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Five re-circulating tracer well tests (RCTWTs) have been conducted in a variety of aquifer settings, at four sites across New Zealand. The tests constitute the first practical assessment of the two-well RCTWT methodology described by Burbery and Wang (Journal of Hydrology, 2010; 382:163-173) and were aimed at evaluating nitrate reaction rates in situ. The performance of the RCTWTs differed significantly at the different sites. The RCTWT method performed well when it was applied to determine potential nitrate reaction rates in anoxic, electro-chemically reductive, nitrate-free aquifers of volcanic lithology, on the North Island, New Zealand. Regional groundwater flow was not fast-flowing in this setting. An effective first-order nitrate reaction rate in the region of 0.09 d(-1) to 0.26 d(-1) was determined from two RCTWTs applied at one site where a reaction rate of 0.37 d(-1) had previously been estimated from a push-pull test. The RCTWT method performed poorly, however, in a fast-flowing, nitrate-impacted fluvio-glacial gravel aquifer that was examined on the South Island, New Zealand. This setting was more akin to the hypothetical physiochemical problem described by Burbery and Wang (2010). Although aerobic conditions were identified as the primary reason for failure to measure any nitrate reaction in the gravel aquifer, failure to establish significant interflow in the re-circulation cell due to the heterogeneous nature of the aquifer structure, and natural variability exhibited in nitrate contaminant levels of the ambient groundwater further contributed to the poor performance of the test. Our findings suggest that in practice, environmental conditions are more complex than assumed by the RCTWT methodology, which compromises the practicability of the method as one for determining attenuation rates in groundwater based on tracing ambient contaminant levels. Although limited, there appears to be a scope for RCTWTs to provide useful information on potential attenuation rates when reactants are supplemented to the aquifer system under examination., (Copyright © 2012 Elsevier B.V. All rights reserved.)

The relative transport and attenuation of bacteria, bacteriophages, and bromide was determined in a 5m long x 0.3m diameter column of saturated pea gravel. The velocity (V), longitudinal dispersivity (alpha(x)) and total removal rate (lambda) were calculated from the breakthrough curves at 1m, 3m, and 5m, at a flow rate of 32Lh(-1). Inactivation (mu) rates were determined in survival chambers. Two pure culture experiments with Escherichia coli J6-2 and F-RNA phage MS2 produced an overall V ranking of E. coli J6-2>MS2>bromide, consistent with velocity enhancement, whereby larger particles progressively move into faster, central streamlines of saturated pores. Removal rates were near zero for MS2, but were higher for E. coli J6-2. In two sewage experiments, E. coli and F-RNA phage Vs were similar (but > bromide). This was attributed to phage adsorption to colloids similar in size to E. coli cells. Sewage phage removal rates were higher than for the pure MS2 cultures. The application of filtration theory suggested that, whereas free phage were unaffected by settling, this was the primary removal mechanism for the colloid-associated phage. However, cultured and sewage E. coli removal rates were similar, suggesting the dominance of free E. coli cells in the sewage. When MS2 was attached to kaolin particles, it was transported faster than free MS2, but at similar rates to sewage phage. The mu values indicated little contribution of inactivation to removal of either cultured or sewage microorganisms. The results showed the importance of association with colloids in determining the relative transport of bacteria and viruses in gravels., (Copyright (c) 2010 Elsevier B.V. All rights reserved.)

The ability to quantify the mass flux of a groundwater contaminant that is leaching from a source area is critical to enable us to: (1) evaluate the risk posed by the contamination source and prioritize cleanup, (2) evaluate the effectiveness of source remediation technologies or natural attenuation processes, and (3) quantify a source term for use in models that may be applied to predict maximum contaminant concentrations in downstream wells. Recently, a number of new methods have been developed and subsequently applied to measure contaminant mass flux in groundwater in the field. However, none of these methods has been validated at larger than the laboratory-scale through a comparison of measured mass flux and a known flux that has been introduced into flowing groundwater. A couple of innovative flux measurement methods, the tandem circulation well (TCW) and modified integral pumping test (MIPT) methods, have recently been proposed. The TCW method can measure mass flux integrated over a large subsurface volume without extracting water. The TCW method may be implemented using two different techniques. One technique, the multi-dipole technique, is relatively simple and inexpensive, only requiring measurement of heads, while the second technique requires conducting a tracer test. The MIPT method is an easily implemented method of obtaining volume-integrated flux measurements. In the current study, flux measurements obtained using these two methods are compared with known mass fluxes in a three-dimensional, artificial aquifer. Experiments in the artificial aquifer show that the TCW multi-dipole and tracer test techniques accurately estimated flux, within 2% and 16%, respectively; although the good results obtained using the multi-dipole technique may be fortuitous. The MIPT method was not as accurate as the TCW method, underestimating flux by as much as 70%. MIPT method inaccuracies may be due to the fact that the method assumptions (two-dimensional steady groundwater flow to fully-screened wells) were not well-approximated. While fluxes measured using the MIPT method were consistently underestimated, the method's simplicity and applicability to the field may compensate for the inaccuracies that were observed in this artificial aquifer test.

Conventional methods to measure the hydraulic conductivity of an aquifer on a relatively large scale (10-100 m) require extraction of significant quantities of groundwater. This can be expensive, and otherwise problematic, when investigating a contaminated aquifer. In this study, innovative approaches that make use of tandem circulation wells to measure hydraulic conductivity are proposed. These approaches measure conductivity on a relatively large scale, but do not require extraction of groundwater. Two basic approaches for using circulation wells to measure hydraulic conductivity are presented; one approach is based upon the dipole-flow test method, while the other approach relies on a tracer test to measure the flow of water between two recirculating wells. The approaches are tested in a relatively homogeneous and isotropic artificial aquifer, where the conductivities measured by both approaches are compared to each other and to the previously measured hydraulic conductivity of the aquifer. It was shown that both approaches have the potential to accurately measure horizontal and vertical hydraulic conductivity for a relatively large subsurface volume without the need to pump groundwater to the surface. Future work is recommended to evaluate the ability of these tandem circulation wells to accurately measure hydraulic conductivity when anisotropy and heterogeneity are greater than in the artificial aquifer used for these studies.

Consumption of microbially contaminated ground water can cause adverse health effects and the processes involved in pathogen transport in aquifers need to be understood. The influences of distance, flow velocity, and colloid size on colloid transport were examined in homogenous pea-gravel media using an 8-m column and three sizes (1, 5, and 10 microm) of microspheres. Experiments were conducted at three flow rates by simultaneously injecting microspheres with a conservative tracer, bromide. Observed concentrations were simulated with CXTFIT and analyzed with filtration theory. The results demonstrate that colloid concentration is strongly log-linearly related to transport distance (as suggested by filtration theory) in coarse gravels, similar to our previous field studies. In contrast, the log-linear relationship is often reported to be invalid in fine porous media. The observed log-linear relationship is possibly because straining is negligible in the coarse gravels investigated. This has implications in predicting setback distances for land disposal of effluent, and suggests that setback distances in gravel aquifers can be estimated using constant spatial removal rates (f). There was an inverse relationship between transport distance and colloidal concentration, but not with temporal attachment rate (katt) and collision coefficient (alpha). Increases in flow velocity result in increasing colloidal recovery, katt and alpha but decreasing f. Increases in sphere size result in decreasing colloidal recovery with increasing katt, f, alpha, and velocity enhancement. Diffusion is the dominant collision mechanism for 1-microm spheres (81-88%), while settling dominates for 5- and 10-microm spheres (> 87%), and interception is very small for all spheres investigated.