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The borotellurite glasses whose chemical structure is (29.5-0.4x)CaO + 10CaF 2  + (60-0.6x)B 2 O 3  + xTeO 2 + 0.5Yb 2 O 3 (where x=10, 16, 22, 31, and 54 % mole. represent TCCBY1-TCCBY5, respectively) are Pb-free, thermally stable, and transparent glasses with attractive optical features for technological applications. The gamma-photons, electrons, protons, neutrons, carbon ions, fast neutrons, and fast neutron interaction parameters of these glasses are presented in this study to better understand the role of TeO 2 in influencing their radiation shielding properties and radiation protection applications. The photon mass attenuation coefficient was evaluated by XCOM computation and simulation using the FLUKA code. The FLUKA code was also used to evaluate the mass stopping powers of the charged radiations, while neutrons' cross sections were evaluated using standard expressions. For 0.015 MeV-15 MeV photons, the mass attenuation coefficients of the glasses fell from 17.9499 to 0.0246 cm 2 /g for TCCBY1, 20.5628 to 0.0263 cm 2 /g for TCCBY2, 23.2756 to 0.079 cm 2 /g for TCCBY3, 26.7487 to 0.0298 cm 2 /g for TCCBY4, and 33.3591 to 0.0335 cm 2 /g for TCCBY5. The photon half-value layer at 15 keV is reduced by about 19.57%, 32.68%, 48.84%, and 63.89% when the TeO 2 content increases from 10 mol to 16, 22, 31, and 54 mol, respectively. TeO 2 was found to suppress photon buildup in the glasses. The mass stopping powers of charged radiation increased as glass density decreased. The addition of TeO 2 into the glass structure increased the ability of the TCCBY glass to absorb fast neutrons by up to 54 % mole. The gamma radiation and fast neutron moderating ability of TCCBY5 glass compared to common shields and other materials is exceptional. The glass is recommended for the design of Pb-free, transparent, and efficient radiation protection structures., Competing Interests: Declaration of competing interest All authors must disclose any financial and personal relationships with other people or organizations that could inappropriately influence (bias) their work. Examples of potential conflicts of interest include employment, consultancies, stock ownership, honoraria, paid expert testimony, patent applications/registrations, and grants or other funding., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

This paper reports the synthesis and the characterization of Yb 3+ -doped calcium borotellurite (CaBTeX) glasses with composition 10CaF 2 -(29.5-0.4x)CaO-(60-0.6x)B 2 O 3 -xTeO 2 -0.5Yb 2 O 3 (x=10, 16, 22, 31 and 54mol%). The results of XRD confirm the amorphous character of all the samples. The density, molar volume, refractive index and electronic polarizability values show an increase with TeO 2 content. Otherwise, the optical band gap energy shows a decrease with the increase of TeO 2 content. The replacement of CaO and B 2 O 3 by TeO 2 changes the glass structure, which decreases the excited Yb 3+ /cm 3 and, consequently, the luminescence intensity. The temperature dependence of luminescence was studied for all the samples up to 420K. The fluorescence lifetime does not change significantly due to TeO 2 addition. In addition, absorption and emission cross section were calculated and present high values as compared to other tellurite and phosphate glasses., (Copyright © 2017 Elsevier B.V. All rights reserved.)