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Enteromorpha prolifera-derived Fe 3 C/C composite has been fabricated through a facile one-step calcination method. As an advanced Fenton-like catalyst, the obtained Fe 3 C/C composite displayed high catalytic reactivity to generate hydroxyl radicals. It is worth to note that the removal rate of methylene blue (MB) could effectively reach 100% in a wide pH range (pH = 2˜12) and the maximum degradation capacity of the composite is 660 mg/g. The stability and reusability of Fe 3 C/C composite catalyst have also been tested, which could remain the removal rate at 100% after 6 consecutive runs. To illustrate the practical application possibility, the Fe 3 C/C composite catalyst was used for degradation of papermaking and dyeing waste water, which could reduce the COD (chemical oxygen demand) value to less than 50. Additionally, the antibiotic norfloxacin (NOR) could also be catalytically removed by the Fe 3 C/C composite and the possible removal pathway has also been proposed. The excellent removal performance of Fe 3 C/C composite for MB and NOR may be attributed to the synergistic effect between porous carbon adsorption and Fe 3 C catalysis. This study not only provides novel insights into recycling of waste biomass, but also paves a new way for the application of Fe 3 C/C in dyes and antibiotics waste water treatment areas., (Copyright © 2019. Published by Elsevier B.V.)

Characteristics and catalytic properties of a series of carbon-based catalysts (CBCs) produced from paper mill sludge were evaluated. The major processes involved in the production of the catalysts were chemical activation, impregnation, pyrolysis, and post pyrolysis rinsing. The porous structure, catalytic activity and thermostability of the catalysts were tailored during the production stage by introducing hetero-atoms (zinc chloride, and ferric nitrate) in the carbon structure. Characterization of the produced CBCs included determination of the surface area, pore size, and pore size distribution (PSD) from standard N2-adsorption isotherm data. The extent of graphitization and the presence of metal crystals were identified from X-ray diffraction (XRD). The limit of the catalyst gasification was estimated from thermogravimetric analysis (TGA) conducted in an oxidized environment. The NOx reduction capability of the produced catalysts was evaluated in the presence of carbon monoxide using a fixed bed reactor. The reaction temperature ranged from 300 to 500 degrees C. It was shown that paper mill sludge is an excellent precursor for the production of CBCs with NOx removal capability of 66-94%. The catalytic capability of the produced CBCs varied according to the method of production, catalyst surface properties (surface area, pore structure, PSD), metal composition and reaction temperature. The highest NOx removal capacity was observed for the catalytic reactions carried out at 400 degrees C. The mesoporous catalyst produced with a Zn:Fe molar ratio of 1:0.5 exhibited the maximum NOx removal catalytic activity of 94%.