Search

Biochar materials have shown great potential for broad catalytic application. However, using these materials in the capacitive deionization technology (CDI) system for heavy metal removal still faces a significant challenge due to their low specific capacity and removal capability. Here, a comprehensive regulation on the interfacial/bulk electrochemistry of biochar by Zn doping is reported, which suggests a high renewable capacity (20 mg g -1 ) and outstanding selective capacitive removal ability (SCR) of Pb 2+ from leachate. The SCR efficiency of Pb 2+ is as high as 99% compared to K + (8%), Na + (13%), and Cd 2+ (37%). This work proves that the doped Zn on the biochar can combine with OH - generated by water splitting to form M─OH bonds, which is beneficial for improving the specific capacity. Significantly, the relationship between double-layer capacitance and pseudo-capacitance can also be optimized by regulating the content of Zn, leading to different removal abilities of heavy metals. Therefore, this work offers insights into charge-storage kinetics, which provide valuable guidelines for designing and optimizing the biochar electrode for broader environmental applications., (© 2024 Wiley‐VCH GmbH.)

Heavy metal pollution treatment in industrial wastewater is crucial for protecting biological and environmental safety. However, the highly efficient and selective removal of heavy metal ions from multiple cations in wastewater is a significant challenge. This work proposed a pulse electrochemical method with a low-/high-voltage periodic appearance to selectively recover heavy metal ions from complex wastewater. It exhibited a higher recovery efficiency for heavy metal ions (100% for Pb 2+ and Cd 2+ , >98% for Mn 2+ ) than other alkali and alkaline earth metal ions (Na + , Ca 2+ , and Mg 2+ were kept below 3.6, 1.3, and 2.6%, respectively) in the multicomponent solution. The energy consumption was only 34-77% of that of the direct current electrodeposition method. The results of characterization and experiment unveil the mechanism that the low-/high-voltage periodic appearance can significantly suppress the water-splitting reaction and break the mass-transfer limitation between heavy metal ions and electrodes. In addition, the plant study demonstrates the feasibility of treated wastewater for agricultural use, further proving the high sustainability of the method. Therefore, it provides new insights into the selective recovery of heavy metals from industrial wastewater.

Mycotoxin contaminations in food and environment seriously harms human health. Constructing sensitive and point-of-test early-warning tools for mycotoxin determination is in high demand. In this study, a CuCo@PDA nanozyme-based aptamer-mediated lateral flow assay (Apt-LFA) has been elaborately designed for on-site and sensitive determination of mycotoxin Aflatoxin B1 (AFB1). Benefiting from the rich functional groups and excellent peroxidase-like activity, the CuCo@PDA with original dark color can be conjugated with the specific recognition probe (i.e., aptamer), generating colorimetric signal on the test lines of Apt-LFA via a competitive sensing strategy. The signal can further be amplified in-situ by catalytic chromogenic reaction. Therefore, a visual and dual-readout detection of AFB1 has been realized. The developed Apt-LFA provides a flexible detection mode for qualitative and quantitative analysis of AFB1 by naked-eyes observation or smartphone readout. The smartphone-based LFA platform shows a reliable and ultrasensitive determination of AFB1 with the limit of detection (LOD) of 2.2 pg/mL. The recoveries in the real samples are in the range of 95.11-113.77% with coefficients of variations less than 9.84%. This study provides a new approach to realize point-of-test and sensitive detection of mycotoxins in food and environment using nanozyme-based Apt-LFAs., Competing Interests: Declaration of Competing Interest No conflict of interest exits in the submission of this manuscript, and the manuscript is approved by all the authors for publication. We would like to declare that this work described is original research that has not been published previously, and not under consideration for publication elsewhere, in whole or in part., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Surfactant-like contaminants (SLCs) with distinctive amphiphilic structures have become a global concern in wastewater due to their toxicity and persistency. Despite extensive efforts, achieving efficient and selective SLCs removal remains challenging because of their wide range of molecular weights and complex functional group compositions. Superhydrophobic nanoparticles can potentially tackle this challenge by targeting the long oleophilic chains of SLCs. However, conventional contact angle measurements hinder hydrophobicity characterization and corresponding selectivity research because of the powder morphology of nanoparticles. Herein, the authors offered information regarding the distribution of water molecular probes in surfaces and proposed a quantitative characterization approach based on low-field nuclear magnetic resonance. Through synthesizing superhydrophobic and hydrophilic polydopamine nanospheres with similar morphologies, the selective adsorption potential of superhydrophobic nanoparticles for SLCs is systematically demonstrated. As revealed by the interaction mechanisms, the superhydrophobic surface of nanospheres increased its affinity and selectivity for SLCs adsorption by enhancing hydrophobic interactions. Superhydrophobic modification achieved ten times the adsorption capacity of sodium dodecyl benzene sulfonate, an exemplified surfactant, compared with pristine nanoparticles. By regulated self-polymerization, the superhydrophobic nanospheres are coated onto the surface of a 3D sponge and enable efficient selective SLCs adsorption from highly polluted leachate matrices with long-term stability and reusability., (© 2023 Wiley-VCH GmbH.)

Exploring the vegetation carbon cycle and the factors influencing vegetation carbon sequestration in areas with complex plateau-basin topography and fragile ecosystems is crucial. In this study, spatial and temporal characteristics of carbon sequestration by vegetation in Sichuan and Chongqing from 2010 to 2020 and the influencing factors were investigated through simulations of net primary productivity (NPP) using the modified Carnegie-Ames-Stanford approach (CASA) and the Thornthwaite Memorial (TM) model and using chemical equations of photochemical reactions. The results indicated that: The spatial distribution of carbon sequestration capacity (CSC) trends showed an increase in the east (the most prominent increased trend along the mountainous areas of the basin) and a decrease in the west (western Sichuan plateau). Differences exist in the impact factors of CSC in different regions. In the basin margins and mountainous areas, where the proportion of forests was high, a combination of climate change and human activities contributed to the increase in CSC. The relatively warm and humid meteorological conditions in the hinterland of the basin were more conducive to the increase in CSC, and climate change also affected the region more significantly. In contrast, in the relatively high altitude of western Sichuan, controlled human activities were the key to improving CSC. The results of the study contribute to the understanding of the basic theory of vegetation carbon cycle in areas with complex plateau-basin topography and fragile ecosystems, as well as to provide suggestions for ecological shelter construction and ecological restoration in the upper Yangtze River., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Inc. All rights reserved.)

Thallium is widely used in industrial and agricultural development. However, there is still a lack of systematic understanding of its environmental hazards and related treatment methods or technologies. Here, we critically assess the environmental behavior of thallium in aqueous systems. In addition, we first discuss the benefits and limitations of the synthetic methods of metal oxide materials that may affect the practicality and scalability of TI removal from water. We then assess the feasibility of different metal oxide materials for TI removal from water by estimating the material properties and contaminant removal mechanisms of four metal oxides (Mn, Fe, Al, and Ti). Next, we discuss the environmental factors that may inhibit the practicality and scalability of Tl removal from water. We conclude by highlighting the materials and processes that could serve as more sustainable alternatives to TI removal with further research and development.

Antibiotic residues in the environment and in foods pose a serious threat to ecosystems and human health. Developing sensitive and on-site detection methods is therefore in high demand. In this work, a portable paper-based colorimetric sensor with a smartphone platform with an ultrahigh sensitivity has been designed for on-site and quantitative analysis of antibiotic residues based on aptamer-regulated nanozyme activity. The developed excellent peroxidase-like nanozymes, carbon-protected NiCo bimetal oxides with a unique hollow nanocage structure (NiCo@C HCs), could effectively catalyze the oxidation of chromogenic substrates by H 2 O 2 . Once bound to a specific aptamer, the enzyme-mimicking activity of NiCo@C HCs is obviously inhibited as a result of the masking of active sites but could be restored via the target-aptamer recognition. Herein, the aptamer-modified NiCo@C HCs are embedded on paper pieces to construct paper-based biochips for visual detection. Meanwhile, a smartphone platform is integrated for the signal readout. Using enrofloxacin (ENR) as an analyte model, the proposed paper-based analysis platform shows a reliable and sensitive detection of ENR with an ultralow detection limit of 0.029 ng/mL. The platform also works well in various real samples. This analysis method is facile in design, showing a great application potential for on-site and mass screening of antibiotic residues in the environment and in foods.

In this study, a novel and efficient heterogeneous electro-Fenton (EF) process with a potassium ferrate (K 2 FeO 4 ) modified carbon felt (Fe-CF) cathode was developed for chloramphenicol (CAP) removal. The catalytic activity was assessed by the comparison of different systems and the effects of multiple operating parameters (K 2 FeO 4 dosage, initial solution pH, applied current) and co-existing constituents. Results indicated that the Fe-CF cathode exhibited excellent performance for CAP degradation (almost 100% removal efficiency within 60 min) over a wide range of pH (pH 3-9) during heterogeneous EF ascribed to the synergistic effect of embedded iron species and porous graphitic carbon structure and effective utilization of the in-situ generated H 2 O 2 . Moreover, the Fe-CF cathode possessed good recyclability with low metal leaching (98.2% CAP removal efficiency after reused for 5 times) and outstanding real water application performance. The ∙OH and O 2 ∙ - were responsible for CAP degradation, while ∙OH played a main role. Moreover, the toxicity evaluation by E. coli growth experiments demonstrated an efficient toxicity reduction in this system. Overall, a novel heterogeneous EF functional cathode with superior performance was fabricated via a green, low-cost one-step method, which shows promising application potential for actual wastewater treatment., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

Accurate on-site analysis of food quality, environmental pollutants, and disease biomarkers is of great significance for safeguarding public health. In this work, based on the novel nanozymes, MnCo oxides@carbon yolk-shell nanocages (MnCo@C NCs), a portable colorimetric sensor with smartphone platform has been developed for rapid, on-site and quantitative analysis of total antioxidant capacity (TAC) and phenolic compounds. The MnCo@C NCs are synthesized via one-step calcination of polydopamine-coated MnCo Prussian blue analogs (MnCo-PBA@PDA). The PDA-derived carbon shell is found to be able to protect the nanocages from collapsing, thus increasing their specific surface areas and porosity. Benefiting from the unique structure and multivalent MnCo bimetallic oxides, the MnCo@C NCs perform outstanding catalytic performance and multiple enzyme-mimicking activities including oxidase, laccase and catalase. Hence, a multifunctional application platform integrated smartphone has been constructed for rapid and sensitive colorimetric detection of three model analytes (i.e., ascorbic acid (AA), 2,4-dichlorophenol (2,4-DP), and epinephrine) with extremely low detection limits of 0.29 μM, 0.76 μM, and 0.70 μM, respectively. This sensor device is successfully applied in TAC analysis in vegetables, fruits, and beverages, as well as epinephrine determination in human serum samples. This work provides new insights into designing multifunctional nanozymes to advance the instant detection technology in the field of food supervision, environment monitoring, and human health., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The Fenton-like processes are considered to be one of the most promising strategies for inactivating bacteria due to their capacity to produce reactive oxygen species (ROS). Herein, a catalytic system for efficient inactivation of Escherichia coli (E. coli) was developed by anchoring single-atom Ru on layered double hydroxides (LDH). The Ru/NiFe-LDH catalyst showed excellent performance in activating peroxymonosulfate (PMS) to inactivate E. coli. Under the combined action of the ultra-low concentrations of Ru/NiFe-LDH (40 mg/L) and PMS (5 mg/L), 7 log E. coli can be totally inactivated within 90 s. This was attributed to the combined effect of single-atom Ru adsorption to E. coli and the ROS produced in situ. Mechanism studies indicated that the 1 O 2 with electrophilic properties was the key active species responsible for the rapid inactivation of E. coli. The E. coli inactivation process suggested that the ROS produced first attacked the outer membrane of the cell, then the antioxidant enzymes in the cell were induced, the macromolecule substances were released and mineralized, eventually leading to irreversible cell death. This work firstly loads monoatomic Ru on LDH for bacterial inactivation, providing a feasible method for rapid inactivation of E. coli., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The design of a photocatalyst for efficient algal inactivation under visible light is essential for the application of photocatalysis to the control of harmful algal blooms. In this study, a novel Z-scheme heterojunction tubular photocatalyst, Ag 2 O@PG, was synthesized by chemically depositing silver oxide compounded with P-doped hollow tubular graphitic carbon nitride for the photocatalytic inactivation of Microcystis aeruginosa (M. aeruginosa). The photocatalytic algal inactivation experiments showed that the photocatalytic activity of Ag 2 O@PG was influenced by the ratio of the composition of the obtained materials. The optimal algal inactivation efficiency was observed when using Ag 2 O@PG-0.4 at a dosage of 0.2 g/L. It was able to achieve a 99.1 % M. aeruginosa inactivation at an initial concentration of 4.5 × 10 6 cells/mL following 5 h' visible light irradiation. During the process, the cell membrane permeability and cell morphology changed. Furthermore, under the constant attack of superoxide radicals and holes caused by Ag 2 O@PG, the superoxide dismutase, glutathione and malondialdehyde of algae cells increased during the experiments to alleviate oxidative damage. Eventually, the antioxidant system of algae cells was destroyed. To further validate the potential application of Ag 2 O@PG-0.4 in real algal bloom environment, an experiment in real water samples was carried out. Overall, the Ag 2 O@PG-0.4 as an efficient photocatalyst has a promising potential for emergency treatment measures to alleviate algal blooms., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Inc. All rights reserved.)

The problems of high salinity and coexistence of antibiotics in mariculture wastewater pose a great challenge to the traditional wastewater treatment technology. Herein, an electrocatalytic system based on cathodes to sustain reactive chlorine species (RCS) in a high chlorine environment was proposed. The results show that the content of RCS is affected by cathodes. The electrocatalytic system with FeNi/NF as cathode has the largest RCS retention capacity when compared with other cathode systems (carbon felt, nickel foam, copper foam, stainless steel, and nickel-iron foam). This is related to FeNi/NF's higher hydrogen production activity, which inhibits the reduction reaction of RCS. Furthermore, the degradation of tetracycline by the proposed FeNi/NF system maintained long-term effective performance across 20 cycles. Thus, the application of high chlorine resistance electrocatalysis system provides a possibility for practical electrocatalysis treatment of mariculture wastewater., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Iron-cobalt layered double hydroxides (FeCoLDH) showed superior oxygen evolution reaction (OER) performance, but the sluggish water adsorption and dissociation dynamics restrict its capacity to degrade organic pollutants by electro-oxidation. Herein, enhanced electro-oxidation performance of FeCoLDH with hydrophilic structure was designed and exhibited efficient removal efficiency of tetracycline. Theoretical calculation and characterization results consistently elucidated that the electronic structure of FeCoLDH is optimized by doping phosphorus and depositing copper nanodots (NDs). In addition, the obtained Cu NDs/P-FeCoLDH shows higher degradation ability of tetracycline in all-pH conditions than pristine FeCoLDH. That's because it owns smaller barrier with 0.6 eV to generate hydroxyl radicals (•OH) than pristine FeCoLDH. Furthermore, it can effectively degrade organic pollutants in seawater, river water and pharmaceutical wastewater samples. This work provides novel and rational electrode materials for electro-oxidation system with practical application potential, which could offer new insights into the fundamental understanding of electrochemistry., (Copyright © 2022 Elsevier B.V. All rights reserved.)

The photo-Fenton-like catalytic process has shown great application potential in environmental remediation. Herein, a novel photo-Fenton-like catalyst of Bi 2 WO 6 nanosheets decorated hortensia-like CoAl-layered double hydroxides (Bi 2 WO 6 /CoAl-LDHs) was synthesized via hydrothermal process. The optimized Bi 2 WO 6 /CoAl-LDHs composite performed the high-efficiency photo-Fenton-like catalytic performance for oxytetracycline (OTC) removal (98.47%) in the mediation of visible-light and H 2 O 2 . The comparative experiment, technical characterization and density functional theory calculation results indicated that the efficient photo-Fenton-like catalytic performance of Bi 2 WO 6 /CoAl-LDHs was attributed to the synergistic action of the Fenton-like process of cobalt ions in CoAl-LDHs, an internal electric field and the S-scheme heterojunction form between Bi 2 WO 6 and CoAl-LDHs, which could significantly promote the active substance formation and the photocatalytic process in the catalytic system. This study will stimulate the new inspiration of designing the efficient catalytic system for environmental remediation and other fields., (Copyright © 2021. Published by Elsevier Ltd.)

Finding a low cost and effective alternative to noble metal based catalyst has long been concerned in wastewater treatment and organic transformation. This work developed a highly efficient sewage sludge-based catalyst via a simple one-step pyrolysis method, and for the first time, applied it in the catalytic reduction of nitrophenols. Due to the higher content of graphitic nitrogen, abundant defect sites and low electron transfer resistance, sewage sludge derived biochar obtained at 800 °C (SSBC-800) exhibits the best catalytic performance, with the reaction rate of 0.48 min -1 and turnover frequency for 4-nitrophenol calculated to be 1.25 × 10 -4 mmol•mg -1 min -1 , which is comparable to or even superior than some reported noble metal-based catalyst. Moreover, SSBC-800 showed good recyclability of 90% 4-nitrophenol removal within 8 min after 4 runs, and maintained high catalytic activity in reduction of other substituent nitrophenols, such as 2-nitrophenol (0.54 min -1 ), 3-nitrophenol (0.61 min -1 ) and 2,4-dinitrophenol (0.18 min -1 ), and in real water samples, indicating its practical applicability. The electron paramagnetic resonance spectra and electrochemical characterization demonstrate that SSBC-800 accelerates the dissociation of BH 4 - to form active hydrogen, which is the main species responsible for 4-nitrophenol reduction, while electron transfer reaction involving the surface bound hydride derived from the intimate contact between BH 4 - and SSBC-800 plays an important role in this process. This research not only provides a novel valorization pathway for sewage sludge, but also sheds new light on further designing of carbon-based catalyst for nitrophenol reduction., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Low-cost biochar adsorbent owning great potential for environmental remediation faces a bottleneck in application for its unsatisfied adsorption performance. Compared to the efforts on increasing adsorption capacity, improving adsorption speed which is important for treatment efficiency is often neglected. Herein, a hierarchical porous biochar (HPB) derived from shrimp shell was prepared and exhibited good adsorption capacity (Q m >300 mg/g) and fast adsorptive equilibrium (≤10 min) towards three typical aromatic organics, whose adsorption universality was further proved by two-way ANOVA analysis. Whereafter, model analysis demonstrated that, the adsorptive forms (mono- and multi-layers) on HPB depended on whether the contaminant is charged. Compared to the benzene-ring site of organics, the charged site contributed 5.13 times to adsorption promotion in monolayer but -0.49 times in inhibition for multilayers forms. Simultaneously, functional group sites contributed relatively weak (0.023 to 0.342 times only). Following structural control revealed that, hierarchical pore structure of HPB was the key for the fast adsorption speed, and highly graphitic structure was important for the high adsorption capacity. This study aims to provide an advanced biochar adsorbent, not only in adsorption capacity but also in adsorptive speed, and reveal the relationship between the structure and adsorption performance of biochar., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Herein, we developed an unmodified hexagonal boron nitride (h-BN) photoelectrochemical (PEC) biosensing platform with a low background signal and high sensitivity based on CuS quantum dots (QDs)/Co 3 O 4 polyhedra-driven multiple signal amplifications. The prepared porous h-BN nanosheets with large specific surface areas, as the photoelectric substrate material, can provide extensive active reaction sites. Meanwhile, the CuS QDs/Co 3 O 4 polyhedra were synthesized by the zeolitic imidazolate framework (ZIF-67) and utilized as a multiple signal amplifier, which can not only drive the p-n semiconductor quenching effect to compete with the h-BN photoelectrode for the consumption of electron donors and exciting light but also trigger a mimetic enzymatic catalytic precipitation effect to inhibit electron transfer. The quenching ability and peroxidase-like activity of CuS QDs/Co 3 O 4 polyhedra were evaluated to prove its superiority, and the possible mechanisms of electron transfer and enzymatic catalytic were further analyzed in detail. The developed PEC biosensing platform for the chlorpyrifos assay presented outstanding performance with a wide linear range from 1 × 10 -1 to 1 × 10 7 ng mL -1 and a low detection limit of 0.34 pg mL -1 and exhibited excellent selectivity, reproducibility, and stability. In addition, the CuS QDs/Co 3 O 4 polyhedra-activated h-BN PEC biosensing platform may exhibit universality for various analytes via replacing the corresponding target aptamer sequence. This work provides a remarkable inspiration and valuable reference for the development of the PEC biosensor, and the signal amplifier-enabled unmodified PEC biosensing platform strategy has a bright application in early safety warning, bioanalysis and clinical diagnosis.

To explore a green, low-cost, and efficient strategy to synthesis reduced graphene oxide (RGO), the process and mechanism of the graphene oxide (GO) reduction by a model electrochemically active bacteria (EAB), Geobacter sulfurreducens PCA, were studied. In this work, up to 1.0 mg mL -1 of GO was reduced by G. sulfurreducens within 0.5-8 days. I D /I G ratio in reduced product was similar to chemically RGO. After microbial reduction, the peak which corresponded to the reflection of graphene oxide (001) disappeared, while another peak considered as graphite spacing (002) appeared. The peak intensity of typical oxygen function groups, such as carboxyl C-O and >O (epoxide) groups, diminished in bacterially induced RGO comparing to initial GO. Besides, we observed the doping of nitrogen and phosphorus elements in bacterially induced RGO. In a good agreement with that, better electrochemical performance was noticed after GO reduction. As confirmed with differential pulse voltammetry (DPV) and cyclic voltammetry (CV) analysis, the maximum value of peak currents of bacterially induced RGO were significantly higher than those of GO. Our results showed the electron transfer at microbial cell/GO interface promoted the GO reduction, suggesting a broader application of EAB in biological mediated production of RGO., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Pollution of Sb(III) in water has caused great concern in recent years. Nanoscale zero-valent iron (nZVI) can detoxify Sb(III) polluted water, but the rapid passivation and low adsorption capacity limit its practical application. Hence, this study provides a new and efficient nanotechnology to remove Sb(III) using the sulfidated nanoscale zero-valent iron (S-nZVI). The S-nZVI exhibits higher Sb(III)-removal efficiency than pristine nZVI under both aerobic and anoxic conditions. The adsorption capacity of Sb(III) by optimized S-nZVI (465.1 mg/g) is 6 times as high as that of the pristine nZVI (83.3 mg/g) under aerobic conditions. The results indicate that Sb(III) and Sb(V) can be immobilized on the surface of S-nZVI by forming Fe-S-Sb precipitates. Moreover, characterization results demonstrate that the existence of S 2- can not only activate H 2 O 2 to produce hydroxyl radical, but also accelerate the cycle of Fe 3+ /Fe 2+ to improve the efficiency of Fenton reaction. Therefore, S-nZVI can produce more hydroxyl radicals to oxidize Sb (III) to Sb (V) and results in 2.3-fold higher oxidation rate of Sb(III) compared to pristine nZVI. The formed FeS layer on the S-nZVI surface can also improve the release ability of Fe 2+ and accelerate the formation of nZVI corrosion products. S-nZVI thus holds great potential to be applied in antimony removal., Competing Interests: Declaration of competing interest The authors declared that they have no conflicts of interest to this work. We declare that we do not have any commercial or associative interest that represents a conflict of interest in connection with the work submitted., (Copyright © 2020 Elsevier B.V. All rights reserved.)

The rise in manufacture and use of carbon nanotubes has aroused the concern about their potential risks associated with coexisting pollutants in the aquatic environment. 2,4-dichlorophenol (2,4-DCP), with a high toxicity to many aquatic organisms, is a widespread pollutant resulting from the extensive use of pesticides and preservatives. In this article, the adsorption of 2,4-DCP by riverine sediment and the responses of sediment microbial community to 2,4-DCP were studied in the presence of multi-walled carbon nanotubes (MWCNTs). Adding MWCNTs significantly increased the adsorption amount of sediment for 2,4-DCP from 0.541 to 1.44 mg/g as the MWCNT concentration increased from 0 to 15 mg/g. The responses of sediment microbial community were determined after one-month exposure to MWCNTs at different concentrations (0.05, 0.5, 5, and 50 mg/g). The microbial biomass carbon in the sediment contaminated with 2,4-DCP increased in the presence of 5 mg/g of MWCNTs (from 0.06 to 0.11 mg/g), but not significantly changed at other MWCNT concentrations. For the sediments contaminated with 2,4-DCP, the presence of MWCNTs made no difference to urease activity, while the dehydrogenase activity slightly increased with the addition of 5 mg/g of MWCNTs and decreased in the presence of 50 mg/g of MWCNTs. The changes of sediment bacterial communities were further determined by 16S rRNA gene sequencing. Based on the weighted UniFrac distance between communities, the clustering analysis suggested that the contamination of 2,4-DCP affected the bacterial community structure in a greater degree than that caused by MWCNTs at relatively low concentrations (≤5 mg/g). Bacteroidetes, Planctomycetes, and Nitrospirae were feature bacterial phyla to reflect the effects of MWCNTs and 2,4-DCP on sediment bacterial community. These results may contribute to the understanding of microbial community response to co-exposure of MWCNTs and 2,4-DCP and the assessment of associated ecological risks., (Copyright © 2020 Elsevier B.V. All rights reserved.)

The good performance of base metal catalysts for the electrooxidation of organic pollutants has attracted great attention. However, base metal phosphides for electrooxidation are seldom studied owing to the sluggish water adsorption and dissociation dynamics, which will hinder the production of the sorbed hydroxyl radicals (M( • OH)) and thus inhibit the electrooxidation of organic pollutants. Herein, we proposed a universal strategy to improve the electrooxidation capability of metal phosphides by modulating the surface electron densities. The electron interactions between cobalt (Co) and phosphorus (P) are modulated after iron doping, resulting in more positively charged Co and more negatively charged P, which can promote the adsorption and activation of water molecules and produce large quantities of M( • OH). Meanwhile, the experimental results show that the iron-modulated Fe 0.53 Co 0.47 P nanosheet arrays exhibit higher removal efficiency of tetracycline than the boron-doped diamond and Pt anode at low current intensity. Based on experimental results and density functional theory + U calculations (DFT + U ), it is found that Fe 0.53 Co 0.47 P has lower barrier (0.45 eV) to form the sorbed hydroxyl radicals (M( • OH)) and higher overpotential to produce O 2 than its counterparts, suggesting that Fe 0.53 Co 0.47 P can produce more M( • OH) instead of O 2 . The above results highlighted the feasibility of these base metal phosphides for electrooxidation for advanced water purification.

The degradation of norfloxacin by Fenton reagent with core-shell Fe@Fe 2 O 3 nanomaterials was studied under neutral conditions in a closed batch system. Norfloxacin was significantly degraded (90%) in the Fenton system with Fe@Fe 2 O 3 in 30 min at the initial pH 7.0, but slightly degraded in Fenton system without Fe@Fe 2 O 3 under the same experimental conditions. The intermediate products were investigated by gas chromatography-mass spectrometry, and the possible Fenton oxidation pathway of norfloxacin in the presence of Fe@Fe 2 O 3 nanowires was proposed. Electron spin resonance spectroscopy was used to identify and characterize the free radicals generated, and the mechanism for norfloxacin degradation was also revealed. Finally, the reusability and the stability of Fe@Fe 2 O 3 nanomaterials were studied using x-ray diffraction and scanning electron microscope, which indicated that Fe@Fe 2 O 3 is a stable catalyst and can be used repetitively in environmental pollution control.

The adsorbability on the carbonaceous cathode plays an important role in electro-Fenton systems but does not obtain enough attention. In this work, various carbon felts were obtained with different adsorption property by using the method of KOH activation at different temperatures to explore the influence of adsorption on the degradation efficiency of tetracycline (TC). The results of morphology characterization, nitrogen adsorption-desorption tests, XPS and FTIR analysis revealed that the surface area of carbon felt was improved, and the oxygen-containing functional groups on the surface were increased via KOH method with significantly enhanced adsorption capacity. In the batch experiment of TC electro-Fenton degradation, the carbon felt with better adsorption capacity tended to get higher degradation and mineralization efficiency. With the KOH activation process, CF-900 (carbon felt at 900 °C for 1 h) exhibited the best TC adsorption property for the removal of TC within 30 min (initial concentration: 80 mg/L). Meanwhile, the constant of reaction rate for TC degradation at the CF-900 is 0.0648 min -1 . It is higher than that (0.012 min -1 ) obtained at the raw carbon felt (∼5 times of enhancement). There are also synergistic effects between adsorption and degradation performance on some other organic pollutants. In addition, the degradation pathway was also studied by the methods of solid-phase extraction and high performance liquid chromatography-mass spectrometry (HPLC). From the obtained results, it is shown that good adsorbability is favorable for degradation in the homogeneous electro-Fenton system., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Although oxidation of As(III) to As(V) is deemed necessary to promote arsenic removal, the oxidation process usually involves toxic byproducts, well-defined conditions, energy input or sludge generation. Moreover, extra operations are required to remove the resulting As(V). A heterogeneous catalytic process of CuFe 2 O 4 with peroxymonosulfate (PMS) is established for As(III) oxidation and adsorption. The PMS can be activated by CuFe 2 O 4 to generate radical species for As(III) oxidation. The CuFe 2 O 4 /PMS has a stronger affinity for arsenic than CuFe 2 O 4 alone. Oxidation and adsorption promote each other. As a result, the heterogeneous catalytic process is more efficient for As(III) removal than a preoxidation of As(III) followed by adsorption. The adsorption capacity for As on CuFe 2 O 4 /PMS reached up to 63.9 mg/g, which is much higher than that of As(III) (36.9 mg/g) or As(V) (45.4 mg/g) on CuFe 2 O 4 alone. The process can work effectively over a wide range of pH values (3-9) and temperatures (10-40 °C). Coexisting ions such as sulfate, carbonate, silicate and humic acid have an insignificant effect on As(III) removal. The As(III) (1415 μg/L) can be completely oxidized to As(V) and rapidly removed to below 10 μg/L (less than 15 min) using CuFe 2 O 4 (0.2 g/L)/PMS(100 μM). Moreover, the As(III) (50 μg/L) can be completely oxidized and removed within 1 min. The proposed process is easily applicable for the remediation of As(III)-contaminated water under ambient conditions., (Copyright © 2018 Elsevier Ltd. All rights reserved.)

Photocatalytic degradation is an alternative method to remove pharmaceutical compounds from water, however it is hard to achieve efficient rate because of the low efficiency of photocatalysts. In this study, an efficient Z-Scheme photocatalyst was constructed by integrating graphitic carbon nitride (CN) and reduced graphene oxide (rGO) with AP via a simple facile precipitation method. Excitedly, ternary AP/rGO/CN composite showed superior photocatalytic and anti-photocorrosion performances under both intense sunlight and weak indoor light irradiation. NOF can be completely degraded in only 30 min and about 85% of NOF can be mineralized after 2 h irradiation under intensive sunlight irradiation. rGO could work not only as a sheltering layer to protect AP from photocorrosion but also as a mediator for Z-Scheme electron transport, which can protect AP from the photoreduction. This strategy could be a promising method to construct photocatalytic system with high efficiency for the removal of antibiotics under natural light irradiation., (Copyright © 2018 Elsevier B.V. All rights reserved.)

To realize the full utilization of solar energy, the design of highly efficient photocatalyst with improved visible-near-infrared photocatalysis performance has attracted great attentions for environment pollutant removal. In this work, we rationally employed the surface plasmon resonance effect of metallic Ag in the phosphorus doped ultrathin g-C 3 N 4 nanosheets (PCNS) and BiVO 4 composites to construct a ternary Ag@PCNS/BiVO 4 photocatalyst. It was applied for the photodegradation of ciprofloxacin (CIP), exhibiting 92.6% removal efficiency under visible light irradiation (λ>420nm) for 10mg/L CIP, and presenting enhanced photocatalytic ability than that of single component or binary nanocomposites under near-infrared light irradiation (λ>760nm). The improved photocatalytic activity of the prepared Ag@PCNS/BiVO 4 nanocomposite can be attributed to the synergistic effect among the PCNS, BiVO 4 and Ag, which not only improves the visible light response ability and hinders the recombination efficiency of the photogenerated electrons and holes, but also retains the strong the redox ability of the photogenerated charges. According to the trapping experiment and ESR measurements results, OH, h + and O 2 - all participated in the photocatalytic degradation process. Considering the SPR effect of metallic Ag and the established local electric field around the interfaces, a dual Z-scheme electrons transfer mechanism was proposed., (Copyright © 2017 Elsevier B.V. All rights reserved.)

High concentration of arsenic in acid wastewater and polluted river sediment caused by metallurgical industry has presented a great environmental challenge for decades. Nanoscale zero valent iron (nZVI) can detoxify arsenic-bearing wastewater and groundwater, but the low adsorption capacity and rapid passivation restrict its large-scale application. This study proposed a highly efficient arsenic treatment nanotechnology, using the core-shell Fe@Fe 2 O 3 nanobunches (NBZI) for removal of arsenic in acid wastewater with cyclic stability and transformation of arsenic speciation in sediment. The adsorption capacity of As(III) by NBZI was 60 times as high as that of nanoscale zero valent iron (nZVI) at neutral pH. Characterization of the prepared materials after reaction revealed that the contents of As(III) and As(V) were 65% and 35% under aerobic conditions, respectively, which is the evidence of oxidation included in the reaction process apart from adsorption and co-precipitation. The presence of oxygen was proved to improve the adsorption ability of the prepared NBZI towards As(III) with the removal efficiency increasing from 68% to 92%. In order to further enhance the performance of NBZI-2 in the absence of oxygen, a new Fenton-Like system of NBZI/H 2 O 2 to remove arsenic under the anoxic condition was also proposed. Furthermore, the removal efficiency of arsenic in acid wastewater remained to be 78% after 9 times of cycling. Meanwhile, most of the mobile fraction of arsenic in river sediment was transformed into residues after NBZI treatment for 20 days. The reaction mechanism between NBZI and arsenic was discussed in detail at last, indicating great potential of NBZI for the treatment of arsenic in wastewater and sediment., (Copyright © 2017 Elsevier Ltd. All rights reserved.)

Sulfidated nanoscale zerovalent iron (S-NZVI) is attracting considerable attention due to its easy production and high reactivity to pollutants. We studied the reactivity of optimized S-NZVI (Fe/S molar ratio 6.9), comparing with pristine nanoscale zerovalent iron (NZVI), at various pH solutions (6.77-9.11) towards p-nitrophenol (PNP) under aerobic and anoxic conditions. Studies showed that the optimized extent of sulfidation could utterly enhance PNP degradation compared to NZVI. Batch experiments indicated that in anoxic S-NZVI systems the degradation rate constant increased with increasing pH up to 7.60, and then declined. However, in aerobic S-NZVI, and in anoxic or aerobic NZVI systems, it decreased as pH increased. It was manifested that anoxic S-NZVI systems preferred to weaker alkaline solutions, whereas aerobic S-NZVI systems performed better in acidic solutions. The highest TOC removal efficiency of PNP (17.59%) was achieved in the aerobic S-NZVI system at pH 6.77, revealing that oxygen improved the degradation of PNP by excessive amounts of hydroxyl radicals in slightly acidic conditions, and the TOC removal efficiency was supposed to be further improved in moderate acidic solutions. Acetic acid, a nontoxic ring opening by-product, confirms that the S-NZVI system could be a promising process for industrial wastewater containing sulfide ions., (Copyright © 2016 Elsevier B.V. All rights reserved.)