Search

The increase in maritime traffic has led to substantial greywater discharges into the marine environment. Greywater, originating from sinks, showers, kitchen, and laundry facilities, contains a wide array of chemical contaminants influenced by on-board activities, ship size, and management practices. The lack of comprehensive regulations for greywater management, along with limited research on its chemical composition, highlights the need to characterize these waste streams. This study is one of the first to provide a comprehensive characterization of greywater samples from ships using advanced liquid chromatography coupled to high-resolution-mass-spectrometry (LC-HRMS) strategies, including wide-scope target and suspect screening. The target analysis detected 86 compounds, such as pharmaceuticals, stimulants, tobacco and food-related products, personal care products, UV filters, surfactants, perfluoroalkyl compounds, plasticizers, and flame retardants, many of which are rarely measured in routine monitoring programs. Furthermore, 11 additional compounds were tentatively identified through suspect screening. A novel scoring system further highlighted 25 priority compounds posing ecological risks to marine ecosystems, including pharmaceuticals such as tapentadol, dextrorphan, citalopram, or irbesartan. This study emphasizes the significant introduction of chemicals at μg L -1 levels through greywater discharges, underscoring the urgent need for improved management practices to mitigate ecological risks to the marine ecosystem., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier Ltd.. All rights reserved.)

This work demonstrates a thorough investigation into the synthesis and characterization of bismuth ferric oxide (BFO) photocatalyst for microwave-induced photodegradation of organic pollutants in greywater. Microwave (MW) irradiation was executed to enhance the generation of reactive oxygen species, contributing to the catalytic effectiveness of the synthesized photocatalyst. Through an efficient ultrasound-assisted synthesis process, perovskite BFO nanoparticles with a rhombohedral crystal structure and a crystallite size of around 15 nm were successfully manufactured. Comprehensive characterization employing various analytical techniques including X-ray diffraction (XRD), Energy Dispersive X-ray Analysis (EDAX), Fourier Transform Infrared and Raman Spectroscopy, UV-Visible Diffuse Reflectance Spectroscopy (UVDRS), photoluminescence spectroscopy, Scanning Electron Microscopy (SEM), and Brunauer-Emmett-Teller (BET) studies provided insights into the structural, elemental, spectral, optical, morphological, and surface area properties of the nanoparticles. The UV-vis spectroscopy and Tauc's plot were employed to elucidate the band structure of the photocatalyst, providing insights into its essential electronic properties for catalytic applications. With a narrow optical band gap of 2.13 eV, the synthesized photocatalyst demonstrated suitability for optical applications and exhibited substantial catalytic activity in the microwave-induced photocatalytic degradation of greywater. Remarkably, it achieved a 93.5% reduction in total organic carbon (TOC) within 180 min under moderate 50-W illumination. Refining process parameters through optimization studies notably augmented degradation efficiency. Scavenging investigations validated the efficient mineralization of total organic carbon content. Kinetic assessments provided mechanistic insights into improved catalytic activity of BFO, which was attributed to a changed band structure that allows for fast charge transfer across interfacial layers. Moreover, the stability and reusability of the BFO photocatalyst were assessed over five cycles, highlighting its potential practical application as an efficient and reusable photocatalyst for greywater treatment. These findings underscore the promising prospects of BFO in addressing environmental challenges and advancing sustainable wastewater treatment technologies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

The current global water crisis has prompted research into technologies that can reuse different water resources to mitigate water scarcity. The use of treated greywater can be proposed to provide additional water resources. By reusing this water in different applications, this water crisis can be mitigated at the local scale. This study presents a bibliometric analysis to assess the state of the art of greywater treatment and its reuse technologies. This analysis is based on the scientific literature published until 2023 in Scopus regarding greywater treatment and 1,024 documents were found. The results showed a clear exponential increase in the accumulated number of publications in this topic, which was spurred during the mid-1990s. The most prolific country was the United States, while China, the other typical scientific superpower in most fields, occupied the sixth position in the ranking. Environmental Sciences was the knowledge subject with more documents, followed by Engineering and Chemical Engineering. The bibliometric study was complemented using SciMAT to create bibliometric networks that represent the dynamic evolution of the themes. The most important themes were identified, among which three key points stand out: greywater characterization, technologies for greywater treatment, and water management, including the reuse of treated greywater., Competing Interests: The authors declare there is no conflict., (© 2024 The Authors This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY-ND 4.0), which permits copying and redistribution with no derivatives, provided the original work is properly cited (http://creativecommons.org/licenses/by-nd/4.0/).)

Microalgal-bacteria biofilm shows great potential in low-cost greywater treatment. Accurately predicting treated greywater quality is of great significance for water reuse. In this work, machine learning models were developed for simulating and predicting linear alkylbenzene sulfonate (LAS) removal using 152-days collected data from a battled oxygenic microalgal-bacteria biofilm reactor (MBBfR). By using nine variables including influent LAS, hydraulic retention time (HRT), biofilm density and thickness, specific oxygen production and consumption rates, microalgae and bacteria concentrations, and dissolved oxygen (DO), the support vector machine (SVM) model enabled the accurate LAS removal prediction (training set: R 2  = 0.995, (root mean square error, RMSE) = 0.076, (mean absolute error, MAE) = 0.069; testing set: R 2  = 0.961, RMSE = 0.251, MAE = 0.153). SVM can be also successfully applied for MBBfR operation optimization (HRT = 4.28 h, DO = 0.25 mg/L) that achieving accurate prediction of LAS mineralization., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The goal of this study is to examine the reactions of tomato ( Solanum lycopersicum ) plants to both untreated greywater and treated greywater filtered through a zeolite. In a randomized block arrangement, tomato plants were irrigated with greywater, treated greywater, or tap water. Number and total fecal coliforms were found in soil, tomato leaves, and fruits. Compared to tap water, greywater has higher levels of Ec, TDS, and COD. The average fruit weight and number for plants irrigated with tap water was 64.42 g and 4.2, while those irrigated with treated greywater were 55.4 g and 3.6, exceeding those irrigated with untreated greywater 39.6 g and 3.2. Treated greywater irrigation increased total chlorophyll content (SPAD) from 57.6 to 62.4 and relative water content from 49.6% to 63%. The leaves contained lower levels of proline (55.9 μmol/g) and total soluble sugar (32.24 mg/g). Researchers found total fecal coliforms in the soil, tomato leaves, and fruits. According to the research, treated greywater may prevent contamination of soil and save water.

Nitrogen (N) source is an important factor affecting biological wastewater treatment. Although the oxygen-based membrane biofilm showed excellent greywater treatment performance, how N source impacts the synchronous removal of organics and N is still unclear. In this work, how N species (urea, nitrate and ammonia) affect synchronous metabolic pathways of organics and N were evaluated during greywater treatment in the membrane biofilm. Urea and ammonia achieved efficient chemical oxygen demand (>97.5%) and linear alkylbenzene sulfonate (LAS, >98.5%) removal, but nitrate enabled the maximum total N removal (80.8 ± 2.6%). The nitrate-added system had poor LAS removal ratio and high residual LAS, promoting the accumulation of effluent protein-like organics and fulvic acid matter. N source significantly induced bacterial community succession, and the increasing of corresponded functional flora can promote the transformation and utilization of microbial-mediated N. The nitrate system was more conducive to the accumulation of denitrification related microorganisms and enzymes, enabling the efficient N removal. Combining with high amount of ammonia monooxygenase that contributing to LAS and N co-metabolism, LAS mineralization related microbes and functional enzymes were generously accumulated in the urea and ammonia systems, which achieved the high efficiency of organics and LAS removal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)

In light of increasingly diverse greywater reuse applications, this study proposes risk-based log-removal targets (LRTs) to aid the selection of treatment trains for greywater recycling at different collection scales, including appliance-scale reuse of individual greywater streams. An epidemiology-based model was used to simulate the concentrations of prevalent and treatment-resistant reference pathogens (protozoa: Giardia and Cryptosporidium spp., bacteria: Salmonella and Campylobacter spp., viruses: rotavirus, norovirus, adenovirus, and Coxsackievirus B5) in the greywater streams for collection scales of 5-, 100-, and a 1000-people. Using quantitative microbial risk assessment (QMRA), we calculated LRTs to meet a health benchmark of 10 -4 infections per person per year over 10'000 Monte Carlo iterations. LRTs were highest for norovirus at the 5-people scale and for adenovirus at the 100- and 1000-people scales. Example treatment trains were designed to meet the 95 % quantiles of LRTs. Treatment trains consisted of an aerated membrane bioreactor, chlorination, and, if required, UV disinfection. In most cases, rotavirus, norovirus, adenovirus and Cryptosporidium spp. determined the overall treatment train requirements. Norovirus was most often critical to dimension the chlorination (concentration × time values) and adenovirus determined the required UV dose. Smaller collection scales did not generally allow for simpler treatment trains due to the high LRTs associated with viruses, with the exception of recirculating washing machines and handwashing stations. Similarly, treating greywater sources individually resulted in lower LRTs, but the lower required LRTs nevertheless did not generally allow for simpler treatment trains. For instance, LRTs for a recirculating washing machine were around 3-log units lower compared to LRTs for indoor reuse of combined greywater (1000-people scale), but both scenarios necessitated treatment with a membrane bioreactor, chlorination and UV disinfection. However, simpler treatment trains may be feasible for small-scale and application-scale reuse if: (i) less conservative health benchmarks are used for household-based systems, considering the reduced relative importance of treated greywater in pathogen transmission in households, and (ii) higher log-removal values (LRVs) can be validated for unit processes, enabling simpler treatment trains for a larger number of appliance-scale reuse systems., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy R. Julian reports financial support was provided by Eawag Swiss Federal Institute of Aquatic Science and Technology. Eberhard Morgenroth reports financial support was provided by ETH Zurich. Eberhard Morgenroth reports financial support was provided by Eawag Swiss Federal Institute of Aquatic Science and Technology. Eberhard Morgenroth is Editor in Chief of Water Research. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Greywater reuse has emerged as a promising solution for addressing water shortages. However, greywater needs treatment before reuse to meet the required water quality standards. Conventional wastewater treatment technologies are unsuitable for recreating highly decentralized domestic greywater. This study evaluated bioelectrochemical reactors (BERs) with granular activated carbon (GAC) as a sustainable alternative for developing decentralized and low-cost biological treatment systems. BERs using GAC as the anode material and conventional GAC biofilters (BFs) for synthetic greywater treatment were operated in batch mode for 110 days in two stages: (i) with polarized anodes at -150 mV vs. Ag/AgCl and (ii) as a microbial fuel cell with an external resistance of 1 kΩ. Anode polarization produced an electrosorption effect, increasing the ion removal of the BERs. Power production during the operation and cyclic voltammetry tests of the extracted granules revealed electrochemically active biofilm development on the BERs. Although low power density (0.193 ± 0.052 µW m -3 ) was observed in BERs, they showed a similar performance in sCOD removal (BER = 91.6-89.6 %; BF = 96.2-93.2 %) and turbidity removal (BER = 81-82 %; BF = 30-62 %) to BFs that used 50 % aeration. Additionally, scanning electron microscopy of sampled granules showed higher biomass formation in BER granules than in BF granules, suggesting a higher contribution of sessile (vs. planktonic) cells to the treatment. Thus, the results highlight the synergistic removal effect of the GAC-based BER. The scalable design presented in this study represents a proof-of-concept for developing BERs to use in decentralized greywater treatment systems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The discharge of wastewater into ground and surface waters can cause human and ecological health problems, hence eco-friendly, sustainable and cost-effective methods for removing toxic metals from wastewater are required. The study employed coconut husk biochar and spent impra ginseng flavoured green tea to adsorb cadmium (Cd), chromium (Cr) and lead (Pb) from greywater. The adsorption capacity of coconut husk biochar ranged from 88.70 % to 98.20 % for cadmium, 78 %-96 % for chromium and 95.71 %-99.29 % for lead whilst the spent impra ginseng flavoured green tea ranged from 94.03 % to 96.87 % for cadmium, 52 %-74 % for chromium and 98.52 %-99.48 % for lead. The maximum adsorption capacity (Q e ) of coconut husk biochar ranged from 235.64 to 1132.40 mg/g for Cd, 1.31-8.80 mg/g for Cr and 58.85-415.80 mg/g for Pb. Lead demonstrated the highest affinity for the binding of coconut husk biochar and spent impra ginseng flavoured green tea adsorbent with a trend of Pb > Cd > Cr. Coconut husk biochar and spent impra ginseng flavoured green tea adsorbent were suitable for the toxic metals adsorption in the greywater. Cr showed different removal efficiencies where coconut husk biochar showed more effective removal than spent impra ginseng flavoured green tea. The application of coconut husk biochar and spent impra ginseng flavoured green tea in wastewater treatment is a green technology means and can lead to zero pollution of freshwater., Competing Interests: The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Not applicable reports was provided by University for Development Studies. Abudu Ballu Duwiejuah reports a relationship with University for Development Studies that includes: employment. Emmanuel Frimpong Adjei reports a relationship with University for Development Studies that includes: employment. Elliot Haruna Alhassan reports a relationship with University for Development Studies that includes: employment. Abudu Ballu Duwiejuah has patent pending to Abudu Ballu Duwiejuah. Not applicable If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2024 University for Development Studies.)

The management of greywater and sanitation in South Africa's urban informal settlements is a pressing concern. This review critically examines the legal framework that governs greywater management in South Africa's informal settlements, aiming to shed light on the existing regulations, gaps, and opportunities for sustainable greywater reuse. By scrutinizing the legal framework, the review identifies gaps and challenges in the regulatory environment, including inconsistencies, lack of clarity, and limited enforcement mechanisms. It explores the potential for international best practices to inform possible amendments to the existing legal framework. This was a quantitative research design utilizing a cross sectional survey model. Questionnaires were administered electronically to a sample of 17 municipal leaders from the City of Tshwane, City of Johannesburg and Buffalo City municipalities whose responsibilities were on water management. Descriptive statistics were employed in analysis of the data. Outcomes were reviewed against the alignment or the lack thereof with the SANS 1732:201x standards. This paper underscores the critical need for a coherent and robust legal framework to support responsible greywater management in South Africa's informal settlements. The paper's insights contribute to the ongoing discourse on water governance, shedding light on the pathways toward a more equitable water future., Competing Interests: The authors declare there is no conflict., (© 2024 The Authors This is an Open Access article distributed under the terms of the Creative Commons Attribution Licence (CC BY-NC-ND 4.0), which permits copying and redistribution for non-commercial purposes with no derivatives, provided the original work is properly cited (http://creativecommons.org/licenses/by-nc-nd/4.0/).)

The practical application of electrochemical oxidation technology for the removal of surfactants from greywater was evaluated using sodium dodecyl sulfate (SDS) as a model surfactant. Careful selection of electrocatalysts and optimization of operational parameters demonstrated effective SDS removal in treating a complex greywater matrix with energy consumption below 1 kWh g -1 COD (Chemical Oxygen Demand), paving the way for a more sustainable approach to achieving surfactant removal in greywater treatment when aiming for decentralized water reuse. Chromatographic techniques identified carboxylic acids as key byproducts prior to complete mineralization. These innovative approaches represent a novel pathway for harnessing electrochemical technologies within decentralized compact devices, offering a promising avenue for further advancements in this field., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2024 The Authors.)

Floating treatment wetlands are considered a promising and low-cost technology for the treatment of polluted water and wastewater. However, their functionality and efficiency in different types of wastewater are not fully understood. In this study, several ornamental plant species (monocultures: Canna sp., Iris sp., polyculture: Iris orientalis, Cyperus sp., Acorus gramineus) were tested in two different types of floating mats, including a media supported floating mat (MSFM) or a simple plastic grid, and evaluated for optimal removal of the studied pollutants. The results regarding pollutant removal revealed that planted systems grown in MSFM achieved significantly higher removal rates (up to 90 %) compared to the plastic grid (up to 80 %). Statistically significant higher removal rates were obtained for the planted systems compared to the unplanted systems either grown in MSFM (for turbidity (planted: 82-90 %; unplanted: 44 %), COD (planted: 74-84 %; unplanted: 32 %) and BOD 5 (planted: 76-85 %; unplanted: 51 %), respectively) or grown in the plastic grid (for turbidity (planted: 64-78 %; unplanted: 44 %) and COD (planted: 43-75 %; unplanted: 32 %), respectively). During the experimental period (7 months), all plants managed to survive and withstand the weather variations. The plants in polyculture followed by Iris sp. plants in plastic grid floating mats were better adapted, as indicated by maximum quantum efficiency of PSII values and chlorophyll content index, while all the plants were considered well adapted in the MSFM. Overall, the implementation of floating treatment wetlands with ornamental vegetation for greywater treatment in urban areas seems to be a sustainable and efficient approach., Competing Interests: Declaration of competing interest The authors declare that there is no conflict of interest regarding the publication of this article., (Copyright © 2023. Published by Elsevier B.V.)

Spruce wood and Typha (wetland plant) derived biochars pyrolyzed at 350 °C and 600 °C were tested for their sorption affinity for organic pollutants (diclofenac, methylparaben, benzotriazole and sodium 1-decanesulfonate) and nutrients (nitrate, ammonium, phosphate and boron) commonly found in greywater. Batch and column studies combined with molecular dynamics modelling determined the sorption capacity, kinetics, and described the underlying mechanisms. The spruce biochar (600 °C) exhibited the highest sorption capacity mainly for the tested organics. The dynamic test performed for spruce biochar (600 °C) showed that the magnitude of desorption was low, and the desorbed amount ranged between 3 and 11 %. Molecular dynamics modelling (a computational tool for elucidating molecular-level interactions) indicated that the increased sorption of nitrate and boron on spruce biochar (600 °C) could be attributed to hydrophobic interactions. The molecular dynamics shows that predominant adsorption of organic pollutants was governed by π-π stacking, with a minor role of hydrogen-bonding on the biochar surface. In summary, higher pyrolysis temperature biochar yielded greater adsorption capacity greywater borne contaminants and the reaction temperature (10-34 °C) and presence of anionic surfactant had a limited effect on the adsorption of organic pollutants, suggesting efficacious application of biochar in general for greywater treatment in nature-based systems., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Membrane fouling caused by complex greywater synthesized by personal care products and detergents commercially available for household applications was investigated using dead-end microfiltration (MF) and analyzed systematically by a multistage Hermia blocking model as a first attempt. The highest flux decline was associated with the smallest pore size of the membrane (0.03 μm). This effectiveness was more pronounced at higher applied pressures to the membrane. A cake layer was formed on the membrane consisting mainly of silica particles present as ingredients in greywater. Although organic rejection was low by the porous MF membrane, the organic compound contributed to membrane fouling in the filtration stage. With a 0.03 μm pore size of the membrane, dominant fouling mechanisms were classified into three stages as applied pressure increased, such as complete pore blocking, intermediate pore blocking, and cake layer formation. Specifically, during the early stage of membrane filtration at 1.5 bar, membrane fouling was determined by complete pore blocking in the 0.10 μm pore size of the membrane. However, the later stage of membrane fouling was controlled mainly by intermediate pore blocking. Regardless of the applied pressure, pore constriction or standard blocking played an important role in the fouling rate with a 0.45 μm pore size of the membrane. Our results also support that complex formation can occur due to the concentration of organic and inorganic species present in simulated greywater. Thus, strategic approaches such as periodic, chemically enhanced backwashing need to be developed and tailored to remove both organic and inorganic fouling from MF membranes treating greywater.

The discharge of greywater from ships, an uncounted sea-based source of microplastics (MPs), is a growing concern. Yet, empirical data on MPs from this source are currently limited. Here, the abundances and characteristics of MPs in greywater from a research vessel were investigated according to water usage type (e.g., galley, cabin, and laundry). The mean abundance of MPs was highest in greywater from the laundry (177,667 n/m 3 ), followed by the cabins (133,833 n/m 3 ) and galley (75,000 n/m 3 ). However, no significant differences were found in the MP abundances among greywater types due to high variability of triplicate samples collected every five days. Fiber-type MPs accounted for 66% of the total MP abundance and fragment-type MPs for 34%. Microplastics in the size range of 100-200 μm exhibited the highest levels among size classes. The dominant polymer identified in all greywater samples was polyester (53%), followed by polypropylene (23%). Marine coating origin MPs (6%) were also observed in all types of greywater. The greywater generation rate during the cruise was 0.15 m 3 /person∙day. Annual MP emissions per person by the greywater discharge of the research vessel was estimated to be 4.1 × 10 6 n/person∙year (equivalent to 3.0 g/person∙year)., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Greywater, with limited content of pathogens, makes up more than half of the produced wastewater in urban areas. Given the high cost of wastewater management and treatment, it causes sense to collect greywater separately at the source and employ an on-site treatment system to increase opportunities for on-site water reuse. For this purpose, this paper aims to propose a multilayer granular filter as an inexpensive and simple on-site treatment method for greywater reuse. Furthermore, as determining the optimal structure of multilayer filters is a serious challenge, a simulation-optimization model is developed for determining the best filter configuration. An Artificial Neural Network (ANN) is trained based on experimental results to simulate the filter performance with different combinations of layers and the Genetic Algorithm (GA) is used to find the optimal thickness of different layers based on ANN simulation results. The proposed filter in this paper for greywater treatment consists of silica sand (in three different gradings) and activated carbon (with fixed grading) and treatment measures for evaluation of filter performance are considered as Chemical Oxygen Demand (COD) and Electrical Conductivity (EC). Due to difficulties in collecting, transferring, and storing the real greywater, synthetic greywater was used in this study. 49 experiments with different combinations of filter media thicknesses were performed and the performance of the filter was analyzed. Generally, three-layer filters perform better in COD and EC reduction, however, the average COD and EC elimination equals 36.3% and 15.1%, respectively, which indicates more efficiency of filter in COD reduction in comparison with EC. Based on the optimization-simulation model and experimental results, a filter consisting of 33 cm of fine sand, 20 cm of activated carbon, and 7 cm of medium sand results in the maximum efficiency and can reduce the COD and EC of greywater by 72% and 30%, simultaneously. According to the optimization outputs, the ideal filter can treat greywater up to having EC of 1000 μS/cm and COD of 321 mg/L, which is generally suitable for irrigation purposes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, simultaneous nitrification and denitrification-sequencing batch reactor (SND-SBR) process was investigated to treat greywater. The effect of three process parameters, including hydraulic retention time (HRT), volumetric exchange ratio (VER) and sludge retention time (SRT), was optimised using a 2 3 full factorial design. The statistic model was developed for two response variables, i.e. chemical oxygen demand (COD) and ammonia (NH 3 -N) removal. The optimum conditions were 6.8 h HRT (anaerobic/aerobic/anoxic: 1.77 h/2.77 h/2.27 h), 0.7 VER and 7.94 d SRT, which resulted in 93.9% COD and 84.6% NH 3 -N removal efficiency. SRT was the most significant factor, followed by HRT and VER for COD and NH 3 -N removal. The interaction effect of VER and SRT was significant in COD removal. On the other hand, the interaction effects of HRT-VER and HRT-SRT were significant in NH 3 -N removal. The removal efficiencies of 89.6 ± 1.1% and 83.7 ± 2.3% were observed for TKN and TN, respectively, in the optimised SND-SBR system. NH 3 -N removal was obtained via nitrate pathway in the SND-SBR system. The PO 4 3- -P removal of 74.2 ± 3.4% was obtained via aerobic phosphorus uptake and post anoxic denitrification at the optimal condition. To enhance PO 4 3- -P removal, adsorption (using corn cob adsorbent) was integrated with SBR by adding the optimum adsorbent dose (0.5 g/L). The PO 4 3- -P removal efficiency in the SBR-adsorption system was found to be 80 ± 1.5%. The biodegradation of emerging contaminants (ECs) was also carried out in the SND-SBR system, and the results showed removal rate of 58.9 ± 2.3% benzophenone-3 (BP) and 80.1 ± 2.2% anionic surfactant (AS).

Forward osmosis (FO) technology is regarded as an alternative to wastewater treatment due to its high permeate flux, excellent solute selectivity and low fouling tendency. In this study, two novel aquaporin based biomimetic membranes (ABMs) were used for comparison in short-term experiments to investigate the impact of membrane surface properties on greywater treatment. The impact of feed solution (FS) temperature on the filtration performance and membrane fouling behavior of ABM was further analyzed in the sequential batch experiments. Results indicated that the membranes with rough surface morphology and low zeta potential (absolute value) facilitated the adsorption of linear alklybezene sulfonates (LAS), thus improving the water flux and the rejection of Ca 2+ and Mg 2+ . The increase in FS temperature enhanced the diffusion of organic matter and the water flux. In addition, sequential batch experiments showed that the membrane fouling layer was mainly in the form of organic and inorganic composite fouling, which was mitigated at FS temperature of 40 °C. Microbial community analysis revealed that the increase in FS temperature affected the diversity of microbial communities. More heterotrophic nitrifying bacteria were enriched in the fouling layer at FS 40 °C than at FS 20 °C. This study provides a novel strategy for employing ABM FO in greywater treatment and reuse., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Greywater is an attractive source for water reuse at the household or building level, particularly for non-potable applications. Two greywater treatment approaches are membrane bioreactors (MBR) and moving bed biofilm reactors (MBBR), yet, their performance has not been compared so far within their respective treatment flowsheets, including post-disinfection. Two lab-scale treatment trains were operated on synthetic greywater: a) MBR with either polymeric (chlorinated polyethylene, C-PE, 165 days) or ceramic (silicon carbide, SiC, 199 days) membranes coupled with UV disinfection; and b) single-stage (66 days) or two-stage (124 days) MBBR coupled with an electrochemical cell (EC) for in-situ disinfectant generation. Water quality was constantly monitored, and Escherichia coli log removals were assessed through spike tests. Under low-flux operation of the MBR (<8 L·m  -   2 ·h  -   1 ), the SiC membranes delayed the onset of membrane fouling and needed less frequent cleaning compared to C-PE membranes. Both treatment systems met most water quality requirements for unrestricted greywater reuse, at a 10-fold lower reactor volume for the MBR than the MBBR. However, neither the MBR nor the two-staged MBBR allowed adequate nitrogen removal, and the MBBR did not consistently meet effluent chemical oxygen demand and turbidity requirements. Both EC and UV provided non-detectable E. coli concentrations in the effluent. Although the EC provided residual disinfection, scaling and fouling decreased its energetic and disinfection performance over time, making it less efficient than UV disinfection. Several outlines to improve the performance of both treatment trains and disinfection processes are proposed, thus, allowing a fit-for-use approach that leverages the advantages of the respective treatment trains. Results from this investigation will assist in elucidating the most efficient, robust, and low-maintenance technology and configurations for small-scale greywater treatment for reuse., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier Ltd.)

Implementation of green roofs requires a large amount of primary material, especially for constructing the growing media layer. In addition, irrigation of green roofs with potable water is uneconomical and unsustainable. The novel hybrid green roof system proposed in this paper is in line with the principles of circular economy as it incorporates recycled materials into green roof growing media and greywater for irrigation. Two experimental beds were built to evaluate the concept of treating greywater in a constructed wetland prior to using it to irrigate a dual-layer extensive green roof. The growing media in both two extensive green roof beds contained ca. 37.5% by volume of recycled crushed building rubble containing a large proportion of brick. One of the two beds additionally contained 9.5% by volume of sewage sludge-based biochar. The concept of the hybrid roof and novel growing media was evaluated based on laboratory analysis of the growing media and on onsite measurements of hydraulic and thermal performance. The growing media amended with recycled materials developed in this study had hydrophysical properties comparable to commercially available growing media without recycled materials. Observations made during one vegetation season from June to October and a ten day-intensive water quality monitoring campaign during September 2020 showed that the constructed wetland significantly reduced total nitrogen and orthophosphate concentrations in pre-treated greywater. Due to the irrigation method employed, in which water flowed predominantly through drainage mats below the growing media, nutrient-leaching by the irrigation water was avoided. Concentrations of nutrients in the effluent were observed to increase only in response to precipitation. The temperature peak of the bottom green roof layer was shifted by almost 9 h from the peak in air temperature, and temperature fluctuations were significantly reduced. Vegetation on the bed amended with biochar demonstrated more vigorous growth due to available nutrients in the biochar which increased the rate of temperature-reducing evapotranspiration. More water evapotranspirated more water, which provided more water retention capacity confirmed by a lower runoff coefficient. Simple storage routing hydraulic modeling of hybrid green roof runoff using a nonlinear reservoir was performed., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

ABSTRACT Chemical fertilizers boost crop production; however, their continued use decreases soil fertility in the long run. Nutrient recycling by the beneficiation of poultry manure into biochar and application as a soil amendment is a long-term solution for plant nutrition. The effect of poultry manure, poultry biochar and crop irrigation with 50% and 100% greywater (GW) was assessed on soil properties and growth of wheat ( Triticum aestivum L. HD-2967) on the 7th and 14th day of sowing. This resulted in greater nutrients (OC, OM, C:N have values of 3.51%, 6.58%, and 16.52, respectively) in soil on the 14th day after sowing irrigated with 100% GW for soil and 10 g biochar amendments than manure. The germination and growth were boosted to 100% on day 6 after seed sowing soil and 5 g biochar. The maximum number of leaflets (4), rootlets (7) and shoot length (26.58 cm) was obtained for soil and 10 g biochar amendments with 100% GW on the 14th day of sowing. The significance of the work is that greywater and poultry biochar has been used for the irrigation of wheat as a step towards the management of both solid and liquid waste. Biochar being a potential adsorbent reduces the pollutant load of greywater while increasing the nutritive value of soil substratum and influencing plant growth. The findings could offer crucial knowledge for creating agronomic procedures to repurpose the nutrients in poultry manure and biochar to grow crops by adding value to waste and meeting the goal of bioeconomic sustainability.

Bioretention systems are among the most popular stormwater best management practices (BMPs) for urban runoff treatment. Studies on plant performance using bioretention systems have been conducted, especially in developed countries with a temperate climate, such as the USA and Australia. However, these results might not be applicable in developing countries with tropical climates due to the different rainfall regimes and the strength of runoff pollutants. Thus, this study focuses on the performance of tropical plants in treating urban runoff polluted with greywater using a bioretention system. Ten different tropical plant species were triplicated and planted in 30 mesocosms with two control mesocosms without vegetation. One-way ANOVA was used to analyze the performance of plants, which were then ranked based on their performance in removing pollutants using the total score obtained for each water quality test. Results showed that vetiver topped the table with 86.4% of total nitrogen (TN) removal, 93.5% of total phosphorus (TP) removal, 89.8% of biological oxygen demand (BOD) removal, 90% of total suspended solids (TSS) removal, and 92.5% of chemical oxygen demand (COD) removal followed by blue porterweed, Hibiscus, golden trumpet, and tall sedge which can be recommended to be employed in future bioretention studies., (© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Laundry greywater is considered as an alternative source of non-potable water, as it is discharged in approximately 70% of homes. Because this water contains compounds such as biodegradable and recalcitrant organic matter, surfactants, and microbiological compounds, it must be treated prior to reuse. Therefore, the objective of this study was to assess the behavior of organic matter and antibiotic-resistant bacteria (ARB) in greywater treated by a constructed wetland (CW). The results show that the organic matter removal efficiencies were 67.19%, 50.15%, and 63.57% for biological oxygen demand (BOD 5 ), chemical oxygen demand (COD) and total organic carbon (TOC), respectively; these efficiencies were not significant ( p > 0.05). In addition, the CW allows the distribution of TOC and ionic compounds in the fractions below 1000 Da to increase by 5.03% and 13.05%, respectively. Meanwhile, the treatment of microbiological compounds generated non-significant removals ( p > 0.05), along with increases in bacteria resistant to the antibiotics ciprofloxacin (CIP) and ceftriaxone (CTX) of 36.34%, and 40.79%, respectively. In addition, a strong association between ARB to CIP, CTX, cationic and non-ionic surfactants was determined, indicating the role of surfactants in ARB selection. It is suggested that disinfection systems should be employed prior to the reuse of the treated water.

The objective of this investigation was to determine whether Canna indica and Oryza sativa L . plants have the phytoremediation potential for removing heavy metals and nutrients from greywater treated in batch-fed Horizontal sub-surface Flow Constructed Wetlands (HssFCW). The HssFCW had a Hydraulic Retention Time (HRT) and organic loading rate (OLR) of 3 days and 3.96 (g.BOD/m 2 .day) respectively. Greywater (GW) samples were characterized for electrical conductivity (EC), total nitrogen (TN), total phosphorous (TP), pH, sodium adsorption ratio (SAR), metals (Al, Fe, Mg, Ca) and Biochemical Oxygen Demand (BOD 5 ). The accumulation of metals in the soil and edible parts of plants was evaluated in terms of bioconcentration and translocation factors. Metal concentrations were determined using an atomic absorption spectrometer, while nutrients were by colorimetric method. The result shows that the metals and nutrients were below the WHO allowable limit for treated greywater recycling in agriculture. Nutrient removal was insignificantly different while metal removal was significantly different in the constructed wetlands (CW). The results indicated that C. indica is preferred as a perennial plant with unlimited metal accumulation and high nutrient removals compare to O . sativa L . with a high metal concentration in the above-ground plant tissue and also an annual plant.

Domestic hot water systems are large energy consumers. With the aim of reducing the energy footprint of these systems, we selected and simulated five technologies across a wide range of technology readiness levels: established technologies - pipe insulation and low-flow faucets -, relatively new technologies - shower drain heat exchangers and an innovative pipe system - and a novel experimental technology - a heat exchanger connected to membrane bioreactor for on-site greywater treatment. Using the WaterHub modeling framework, we simulated the technologies alone and in combination and compared the energetic performance of fifteen scenarios with a validated reference domestic hot water system. Low-flow appliances as standalone technologies performed best with 30% less energy required for the boiler tank, but combining low-flow appliances with a membrane bioreactor heat exchanger performed best overall (50% reduction). Deep insights into the temperature dynamics at all locations in the system led to the identification of technological competition patterns to prevent and synergies to exploit. Through our results, we are able to discuss and recommend further investigations regarding critical aspects like hygiene and economic performance., (Copyright © 2022 The Authors. Published by Elsevier Ltd.. All rights reserved.)

The current work reviews the quantitative microbiological risk assessment of antibiotic-resistant bacteria (ARB) in greywater and discusses the international strategies currently used for reducing antimicrobial resistance. The work highlights the countries that have a plan for the treatment and reuse of greywater and the current guidelines used in these countries. The paper also investigates the role of greywater in the distribution of antimicrobial resistance because of antibiotics and ARB. A bibliometric analysis was conducted for the studies on greywater, pathogenic bacteria, and antibiotics. The studies obtained from Scopus database were screened and compared to obtain the data for global antimicrobial resistance in 2000 and 2021. The strategies used by developed countries that led to the reduction in the recorded antimicrobial resistance are also listed. The challenges and limitations associated with the current plans adopted by several countries to minimise the spreading of the antimicrobial resistance are highlighted, while proposed solutions are provided. Two main issues associated with the distribution of antimicrobial resistance are (1) the absence of a plan in developing counties and presence of antimicrobial agents and ARB in the environment and (2) the difficulties in the current treatment technologies used for the removal of these antimicrobial agents from the water and wastewater. Based on the review and discussion, it was concluded that more advanced technologies are required to ensure total elimination of the antimicrobial agents and ARB from the environment. In addition, a new international standard should be drafted for the ARB in the environment, as they differ from the one currently used for medical applications., (Copyright © 2022 Elsevier Inc. All rights reserved.)

In the present study, removal of pollutants in greywater was investigated using a novel bacterial-fungal consortium. Response surface methodology was used for the optimization of process variables like pH, temperature, inoculum size, and Carbon/Nitrogen (C/N ratio) for degradation of pollutants. Experiments were based on Box Behnken statistical design and the results show a good fit with the quadratic model, coefficient of determination ( R ) value of 0.9499. The reliability of the model was established by various statistical parameters like lack of fit, pure error, and residual sum of squares. The optimized conditions for maximum reduction in chemical oxygen demand, oil & grease and sulphate were found to be 78.7%, 82.6% and 89.7%, respectively after 96 h of incubation of the reaction mixture at pH 7; temperature 35°C; inoculum size 150 µl and C/N ratio of 1:2. Our results clearly demonstrate that the developed novel bacterial-fungal consortium can be a cost-effective, safe, and environment-friendly alternative for remediation of greywater.2 ) value of 0.9499. The reliability of the model was established by various statistical parameters like lack of fit, pure error, and residual sum of squares. The optimized conditions for maximum reduction in chemical oxygen demand, oil & grease and sulphate were found to be 78.7%, 82.6% and 89.7%, respectively after 96 h of incubation of the reaction mixture at pH 7; temperature 35°C; inoculum size 150 µl and C/N ratio of 1:2. Our results clearly demonstrate that the developed novel bacterial-fungal consortium can be a cost-effective, safe, and environment-friendly alternative for remediation of greywater.

Water shortages around the world have intensified the search for substitute sources. Greywater can serve as a solution for water requirements. Compared to two-dimensional electrochemical processes for water treatment, the addition of particle activated carbon enhances the conductivity and mass transfer or the adsorption of pollutants in a three-dimensional (3D) electrochemical process. The large specific surface areas of these particles can provide more reactive sites, resulting in a higher removal efficiency. In this study, the treatment of greywater by the electro-Fenton (E-Fenton) method was carried out in a 3D electrolytic reactor. The effects of the operating conditions, such as electrode spacing, applied voltage, treatment time, and activated carbon loading, on the efficacy of the E-Fenton process were investigated, and the corresponding optimum conditions were found to be 7 cm, 9 V, 2 h, and 10 g. The results showed that COD Cr removal of greywater treated using the 3D electrochemical process was 85%. With the help of the Box-Behnken experiment design and the response surface methodology, the parameters were optimized to determine the optimal conditions. The results of the response surface analysis were consistent with the experimental results. The above findings illustrate that the proposed three-phase 3D electrochemical process is feasible for the efficient treatment of greywater.

Residents of informal settlements, the world over, suffer consequences due to the lack of drainage and greywater management, impacting human and environmental health. In Brazil, the presence of the Aedes aegypti mosquito in urban areas promotes infections of the Zika virus as well as companion viruses, such as dengue, chikungunya and yellow fever. By using observation and interviews with the community, this paper shows how a simple sustainable drainage system approach could prevent the accumulation of on-street standing water, and thus reduce opportunities for the mosquito to breed and reduce infection rates. During the interview phase, it became apparent that underlying misinformation and misunderstandings prevail related to existing environmental conditions in favelas and the role of the mosquito in infecting residents. This inhibits recommendations made by professionals to reduce breeding opportunities for the disease vector. Whilst unrest is an issue in favelas, it is not the only issue preventing the human right to reliable, safe sanitation, including drainage. In "pacified" favelas which may be considered safe(r), the infrastructure is still poor and is not connected to the city-wide sanitation/treatment networks.

A year-long study was conducted to assess the quantity and quality characteristics of greywater generated from different sources of an Indian household. The effect of source separation on greywater quantity and pollutant load contribution was also assessed. Composite samples were collected separately over a period of 24 h from each of the greywater source, namely hand basin, bathroom, kitchen, and laundry, and were analysed for different physico-chemical and microbiological parameters. The mean greywater generation averaged 62 L per person per day. Quantitatively, kitchen and bathroom greywater contributed 37 and 31% of the total greywater volume, respectively, while hand basin and laundry greywater accounted for 11 and 21% of the total greywater generation. Kitchen greywater contributed about 60% of the organic load in terms of biochemical oxygen demand (BOD) and chemical oxygen demand (COD), while laundry greywater was the major contributor of heavy metals and PO 4 -P loads. Hand basin and bathroom greywaters were the major sources of total coliforms. The analysis shows that separation of kitchen and laundry greywater is beneficial as it reduces pollutant load considerably., (© 2022. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

The gap between water demand and available water supply led to wastewater treatment, particularly greywater. Due to specific characteristics of grey wastewater, treatment and recycling of this type of wastewater capture global attention. This paper presents a literature review of the remediation of greywater by adsorption processes. Besides, the reclamation of the grey wastewater in the context of the circular economy is highlighted. In this regard, the characterization of various types of grey wastewater, the potential risks associated with greywater, and the properties of reclaimed water as per the regulation or guideline are summarized. These standards vary based on the application of reused water and from a country to another country. Furthermore, this review elucidates the adsorption process in terms of the type of adsorbents, modification of adsorbents and their regeneration process, adsorption isotherm, kinetics and thermodynamic of adsorption, and optimization of adsorption system. Finally, the removal of different pollutants from greywater by various adsorbents and techno-economic aspects are illustrated., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

This work evaluated the fates of linear alkylbenzene sulfonate (LAS), chemical oxygen demand (COD), ammonia nitrogen (NH 4 -N), and total nitrogen (TN) when treating greywater (GW) in an oxygen-based membrane biofilm reactor (O + -N), and total nitrogen (TN) when treating greywater (GW) in an oxygen-based membrane biofilm reactor (O 2 -MBfR). An influent ratio of chemical oxygen demand to total nitrogen (COD/TN) of 20 g COD/g N gave the best removals of LAS, COD, NH 4 + -N and TN, and it also had the greatest EPS accumulation in the biofilm. Higher EPS and improved performance were linked to increases in the relative abundances of bacteria able to biodegrade LAS (Zoogloea, Pseudomonas, Parvibaculum, Magnetospirillum and Mycobacterium) and to nitrify (Nitrosomonas and Nitrospira), as well as to ammonia oxidation related enzyme (ammonia monooxygenase). The EPS was dominated by protein, which played a key role in adsorbing LAS, achieving short-time protection from LAS toxicity and allowed LAS biodegradation. Continuous high-efficiency removal of LAS alleviated LAS toxicity to microbial physiological functions, including nitrification, nitrate respiration, the tricarboxylic acid (TCA) cycle, and adenosine triphosphate (ATP) production, achieving the stable high-efficient simultaneous removal of organics and nitrogen in the O 2 -MBfR., (Copyright © 2021 Elsevier B.V. All rights reserved.)

According to the European Research and Innovation Policy Agenda, nature-based solutions (NBSs) are key technologies to improve the sustainability of urban areas. Among NBSs, green walls have been recently studied for several applications, among the others the treatment of lowly polluted wastewater flows as greywater (GW, e.g. domestic wastewater excluding toilet flushes). This work is aimed at the evaluation of the influence of four additives (compost, biochar, granular activated carbon, polyacrylate) mixed with a base filter medium made of coconut fibre and perlite, on the performances of a green wall fed in batch mode with synthetic GW. The green wall was operated with a high hydraulic loading rate of GW (740.8 L/m 2 /day) in open-air winter conditions (3.5-15 °C measured for GW) between January and April. The performances of the green wall have been assessed though the monitoring every 1-2 weeks of physicochemical and biological parameters (pH, electric conductivity, total suspended solids, dissolved oxygen, BOD 5 and COD, nitrogen and phosporus compounds, chlorides and sulphates, anionic surfactants and E. coli). Removal performances were excellent for BOD 5 (>95%) and E.coli (>98%) for all additives; compared to the base medium, biochar was the best performing additive over the highest number of parameters, achieving removals equal to 51% for COD, 47% for TKN and nitric nitrogen and 71% for anionic surfactants. Compost also achieved high removal performances, but the frequent clogging events occurred during the monitoring period do not make its use recommendable. Granular activated carbon and the combination of biochar and polyacrylate performed better than the base medium, but only about the removal of nitric nitrogen. These results demonstrated that, in the considered experimental boundaries, biochar could improve the overall treatment performances of a green wall fed by GW and operated in challenging conditions., (Copyright © 2021 The Authors. Published by Elsevier Ltd.. All rights reserved.)

Personal care products (PCPs) are contaminants of emerging concern because of their continuous input into the environment. In this study, membrane bioreactor (MBR) and constructed wetland (CW) methods were used to investigate the effect and mechanism of conventional pollutant and PCP removal from greywater. The effluent of both the MBR- and CW-treated greywater met the reclaimed water reuse standard in China. Conventional pollutants and five target PCPs had a higher removal efficiency in the MBR than in the CW. The removal rates of the PCPs, including Tuina musk (AHTN), were >80% using MBR and CW methods. The main pathway of removing PCPs in the MBR was sludge adsorption and biodegradation, whereas the contribution of the membrane module was weak. The main pathway of removing PCPs in the CW was the combined action of plant absorption, microbial biodegradation, and substrate adsorption, depending on the PCP type. Ethyl hexyl methoxycinnamate (EHMC) has strong biological oxidizability and was mainly removed by biodegradation, whereas Jiale musk (HHCB) and AHTN were mainly removed by adsorption. Six types of CW substrates were investigated, and perlite showed the best adsorption effect for the five target PCPs. The optimal substrate adsorption pH was 7. This study provides important technical information on the effective removal of conventional pollutants and PCPs in greywater and the preparation of high-quality reclaimed water., Competing Interests: Declaration of competing interest The authors report no relationships that could be construed as a conflict of interest., (Copyright © 2021. Published by Elsevier B.V.)

The annual risks of colonization, skin infection, bloodstream infection (BSI), and disease burden from exposures to antibiotic-resistant and susceptible Staphylococcus aureus ( S. aureus ) were estimated using quantitative microbial risk assessment (QMRA). We estimated the probability of nasal colonization after immersion in wastewater (WW) or greywater (GW) treated across a range of treatment alternatives and subsequent infection. Horizontal gene transfer was incorporated into the treatment model but had little effect on the predicted risk. The cumulative annual probability of infection (resulting from self-inoculation) was most sensitive to the treatment log 10 reduction value (LRV), S. aureus concentration, and the newly calculated morbidity ratios and was below the health benchmark of 10 -4 infections per person per year (ppy) given a treatment LRV of roughly 3.0. The predicted annual disability-adjusted life years (DALYs), which were dominated by BSI, were below the health benchmark of 10 -6 DALYs ppy for resistant and susceptible S. aureus, given LRVs of 4.5 and 3.5, respectively. Thus, the estimated infection risks and disease burdens resulting from nasal colonization are below the relevant health benchmarks for risk-based, nonpotable, or potable reuse systems but possibly above for immersion in minimally treated GW or WW. Strain-specific data to characterize dose-response and concentration in WW are needed to substantiate the QMRA.

The present study involves a novel protocol to develop a ternary composite catalyst for an effective post-treatment technique for greywater. The ternary film of Fe 2 O 3 -TiO 2 /polyvinyl pyrrolidine (PVP) is coated on a glass tube using spray coating with annealing at 320 °C. The structure, thermal, microstructure, and surface properties of the coated film are characterized by X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), and Thermo Gravimetric Analysis (TGA). The scratch hardness of photocatalysts at different Fe 2 O 3 /TiO 2 compositions is investigated based on the width measurement of scratch using FESEM analysis. Results show that at an optimum coating of 5% of Fe 2 O 3 /TiO 2 composition catalytic film, the maximum scratch hardness (7.984 GPa) is obtained. Also, the photocatalyst has the highest cohesive bond strength and wearing resistance. The degradation of triclosan (TCS) in treated greywater, discharged from the anaerobic-aerobic treatment system, is investigated at a lab-scale using a solar photocatalytic reactor. The response surface analysis has been performed from the different sets of experimental trials for various optimal parameters. It is observed that the TCS degradation efficiency of 83.27% has resulted under optimum conditions., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Carbon/nitrogen ratio is an important parameter during the biological wastewater treatment. Our study emphasizes revealing the mechanisms of chemical oxygen demand/total nitrogen (COD/TN) ratio dependent improved greywater (GW) treatment in an oxygen based membrane biofilm reactor (O 2 -MBfR). Results showed that reducing COD/TN ratio from 40 to 20 g COD/g N by supplementing NH 4 Cl to GW improved the relative abundance of genera related to LAS-biodegradation (from 8.39% to 35.7%), nitrification (from 0.20% to 0.62%) and denitrification (from 3.01% to 7.59%). Reducing COD/TN ratio also led to an increase in the ammonia monooxygenase (AMO) activity (from 7.56 to 10.2 mg N/g VSS-h), as well as improved ammoxidation and linear alkylbenzene sulfonate (LAS) mineralization although the dissolved oxygen (DO) concentration and pH decreased. Much higher NH 4 +  - N at lower COD/TN ratio (10 units) led to lower DO (0.13 ± 0.01 mg/L) and pH (6.72 ± 0.02), but the continuously increased AMO activity (up to 12.9 mg N/g VSS-h) enabled the cometabolism of ammoxidation and LAS mineralization, leading to the efficient removal of organics and nitrogen under the low DO condition., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

To counteract increasing water scarcity in the Mediterranean region, this study provides data on the efficiency of a decentralized, nature-based solution for hotel greywater (GW) treatment and reuse. A pilot plant of a constructed wetland called Vertical Ecosystem (vertECO), installed in a large hotel with GW separation, was operated continuously for 12 months. vertECO achieved a removal efficiency higher than 84.0% for COD and TSS and higher than 95.4% for turbidity and BOD 5 . The monitored physicochemical parameters in the effluent meet the requirements for many reuse purposes restricted in the water reuse legislation. Based on the pilot operation, an economic model was set to estimate its economic feasibility (CAPEX, OPEX and payback period of investment) at several treated volumes. The payback was calculated, at the water and energy prices of Spain and other countries, with a planned operation period of 20 years. The higher the water price, the lower was the payback period. Treated GW volumes of 10.5 and 20 m 3 /day correspond to payback periods for Spain of 10.1 years and 9.0 years, respectively. Finally, co-benefits of vertECO have been considered alongside economic terms, and compared with another intensive technology (i.e., membrane bioreactor)., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

Municipal activities are one of the most important water users worldwide; thus, the treatment and reuse of greywater for non-potable purposes helps to reduce a remarkable amount of consumed water within urban communities. To achieve greywater reuse standards, and remove surfactants, micropollutants, organic matters, microorganisms and other pollutants various methods including physical, chemical and biological processes have been used. Treated greywater can be used on site for different purposes: carwash, toilet flushing, fire protection, green roofs, green walls, non-food irrigation etc. Among them, the use of greywater is very important in the expansion of the green roofs. Green roofs offer many benefits to urban areas such as decreasing air pollution, reducing building cooling needs, promoting mental health of habitants, noise reduction and aesthetics improvement. Therefore, this article provides an overview mainly from two aspects, the possibilities of greywater reuse by studying the characteristics and available options for greywater treatment and its benefits toward the developing green roofs., (Copyright © 2021. Published by Elsevier Ltd.)

A long-duration laboratory study spanning more than 6 months was conducted to evaluate the effect of operating mode on the performance of sand filters for greywater treatment. Performance of saturated and unsaturated filters operated in continuous or intermittent mode was evaluated using settled real greywater. Effects of pause period and higher loading rate on their performance were also evaluated. Furthermore, the effect of the depth of the filter medium on the performance of the filters was also assessed. The saturated filters operated continuously or intermittently performed significantly better than the respective unsaturated filters. Saturated continuous (SC) and unsaturated intermittent (UI) filters were the best and worst performers amongst the different filters. SC filter removed on an average 98% turbidity, 76% BOD, 88% COD, 84% ammonia-N (NH 4 -N) and 95% phosphate (PO 4 -P). Up to 99.68% (2.40 log) removal of faecal coliforms was also achieved by this filter. SC filter showed stable and reliable performance as its effluent quality was insensitive to fluctuations in influent quality. The pause period significantly affected the removal of some of the parameters. Doubling the hydraulic loading rate significantly affected the performance of continuous filters. Though most of the pollutant removal occurred in the top 10 cm in all the filters, a depth of 50 cm was found optimum for the removal of different pollutants. Whilst all the filters produced effluent conforming to different reuse standards except microbial standards, saturated continuous filter (SC) could also meet the faecal coliform standards towards the end of the filter operation., (© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Water end-use studies disaggregate the quantity and frequency of water uses for various household purposes. Water end-use studies are available but none for India, which is gradually approaching a water-scarce condition from being a water-stressed country at present. This implies a need for incorporating water end-use understanding for augmenting urban recycling plans and strategies. To identify socio-demographic determinants of water end-use consumption for use in targeted urban water management, we focused on the indoor micro-components of bathing, dish-washing, laundering, and cleaning at households across the twin cities of Gujarat, a water-scarce province of India. A mixed-method approach was used for data collection in which questionnaire surveys (estimated or indirect measurements) were coupled with water meters (direct measurements) at households. The twin cities of Gujrat represent a spatial variation in greywater production at homes even at a distance of 30-40 km. Direct measurement showed less total average water consumption in Ahmedabad (83 L/HH/d) than Gandhinagar (105 L/HH/d), while indirect measurement showed indoor average consumption of 427 and 497 L/HH/d in the respective cities. Statistical significance of income, family size, and education was noticed on the water consumption pattern of a household. Besides, the study provides the attitude and practice of users towards water conservation behavior. We present new insights and recommendations for future urban water sustainability that are specific to India and applicable to several south-Asian countries., (Copyright © 2021 Elsevier Ltd. All rights reserved.)

An aerated membrane reactor (25 L working volume) equipped with 1.5 m 2 hollow-fiber module was designed and operated using synthetic greywater for household water reuse. Activated sludge (MBR), activated carbon (PAC), zeolite (ZEO) and iron hydroxide (GEH) were added in separate experiments to optimize membrane hydraulic performance and removal efficiency of organics. The use of additives improved permeate quality (in terms of Chemical Oxygen Demand-COD) compared to the direct membrane filtration mode of operation. GEH and MBR were efficient for phosphorus removal, which was not the case for PAC and ZEO. No significant improvement of membrane flux was recorded when PAC, ZEO or GEH were added inside the membrane tank. The MBR system displayed optimum performance during medium-term operation, with COD removal efficiency 85% and permeate flux between 40 and 25 L m -2 h -1 . The capital costs of the proposed technology were around 300 € and the operational costs below 80 € yr -1 , rendering the process feasible at household level. Greywater treatment systems for household applications are still on their infancy; however, this trend is expected to change due public perception towards circular economy, water conservation and reuse.

Reclaimed water can significantly reduce household water consumption. However, microbial growth introduces several problems to reclaimed water, including health concerns, aesthetic deterioration and biofouling. Biological stability refers to the potential of organic matter or nutrients in water to support heterotrophic bacterial growth (HPC). Assimilable organic carbon (AOC) and biodegradable organic carbon (BDOC) are often used as indicators to evaluate the biological stability of water. This study investigated the effect of residual chlorine on the interaction between bacterial regrowth and AOC or BDOC and the variation of AOC after chlorine disinfection in reclaimed water. The results show that the HPC level is insensitive to AOC concentration when residual chlorine is >0.5 mg/L; however, the effects are more pronounced when residual chlorine is <0.5 mg/L. A residual chlorine concentration of >0.5 mg/L therefore maintains biological stability in reclaimed water. When residual chlorine was <0.5 mg/L, HPC levels were found to be limited when AOC was <128 μg/L or BDOC was <0.25 mg/L; and when residual chlorine was >0.5 mg/L, HPC levels were found to be limited when AOC was <796 μg/L or BDOC was <0.85 mg/L in reclaimed water. After chlorine disinfection, AOC contents initially increase and then decrease gradually, reaching minimum levels around day 20, and then increase in both greywater reclaimed water and mixed wastewater reclaimed water. Maintaining the chlorine demand and controlling the AOC level is critical for producing an effect on microbial regrowth and stabilising reclaimed water. The results of this study are conducive to the popularisation of reclaimed water use and also provide reference for reuse standards of reclaimed water., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

The high adsorption capacity of granular activated carbon (GAC) makes it an effective biofilter media for greywater (wastewater generated in households and office buildings from streams without fecal contamination). This study investigates the mechanisms and kinetics of greywater treatment using biologically active GAC (BAC). This was achieved by assessing the role of each of the sorption and biodegradation mechanisms to the overall treatment process, characterizing and modelling the adsorption capacity of the media, and analysing and modelling the kinetics of adsorption. The biodegradation mechanism was found to contribute less than 26% to the overall treatment process with biomass density of 178.71 ± 14.12 mg g -1 BAC, whereas sorption mechanisms were responsible for the remaining greywater treatment. The Freundlich isotherm was found to best-represent the equilibrium adsorption data with Freundlich constant and intensity parameter of 1.48 × 10 -5  L g -1 and 0.39, respectively. Pseudo-second order and intraparticle diffusion models were created to fit the kinetics adsorption with rate constant values of 0.12 g mg -1 h -1 and 1.91 mg g -1 h -0.5 during the first 2 h of the experiment and 0.08 g mg -1 h -1 and 0.50 mg g -1 h -0.5 onwards, respectively. Intraparticle pore diffusion was determined to be the rate limiting step of the greywater treatment; some mass transfer resistance was observed due to external film diffusion at lower substrate gradients during greywater treatment. This study improves our understanding of the behaviour of GAC biofilters through understanding their treatment mechanisms and kinetics, leading to more efficient greywater treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

Accounting for up to three quarters of the wastewater volume resulting from domestic activities but containing only a third of its organic content, greywater is seen as an alternative water source for non-potable reuse. This unique study explores the question whether consumers' product selection could affect the treatability and reuse of bathroom greywater. Fifty five personal care and household products (PCHP) were analysed for their effects on a range of water quality parameters including their aquatic and soil toxicity using Microtox® and MicroResp™. The organic content of these PCHPs varied considerably, not only from one category to another (0.2 g TOC .L -1 for hair conditioners to 2.7 g TOC .L -1 for toothpastes), but also within each category (0.1 g TOC .L -1 to 3.6 g TOC .L -1 amongst the shampoos). As expected, the PCHPs' macronutrient content was low, suggesting some limitation towards biological treatment of bathroom greywater. Regarding the impact of product selection on toxicity towards aquatic and soil microorganisms, the results revealed a higher sensitivity of Vibrio fischeri to the individual PCHPs than the MicroResp™ soil microorganisms. In the latter case, 75% of the products caused a stimulation response from the microorganisms although some decreases in basal respiration were observed for specific PCHPs within product categories. However, based solely on MicroResp™, the short-term discharge of treated bathroom greywater, regardless of consumer product selection, is unlikely to have a negative impact on soil microbial activity. Overall, the work has demonstrated the importance of consumer choice on the pollution load and treatability of greywater. However, no clear link between greywater characteristics and factors that normally determine consumer product selection (branding, type) were identified. This means it is not currently possible for consumers to actively manage the issue through choice such that process designers and technology developers must ensure technologies are sufficiently robust to manage the potential variations that could occur., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Highly variable flow has to be expected in decentralized greywater treatment and can lead to intermittent operation of the treatment system. However, few studies have addressed the influence of variable flow on the treatment performance of a biological activated carbon filter (BAC). In this study, we investigated the influence of intermittent flow using small-scale BAC columns, which treat greywater as a second treatment step following a membrane bioreactor (MBR). Three operating strategies to respond to variable flow were evaluated. The activated carbon was characterized before and after the experiments in terms of biological activity and sorption capacity. The performance of the BAC filters was assessed based on total organic carbon (TOC) removal, TOC fractions and growth potential. No significant differences were observed between constant flow compared to on-off operation with intermittent flow over the range of tested influent concentrations. Peaks with high TOC during 24 h periods were attenuated by sorption and biological degradation. Adsorbed TOC was released after switching back to normal concentrations for influent concentrations more than 5 times higher than usually observed, the BAC functioned as a temporary sink. In line with these results, the high influent TOC values led to increased biological activity in the filter but did not influence the sorption capacity. The experiments showed that intermittent flow does not negatively impact the performance of a BAC and that there is no need for additional equalization tanks to buffer the variable flow, for example in household-scale greywater treatment., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2020 The Authors.)

There is limited information on the optimal processes to remove heavy metals in greywater. A Response Surface Methodology (RSM) via the Box-Behnken Design (BBD) approach was applied in this study to investigate and optimise the process variables of activation time (1.5-2.5 h), impregnation ratio (0.25-0.75) and zinc chloride (ZnCl 2 ) percentage (20-60%) for the removal of heavy metal ions (Cd, Cu, Pb and Ni) associated with greywater treatment. The quadratic model was chosen to describe the effects of the process variables (activation time, impregnation ratio, ZnCl2 percentage) on predicting the responses (heavy metal ions removal) with low p -values (<.0001), high-adjusted R 2 and predicted R and 0.60 impregnation ratio. This showed that the observed values for removing the heavy metal ions (Cu, Cd, Pb and Ni) were close to the predicted values. A RSM-based field test via the BBD approach, involving different types of greywater samples (bathtubs, showers, hand basins and laundry machines) showed that the percentages of heavy metal ions removal fit the experimental results.2 values. Second order polynomial equations, ANOVA and three-dimensional surface plots were developed to evaluate the effects of each independent process variable and determine the optimal condition of each factor for heavy metal ions removal. The optimal activation time for the activated carbon variables was 1.8 h, with 56% ZnCl 2 and 0.60 impregnation ratio. This showed that the observed values for removing the heavy metal ions (Cu, Cd, Pb and Ni) were close to the predicted values. A RSM-based field test via the BBD approach, involving different types of greywater samples (bathtubs, showers, hand basins and laundry machines) showed that the percentages of heavy metal ions removal fit the experimental results.

This study investigated the impact of greywater application for home yard gardening. Greywater was collected and treated using screening, sedimentation and solar disinfection methods. Finally, a field experiment was conducted to investigate the impact of untreated and treated greywater on a selected vegetable, Capsicum frutescens and flowering plant, Calendula officinalis for 2 months. The findings depicted that untreated greywater contains higher macro-nutrients with excessive bacterial population compared with tap water (control), however, the treatment process reduced the concentration of most of the unwanted parameters from greywater samples to bring them into irrigation standards. Overall, treated greywater irrigation showed the species-specific impact on experimental plants with more stimulation in Capsicum frutescens species compared with tap water irrigation. Both treated and untreated greywater irrigation increased the growth parameters of Calendula officinalis in comparison with control. The impact was not significant for most of the parameters of Calendula officinalis while compared between greywater (treated and untreated) and control, and between treated and untreated greywater irrigation. Treated greywater irrigation significantly stimulated most of the parameters of Capsicum frutescens while untreated greywater increased only moisture content, and number of branches compared with control. Most interestingly, treated greywater irrigation had significant impact on Capsicum frutescens particularly for number of branches and leaves compared with untreated greywater irrigation. In fine, the greywater, after treatment was bacterially safe and had positive impact on plant growth. The findings of this study will help to conserve irrigation water and to protect and manage aquatic ecosystem from the adverse impact of wastewater., (Copyright © 2020 Elsevier Ltd. All rights reserved.)

This original research examines a full-scale subsurface Constructed Wetland (CW) system in Indonesia, where most CW research has been limited to laboratory scale experiments. The CW system was located in Bali and built in 2015 in a single series formation. This study aims to demonstrate the performance of the system in treating greywater and examine the nutrient content plants' above-ground biomass. The CW was arranged in linear sequence composed of one unplanted (CW1) and five planted treatments of Iris pseudacorus (CW2), Caladium bicolor (CW3) , Rhoe discolor (CW4) , Sansevieria trifasciata (CW5) and Heliconia psittacorum (CW6). There has been little research on Caladium bicolor, Rhoe discolor and Sansevieria trifasciata in a full-scale CW application. Our results showed fluctuating efficiency (%) in the reduction of Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Total Suspended Solid (TSS), Oil and Grease (O&G), Nitrate and Phosphate. The highest removal efficiency for CW1, CW2, CW3, CW4, CW5, CW6 were O&G (63.63%), BOD (90.66%), Nitrate (83.55%), BOD (80%), BOD (82.88%) and Phosphate (89.93%) respectively. After the experimental period, S. trifasciata and H. psittacorum experienced a decrease in Total N concentration, while H. psittacorum experienced a decrease in phosphate in above-ground biomass. Species of R. discolor, C. bicolor and I. pseudacorus showed good performance in terms of their growth and development. Although high removal efficiency was observed at certain times, this study showed the negative removal efficiencies at times among parameters as a consequence of the low Hydraulic Retention Time (HRT) and high Hydraulic Loading Rate (HLR)., (© 2020 Published by Elsevier Ltd.)

Temporary events such as music festivals are often organized in places that are not connected to a sewage network. As such, the waste (water) generated and discharged can place a heavy burden on the environment. A mobile vertical flow constructed wetland (MCW) with an area of 15 m 2 was constructed, optimized and operated for three years treating grey water (GW) as well as grey and black water (GW + BW) at different festival locations to tackle this problem. During the initial development phase, the appropriate influent type (GW and/or GW + BW) was determined and challenge tests with pre-settled diluted domestic waste water (mimicking GW) were carried out to determine the maximal allowable loading rate. The MCW was able to treat both types of water. However, for further experiments GW was selected as the discharge limits could not be met when treating GW + BW. The challenge tests demonstrated that the MCW could be operated at a maximal allowable hydraulic loading rate of 1.1 m 3 ·m -2 ·d -1 , corresponding to mass loading rates of 68 gTSS·m -2 ·d -1 , 160 gCOD·m -2 ·d -1 and 137 gBOD·m -2· d -1 . During treatment of GW, the MCW achieved effluent concentrations for respectively chemical oxygen demand (COD), biological oxygen demand (BOD), total suspended solids (TSS) and total phosphorus (TP) of 43 mg·L -1 , 16 mg·L -1 , 2.7 mg·L -1 and 1.7 mgP·L -1 . This corresponds to a removal of 90% (COD), 95% (BOD), 97% (TSS) and 76% (TP) respectively. Total nitrogen removal was 25% (from 45 mgN·L -1 to 34 mgN·L -1 ) as particularly denitrification was not complete. As a further development, the MCW was coupled to a drinking water treatment system using ultrafiltration and reverse osmosis (UF-RO) membranes to produce potable water on site. The drinking water system produced potable water that met the legislative criteria. As such, a sustainable and mobile water treatment system aiming at producing potable water at temporary events was demonstrated., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)