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Knowledge on corrosion behaviors and kinetics of nanoscale zero-valent iron (nZVI) in aquatic environment is particularly significant for understanding the reactivity, longevity and stability of nZVI, as well as providing theoretical guidance for developing a cost-effective nZVI-based technology and designing large-scale applications. Herein, this review gives a holistic overview on the corrosion behaviors and kinetics of nZVI in water. Firstly, Eh-pH diagram is introduced to predict the thermodynamics trend of iron corrosion. The morphological, structural, and compositional evolution of (modified-) nZVI under different environmental conditions, assisted with microscopic and spectroscopic evidence, is then summarized. Afterwards, common analytical methods and characterization technologies are categorized to establish time-resolved corrosion kinetics of nZVI in water. Specifically, stable models for calculating the corrosion rate constant of nZVI as well as electrochemical methods for monitoring the redox reaction are discussed, emphasizing their capabilities in studying the dynamic iron corrosion processes. Finally, in the future, more efforts are encouraged to study the corrosion behaviors of nZVI in long-term practical application and further build nanoparticles with precisely tailored properties. We expect that our work can deepen the understanding of the nZVI chemistry in aquatic environment., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

β-Type Ti alloys have been widely investigated as implant materials owing to their excellent mechanical properties, corrosion resistance, and biocompatibility. In the present work, the effects of Zr on the microstructure, mechanical properties, and corrosion behaviors of Ti-Zr-Mo-Mn alloys were systematically studied. With the increase of Zr content, the phase composition gradually changed from intragranular-α + β of (TZ) 5:1 MM alloy to grain-boundary-α + β of (TZ) 2:1 MM alloy and finally transferred to a single β phase structure of (TZ) 1:1 MM alloy. The (TZ) 1:1 MM alloy exhibited a good mechanical combination with a yield strength of 750.8 MPa, an elastic modulus of 61.3 GPa, and a tensile ductility of 14.6%. Moreover, the addition of Zr can effectively stabilize the passivation film and reduce the sensitivity of microgalvanic corrosion in simulated body fluid, leading to enhanced corrosion resistance in the TZMM alloys. X-ray photoelectron spectroscopy analysis together with the ion-sputtering technique revealed that the passivation films formed on TZMM alloys possessed a bilayered structure (outer Ti+Zr mixed-oxide layer and inner Zr-oxide-rich layer), in which the inner Zr oxide layer plays an important role in the corrosion resistance of the TZMM alloys. In vitro biocompatibility evaluations demonstrated that the TZMM alloys can support cell adhesion and proliferation with high biocompatibility comparable to that of CP-Ti, while in vivo biocompatibility evaluations validated the bone osteointegration ability of TZMM alloys after long-term implantation. The above results indicate that novel TZMM alloys are promising candidates for implant material.

The effect of the Ca 2 Mg 6 Zn 3 phase on the corrosion behavior of biodegradable Mg-4.0Zn-0.2Mn- x Ca (ZM-xCa, x = 0.1, 0.3, 0.5 and 1.0 wt.%) alloys in Hank's solution was investigated with respect to phase spacing, morphology, distribution and volume fraction. With the increase in Ca addition, the volume fraction of the Ca 2 Mg 6 Zn 3 phase increased from 2.5% to 7.6%, while its spacing declined monotonically from 43 μm to 30 μm. The Volta potentials of secondary phases relative to the Mg matrix were measured by using scanning kelvin probe force microscopy (SKPFM). The results show that the Volta potential of the intragranular spherical Ca 2 Mg 6 Zn 3 phase (+109 mV) was higher than that of the dendritic Ca 2 Mg 6 Zn 3 phase (+80 mV). It is suggested that the Ca 2 Mg 6 Zn 3 acted as a cathode to accelerate the corrosion process due to the micro-galvanic effect. The corrosion preferred to occur around the spherical Ca 2 Mg 6 Zn 3 phase at the early stage and developed into the intragranular region. The corrosion rate increased slightly with increasing Ca content from 0.1 wt.% to 0.5 wt.% because of the enhanced micro-galvanic corrosion effect. The decrease in the phase spacing and sharp increase in the secondary phase content resulted in a dramatic increase in the corrosion rate of the ZM-1.0Ca alloy.

To enhance the cavitation erosion resistance of industrial components, two types of Cr-rich diffusion layers were fabricated on 316L stainless steel through pack chromizing process. The chromizing layer before post heat treatments exhibited poor cavitation erosion performances, which could be ascribed to its high brittleness and the galvanic corrosion. The chromizing layer after post heat treatments showed the excellent cavitation erosion resistance with a 3.97 times lower erosion mass loss compared with that of 316L stainless steel. The corrosion resistance was significantly improved with a 12.5-time lower free corrosion current density than 316L stainless steel, and the surface mechanical properties of chromizing layer also exhibited great combination of hardness and toughness. Therefore, the higher cavitation resistance was attributed to the better corrosion and mechanical performances originating from the more homogeneous microstructure after post heat treatments., (Copyright © 2019 Elsevier B.V. All rights reserved.)

The novel interpenetrating (HA+β-TCP)/MgCa composites were fabricated by infiltrating MgCa alloy into porous HA+β-TCP using suction casting technique. The microstructure, mechanical properties and corrosion behaviors of the composites have been evaluated by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), mechanical testing, electrochemical and immersion tests. It was shown that the composites had compact structure and the interfacial bonding between MgCa alloy and HA+β-TCP scaffolds was very well. The ultimate compressive strength of the composites was about 500-1000 fold higher than that of the original porous scaffolds, and it still retained quarter-half of the strength of the bulk MgCa alloy. The electrochemical and immersion tests indicated that the corrosion resistance of the composites was better than that of the MgCa matrix alloy, and the corrosion products of the composite surface were mainly Mg(OH)2, HA and Ca3(PO4)2. Meanwhile, the mechanical and corrosive properties of the (HA+β-TCP)/MgCa composites were adjustable by the choice of HA content., (© 2013.)