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Your search keyword '"Licciulli, Sebastiano"' showing total 3 results
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3 results on '"Licciulli, Sebastiano"'

1. Radical Behavior of CO 2 versus its Deoxygenation Promoted by Vanadium Aryloxide Complexes: How the Geometry of Intermediate CO 2 -Adducts Determines the Reactivity.

Author

Viasus CJ, Alderman NP, Licciulli S, Korobkov I, and Gambarotta S

Abstract

The reactivity of carbon dioxide with vanadium(III) aryloxo complexes has been investigated. The formation of either carbon monoxide or incorporation into the ligand system with the ultimate formation of organic ester was observed depending on the overall electron donor ability of the ligand field. DFT calculations were carried out to investigate the proposed mechanism for carbon dioxide coordination and reduction., (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)

Published
2017
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