Search

Your search keyword '"Jun Ho Shin"' showing total 1 results
Start Over Author "Jun Ho Shin" Database Gale General OneFile
1 results on '"Jun Ho Shin"'

1. Molybdenocene trihydride complexes: influence of [Me2Si] ansa bridge on classical versus nonclassical nature, stability with respect to elimination of dihydrogen, and acidity

Author

Janak, Kevin E., Jun Ho Shin, and Parkin, Gerard

Subjects
Tungsten -- Chemical properties, Dehydrogenation -- Methods, Molybdenum compounds -- Chemical properties, Chemistry
Abstract

Experimental and computational studies on cationic molybdenocene trihydride complexes, namely [cp2MoH3]+, [(Cp(Super But)2MoH3]+, [Cp*2MoH3]+, and {[Me2Si(C5Me4)2]MoH3}+, demonstrate that the most stable form for the ansa molybdenocene derivative is a nonclassical dihydrogen-hydride isomer, {[Me2Si(C5Me4)2]Mo(n2-H2)(H)}+, whereas the stable forms for the non-ansa complexes are classical triydrides, [Cp2Mo(H)3]+, [(Cp(Super But)2Mo(H)3]+, and [Cp*2MoH3].

Published
2004

Catalog

Books, media, physical & digital resources
See catalog results