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The molecular fractionation of organic compounds through adsorption in minerals has wide implications, including tracing the origins of life, carbon sequestration, and climate change. Here we present the first in situ examination of molecular fractionation within individual crystals via optical-photothermal infrared (O-PTIR) spectroscopy. Our study focuses on a unique inclusion trail within deeply buried halite crystals, characterized by a distinctive orange-to-blue fluorescence gradient, providing primary evidence of molecular variation in ancient carbon-based fluids within the inclusion trail. The findings reveal a trend in the CH 2 /C=O and CH 3 /C=O ratios, conforming with a consistent decrease from the blue fluorescence region to the orange fluorescence region. The chemically influenced fluorescent behavior of these ancient liquid carbon-based compounds is attributed to the fractionation of fluids in the inclusions as a result of microfractures within the crystal acting as chromatography capillaries. These capillaries facilitated interactions between specific organic compounds, serving as adsorbates, and the halite mineral, representing the adsorbent. Our study provides insights into the fluid-solid physicochemical interactions within extreme environments and extends our understanding of molecular processes in such settings.

The carbonaceous asteroid Ryugu has been explored by the Hayabusa2 spacecraft to elucidate the actual nature of hydrous asteroids. Laboratory analyses revealed that the samples from Ryugu are comparable to unheated CI carbonaceous chondrites; however, reflectance spectra of Ryugu samples and CIs do not coincide. Here, we demonstrate that Ryugu sample spectra are reproduced by heating Orgueil CI chondrite at 300°C under reducing conditions, which caused dehydration of terrestrial weathering products and reduction of iron in phyllosilicates. Terrestrial weathering of CIs accounts for the spectral differences between Ryugu sample and CIs, which is more severe than space weathering that likely explains those between asteroid Ryugu and the collected samples. Previous assignments of CI chondrite parent bodies, i.e., chemically most primitive objects in the solar system, are based on the spectra of CI chondrites. This study indicates that actual spectra of CI parent bodies are much darker and flatter at ultraviolet to visible wavelengths than the spectra of CI chondrites.

Without a protective atmosphere, space-exposed surfaces of airless Solar System bodies gradually experience an alteration in composition, structure and optical properties through a collective process called space weathering. The return of samples from near-Earth asteroid (162173) Ryugu by Hayabusa2 provides the first opportunity for laboratory study of space-weathering signatures on the most abundant type of inner solar system body: a C-type asteroid, composed of materials largely unchanged since the formation of the Solar System. Weathered Ryugu grains show areas of surface amorphization and partial melting of phyllosilicates, in which reduction from Fe 3+ to Fe 2+ and dehydration developed. Space weathering probably contributed to dehydration by dehydroxylation of Ryugu surface phyllosilicates that had already lost interlayer water molecules and to weakening of the 2.7 µm hydroxyl (-OH) band in reflectance spectra. For C-type asteroids in general, this indicates that a weak 2.7 µm band can signify space-weathering-induced surface dehydration, rather than bulk volatile loss., Competing Interests: Competing interestsThe authors declare no competing interests., (© The Author(s) 2022.)

Before Perseverance, Jezero crater's floor was variably hypothesized to have a lacustrine, lava, volcanic airfall, or aeolian origin. SuperCam observations in the first 286 Mars days on Mars revealed a volcanic and intrusive terrain with compositional and density stratification. The dominant lithology along the traverse is basaltic, with plagioclase enrichment in stratigraphically higher locations. Stratigraphically lower, layered rocks are richer in normative pyroxene. The lowest observed unit has the highest inferred density and is olivine-rich with coarse (1.5 millimeters) euhedral, relatively unweathered grains, suggesting a cumulate origin. This is the first martian cumulate and shows similarities to martian meteorites, which also express olivine disequilibrium. Alteration materials including carbonates, sulfates, perchlorates, hydrated silicates, and iron oxides are pervasive but low in abundance, suggesting relatively brief lacustrine conditions. Orbital observations link the Jezero floor lithology to the broader Nili-Syrtis region, suggesting that density-driven compositional stratification is a regional characteristic.

The ~31-km-wide Hiawatha structure, located beneath Hiawatha Glacier in northwestern Greenland, has been proposed as an impact structure that may have formed after the Pleistocene inception of the Greenland Ice Sheet. To date the structure, we conducted 40 Ar/ 39 Ar analyses on glaciofluvial sand and U-Pb analyses on zircon separated from glaciofluvial pebbles of impact melt rock, all sampled immediately downstream of Hiawatha Glacier. Unshocked zircon in the impact melt rocks dates to ~1915 million years (Ma), consistent with felsic intrusions found in local bedrock. The 40 Ar/ 39 Ar data indicate Late Paleocene resetting and shocked zircon dates to 57.99 ± 0.54 Ma, which we interpret as the impact age. Consequently, the Hiawatha impact structure far predates Pleistocene glaciation and is unrelated to either the Paleocene-Eocene Thermal Maximum or flood basalt volcanism in east Greenland. However, it was contemporaneous with the Paleocene Carbon Isotope Maximum, although the impact's exact paleoenvironmental and climatic significance awaits further investigation.

The goal of Project GAUSS (Genesis of Asteroids and evolUtion of the Solar System) is to return samples from the dwarf planet Ceres. Ceres is the most accessible candidate of ocean worlds and the largest reservoir of water in the inner Solar System. It shows active volcanism and hydrothermal activities in recent history. Recent evidence for the existence of a subsurface ocean on Ceres and the complex geochemistry suggest past habitability and even the potential for ongoing habitability. GAUSS will return samples from Ceres with the aim of answering the following top-level scientific questions: What is the origin of Ceres and what does this imply for the origin of water and other volatiles in the inner Solar System?What are the physical properties and internal structure of Ceres? What do they tell us about the evolutionary and aqueous alteration history of dwarf planets?What are the astrobiological implications of Ceres? Is it still habitable today?What are the mineralogical connections between Ceres and our current collections of carbonaceous meteorites?, (© The Author(s) 2021.)

The determination of the abundances of the CH x , C = O and aromatic groups in chondritic Insoluble Organic Matter (IOM) and coals by Infrared (IR) spectroscopy is a challenging issue due to insufficient knowledge on the absorption cross-sections and their sensitivity to the molecular environment. Here, we report a calibration approach based on a 13 C synthetic model material whose composition was unambiguously determined by Direct-Pulse/Magic Angle Spinning Nuclear Magnetic Resonance (DP/MAS NMR). Ratios of the cross-sections of the CH x , C = O and aromatic groups have been determined, and the method has been applied to IOM samples extracted from four chondrites as Orgueil (CI), Murchison (CM), Tagish Lake (C2-ungrouped) and EET 92042 (CR2), and to a series of coals. The estimate of the aliphatic to aromatic carbon ratio (n CHx /n Aro ) in IOM samples from Orgueil, Murchison and Tagish Lake chondrites is in good agreement with Single-Pulse/NMR estimates earlier published, and is lower by a factor of 1.3 in the case of the CR chondrite EET 92042 (but the error bars overlap). In contrast, the aliphatic to carbonyl ratio (n CHx /n C=O ) is overestimated for the four chondrites. These discrepancies are likely due to the control of the absorption cross-section of the C = O and C = C bonds by the local molecular environment. Regarding coals, the use of published NMR analyses has brought to light that the integrated cross-section ratio A CHx /A Aro varies with the vitrinite reflectance over an order of magnitude. Here as well, the local oxygen speciation plays a critical control in A Aro , which decreases with increasing the vitrinite reflectance. We provide an analytical law that links A CHx /A Aro and vitrinite reflectance, which will allow the determination of n CHx /n Aro for any coal sample, provided its vitrinite reflectance is known., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Tektites are terrestrial impact-generated glasses that are ejected long distance (up to 11,000 km), share unique characteristics and have a poorly understood formation process. Only four tektite strewn-fields are known, and three of them are sourced from known impact craters. Here we show that the recently discovered Pantasma impact crater (14 km diameter) in Nicaragua is the source of an impact glass strewn-field documented in Belize 530 km away. Their cogenesis is documented by coincidental ages, at 804 ± 9 ka, as well as consistent elemental compositions and isotopic ratios. The Belize impact glass share many characteristics with known tektites but also present several peculiar features. We propose that these glasses represent a previously unrecognized tektite strewn-field. These discoveries shed new light on the tektite formation process, which may be more common than previously claimed, as most known Pleistocene >10 km diameter cratering events have generated tektites., Competing Interests: Competing interests The authors declare no competing interests

The European Space Agency and Roscosmos' ExoMars rover mission, which is planned to land in the Oxia Planum region, will be dedicated to exobiology studies at the surface and subsurface of Mars. Oxia Planum is a clay-bearing site that has preserved evidence of long-term interaction with water during the Noachian era. Fe/Mg-rich phyllosilicates have previously been shown to occur extensively throughout the landing area. Here, we analyze data from the High Resolution Imaging Science Experiment (HiRISE) and from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instruments onboard NASA's Mars Reconnaissance Orbiter and the Colour and Stereo Surface Imaging System (CaSSIS) onboard ESA's Trace Gas Orbiter to characterize, at a high spatial resolution, the morphological and spectral variability of Oxia Planum's surface deposits. Two main types of bedrocks are identified within the clay-bearing, fractured unit observed throughout the landing site: (1) an orange type in HiRISE correlated with the strongest detections of secondary minerals (dominated by Fe/Mg-rich clay minerals) with, in some locations, an additional spectral absorption near 2.5 μm, suggesting the mixture with an additional mineral, plausibly carbonate or another type of clay mineral; (2) a more bluish bedrock associated with weaker detections of secondary minerals, which exhibits at certain locations a ∼1 μm broad absorption feature consistent with olivine. Coanalysis of the same terrains with the recently acquired CaSSIS images confirms the variability in the color and spectral properties of the fractured unit. Of interest for the ExoMars mission, both types of bedrocks are extensively outcropping in the Oxia Planum region, and the one corresponding to the most intense spectral signals of clay minerals (the primary scientific target) is well exposed within the landing area, including near its center.

The age of iron meteorites implies that accretion of protoplanets began during the first millions of years of the solar system. Due to the heat generated by 26 Al decay, many early protoplanets were fully differentiated with an igneous crust produced during the cooling of a magma ocean and the segregation at depth of a metallic core. The formation and nature of the primordial crust generated during the early stages of melting is poorly understood, due in part to the scarcity of available samples. The newly discovered meteorite Erg Chech 002 (EC 002) originates from one such primitive igneous crust and has an andesite bulk composition. It derives from the partial melting of a noncarbonaceous chondritic reservoir, with no depletion in alkalis relative to the Sun's photosphere and at a high degree of melting of around 25%. Moreover, EC 002 is, to date, the oldest known piece of an igneous crust with a 26 Al- 26 Mg crystallization age of 4,565.0 million years (My). Partial melting took place at 1,220 °C up to several hundred kyr before, implying an accretion of the EC 002 parent body ca. 4,566 My ago. Protoplanets covered by andesitic crusts were probably frequent. However, no asteroid shares the spectral features of EC 002, indicating that almost all of these bodies have disappeared, either because they went on to form the building blocks of larger bodies or planets or were simply destroyed., Competing Interests: The authors declare no competing interest.

The Dawn mission found that the dominant colour variation on the surface of dwarf planet Ceres is a change of the visible spectral slope, where fresh impact craters are surrounded by blue (negative spectral-sloped) ejecta. The origin of this colour variation is still a mystery. Here we investigate a scenario in which an impact mixes the phyllosilicates present on the surface of Ceres with the water ice just below. In our experiment, Ceres analogue material is suspended in liquid water to create intimately mixed ice particles, which are sublimated under conditions approximating those on Ceres. The sublimation residue has a highly porous, foam-like structure made of phyllosilicates that scattered light in similar blue fashion as the Ceres surface. Our experiment provides a mechanism for the blue colour of fresh craters that can naturally emerge from the Ceres environment.

The SuperCam instrument suite provides the Mars 2020 rover, Perseverance, with a number of versatile remote-sensing techniques that can be used at long distance as well as within the robotic-arm workspace. These include laser-induced breakdown spectroscopy (LIBS), remote time-resolved Raman and luminescence spectroscopies, and visible and infrared (VISIR; separately referred to as VIS and IR) reflectance spectroscopy. A remote micro-imager (RMI) provides high-resolution color context imaging, and a microphone can be used as a stand-alone tool for environmental studies or to determine physical properties of rocks and soils from shock waves of laser-produced plasmas. SuperCam is built in three parts: The mast unit (MU), consisting of the laser, telescope, RMI, IR spectrometer, and associated electronics, is described in a companion paper. The on-board calibration targets are described in another companion paper. Here we describe SuperCam's body unit (BU) and testing of the integrated instrument. The BU, mounted inside the rover body, receives light from the MU via a 5.8 m optical fiber. The light is split into three wavelength bands by a demultiplexer, and is routed via fiber bundles to three optical spectrometers, two of which (UV and violet; 245-340 and 385-465 nm) are crossed Czerny-Turner reflection spectrometers, nearly identical to their counterparts on ChemCam. The third is a high-efficiency transmission spectrometer containing an optical intensifier capable of gating exposures to 100 ns or longer, with variable delay times relative to the laser pulse. This spectrometer covers 535-853 nm ( 105 - 7070 cm - 1 Raman shift relative to the 532 nm green laser beam) with 12 cm - 1 full-width at half-maximum peak resolution in the Raman fingerprint region. The BU electronics boards interface with the rover and control the instrument, returning data to the rover. Thermal systems maintain a warm temperature during cruise to Mars to avoid contamination on the optics, and cool the detectors during operations on Mars. Results obtained with the integrated instrument demonstrate its capabilities for LIBS, for which a library of 332 standards was developed. Examples of Raman and VISIR spectroscopy are shown, demonstrating clear mineral identification with both techniques. Luminescence spectra demonstrate the utility of having both spectral and temporal dimensions. Finally, RMI and microphone tests on the rover demonstrate the capabilities of these subsystems as well., Competing Interests: Conflicts of interest/Competing interestsThe authors declare that there are no conflicts of interest or competing interests., (© The Author(s) 2020.)

The measured nitrogen-to-carbon ratio in comets is lower than for the Sun, a discrepancy which could be alleviated if there is an unknown reservoir of nitrogen in comets. The nucleus of comet 67P/Churyumov-Gerasimenko exhibits an unidentified broad spectral reflectance feature around 3.2 micrometers, which is ubiquitous across its surface. On the basis of laboratory experiments, we attribute this absorption band to ammonium salts mixed with dust on the surface. The depth of the band indicates that semivolatile ammonium salts are a substantial reservoir of nitrogen in the comet, potentially dominating over refractory organic matter and more volatile species. Similar absorption features appear in the spectra of some asteroids, implying a compositional link between asteroids, comets, and the parent interstellar cloud., (Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.)

Several arguments point to a larger proportion of metal-rich asteroids than that derived from spectral observations, as remnants of collisional disruptions of differentiated bodies. We show experimentally that this apparent deficit may result from the coating of metallic surfaces by silicate melts produced during impacts of hydrated or dry projectiles at typical asteroid impact speeds. Spectral analysis of steel and iron meteorite targets after impact shows a profoundly modified optical signature. Furthermore, hydrated projectiles leave a 3-μm absorption hydration feature. This feature is thus consistent with a metallic surface and does not require an unusual low-speed impact. Unless systematizing radar measurements, ground-based spectral observations can be deceptive in identifying iron-rich bodies. The NASA Psyche mission rendezvous with Psyche will offer the unique opportunity both to measure the relative abundances of regolith and glassy coated surfaces and to substantially increase our understanding of impact processes and signatures on a metal-rich asteroid.

We have developed a new spectro-gonio radiometer, SHADOWS, to study in the laboratory the bidirectional reflectance distribution function of dark and precious samples. The instrument operates over a wide spectral range from the visible to the near-infrared (350-5000 nm) and is installed in a cold room to operate at a temperature as low as -20° C . The high flux monochromatic beam is focused on the sample, resulting in an illumination spot of about 5.2 mm in diameter. The reflected light is measured by two detectors with high sensitivity (down to 0.005% in reflectance) and absolute accuracy of 1%. The illumination and observations angles, including azimuth, can be varied over wide ranges. This paper presents the scientific and technical constraints of the spectro-gonio radiometer, its design and additional capabilities, as well as the performances and limitations of the instrument.

An overview of several innovations regarding in situ laser-heating techniques in the diamond anvil cell at the high-pressure beamline ID27 of the European Synchrotron Radiation Facility is presented. Pyrometry measurements have been adapted to allow simultaneous double-sided temperature measurements with the installation of two additional online laser systems: a CO2 and a pulsed Nd:YAG laser system. This reiteration of laser-heating advancements at ID27 is designed to pave the way for a new generation of state-of-the-art experiments that demand the need for synchrotron diffraction techniques. Experimental examples are provided for each major development. The capabilities of the double pyrometer have been tested with the Nd:YAG continuous-wave lasers but also in a time-resolved configuration using the nanosecond-pulsed Nd:YAG laser on a Fe sample up to 180 GPa and 2900 K. The combination of time-resolved X-ray diffraction with in situ CO2 laser heating is shown with the crystallization of a high-pressure phase of the naturally found pyrite mineral MnS2 (11 GPa, 1100-1650 K).

Iron in crustal and mantle minerals adopts several possible oxidation states: this has implications for biogeochemical processes, oxygenation of the atmosphere and the oxidation state of the mantle. In the deep Earth, iron in silicate perovskite, (Mg(0.9)Fe(0.1))SiO(3), and ferropericlase, (Mg(0.85)Fe(0.15))O, influences the thermal conductivity of the lower mantle and therefore heat flux from the core. Little is known, however, about the effect of iron oxidation states on transport properties. Here we show that the radiative component of thermal conductivity in the dominant silicate perovskite material of Earth's lower mantle is controlled by the amount of ferric iron, Fe(3+). We obtained the optical absorption spectra of silicate perovskite and ferropericlase at pressures up to 133 GPa, corresponding to pressures at the core-mantle boundary. Absorption spectra of ferropericlase up to 800 K and 60 GPa exhibit minimal temperature dependence. The results on silicate perovskite show that optical absorption in the visible and near-infrared spectral range is dominated by O-Fe(3+) charge transfer and Fe(3+)-Fe(2+) intervalence transitions, whereas a contribution from the Fe(2+) crystal-field transitions is substantially smaller. The estimated pressure-dependent radiative conductivity, k(rad), from these data is 2-5 times lower than previously inferred from model extrapolations, with implications for the evolution of the mantle, such as generation and stability of thermo-chemical plumes in the lower mantle.