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Depleting fossil energy sources and conventional polluting power generation pose a threat to sustainable development. Hydroelectricity generation from ubiquitous and spontaneous phase transitions between liquid and gaseous water has been considered a promising strategy for mitigating the energy crisis. Fibrous materials with unique flexibility, processability, multifunctionality, and practicability have been widely applied for fibrous materials-based hydroelectricity generation (FHG). In this review, the power generation mechanisms, design principles, and electricity enhancement factors of FHG are first introduced. Then, the fabrication strategies and characteristics of varied constructions including 1D fiber, 1D yarn, 2D fabric, 2D membrane, 3D fibrous framework, and 3D fibrous gel are demonstrated. Afterward, the advanced functions of FHG during water harvesting, proton dissociation, ion separation, and charge accumulation processes are analyzed in detail. Moreover, the potential applications including power supply, energy storage, electrical sensor, and information expression are also discussed. Finally, some existing challenges are considered and prospects for future development are sincerely proposed., (© 2024. The Author(s).)

Water scarcity is a serious threat to the survival and development of mankind. Interfacial solar steam generation (ISSG) can alleviate the global freshwater shortage by converting sustainable solar power into thermal energy for desalination. ISSG possesses many advantages such as high photothermal efficiency, robust durability, and environmental friendliness. However, conventional evaporators suffered from huge heat losses in the evaporation process due to the lack of efficient thermal management. Herein, hydrophilic Tencel yarn is applied to fabricate a three-dimensional double-layer fabric evaporator (DLE) with efficient multi-stage thermal management. DLE enables multiple solar absorptions, promotes cold evaporation, and optimizes thermal management. The airflow was utilized after structure engineering for enhanced energy evaporation efficiency. The evaporation rate can reach 2.86 kg·m -2 ·h -1 under 1 sun (1 kW·m -2 ), and 6.26 kg·m -2 ·h -1 at a wind speed of 3 m·s -1 . After a long duration of outdoor operation, the average daily evaporation rate remains stable at over 8.9 kg·m -2 , and the removal rate of metal ions in seawater reaches 99%. Overall, DLE with efficient and durable three-dimensional multi-stage thermal management exhibits excellent practicality for solar desalination.

Solar-driven interfacial evaporation is an emerging desalination technology that can potentially relieve the freshwater scarcity issue. To obtain high and continuous evaporation rates for all-weather, chemically engineered structural materials have been widely explored for simultaneous photothermal and electrothermal conversion. However, many previously reported fabrication processes involve poor integration and considerable energy loss. Herein, a scalable photo-electro-thermal textile is proposed to enable high efficiency, long-term salt rejection, and solar-driven desalination. Specifically, the photo-electro-thermal yarns with a core (commercial electric wire)-shell (polypyrrole-decorated Tencel) structure realize the integration of electrothermal and photothermal conversion. The wrapping eccentricity of 1.53 mm and pitch of 3 T cm -1 for the electric wire are rationally regulated to achieve a high surface temperature of over 52 °C at a 3 V DC input. As a result, exceptional and stable evaporation rates of 5.57 kg m -2  h -1 (pure water) and 4.89 kg m -2  h -1 (3.5 wt.% brine) under 1 kW m -2 ·radiation with a 3 V input voltage are realized. Practical application shows that the textiles can achieve high water collection of over 46 kg m -2  d -1 over the whole day of operation. The constructed photo-electro-thermal textile-based evaporator provides an effective method for commercial and scalable photo-electro-thermal conversion to achieve high-performance and salt-resistant solar-driven desalination., (© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)

Although electronic textiles that can detect external stimuli show great promise for fire rescue, existing firefighting clothing is still scarce for simultaneously integrating reliable early fire warning and real-time motion sensing, hardly providing intelligent personal protection under complex high-temperature conditions. Herein, we introduce an "all-in-one" hierarchically sandwiched fabric (HSF) sensor with a simultaneous temperature and pressure stimulus response for developing intelligent personal protection. A cross-arranged structure design has been proposed to tackle the serious mutual interference challenge during multimode sensing using two separate sets of core-sheath composite yarns and arrayed graphene-coated aerogels. The functional design of the HSF sensor not only possesses wide-range temperature sensing from 25 to 400 °C without pressure disturbance but also enables highly sensitive pressure response with good thermal adaptability (up to 400 °C) and wide pressure detection range (up to 120 kPa). As a proof of concept, we integrate large-scalable HSF sensors onto conventional firefighting clothing for passive/active fire warning and also detecting spatial pressure and temperature distribution when a firefighter is exposed to high-temperature flames, which may provide a useful design strategy for the application of intelligent firefighting protective clothing.

Herein, we present a new method for determining the Ca isotopic composition of geological samples. To eliminate matrix elements from Ca, a column chromatography method was developed using a N , N , N ' N ' tetraoctyl-1,5-diglycolamide (TODGA) resin. The Ca isotopic compositions were measured by a multiple collector inductively coupled plasma mass spectrometry (MC-ICP-MS) without collision cell equipment, especially that direct measurement to 44 Ca/ 40 Ca can be achieved. To mitigate the interference from 40 Ar during 40 Ca measurement, the cold plasma technique was used to suppress the Ar + generation, resulting in a background Ar + intensity of <300 mV, in contrast to the conventional hot plasma conditions, which typically yield thousands of volts for Ar + intensities. Given the potential for a concentration mismatch between the sample and bracketed standard solutions to cause an intensive shift in measured Ca isotopic compositions, a correction for the [Ca] match is needed. To avoid matrix effects arising from residue matrix elements, it is crucial to limit the concentrations below 1% of Ca for most matrix elements (including Al, Mg, K, Na, and Sr) and below 1‰ for Fe. Notably, the tolerance of residue Sr is effectively improved compared to measurements with CC-MC-ICP-MS and traditional Hot-plasma-SSB-MC-ICP-MS methods with the conventional hot plasma technique, thereby lowering the complexity of column chemistry. The measured δ 44/40 Ca, δ 44/42 Ca, and ε 40 Ca values for eight reference materials agree well with previously reported values within analytical uncertainties. This method demonstrates long-term precision is better than 0.10‰ (two standard deviations) for both δ values (i.e., δ 44/40 Ca and δ 44/42 Ca). We anticipate that the proposed method will benefit the growth of the Ca isotope data set and foster an increase in the application of Ca isotope in Earth science studies.

Fabricating highly efficient and long-life redox bifunctional electrocatalysts is vital for oxygen-related renewable energy devices. To boost the bifunctional catalytic activity of Fe-N-C single-atom catalysts, it is imperative to fine-tune the coordination microenvironment of the Fe sites to optimize the adsorption/desorption energies of intermediates during oxygen reduction/evolution reactions (ORR/OER) and simultaneously avoid the aggregation of atomically dispersed metal sites. Herein, a strategy is developed for fabricating a free-standing electrocatalyst with atomically dispersed Fe sites (≈0.89 wt.%) supported on N, F, and S ternary-doped hollow carbon nanofibers (FeN 4 -NFS-CNF). Both experimental and theoretical findings suggest that the incorporation of ternary heteroatoms modifies the charge distribution of Fe active centers and enhances defect density, thereby optimizing the bifunctional catalytic activities. The efficient regulation isolated Fe centers come from the dual confinement of zeolitic imidazole framework-8 (ZIF-8) and polymerized ionic liquid (PIL), while the precise formation of distinct hierarchical three-dimensional porous structure maximizes the exposure of low-doping Fe active sites and enriched heteroatoms. FeN 4 -NFS-CNF achieves remarkable electrocatalytic activity with a high ORR half-wave potential (0.90 V) and a low OER overpotential (270 mV) in alkaline electrolyte, revealing the benefit of optimizing the microenvironment of low-doping iron single atoms in directing bifunctional catalytic activity., (© 2023 Wiley-VCH GmbH.)

The motion detection and thermotherapy provides a convenient strategy for the diagnosis and rehabilitation assessment of joint injuries. However, it is still challenging to simultaneously achieve accurate joint motion monitoring and on-demand thermotherapy. Herein, core-sheath sensing yarns (CSSYs) is proposed and fabricated for excellent electrical and photothermal heating, which consists of carbon black (CB)-coated nylon (sheath layer), silver-plated nylon and elastic spandex yarns (core layer). The CSSYs demonstrates great joule heating performance, which reaches 75 °C at 2 V applied voltage. The good thermal management performance can be well maintained when weaving these yarns into bifunctional smart textile. Further, the optimized double-ply CSSYs (DPCSSYs) with helically twisted structure possess several appealing sensing performance, including preferable strain sensitivity (0.854), excellent linearity (0.962), and superior durability (over 5000 cycles). The as-woven bifunctional smart textile can provide instant and convenient thermotherapy to the injured joints, and simultaneously monitor the injury and recovery conditions of the joint. Therefore, the designed bifunctional smart textile can provide a promising route for developing next-generation healthcare smart textile., (© 2023 The Authors. Advanced Science published by Wiley-VCH GmbH.)

The shortage of fossil fuels and freshwater resources has become a serious global issue. Using solar energy to extract clean water with a photothermal conversion technology is a green and sustainable desalination method. Integrated electricity generation during the desalination process maximizes energy utilization efficiency. Herein, a solar-driven steam and electricity generation (SSEG) system based on an all-in-one evaporator is prepared via a scalable technology. Carbon black is selected as the absorber for solar energy harvesting as well as the functional substance for simultaneous electricity generation. Fabric substrate with flexible structure, porous channel, and capillary effect is vital for directional brine supply, multiple solar absorption, and thermal management. The high evaporation rate (1.87 kg m -2  h -1 ) and voltage output (324 mV) can be achieved with an all-in-one device. The stable electricity output can be maintained over 40000 s. The SSEG performance remains constant after 15 operation cycles or 20 wash cycles. The integrated device balances excellent effectiveness and practicality, providing a viable path for clean desalination and electricity generation., (© 2023 Wiley-VCH GmbH.)

Capacitance tactile sensors (TSs) based on electrode distance and contact area variations have been notably employed for various purposes due to their magnificent stress sensitivity. Nevertheless, developing TSs with tunable responsiveness in a broad pressure interval is crucial owing to the trade-off between sensitivity and linear identification range. Herein, a TS including Ag-coated Velcro and spacer fabric is constructed, where its sandwich framework provides a sizable expansion in compression deformation ability. In addition, a multilayered framework composed of the stacked TS from self-adhesive Velcro provides more contact area and significant deformation for stress distribution, further balancing the sensitivity, sensing range, and linearity for smart garment application. By utilizing the overlaid selection of multilayer structures, the all-textile TS demonstrates outstanding sensitivity with a one-layer structure (0.036 kPa -1 ) over a pressure range of 0.2-5 kPa and retains a sensitivity of 0.002 kPa -1 in a four-layer structure over a wide pressure range of 0.2-110 kPa, representing a significant improvement compared to previous results. The sensor possesses excellent performance in terms of response speed (104 ms), repeatability (10,000 cycles), and flexibility. In addition, its significant applications, involving human motion detection, pliable keyboards, and human-computer interface, are successfully shown. Based on the facile and scalable manufacturing approach, a suitable procedure is presented to construct next-generation wearable electronics.

Electricity generation triggered by the ubiquitous water evaporation process provides an intriguing way to harvest energy from water. Meanwhile, natural water evaporation is also a fundamental way to obtain fresh water for human beings. Here, a wafer-scale nanostructured silicon-based device that takes advantage of its well-aligned configuration that simultaneously realizes solar steam generation (SSG) for freshwater collection and hydrovoltaic effect generation for electricity output is developed. An ingenious porous, black carbon nanotube fabric (CNF) electrode endows the device with sustainable water self-pumping capability, excellent durable conductivity, and intense solar spectrum harvesting. A combined device based on the CNF electrode integrated with nanostructured silicon nanowire arrays (SiNWs) provided an aligned numerous surface-to-volume water evaporation interface that enables a recorded continuous short-circuit current 8.65 mA and a water evaporation rate of 1.31 kg m -2 h -1 under one sun illumination. Such wafer-scale SiNWs-based SSG and hydrovoltaic integration devices would unchain the bottleneck of the weak and discontinuous electrical output of hydrovoltaic devices, which inspires other sorts of semiconductor-based hydrovoltaic device designs to target superior performance., (© 2022 Wiley-VCH GmbH.)

Control of tension distribution in the spinning triangle region that can facilitate fiber motion and transfer is highly desirable for high quality yarn production. Here, the key mechanisms and a mechanical model of gradient regulation of fiber tension and motion with rotary heterogeneous contact surfaces were theoretically analyzed. The linear velocity gradient, effected on a fiber strand using rotary heterogeneous contact surfaces, could balance and stabilize the structure and stress distribution of spinning triangle area, which could capture exposed fiber to reduce hairiness formation and enhance the internal and external fiber transfer to strengthen the fiber utilization rate. Then, varied yarns spun without and with the rotary grooved and rotary heterogeneous contact surfaces were tested to compare the property improvement for verifying above-mentioned theory. The hairiness, irregularity, and tensity of the yarns spun with rotary heterogeneous contact surfaces spun yarns were significantly improved compared to other spun yarns, which effectively corresponded well to the theoretical analysis. Based on this spinning method, this effective, low energy-consuming, easy spinning apparatus can be used with varied fiber materials for high-quality yarn production.

In this study, a carbon fiber/tencel composite braided fabric was used in stable and continuous all-day desalination technology with superior photothermal and electrothermal conversion capability. The desalination performance was regulated by adjusting the braiding parameters. Because the water in carbon fibers is maintained in the capillary state and thus evaporates more easily in clusters, it required less energy to evaporate water off the composite fabric. Under 1 sun illumination, the average evaporation rate and the evaporation efficiency were 1.84 kg m -2 h -1 and 88.8%, respectively. When a small amount of electricity (3 V) was applied, the evaporation rate of the braided fabric was maintained at over 1.88 kg m -2 h -1 , and a superior desalination performance during the daytime was achieved. Under continuous all-day operation, most of the organics, metal ions, and contaminants were effectively eliminated from the water, which satisfied the WHO drinkable water standards. Our results can contribute to paving the way for efficient and stable wastewater treatment, seawater desalination, and drinking water collection methods.

Rationale: The very small mass difference between 41 K and 40 ArH + makes the flat, hydride interference-free peak shoulders very narrow (0.002-0.003 m/z unit), bringing a number of analytical challenges when measuring K isotopic compositions by multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). In traditional Sequence Run mode, the parameters are loaded every line of the sequence which can introduce tiny drifts of tune parameters and mass peaks. This may occasionally lead to the failure of K isotope measurements when mass drifts exceed 0.002 m/z unit. It is thus essential to keep the tune parameters, especially the magnet current, very stable to achieve high-precision K isotopic compositions., Method: We developed a "Continuous-Acquisition-Method" (CAM) MC-ICP-MS Run mode to improve the stability when determining K isotopes. Two sets of experiments were designed: (a) Stability test: measuring a single pure K solution (viz. NIST-999c) for ~3 h and comparing the stability of the two run modes; and (b) GSB-K test: measuring our inhouse pure K standard solution (GSB-K) in both run modes and comparing the accuracy and precision., Results: The traditional Sequence Run mode only kept the MC-ICP-MS system stable for the first ~1.5 h during the ~3-h test, with an offset of the mass peaks of ~0.003 m/z unit. The CAM Run mode yielded higher stability during the whole test (~3 h), with a peak shift <0.0004 m/z unit. Measurement of the GSB-K standard solution in Sequence Run and CAM Run modes gives identical δ 41 K values when the magnet was kept stable, with the CAM Run mode offering a better precision and keeping the instrument stable for longer time., Conclusions: The MC-ICP-MS CAM Run mode shows higher stability and better precision. It is, therefore, good for high-precision K isotope measurements., (© 2021 John Wiley & Sons Ltd.)

Surface sediment samples were collected from upstream down to the subaqueous delta of the Red River in Vietnam to assess heavy metal pollution. Sediment Cr and V concentrations are strongly correlated with Al, Fe, Mn and total organic carbon concentrations, as well as particle size, suggesting that these two metals are derived primarily from natural sources and enriched in the fine fraction of sediments. In contrast, Cu, Cd, Pb, Ni and Zn concentrations show weaker correlations with particle size, with very high concentrations observed at several sites in the upper reach of the river, pointing to anthropogenic input as a possible source of these heavy metals. Enrichment factors (EF) of Cu, Cd, Pb, Ni and Zn suggest that heavy metal pollution is present in sediments with significantly high values in the upstream. The data analysis indicates that Cd, Cu and Pb are the dominant pollutants in the Red River, with their concentrations reaching moderate to serious pollution levels., (Copyright © 2016 Elsevier Ltd. All rights reserved.)

Introduction: The aim of our study was to determine the efficacy of ureteral stents for extracorporeal shock wave lithotripsy (SWL) treatment of pelvis renalis stones and to compare the results and complications in stented and non-stented patients., Material and Methods: Between 1995 and 2011, 1361 patients with pelvis renalis stones were treated with SWL. Patients were subdivided into three groups according to stone burden: ≤1 cm(2) (group 1; n = 514), 1.1 to 2 cm(2) (group 2; n = 530) and >2 cm(2) (group 3; n = 317). Each group was divided into subgroups of patients who did and did not undergo ureteral stent implantation before SWL treatment. The efficacy of treatment was evaluated by determining the effectiveness quotient (EQ). Statistical analysis was performed by chi-square, Fisher's exact and Mann-Whitney U tests., Results: Of the 514, 530 and 317 patients in groups 1, 2 and 3 respectively, 30 (6%), 44 (8%) and 104 (33%) patients underwent auxiliary stent implantation. Steinstrasse rates did not differ significantly between stented and non-stented patients in each group. The EQ was calculated as 62%, 33% and 70% respectively in non-stented, stented and totally for group 1. This ratio calculated as 58%, 25% and 63% for group 2 and 62%, 26% and 47% for group 3. Stone-free rates were significantly higher for non-stented than for stented patients in groups 2 and 3., Conclusions: Stone free rates are significantly higher in non-stented than in stented patients with pelvis renalis stones >1 cm(2), whereas steinstrasse rates are not affected.