1. Selective adsorption of arsenic by water treatment residuals cross-linked chitosan in co-existing oxyanions competition system.
- Author
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Zeng H, Zeng Y, Xu H, Zhao W, Han S, Zhang J, and Li D
- Subjects
- Adsorption, Anions chemistry, Kinetics, Chitosan chemistry, Arsenic chemistry, Arsenic analysis, Water Pollutants, Chemical chemistry, Water Pollutants, Chemical analysis, Water Purification methods
- Abstract
Selective adsorption of arsenic in co-existing oxyanions competition systems remains a significant challenge in water treatment due to the limitations of adsorbent materials that often overlook competitive adsorption, resulting in an overestimation of their actual purification potential for target contaminants. In this study, a novel hydrogel bead adsorbent, composed of water treatment residuals (WTRs) and chitosan (Chi), was developed to selectively remove arsenic, while minimizing the interference from phosphate, which is the strongest and most representative competitor in multi-oxyanion systems. The WTRs-Chi beads (WCB) adsorbents were optimized by adjusting the ratios of WTRs:Chi, with characterization results indicating that increased WTR doping improved the degree of crosslinking and the formation of bidentate complexes with enhanced electrostatic selectivity. Importantly, the co-existence of phosphate had minimal adverse effects on arsenic removal compared to other reported adsorbents. The maximum adsorption capacity for As (V) in the binary system was 34.12 mg/g, and the adsorption behavior was fitted well by the pseudo-second-order kinetic model and the extended Langmuir isotherm model. The experimental results, supported by X-ray photoelectron spectroscopy analysis (XPS), revealed that both As (V) and P (V) adsorption in the single system were driven by electrostatic attraction and ligand exchange. However, in the binary system, the inhibition of P (V) adsorption was attributed to competitive desorption caused by electrostatic repulsion, which hindered the formation of inner-sphere complexes. This study provides a practical approach for developing selective adsorbents to address arsenic contamination in complex water environments and promotes the recycling of municipal solid waste., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Inc. All rights reserved.)
- Published
- 2024
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