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1. chelate complexes (eta(super 5)-C(sub 5)Me(sub 5))IrL(sub 2)(L(sub 2) = TsNCH(sub 2)CH(sub 2)NTS, TsNCH(sub 2)CO)sub 2), CO(sub 2)CO(sub 2)

Author

Grotjahn, Douglas B., Lo, H. Christine, Dinoso, Jason, Adkins, Charles D., Chunbang, P., Nolan, Steven, and Li, Hubbard

Subjects
Hydrogen bonding -- Research, Iridium -- Research, Iridium -- Chemical properties, Amino acids -- Research, Amino acids -- Chemical properties, Chemistry
Abstract

The roles of carboxylato and sulfonamido ligands is made clear by a comparative synthetic, structural and thermodynamic study of coordinatively unsaturated chelate complexes, which are monomeric in solution and in the solid states. However, the oxalato complex exists as a 'n' oligomer or polymer that serves as a versatile precursor to monomeric adducts 6-L.

Published
2000

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