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In this study, a green zero-valent iron-loaded carbon composite (ZVI-SCG) was synthesized using coffee grounds and FeCl3 solution through two-steps method, and the synthesized ZVI-SCG was used in the activation of peroxydisulfate (PDS) to degrade Levofloxacin (LEX). Results revealed that ZVI-SCG exhibited a great potential for LEX removal by adsorption and catalytic degradation in the ZVI-SCG/PDS system, and 99% of LEX was removed in the ZVI-SCG/PDS system within 60 min. ZVI-SCG/PDS system showed a high reactivity toward LEX degradation under realistic environmental conditions. Also, the ZVI-SCG/PDS system could effectively degrade several quinolone antibiotics including gatifloxacin, ciprofloxacin and LEX in single and simultaneous removal modes. A potential reaction mechanism of LEX degradation by ZVI-SCG/PDS system was proposed, SO 4 •- , HO•, O 2 • - and 1 O 2 involved in radical and non-radical pathways took part in catalytic degradation of LEX by ZVI-SCG/PDS system, but HO• might be the main reactive species for LEX degradation. The possible degradation pathway of LEX was also proposed based on the identified ten intermediate products, LEX degradation was successfully achieved through decarboxylation, opening ring and hydroxylation processes. The potential toxicity of LEX and its oxidation products decreased significantly after treatment. This study provides a promising strategy of water treatment for the antibiotics-containing wastewater., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Nowadays, clean-up of heavy metals from wastewaters using waste residue carbon-based material has received increasing attention. In this work, a novel Chinese medicine residue carbon-based nano zero-valent iron composite (CM-nZVI) had been successfully prepared using the combined Chinese medicine residue, FeCl 3 and green tea extract. Cr(VI) and/ or Cd(II) removal in water by the CM-nZVI were systematacially investigated with a series of batch experiments. The most relevant findings indicated the adsorption efficiecy and capacity of Cr(VI) by CM-nZVI were respecitvely nearly 98% and 26 mg/g under optimized reaction conditions. The negative influences of the cations on the Cr(VI) removal followed the order of Al 3+  > Ca 2+  > Mg 2+ Na +  > K + , but the anions followed the order of HCO 3 -  > PO 4 3-  > NO 3 -  > Cl -  > SO 4 2- . Humic acid (HA) and ionic strength with high concentrations severely inhibited Cr(VI) removal. The Cr(VI) adsorption on CM-nZVI fitted well by the pseudo-second-order kinetic and Langmuir models. A monolayer endothermic chemisorption occurred on Cr(VI) adsorption over CM-nZVI, and Cr(VI) removal by CM-nZVI primarily involved in the absorption, reduction, precipitation and complexation processes. Both Cr(VI) and Cd(II) removals had been achieved by CM-nZVI at their low concentrations. This CM-nZVI showed a better reusability proprity for Cr(VI) and Cd(II) removal with the regeneration of CM-nZVI through simple pickling. The outcomes of this work show that CM-nZVI could be used an effective material for heavy metals removal from water., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Wastewater irrigation is becoming a massive challenge for sustainable agriculture. Particularly, copper (Cu) presence in wastewater poses a great threat to the food chain quality. Thus, scientists need to address this issue by using chemical and organic soil amendments to restore the soil ecosystem. Therefore, this study aims to examine the efficacy of sulphur, compost, acidified animal manure and sesame straw biochar for Cu immobilization, adsorption and Brassica growth in wastewater irrigated soil. The current findings presented that all the soil amendments prominently improved brassica yield and significantly minimized the Cu uptake by Brassica shoots and roots in sesame straw biochar (SB) (64.2% and 50.2%), compost (CP) (48% and 32.5%), acidified manure (AM) (37% and 23.2%) and Sulphur (SP) (16% and 3.1%) respectively relative to untreated soil. In addition, Cu bioavailability was reduced by 51%, 34%, 16.6%, and 7.4% when SB, CP, AM, and SP were incorporated in wastewater irrigated polluted soil. The Cu adsorption isotherm results also revealed that SB treated soil has great potential to increase Cu adsorption capacity by 223 mg g - 1 over control 89 mg g - 1 . Among all the treatments, SB and CP were considered suitable candidates for the restoration of Cu polluted alkaline nature soil., (© 2022. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.)

The interaction of warming and soil texture on responsiveness of the key soil processes i.e . organic carbon (C) fractions, soil microbes, extracellular enzymes and CO 2 emissions remains largely unknown. Global warming raises the relevant question of how different soil processes will respond in near future, and what will be the likely regulatory role of texture? To bridge this gap, this work applied the laboratory incubation method to investigate the effects of temperature changes (10-50 °C) on dynamics of labile, recalcitrant and stable C fractions, soil microbes, microbial biomass, activities of extracellular enzymes and CO 2 emissions in sandy and clayey textured soils. The role of texture (sandy and clayey) in the mitigation of temperature effect was also investigated. The results revealed that the temperature sensitivity of C fractions and extracellular enzymes was in the order recalcitrant C fractions > stable C fractions > labile C fractions and oxidative enzymes > hydrolytic enzymes. While temperature sensitivity of soil microbes and biomass was in the order bacteria > actinomycetes > fungi ≈ microbial biomass C (MBC) > microbial biomass N (MBN) > microbial biomass N (MBP). Conversely, the temperature effect and sensitivity of all key soil processes including CO 2 emissions were significantly ( P < 0.05) higher in sandy than clayey textured soil. Results confirmed that under the scenario of global warming and climate change, soils which are sandy in nature are more susceptible to temperature increase and prone to become the CO 2 -C sources. It was revealed that clayey texture played an important role in mitigating and easing off the undue temperature influence, hence, the sensitivity of key soil processes., Competing Interests: The authors declare that they have no competing interests., (© 2022 Hassan et al.)

Risk associated with heavy metals in soil has been received widespread attention. In this study, a porous biochar supported nanoscale zero-valent iron (BC-nZVI) was applied to immobilize cadmium (Cd) and lead (Pb) in clayey soil. Experiment results indicated that the immobilization of Cd or Pb by BC-nZVI process was better than that of BC or nZVI process, and about 80% of heavy metals immobilization was obtained in BC-nZVI process. Addition of BC-nZVI could increase soil pH and organic matter (SOM). Cd or Pb immobilization was inhibited with coexisting organic compound 2,4-dichlorophenol (2,4-DCP), but 2,4-DCP could be removed in a simultaneous manner with Cd or Pb immobilization at low concentration levels. Simultaneous immobilization of Cd and Pb was achieved in BC-nZVI process, and both Cd and Pb availability significantly decreased. Stable Cd species inculding Cd(OH) 2 , CdCO 3 and CdO were formed, whereas stable Pb species such as PbCO 3 , PbO and Pb(OH) 2 were produced with BC-nZVI treatment. Simultaneous immobilization mechanism of Cd and Pb in soil by BC-nZVI was thereby proposed. This study well demonstrates that BC-nZVI has been emerged as a potential technology for the remediation of multiple heavy metals in soil., (Copyright © 2021. Published by Elsevier B.V.)

Chickpea (Cicer arietinum L.) is of prime importance because of vital source of protein as major food legume. Globally, it is cultivated on large area to meet dietary requirements of humans. Climatic extremes (erratic rainfall, extreme high and low temperature) are key restrains for its production. Optimum sowing time is considered as an important factor to address climatic variations and to attain maximum yield. Foliar application of potassium (K) has also been reported to increase resistance against abiotic stresses. Similarly, exogenous application of plant based growth substances (bio-stimulants) like moringa leaf extract (MLE) are extensively used to enhance productivity of field crops. Therefore, current study was planned to evaluate the impact of foliar applied K and MLE on growth, physiology and productivity of kabuli chickpea grown under varying sowing dates. There were two sowing dates (normal sown; November 15 and late sown; December 15, 2020). Experiment was comprised of treatments i.e. control, water spray, foliar application of K at 1%, foliar application of MLE at 3% and combined application of K and MLE. Foliar applied K and MLE significantly improved physiological, biochemical and yield attributes of kabuli chickpea cultivated under normal and late sown conditions. Increase in growth and yield attributes like plant height, number of nodules per plant, nodules dry weight, branches and pods per plant, 100- grain weight, biological and grain yield were recorded in case of combined foliar application of K and MLE in normal and late sown chickpea. Maximum improvement in gas exchange attributes (stomatal conductance and transpiration rate), chlorophyll contents, antioxidants (catalase, superoxide dismutase and ascorbate peroxidase) and osmolytes (proline) were recorded with combined application of K and MLE in both sowing dates. Thus, combined applied K and MLE can be used to enhance productivity of kabuli chickpea., Competing Interests: The authors declare no any conflict of interest.

Field-based experiments were conducted during wheat cultivation seasons of 2017-2018 and 2018-2019 to minimize the impact of hidden hunger (micronutrient deficiencies) through agronomic biofortification of two wheat cultivars with zinc and iron. Two spring-planted bread wheat cultivars: Zincol-16 (Zn-efficient) and Anaj-17 (Zn-inefficient with high-yield potential) were treated with either zinc (10 kg/ha), iron (12 kg/ha), or their combination to study their effect on some growth attributes (plant height, tillers, and spike length, etc.,), productivity, and quality. No application of zinc and iron or their combinations served as the control. Maximum Zn and Fe contents of grains were improved by sole application of Zn and Fe, respectively. A higher concentration of Ca in grains was observed by the combined application of Zn and Fe. Starch contents were found maximum by sole application of Fe. Sole or combined application of Zn and Fe reduced wet gluten contents. Maximum proteins were recorded in Anaj-17 under control treatments. Zincol-16 produced maximum ionic concentration, starch contents, and wet gluten as compared to Anaj-17. Yield and growth attributes were also significantly ( p < 0.05) improved by combined application as compared to the sole application of Zn or Fe. The combined application also produced the highest biological and grain yield with a maximum harvest index. Cultivar Anaj-17 was found more responsive regarding growth and yield attributes comparatively. The findings of the present study showed that the combined application of Zn and Fe produced good quality grains (more Zn, Fe, Ca, starch, and less gluten concentrations) with a maximum productivity of bread wheat cultivars., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2021 Hafeez, Ramzan, Khan, Ibrar, Bashir, Zahra, Rashid, Nadeem, Rahman, Shair, Ahmad, Hussain, Irshad, Al-Hashimi, Alfagham and Diao.)

The pollution of heavy metals and organic compounds has received increased attention in recent years. In the current study, a novel biochar-based iron oxide composite (FeYBC) was successfully synthesized using pomelo peel and ferric chloride solution through one-step process at moderate temperature. Results clearly demonstrate that FeYBC exhibited more efficient removal of Cr(VI) and/or phenol compared with the pristine biochar, and the maximum adsorption amounts of Cr(VI) and phenol by FeYBC could reach 24.37 and 39.32 mg g -1 , respectively. A series of characterization data suggests that several iron oxides such as Fe 2 O 3 , Fe 0 , FeOOH and Fe 3 O 4 were formed on the FeYBC surface as well as oxygen-containing groups. Thermodynamics study indicates that Cr(VI) and phenol adsorption by FeYBC were endothermic and exothermic processes, respectively. Langmuir adsorption isotherm and pseudo-second order models could better explain the Cr(VI) and phenol adsorption behaviors over FeYBC. The Cr(VI) adsorption might be primarily achieved through the ion exchange and surface complexation and reduction, whereas the π-π interaction and electron donor-acceptor complex mainly contributed to phenol adsorption. The findings indicate that the biochar-based iron oxide composites material was an efficient adsorbent for the remediation of industrial effluents containing Cr(VI) and phenol., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Soil amendment with two types of composts: animal manure (AC) and vegetable waste (VC) induced composts have potential to alleviate Cd toxicity to maize in contaminated soil. Therefore, Cd mobility in waste water irrigated soil can be addressed through eco-friendly and cost effective organic soil amendments AC and VC that eventually reduces its translocation from polluted soil to maize plant tissues. The comparative effectiveness of AC and VC at 3% rate were evaluated on Cd solubility, its accumulation in maize tissues, translocation from root to shoot, chlorophyll contents, plant biomass, yield and soil properties (pH, NPK, OM). Results revealed that the addition of organic soil amendments significantly minimized Cd mobility and leachability in soil by 58.6% and 47%, respectively in VC-amended soil over control. While, the reduction was observed by 61.7% and 57%, respectively when AC was added at 3% over control. Comparing the control soil, Cd uptake effectively reduced via plants shoots and roots by 50%, 46% respectively when VC was added in polluted soil. However, Cd uptake was decreased in maize shoot and roots by 58% and 52.4% in AC amended soil at 3% rate, respectively. Additionally, NPK contents were significantly improved in polluted soil as well as in plant tissues in both composts amended soil Comparative to control, the addition of composts significantly improved the maize dry biomass and chlorophyll contents at 3% rate. Thus, present study confirmed that the addition of animal manure derived compost (AC) at 3% rate performed well and might be consider the suitable approach relative to vegetable compost for maize growth in polluted soil., (© 2021 The Author(s).)

Cadmium contamination in croplands is recognized one of the major threat, seriously affecting soil health and sustainable agriculture around the globe. Cd mobility in wastewater irrigated soils can be curtailed through eco-friendly and cost effective organic soil amendments (biochars) that eventually minimizes its translocation from soil to plant. This study explored the possible effects of various types of plants straw biochar as soil amendments on cadmium (Cd) phytoavailability in wastewater degraded soil and its subsequent accumulation in sunflower tissues. The studied biochars including rice straw (RS), wheat straw (WS), acacia (AC) and sugarcane bagasse (SB) to wastewater irrigated soil containing Cd. Sunflower plant was grown as a test plant and Cd accumulation was recorded in its tissues, antioxidant enzymatic activity chlorophyll contents, plant biomass, yield and soil properties (pH, NPK, OM and Soluble Cd) were also examined. Results revealed that addition of biochar significantly minimized Cd mobility in soil by 53.4%, 44%, 41% and 36% when RS, WS, AC and SB were added at 2% over control. Comparing the control soil, biochar amended soil effectively reduced Cd uptake via plants shoots by 71.7%, 60.6%, 59% and 36.6%, when RS, WS, AC and SB. Among all the biochar, rice husk induced biochar significantly reduced oxidative stress and reduced SOD, POD and CAT activity by 49%, 40.5% and 46.5% respectively over control. In addition, NPK were significantly increased among all the added biochars in soil-plant system as well as improved chlorophyll contents relative to non-bioachar amended soil. Thus, among all the amendments, rice husk and wheat straw biochar performed well and might be considered the suitable approach for sunflower growth in polluted soil., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2021 The Author(s).)

In this study, bentonite-supported nZVI (B-nZVI) was used as a catalyst to activate H 2 O 2 for atrazine (ATZ) degradation in the presence of FeS 2 . Results indicated that ATZ degradation by B-nZVI/H 2 O 2 process was significantly enhanced when FeS 2 was introduced, and nearly 98% of ATZ was degraded by B-nZVI/FeS 2 /H 2 O 2 process within 60 min under the optimum conditions. ATZ degradation of B-nZVI/FeS 2 /H 2 O 2 process was much higher than the sum of B-nZVI and FeS 2 /H 2 O 2 processes. The presence of HCO 3 - , PO 4 3- and F - exhibited significant negative effects on the ATZ degradation, whereas both Cu 2+ and Ni 2+ exhibited positive effects on that. Both citric acid (CA) and ethylenediaminetetraacetic acid (EDTA) with lower concentration enhanced ATZ degradation rate, but significant suppression effects on that with higher concentration. The degradation of ATZ and 2,4-Dichlorophenol (2,4-DCP) could be simultaneously achieved in B-nZVI/FeS 2 /H 2 O 2 process under certain conditions. High soluble Fe 2+ induced an excellent decomposition of H 2 O 2 by B-nZVI and FeS 2 . OH was dominant radical, and contributed to nearly 86% of the overall ATZ removal. A total of five intermediate products of ATZ were identified, and ATZ degradation was achieved via de-alkylation and hydroxylation processes. An enhanced reaction mechanism for ATZ degradation by B-nZVI/FeS 2 /H 2 O 2 process was proposed, and B-nZVI/FeS 2 /H 2 O 2 process exhibited an excellect catalytic performance within four successive runs., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Nowadays, nanoscale zero valent iron (nZVI) has been extensively applied for the decontamination of various pollutants, but passivation of nZVI severely affects its reactivity in use. In this study, ultrasound (US)-assisted catalytic reduction of Cr(VI) by an acid mine drainage based nZVI (AMD-nZVI) coupling with FeS 2 system was systematically examined. Results show that the presence of FeS 2 and US induced a synergistic enhancement of Cr(VI) removal by AMD-nZVI. Nearly 98% of Cr(VI) removal was achieved by AMD-nZVI/FeS 2 /US process within 60 min under optimal reaction conditions. Several coexisting substances with lower concentration including Pb(II), Ni(II), bisphenol A (BPA) and 2,4-diclorophenol (2,4-DCP) could be effectively removed in simultaneous manner with Cr(VI) removal. The inhibitory order of water matrix species on Cr(VI) removal was NO 3 -  > PO 4 3-  > HCO 3 -  > Ca 2+  > Mg 2+  > Cl - , and a serious suppression effect was induced by humic acid (HA). Addition of ethylene diamine tetra-acetic acid (EDTA) and citric acid (CA) could enhance Cr(VI) removal rate. An enhanced reaction mechanism was proposed, which involved the regeneration of more Fe 2+ and H + by AMD-nZVI/FeS 2 /US process, leading to the reduction of Cr(VI) by AMD-nZVI and FeS 2 into Cr(III) species inculding Cr 2 O 3 and Cr(OH) 3 . This study well demonstrates that AMD-nZVI/FeS 2 /US process is considered as a potential candidate for the remediation of Cr(VI) in real wasterwater., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

The applicability of sludge biochar catalyst (SBC) coupling with ultrasound (US) irradiation for the simultaneous removal of Pb(II) and phenol was firstly investigated in this study. Results indicate that Pb(II) removal of SBC/US process was superior to that of SBC without US. The inhibitory order of the coexisting anions on Pb(II) removal was PO 4 3- > HCO 3 -  > NO 3 -  > F - > SO 4 2- > Cl - . Also, several coexisting metals ions inculding Cr(VI), Ni(II) and Cu(II) could be removed in a simultaneous manner with Pb(II). A high removal performance of Pb(II) by SBC/US process and its synergism with phenol oxidation had been successfully achieved. The simultaneous removal efficiencies of Pb(II) and phenol were high up to 95% within 60 min at optimum reaction conditions. Four kinds of Pb species inculding Pb 0 , PbCO 3 , PbO and Pb(OH) 2 were formed during the reaction, whereas five kinds of transformation compounds of phenol such as 1,4-benzoquinone, acetic acid, formic acid, maleic acid and propionic acid were detected. Both HO and O 2 - contributed to the oxidation of phenol by SBC/US process, but HO was dominant radical. A reaction mechanism for the synergistic removal of Pb(II) and phenol by SBC/US process involving in four stages-namely adsorption, precipitation, reduction and Fenton-like oxidation processes was proposed. This study demonstrates that SBC/US process could be considered as a potential candidate for the remediation of real wastewaters containing Pb(II) and phenol., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Recently, clean-up of resistant organic compounds has attracted growing attention. In this study, a novel heterogeneous ultrasound-enhanced sludge biochar catalyst/persulfate (BC/PS/US) process was firstly developed for the degradation of bisphenol A (BPA) in water. The results revealed that BC/PS/US process could successfully achieve a positively synergistic effect between sonochemistry and catalytic chemistry on the degradation of BPA compared to its corresponding comparative process. Nearly 98% of BPA could be degraded within 80 min at optimum reaction conditions. The coexisting substances including Cl - , SO 4 2- and NO 3 - had no obvious inhibition on the BPA degradation, whereas HCO 3 - and humic acid (HA) had significant inhibition effects on that. PS decomposition of BC/PS/US process was superior to that of BC/PS or US/PS process. Both SO 4 - and HO participated in the degradation of BPA, but SO 4 - was predominant radical in the BC/PS/US process. A possible pathway of BPA degradation was proposed, and the BPA molecule was attacked by SO 4 - and degraded into five kinds of intermediate products through hydroxylation and demethylation processes. This study helps to comprehend the application of sludge biochar catalyst as a persulfate activator for the degradation of organic compounds under ultrasound irradiation, and provides a new strategy in wastewater treatment., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Great amounts of nutrients discharged into the urbanized coastal areas, which are continuously subject to violently anthropogenic metal contamination, will result in eutrophication and hypoxic episode. In order to study the effects of dissolved oxygen (DO), salinity, nitrogen and phosphorus on the release of six metals including Zn, Pb, Cd, Cu, As and Cr from coastal sediments, a series of 60-days microcosm experiments consisting of sediments and seawater were conducted. Severe hypoxia could result in the enhanced peak values of Pb, Cd, Cu and Cr concentrations in the overlying water. A higher level of water salinity could elevate the peak value of As concentration in water column, and a higher level of nitrogen could increase the peak value of Zn concentration in water. The exchange fluxes demonstrated that the diffusion from the sediments was a dominant process during the first 10 days, However, a relative equilibrium of adsorption and precipitation in the sediment-water interface reached during the later periods. In addition, the bioavailability of the studied metals in sediments was elevated under severe hypoxia, or a high level of water salinity, or high levels of nitrogen and phosphorus. The results of linear regression analysis suggested that higher metal bioavailability in sediments could facilitate the metal release, but the process could be restrained by the higher aqueous phosphorus due to the precipitation of metal phosphates., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Herein, the application of a novel acid mine drainage-based nanoscale zero valent iron (AMD-based nZVI) for the remediation of nitrate and norfloxacin (NOR) was studied. Experimental results indicated that the catalytic reactivity of AMD-based nZVI toward nitrate reduction was superior to that of iron salt-based nanoscale zero valent iron (Iron salt-based nZVI). The presence of ultrasound irradiation could significantly enhance the reactivity toward both the nitrate reduction and NOR oxidation processes. The optimal efficiencies of nitrate and NOR by AMD-based nZVI/US process could be kept 96 and 94% within 120 min, respectively. Ammonia was identified as a major product in nitrate reduction process, while three oxidation products were observed in NOR degradation process. Both reduction reaction of nitrate from AMD-based nZVI and oxidation reaction of NOR from US-assisted Fenton system might be involved in AMD-based nZVI/US process. The AMD-based nZVI/US process showed a better performance on the removal of NOR compared with that of nitrate. The findings of the present work could be as a guide and show that AMD-based nZVI/US process is feasible for the remediation of both nitrate and NOR in real wastewater., (Copyright © 2019 Elsevier B.V. All rights reserved.)

In this study, the feasibility of a novel Ca-Ag 3 PO 4 composite with visible light irradiation for the phenanthrene (PHE) degradation and algae inactivation in artificial seawater was firstly investigated. The experimental findings revealed that Ag 3 PO 4 phase was sucessfully formed on the Ca-based material, and the presence of Ca-based material could effectively keep Ag 3 PO 4 particles stable. An excellent performance on PHE degradation or algae inactivation was observed from Ca-Ag 3 PO 4 composite under visible light irradiation. The degradation of PHE or inactivation of algae not only could be efficiently achieved in the single mode, but also could be successfully achieved in the coexisting mode. Above 96% of PHE and algae were simultaneously removed within 12 h in the Ca-Ag 3 PO 4 /visible light system. It was further observed that the degradation of PHE and/or inactivation of algae increased with the increase of Ca-Ag 3 PO 4 dosage. HO was the primary radical responsible for PHE degradation, whereas HO and Ag + released from Ca-Ag 3 PO 4 mainly contributed to the algae inactivation. A possible mechanism involving the catalytic removal of PHE and algae by Ca-Ag 3 PO 4 under visible light irradiation was proposed. This study provides helpful guide for the simultaneous removal of various pollutants in real seawater., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

In-situ study on arsenic speciation and the release kinetics in marine sediments was scarce. In this study, the distributions of labile As and their speciation in coastal sediments of Daya Bay were obtained by separate diffusive gradients in thin films (DGT) probes. Results showed that the DGT-labile As(V) was the main speciation in surface sediments (from -20 to 0 mm) with a concentration range of 0.07-3.05 μg·L -1 , while the labile As(III) was the main speciation in deep layers of sediments (from -100 to -20 mm). In coastal areas, mariculture farms was the most dominated contributor to As(V) contamination in surface sediments. Both the apparent diffusion flux estimation and the DGT induced flux in sediments (DIFS) simulation indicated that As(V) contamination in surface sediments of mariculture, harbor and petrochemical areas suffered the potential risk of As(V) release into the overlying water from sediments. DIFS modeling also found that the sediments of mariculture farms were the main sediment As pools. Linear regression analysis indicated that the mobility of As mainly attributed to the As(V) in sediments., (Copyright © 2018. Published by Elsevier B.V.)

Biodegradable plastics, as alternatives to conventional plastics, are increasingly used, but their interactions with organic pollutants are still unknown. In this study, the sorption and desorption behaviors on a type of biodegradable plastic-poly(butylene adipate co-terephtalate) (PBAT) were investigated, and at the same time two types of conventional plastics-polyethylene (PE c and PE v ) and polystyrene (PS) were used for comparison. Phenanthrene (PHEN) was chosen as one of representative organic pollutants. Results indicated that the sorption and desorption capacities of PBAT were not only higher than those of the other types of microplastics, but also higher than those of carbonaceous geosorbents. The surface area normalized results illustrated that sorption and desorption of the microplastics were positively correlated with their abundance of rubbery subfraction. The sorption kinetic results showed that the sorption rates of PBAT and PE c were higher than PE v and PS. The effects of water chemistry factors including salinity, dissolved organic matter and Cu 2+ ion on the sorption process displayed the same trend, but the degrees of influence on the four microplastics differed. The degrees of influence were mainly dependent on the abundance of rubbery subfraction for microplastics. These findings indicate that the biodegradable poly(butylene adipate co-terephtalate) microplastics are actually stronger vectors than the conventional microplastics, and crystallization characteristics of the microplastics have great influences on the vector effect., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

Cr 6+ and Pb 2+ are both highly toxic pollutants and commonly co-exist in some industrial effluents and contaminated waters. In this study, simultaneous removal of Cr 6+ and Pb 2+ by a novel sewage sludge-derived biochar immobilized nanoscale zero-valent iron (SSB-nZVI) was systematically investigated. It was well demonstrated that a porous structure was successfully formed on the SSB-nZVI when the starch was used as an additive. A synergistic effect on the adsorption and reduction over the SSB-nZVI was achieved, resulting in nearly 90 and 82% of Cr 6+ and Pb 2+ removal within 30 min, respectively. Cr 6+ was reduced prior to Pb 2+ . A low pH could accelerate the corrosion of nZVI as well as phosphate leaching. When Malachite green was added as a coexisting organic pollutant, its effective removal was found due to the formation of a Fenton-like system. The SSB-nZVI could be run consecutively three times with a relatively satisfactory performance. Most of Cr 6+ was converted into Cr 2 O 3 and Cr(OH) 3 on the SSB-nZVI surface, whereas most of Pb 2+ species existed as Pb(OH) 2 (or PbO). A possible reaction mechanism on the SSB-nZVI involved the adsorption, reduction and precipitation of both Cr 6+ and Pb 2+ over the particles. Present study sheds light on the insight of the fate and transport of Cr 6+ and Pb 2+ in aquatic environment, as well provides helpful guide for the remediation of coexistence of pollutants in real applications., (Copyright © 2018 Elsevier B.V. All rights reserved.)

In this study, a novel biochar-supported zero valent iron (BC-nZVI) was synthesized through a green method. A high performance on the simultaneous removal of Cu 2+ and bisphenol A (BPA) by a combination of BC-nZVI with persulfate (BC-nZVI/PS) system was successfully achieved. The simultaneous efficiencies of Cu 2+ and BPA could reach 96 and 98% within 60 min, respectively. Both HO• and SO 4 •- were two major reactive species in BC-nZVI/PS system, and SO 4 •- was primary radical responsible for the degradation of BPA. Four kinds of Cu species, such as Cu(OH) 2 , CuO, Cu 2 O and Cu 0 were generated via the adsorption and reduction of the BC-nZVI, whereas six kinds of products of BPA including p-isopropenyl phenol and 4-isopropylphenol were generated via the combined oxidation of SO 4 •- and HO•. The possible reaction mechanism for the simultaneous removal of Cu 2+ and BPA by BC-nZVI/PS system contained a synergistic effect between the reduction of Cu 2+ and the oxidation of BPA. This is the first report on the feasibility of the remediation of coexistence of heavy metal and organic compound in aquatic environment using the BC-nZVI/PS system., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

Contamination level, chemical fraction and ecological risk of heavy metals in sediments from Daya Bay (DYB) were conducted in this study. The results revealed that the concentration of Cr, Cu, Zn, As, Cd and Pb in sediments were in the range of 36.38-90.33, 9.54-61.32, 33.54-207.33, 7.80-18.43, 0.13-0.43 and 15.89-30.01 mg kg -1 , respectively, with bioavailable fractions of 13.29, 54.16, 47.60, 32.74, 68.14, 26.59%, respectively. A modified potential ecological risk index (MRI) was used for the ecological risk assessment, with ecological risk contribution ratios of 75.73, 14.29, 5.47, 1.74, 1.57 and 1.21% for Cd, As, Cu, Cr, Pb and Zn, respectively. The main contaminants were Cd and As, with their ecological risks "High" and "Moderate" levels, and their enrichment degrees "Moderately Severe" and "Moderate", respectively. The multivariate statistical analysis suggested that the various anthropogenic activities along the bay might contribute mainly to the heavy metals contamination in DYB., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

The negative impacts of residual antibiotics in the environment on ecosystem and human health are big concerns. However, little information is available on the antibiotic bioaccumulation in aquaculture farms. In this study, the bioaccumulative potentials of 21 antibiotics in the plasma, bile, liver and muscle of cultured fish from a typical aquaculture area were systematically investigated., Results: indicated that antibiotic distribution in the cultured fish was mainly influenced by species and specific substances. The mean values of log bioaccumulation factors (Log BAFs) for the detected antibiotics were in the range of 0.43-3.70, 0.36-4.75, -0.31-4.48, and 0.23-4.33 in the fish plasma, bile, liver and muscle tissues, respectively. For grass carp, both ciprofloxacin and enrofloxacin showed high transportability from the plasma to the muscle and liver. The correlations of various antibiotic concentrations between the plasma and the other three tissues indicated that the concentrations of ciprofloxacin and enrofloxacin in the fish tissues could be predicted by their concentrations in the plasma. Based on the calculated hazard quotients, human health risk evaluation of antibiotic exposure by fish consumption indicated that the consumption of these cultured fish posed low risks to human health., (Copyright © 2017 Elsevier B.V. All rights reserved.)

In this study, the application of FeS 2 /SiO 2 microspheres as a catalyst to activate H 2 O 2 for the degradation of ciprofloxacin (CIP) was systematically investigated. Results demonstrated that the presence of SiO 2 microspheres on the surface of FeS 2 could effectively make the reaction of aqueous Fe 2+ and H 2 O 2 smoothly continuous by controlling the release of aqueous Fe 2+ from FeS 2 . Nearly 100% of CIP was degraded after 60min under the optimum conditions. A superior performance on the CIP degradation and high reusability of the catalyst was obtained in FeS 2 /SiO 2 microspheres activated H 2 O 2 system. A low concentration of ethylene diamine tetraacetie acid (EDTA) did positively affect the degradation rate of CIP. A synergetic effect between adsorption and oxidation processes contributed to the significant enhancement of CIP degradation. Seven oxidation intermediates were identified during the CIP degradation process, and the direct HO oxidation proved to be a main CIP degradation pathway. For degradation pathway of CIP, oxidation of piperazine ring would be its first step, followed by cleavage of the heterocyclic ring. Subsequently, the substitution, hydroxylation and decarboxylation processes occurred. This is the first report on the feasibility of FeS 2 /SiO 2 microspheres activated H 2 O 2 system for the enhanced degradation of CIP., (Copyright © 2016 Elsevier B.V. All rights reserved.)

The applicability of bentonite-supported nanoscale zero-valent iron (B-nZVI) as a catalyst to activate persulfate (PS) for the simultaneous removal of Cr(VI) and phenol was systematically investigated in this study. Experimental results demonstrated that phenol degradation was significantly enhanced under acidic condition and with oxygen supply, whereas the Cr(VI) reduction was not obviously declined. The removal efficiencies of Cr(VI) and phenol in B-nZVI/PS combined system were 99.8 and 72.3%, respectively. Cr(VI) reduction and phenol oxidation was simultaneously achieved in B-nZVI/PS combined system, which provided a promising environmental treatment for industrial wastewater containing metal ions and organic compounds. An acidic condition was more favorable to the decomposition of persulfate for the production of sulfate radicals. Radical scavenging tests revealed that the predominant reactive oxygen species for phenol degradation was SO4(-), neither HO nor O2(-). A reaction mechanism, which involves the Cr(VI) removal mainly by the reduction of nZVI and the degradation of phenol mainly by the SO4(-) from the decomposition of persulfate, was proposed. These findings revealed that B-nZVI/PS combined system has a potential in the environmental remediation polluted jointly by organic compounds and/or heavy metals., (Copyright © 2016 Elsevier B.V. All rights reserved.)

Thirty surface sediments and three sediment cores were collected from mangrove wetlands in the Pearl River Estuary of South China to investigate the spatial and vertical distribution of Dechlorane Plus (DP). DP concentrations in the mangrove surface sediments ranged from 0.0130 to 1.504 ng/g dry weight (dw). DP concentrations in sediments from Shenzhen were significantly greater than those from Guangzhou and Zhuhai. Anti-Cl11-DP, the dechlorinated product of anti-DP, was also detected in the mangrove sediments with concentrations ranged from not detected to 0.0198 ng/g dw. Significant positive relationship between anti-Cl11-DP and anti-DP levels was observed in the mangrove sediments, suggesting that photo and/or microbial degradation of anti-DP might occur in the sediments. The f anti values in the mangrove sediments were close to those in the technical DP products, suggesting that stereoselective enrichment of anti-DP may not exist in the mangrove sediments. DP concentrations in the mangrove sediment cores generally showed an increasing trend from the bottom to top layers. This is the first study to report the occurrence of DP and its degradation product in the mangrove wetlands.

Sediments were collected from three mangrove wetlands in the Pearl River Estuary (PRE) of South China to investigate spatial and temporal distributions of polybrominated diphenyl ethers (PBDEs), decabromodiphenyl ethane (DBDPE) and 1,2-bis(2,4,6-tribromophenoxy)ethane (BTBPE). Concentrations of ΣPBDEs, DBDPE and BTBPE in mangrove sediments of the PRE ranged from 1.25-206, 0.364-34.9, and not detected-0.794 ng g(-1) dry weight, respectively. The highest concentrations of ΣPBDEs, DBDPE and BTBPE were found at the mangrove wetland from Shenzhen, followed by Zhuhai and Guangzhou, showing the dependence on the proximity to urban areas. PBDEs were the predominant brominated flame retardants (BFRs) in mangrove sediments. The concentrations of ΣPBDEs, DBDPE and BTBPE in sediment cores showed an increasing trend from the bottom to top layers, reflecting the increasing usage of these BFRs. The inventories of ΣPBDEs, DBDPE and BTBPE in mangrove sediments were 1962, 245, and 4.10 ng cm(-2), respectively. This is the first study to report the occurrence of DBDPE and BTBPE in mangrove ecosystems., (Copyright © 2014 Elsevier Ltd. All rights reserved.)

A novel two-compartment photo-electro-chemical catalytic reactor was designed. The TiO2/Ti thin film electrode thermally formed was used as photo-anode, and graphite as cathode and a saturated calomel electrode (SCE) as the reference electrode in the reactor. The anode compartment and cathode compartment were connected with the ionic exchange membrane in this reactor. Effects of initial pH, initial concentration of malachite green and connective modes between the anode compartment and cathode compartment on the decolorization efficiency of malachite green were investigated. The degradation dynamics of malachite green was studied. Based on the change of UV-visible light spectrum, the degradation process of malachite green was discussed. The experimental results showed that, during the time of 120 min, the decolouring ratio of the malachite green was 97.7% when initial concentration of malachite green is 30 mg x L(-1) and initial pH is 3.0. The catalytic degradation of malachite green was a pseudo-first order reaction. In the degradation process of malachite green the azo bond cleavage and the conjugated system of malachite green were attacked by hydroxyl radical. Simultaneity, the aromatic ring was oxidized. Finally, malachite green was degraded into other small molecular compounds.