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1. Long-Lived Photoinduced Charge Separation in Ru(Bpy)(sub 3)(super 2+)/Viologen System at Nafion Membrane -Solution Interface

Author

Xiu-Yu Yi, Li-Zhu Wu, and Chen-Ho Tung

Subjects
Photochemistry -- Research, Electron transport -- Research, Ruthenium -- Electric properties, Chemicals, plastics and rubber industries
Abstract

The photoinduced electron transfer from the excited state of tris (2,2'-bipyridine) ruthenium (II)(Ru (bpy)(sub 3)(super 2+) incorporated into Nafion membranes to propylviologen sulfonate (PVS) in the surrounding solution is examined by both photochemical and photoelectrochemical measurements. An extremely long lifetime of photoinduced charge-separated pair, albeit in low yield at present, is observed.

Published
2000

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