chemistry) -- Analysis, Glycine -- Usage, Chemistry
Abstract

Crystallographic, spectroscopic and potentiometric techniques are used in an analysis of structures and stabilities of metal(II) complexes of tyrosine- (tyr-) containing dipeptide (L), L-tyr.X (X = glycine (gly), L-/D-alanine, -tyr, -tryptophan and -phenylalanine) and diamines (DA = ethylenediamine (en), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen)). Stabilization of Cu(DA)(L) is validated. Intramolecular stacking can control the conformation of side chain aromatic rings and coordination structures.

Published
1993

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