1. Rapid separation of the low concentration Pd from Pd-Pt coexisting systems: Cyano-group's monomer-specific affinity.
- Author
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Liu M, Du Y, Liu Y, Li X, Yang S, Feng J, Huang Z, Chen Y, Wang B, and Chen R
- Abstract
Rapid separation of low concentration palladium (Pd) from Pd-Platinum (Pt) coexisting systems remains a formidable challenge, primarily due to the undifferentiated substitution of ligands in Pd/Pt complexes by adsorption sites. The development of an adsorbent featuring monomer-specific affinity adsorption sites for Pd/Pt could mitigate this drawback. Herein, Manganese hexacyanoferrate (MnHCF) possessing the sensitivity and specificity to Pd ions (Pd(II)) was synthesized via the facile co-precipitation method. MnHCF could rapidly and selectively capture 90.30 % of Pd(II) from a 10 ppm Pd-Pt coexisting system within just 5 min. Spectroscopic analyses and density functional theory (DFT) calculations indicated that cyano-group (CN) in MnHCF exhibited the monomer-specific affinity for targeted capturing Pd via the direct and strong coordination interaction (Fe-CN-PdCl
2 ), which was co-determined by the electron-losing of C (0.06 e) and N (0.07 e) atom. At the same time, CN could neither react directly with the fully coordinated [PtCl6 ]2- species nor substitute the Cl- ligand, both of which contributed to the non-adsorption of Pt, thus triggering the Pd-Pt separation. This study provides a promising candidate adsorbent for practical applications in platinum group metals recovery by the design of adsorption sites with monomer-specific affinity., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)- Published
- 2024
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