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The emergence of degradable orthopedic implants for fracture fixation may abrogate the need for implant removal surgery and minimize pain associated with permanent implants. Magnesium (Mg) and its alloys are being explored as a biomaterial for degradable implants due to mechanical properties similar to those of bone. Previous in vitro studies have determined the degradation rate of pure Mg to be relatively fast when compared to bone regeneration. Hydroxyapatite (HA), the mineral component of bone, may serve as a surface coating on Mg-based implants to effectively slow and control the degradation rate. The objective of this work was to develop and implement a finite element (FE) model that utilizes a damage evolution law for pitting corrosion to predict the degradation of pure Mg (non-coated) and HA-coated pure Mg (coated) materials simulated in physiological conditions. Finite element analysis (FEA) was performed on a cylindrical Mg specimen (25.4 mm diameter, 8 mm height) through Abaqus/Standard software to incrementally monitor the damage value of each Mg element and subsequently delete fully-degraded elements from the simulation. A Fortran user-material (UMAT) subroutine assigned each element a pitting parameter, controlling the rate of degradation throughout the simulation and providing necessary inputs of elastic material properties and degradation model parameters for pure Mg and HA into Abaqus. The simulations allowed for the visualization of both pure Mg and HA-coated pure Mg degradation over a 120-day period, displaying expected degradation trends such as lower corrosion rates for HA-coated Mg and degradation propagating from the edges inward. Simulation results were calibrated with our prior results from a 30-day experimental degradation study via direct comparison with mass loss over time. Additionally, lower length scale, density functional theory (DFT) simulations were performed to provide physical meaning for the model pitting parameter. The FE simulation was extended to model resin-enclosed pure Mg and HA-coated pure Mg degradation, where only the top surface of the specimen was exposed to the corrosion surface, for investigating changes in Mg surface roughness (height) over time. The impacts of this work include the establishment of a computational model of pure Mg and HA-coated pure Mg degradation calibrated using in vitro degradation data to advance the use of Mg-based biomaterials, and more broadly, to predict degradation rates of next-generation orthopedic implants., (© 2024 Wiley Periodicals LLC.)

2205 DSS is an excellent corrosion-resistant engineering metal material, but it is still threatened by microbiological corrosion. The addition of copper elements is a new approach to improving the resistance of 2205 DSS to microbiological corrosion. In this study, 2205-Cu DSS was compared with 2205 DSS to study its antimicrobial properties and resistance to microbiological corrosion in the presence of the electroactive bacterium Shewanella algae. The results showed that compared to 2205 DSS, the biofilm thickness and the number of live bacteria on the surface of 2205-Cu DSS were significantly reduced, demonstrating excellent antimicrobial properties against S. algae. Electrochemical tests and surface morphology characterization results showed that the corrosion rate and pitting of 2205-Cu DSS by S. algae were lower than that of 2205 DSS, indicating better resistance to microbiological corrosion. The good antimicrobial properties and resistance to microbiological corrosion exhibited by 2205-Cu DSS are attributed to the contact antimicrobial properties of copper elements in the 2205-Cu DSS matrix and the release of copper ions for antimicrobial effects. This study provides a new strategy for combating microbiological corrosion., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Surface modifications not only improve the corrosion resistance of Co-Cr-Mo dental alloys (Bego Wirobond ® C) but also ensure their long-term performance and reliability in dental applications. This paper describes the preparation of single-layer TiO 2 -ZrO 2 sol-gel coatings on the Co-Cr-Mo dental alloy using the method of dip-coating. The TiO 2 -ZrO 2 sol-gel coatings were sintered at 300 and 500 °C. SEM analysis shows that sintering at 300 °C produces a uniform, slightly dense structure without micro-cracks, while sintering at 500 °C results in a denser structure with micro-cracks due to higher stress and shrinkage. EDS confirms that sintering temperature affects the elemental composition of the coating, with higher temperatures causing the volatilization or diffusion of Ti and Zr. Roughness measurements indicate that the Ra value increases with the sintering temperature, meeting dental application requirements. Electrochemical measurements by open-circuit potential, EIS, and cyclic potentiodynamic curves demonstrate that sintering temperature and saliva composition affect corrosion resistance, with NaF and mouthwashes (Listerine Total Care Teeth Protection ® and Meridol ® ) generally increasing charge transfer resistance and double-layer capacitance. The ceramic TiO 2 -ZrO 2 coatings significantly reduce pitting corrosion susceptibility at physiological and acidic pH, with the 500 °C sintered coating showing better protective properties. These findings highlight the potential of TiO 2 -ZrO 2 coatings in enhancing the performance of Co-Cr-Mo dental alloys.

Corrosion is a major threat in the aeronautic industry, both in terms of safety and cost. Efficient, versatile, and cost affordable solutions for corrosion monitoring are thus needed. Ultrasonic Lamb Waves (LW) appear to be very efficient for corrosion monitoring and can be made cost effective and versatile if emitted and received by a sparse array of piezoelectric elements (PZT). A LW solution relying on a sparse PZT array and allowing to monitor µm-sized corrosion pit growth on stainless 316L grade steel plate is here evaluated. Experimentally, the corrosion pit size is electrochemically controlled by both the imposed electrical potential and the injection of a corrosive NaCl solution through a capillary located at the desired pit location. In parallel, the corrosion pit growth is monitored in-situ every 10 s by sending and measuring LW using a sparse array of 4 PZTs bonded to the back of the steel plate enduring corrosion. As a ground truth information, the corrosion pit volume is estimated as the dissolved volume balancing the electronic charges exchanged during corrosion. The corrosion pit radius is additionally checked post-experiment precisely with an optical measurement. Measured LW signals are then post-processed in order to compute a collection of synthetic damage indexes (DIs). After dimension reduction steps, obtained DI values correlates extremely well with the corrosion pit radius. Using a linear model relating those DI values to corrosion pit radius, it is demonstrated that corrosion pit from 30 µm to 150 µm can be reliably detected, located, and their upcoming size extrapolated. Two independent experiments were achieved in order to ensure the repeatability of the proposed approach. LW managed by a sparse PZT array thus appears to be reliable and efficient to monitor growth of µm-sized corrosion pits on 316L steel plates. If embedded in aeronautical structure, such an approach could be a versatile and cost-effective alternative to actual non-destructive maintenance procedures that are time and manpower consuming., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: [REBILLAT Marc reports financial support was provided by French National Research Agency. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.]., (Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.)

The development of pitting corrosion on L245 carbon steel in a culture medium solution containing sulfate-reducing bacteria (SRB) was investigated. The results showed that the occurrence of corrosion in L245 carbon steel is closely linked to the evolution of biofilm and product film. As the test duration extended, overall corrosion was inhibited. Simultaneously, bacteria beneath the film layer promoted the generation and development of pitting corrosion, and the aggregation of bacteria (colonies) led to the aggregation of pitting corrosion.

The effect of temperature on the localized corrosion resistance and passive film characteristics of laser powder-bed fusion (LPBF) 316L (UNS S31603) was studied in a buffered 3.5 wt% NaCl solution at 25, 50, and 75 °C. DC techniques such as cyclic potentiodynamic polarization showed lower passive current densities, high breakdown potentials, and a higher resistance to initial breakdown compared with wrought 316L samples at all temperatures. However, LPBF 316L was more susceptible to metastable pitting at potentials before film breakdown and higher damage accumulation post film breakdown. AC techniques, such as Mott-Schottky analysis and electrochemical impedance spectroscopy, showed that the formed passive film was more robust on the LPBF 316L samples at all temperatures, accounting for the higher initial resistance to pitting. However, with increasing temperatures, the film formed had an increasing concentration of defect density. Passive compositions at the various test temperatures studied using X-ray photoelectron spectroscopy (XPS) showed that the LPBF samples showed higher amounts of Cr and Fe oxides and hydroxides compared with the wrought samples, which made the passive films on the LPBF samples more compact and protective. Investigation of the pits formed on the LPBF showed the preferential regions of attack were the melt-pool boundaries and cell interiors due to their being depleted of Cr and Mo when compared with the boundaries and matrix.

Sulfuric acid anodizing assisted by a hydrothermal sealing with inhibitors [Ce 3+ -Mo 6+ ] was used to prevent pitting corrosion on spray-deposited hypereutectic Al-Si alloy (A390). An investigation concerning the evaluation of pitting corrosion resistance on the anodic oxide thin film with ions incorporated was carried out in NaCl solution using electrochemical measurements (i.e., potentiodynamic polarization and electrochemical impedance spectroscopy, EIS). The influence of Si phase morphology and size on the growth mechanism of an anodic oxide film was characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results were then compared with those for its equivalent IM390 alloy (Al-17Si-4.5Cu-0.6Mg) produced through a conventional process ingot metallurgy, IM. The electrochemical findings indicate that sulfuric acid anodizing followed by a simple hot water sealing treatment was ineffective. In this manner, an intense attack was localized by pitting corrosion that occurred on the anodic oxide film in less than three days, as denoted by characteristic changes in the EIS spectra at the lowest frequencies. Improved results were achieved for Ce-Mo surface modification, which can provide better corrosion resistance on the aluminum alloys because no signs of pits were observed during the corrosion testing.

In this paper, the relationship between the pitting corrosion formation of B30 copper-nickel (CuNi) alloy and the metabolism of sulfate-reducing bacteria (SRB) was investigated. Combined with the influence of temperature during the actual operation of the cooling systems, the evolution law of the alloy passivation film was analyzed, and the mechanism of SRB promoting the accelerated development of B30 CuNi alloy pitting corrosion was revealed. The results show that SRB significantly promoted the pitting formation and development of B30 CuNi alloy. The maximum pitting depth was 3.9 μm in the sterile system and 15.3 μm with SRB, which was 3.9 times higher than that of sterile system. The loose porous Cu 2 S film formed by SRB metabolites and copper matrix was easily penetrated by corrosive anions, which promoted copper dissolution and led to pit nucleation. The sulfide adsorbed on the surface prevented or delayed the passivation of B30 CuNi alloy by blocking the adsorption site of O atom, and the corrosion nuclei continued to grow. The non-uniformity caused by the film peeling accelerated the longitudinal development of pitting corrosion, and the expansion and coalescence of adjacent pits caused the transverse development of pitting corrosion. Temperature had a certain influence on the SRB and the formation of B30 CuNi alloy passivation film. The passivation film was formed rapidly at 50 °C with poor quality and the passivation property of Cu 2 O film was weakened. With the increase of temperature, the pitting potential of sterile system negative shifted from 0.447 to 0.360 V (vs. SCE), while SRB system from 0.340 to 0.198 V (vs. SCE), and the pitting resistance decreased. The passivation film with defects and the Cu 2 S reduced the barrier efficiency of the film and accelerated the pitting corrosion of B30 CuNi alloy., Competing Interests: Declaration of competing interest We declare that we have no financial and personal relationships with other people or organizations that can inappropriately influence our work, there is no professional or other personal interest of any nature or kind in any product, service and/or company that could be construed as influencing the position presented in, or the review of, the manuscript entitled., (Copyright © 2024. Published by Elsevier B.V.)

Acetobacter aceti is a microbe that produces corrosive organic acids, causing severe corrosion of industrial equipment. Previous studies have focused on the organic acid corrosion of A. aceti, but neglected the possibility that it has electron transfer corrosion. This study found that electron transfer and organic acids can synergistically promote the corrosion of 2205 duplex stainless steel (DSS). Electrochemical measurement results showed that corrosion of 2205 DSS was more severe in the presence of A. aceti. Surface analysis indicated a thick biofilm formed on the steel surface, with low pH and dissolved oxygen concentrations under the biofilm. Corrosion intensified when A. aceti lacked a carbon source, suggesting that A. aceti can corrode metals by using metallic substrates as electron donors, in addition to its acidic by-products., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The paper introduces a computer vision methodology for detecting pitting corrosion in gas pipelines. To achieve this, a dataset comprising 576,000 images of pipelines with and without pitting corrosion was curated. A custom-designed and optimized convolutional neural network (CNN) was employed for binary classification, distinguishing between corroded and non-corroded images. This CNN architecture, despite having relatively few parameters compared to existing CNN classifiers, achieved a notably high classification accuracy of 98.44%. The proposed CNN outperformed many contemporary classifiers in its efficacy. By leveraging deep learning, this approach effectively eliminates the need for manual inspection of pipelines for pitting corrosion, thus streamlining what was previously a time-consuming and cost-ineffective process.

In the present work, the influence of a corrosive environment and temperature on the corrosion resistance properties of duplex stainless steel S31803 was evaluated. The corrosive process was carried out using solutions of 1.5% HCl (m/m) and 6% FeCl 3 (m/m), at temperatures of 25 and 50 °C. The microstructure of UNS S31803 duplex stainless steel is composed of two phases, ferrite and austenite, oriented in the rolling direction, containing a ferrite percentage of 46.2% in the rolling direction and 56.1% in the normal direction. Samples, when subjected to corrosive media and temperature, tend to decrease their mechanical property values. It was observed, in both corrosive media, that with increasing test temperature, there is an increase in the corrosion rate, both uniform and pitting. The sample in HCl solution obtained a uniform corrosion rate of 0.85% at 25 °C and 0.92% at 50 °C and pitting rates of 0.77% and 1.47% at the same temperatures, respectively. When tested in FeCl 3 solution, it obtained uniform corrosion of 0.0006% and 0.93% and pitting of 0.53% and 18.5%, at the same temperatures. A reduction in dissolution potentials is also noted, thus characterizing greater corrosion in the samples with increasing temperature.

Re-tightening the loosened dental implant abutment screw is an accepted procedure, however the evidence that such screw will hold sufficiently is weak. The purpose of this study was material analysis of lost dental implant abutment screws made of the TiAlV alloy from various manufacturers, which became lost due to unscrewing or damaged when checking if unscrewed; undamaged screws could be safely re-tightened. Among 13 failed screws retrieved from 10 cases, 10 screws were removed due to untightening and 3 were broken but without mechanical damage at the threads. Advanced corrosion was found on nine screws after 2 years of working time on all surfaces, also not mechanically loaded. Sediments observed especially in the thread area did not affect the corrosion process because of no pit densification around sediments. Pitting corrosion visible in all long-used screws raises the question of whether the screws should be replaced after a certain period during service, even if they are well-tightened. This requires further research on the influence of the degree of corrosion on the loss of the load-bearing ability of the screw.

In this study, the efficacy of the combined effect of borate and silicate alkali metal salts added to mortars for controlling the chloride-induced uniform and localized corrosion of embedded steel rebars is examined. The individually added salts in mortars are found to have insignificant effects in terms of reducing the uniform corrosion rate and localized damage. However, their combination (0.50% sodium tetra borate + 0.10% sodium silicate added with respect to the weight of the binder) provides complete protection to reinforcements tested for long durations under wet/dry treatments with mortars in saline water and laboratory atmospheres. Electrochemical impedance spectroscopy, direct current cyclic polarization, polarization resistance, and visual observations are used for quantitative and qualitative evaluations of the protective effects of the tested additives. X-ray diffraction analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy analysis of the corrosion products formed on the embedded steel surfaces help explain the possible mechanisms behind the considerable improvement in the inhibitive effects of a mixed composition of borate and silicate. This combination also improves the compressive strength and workability of the mixed concrete. The results reveal that the synergistic protection provided by a mixture of borate and silicate can be attributed to the co-deposition of an iron-boron + ferrosilicate + cortensitite (an iron-silicon phase) film on the rebar surface., (© 2024. The Author(s).)

The 1100 aluminum alloy has been widely used in many industrial fields due to its high specific strength, fracture toughness, excellent thermal conductivity, and corrosion resistance. In this study, the corrosion behavior of the homogenized and hot-extruded 1100 aluminum alloy in acid salt spray environment for different time was studied. The microstructure of the 1100 aluminum alloy before and after corrosion was characterized by an optical microscope (OM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and a laser scanning confocal microscope (LSCM). The difference in corrosion resistance between the homogenized and extruded 1100 aluminum alloy was analyzed via the electrochemical method. The results indicate that after hot extrusion at 400 °C, the microstructure of the 1100 aluminum alloy changes from an equiaxed crystal structure with (111) preferentially distributed in a fibrous structure with (220) preferentially distributed. There was no obvious dynamic recrystallization occurring during extrusion, and the second-phase particles containing Al-Fe-Si were coarse and unevenly distributed. With the increase in corrosion time, corrosion pits appeared on the surface of the 1100 aluminum alloy, and a corrosion product layer was formed on the surface of the homogenized 1100 aluminum alloy, which reduced the corrosion rate. After 96 h of corrosion, the CPR of the extruded samples was 0.619 mm/a, and that of the homogenized samples was 0.442 mm/a. The corrosion resistance of the extruded 1100 aluminum alloy was affected by the microstructure and the second phase, and no protective layer of corrosion products was formed on the surface, resulting in a faster corrosion rate and deeper corrosion pits.

Unveiling materials' corrosion pathways is significant for understanding the corrosion mechanisms and designing corrosion-resistant materials. Here, we investigate the corrosion behavior of Sn@Ni 3 Sn 4 and Sn nanocrystals in an aqueous solution in real time by using high-resolution liquid cell transmission electron microscopy. Our direct observation reveals an unprecedented level of detail on the corrosion of Sn metal with/without a coating of Ni 3 Sn 4 at the nanometric and atomic levels. The Sn@Ni 3 Sn 4 nanocrystals exhibit "pitting corrosion", which is initiated at the defect sites in the Ni 3 Sn 4 protective layer. The early stage isotropic etching transforms into facet-dependent etching, resulting in a cavity terminated with low-index facets. The Sn nanocrystals under fast etching kinetics show uniform corrosion, and smooth surfaces are obtained. Sn nanocrystals show "creeping-like" etching behavior and rough surfaces. This study provides critical insights into the impacts of coating, defects, and ion diffusion on corrosion kinetics and the resulting morphologies.

Biomedical alloys, like many engineering alloys, have chemical or physical heterogeneities at the surface, and such heterogeneities can potentially act as sites for pit initiation. Alloys of particular interest are 316/316L (and 316LVM) stainless steel, nitinol, and CoCr alloys. This review focuses on the sites-generally inclusions-that have been associated with pitting in various studies of biomedical alloys in simulated physiological solutions. The effect of these sites is discussed in relation to factors such as type and size. For both 316/316L stainless steel and nitinol, pitting has been found to initiate at two different types of inclusions: sulfide and oxide inclusions in stainless steel, and carbide and oxide inclusions in nitinol. Sulfide inclusions tend to be the predominant sites for pitting on 316/316L stainless steel, while there is some evidence to suggest that carbide inclusions may be more effective than oxide inclusions for pitting on nitinol. CoCrMo alloys differ from the other two alloys in that, although particles can be present in the form of carbides, the carbides typically do not provide sites for pit initiation except possibly for alloys with a high-C content, certain heat treatments, and when anodically polarized to high potentials. CoNiCrMo differs further in that TiN inclusions can be present in the vicinity of pits and might be associated with them, but irrespective of the initiation site, any pits are unlikely to grow because of repassivation., (© 2023 Wiley Periodicals LLC.)

The pitting corrosion of orthodontic apparatus elements in the oral environment is an interest of both clinicians and scientists dealing with the assessment of the biocompatibility of medical materials. This work presents a study on the effect of ready-to-use Listerine ® and Meridol ® mouthwashes and sodium fluoride on the resistance of the commercial Remanium ® -type orthodontic archwire to pitting corrosion in artificial saliva at 37 °C. XRD, SEM, EDS, mechanical properties, and microhardness measurements were used to characterize the archwire. The in vitro corrosion resistance of the archwire was examined using the open-circuit potential method, electrochemical impedance spectroscopy, and anodic polarization curves. The physicochemical characteristics confirmed the presence of a bi-phase alloy with a mixed austenite/ferrite structure containing Fe 74.4(7) at.%, Cr 18.4(4) at.%, and Ni 7.2(4) at.%. The Fe-Cr-Ni alloy was characterized by high tensile strength and Vickers microhardness. EIS revealed the capacitive behavior with high corrosion resistance. It was found that the kinetics of pitting corrosion in the artificial saliva decreased in the presence of NaF and mouthwashes. The potentiodynamic characteristics confirmed the decrease in susceptibility to pitting corrosion after the modification of artificial saliva. The pitting corrosion mechanism of the self-passive oxide layer on the surface of the Fe-Cr-Ni electrode in the biological environment containing chloride ions was discussed in detail. Mechanical properties after corrosion tests were weakened.

While chromium-nickel steel is known to be extremely resistant to corrosion, the occurrence of certain factors can unfortunately initiate an uncontrolled corrosion process. This paper presents samples made of 304 stainless steel containing delta ferrite that have been exposed to wastewater for 18 months. Samples placed above the surface of the wastewater (A-series) were intensively corroded. Samples half-submerged in the wastewater and periodically fully submerged at higher effluent flows through the screenings and grit separator (B-series) only suffered minor mechanical erosion. No significant changes in the tested surface were observed on samples fully submerged in wastewater (C-series). The results indicated that the observed pitting corrosion of samples placed above the surface of the wastewater was a consequence of the presence of bacteria in a wet hydrogen sulfide environment. The fluorescence in situ hybridization method showed that either the sludge taken from the wastewater, or from the surface of samples submerged in wastewater exhibited increased amounts of bacteria from the δ-proteobacteria class, indicating the presence of microorganisms involved in the reduction of sulfur or sulfate compounds. A new approach to microbiological evaluation by determining classes of bacteria may be a promising tool for evaluating wastewater in terms of aggressiveness and recognizing favorable corrosive conditions.

The AZ series of Mg alloys have become promising in several industrial fields thanks to its potential microstructure refinement and the β-Mg 17 Al 12 eutectic that controls the mechanical behaviour. Simultaneously, the rapid degradation characterizing Mg alloys makes the investigation of their corrosion behaviour necessary. The present work considers high-pressure die cast (HPDC) AZ91 alloy to evaluate its corrosion behaviour in 1M NaCl solution and investigates how different friction stir process parameters can affect the corrosion responses. No studies analyse the effects induced by the friction stir processed zone, reached using high rotational speeds (>2000 rpm), on the unprocessed HPDC AZ91 alloy. In addition, the morphological analysis of the corroded surfaces having a friction stir processed zone, in which the grain refinement was not obtained, is not present in the literature yet. Microstructural features were investigated by optical microscope and X-ray diffraction analysis before and after the friction stir process. These were subsequently correlated to the corrosion responses after the immersion tests. The results show that HPDC samples with a very smooth surface have the best corrosion resistance with a corrosion rate lower than 3 mm/year, evaluated through the weight loss, compared to the rougher ones. Both the amount of β-Mg 17 Al 12 eutectic and the wt.% Al in the α-Mg matrix, as well as the surface roughness, influence the corrosion behaviour of friction stir processed samples. The best corrosion resistance was obtained with an HPDC alloy processed at 2500 rpm and 50 mm/min.

Carbon starvation can affect the activity of microbes, thereby affecting the metabolism and the extracellular electron transfer (EET) process of biofilm. In the present work, the microbiologically influenced corrosion (MIC) behavior of nickel (Ni) was investigated under organic carbon starvation by Desulfovibrio vulgaris. Starved D. vulgaris biofilm was more aggressive. Extreme carbon starvation (0% CS level) reduced weight loss due to the severe weakening of biofilm. The corrosion rate of Ni (based on weight loss) was sequenced as 10% CS level > 50% CS level > 100 CS level > 0% CS level. Moderate carbon starvation (10% CS level) caused the deepest pit of Ni in all the carbon starvation treatments, with a maximal pit depth of 18.8 μm and a weight loss of 2.8 mg·cm -2 (0.164 mm·y -1 ). The corrosion current density (i corr ) of Ni for the 10% CS level was as high as 1.62 × 10 -5 A·cm -2 , which was approximately 2.9-fold greater than the full-strength medium (5.45 × 10 -6 A·cm -2 ). The electrochemical data corresponded to the corrosion trend revealed by weight loss. The various experimental data rather convincingly pointed to the Ni MIC of D. vulgaris following the EET-MIC mechanism despite a theoretically low E cell value (+33 mV)., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Steel rebar corrosion is one of the predominant factors influencing the durability of marine and offshore reinforced concrete structures, resulting in economic loss and the potential threat to human safety. Distributed fiber optic sensors (DFOSs) have gradually become an effective method for structural health monitoring over the past two decades. In this work, a strain transfer model is developed between a steel rebar and a DFOS, considering pitting-corrosion-induced strain variation in the steel rebar. The Gaussian function is first adopted to describe the strain distribution near the corrosion pit of the steel rebar and then is substituted into the governing equation of the strain transfer model, and the strain distribution in the DFOS is analytically obtained. Tensile tests are also conducted on steel rebars with artificially simulated corrosion pits, which are used to validate the developed model. The results show that the Gaussian function can be used to describe the strain variation near a corrosion pit with a depth less than 50% of the steel rebar diameter, and the strain distribution in the DFOS analytically determined based on the developed strain transfer model agrees well with the tensile test results. The corrosion pit depth and loading force in the steel rebars estimated based on the proposed model agree well with the actual values, and therefore, the developed strain transfer model is effective in detecting pitting corrosion and loading force in steel rebars.

Gas tungsten arc welding (GTAW) is commonly used for joining pipelines; however, it often leads to discoloration in the heat-affected zone (HAZ). In this study, 316L pipes were welded with different concentrations of oxygen present in the argon purge gas during welding. The objective of this study was to investigate the effect of oxygen concentration in the protective gas on the pitting corrosion resistance of welded pipes. The experimental results showed that the thickness of the oxide layer formed in the HAZ depends on the concentration of oxygen in the protective gas. Increasing the oxygen concentration in the protective gas resulted in an increase in pitting corrosion resistance until a critical value, beyond which the resistance decreased. The results showed that the thickness of the oxide layer formed in the HAZ depends on the concentration of oxygen in the protective gas. Increasing the oxygen concentration in the protective gas increased the pitting corrosion resistance until a critical value, beyond which the resistance decreased due to the formation of iron oxide. This study provides valuable insights for improving the corrosion resistance of welded pipes in the oil and gas industry.

Due to the combination of high corrosion resistance and suitable mechanical properties, AISI 316L stainless steel is extensively used as the biomaterial for surgical implants. However, heat exposure in inappropriate temperatures can cause its sensitization accompanied by chromium depletion along the grain boundaries. This study deals with an assessment of the susceptibility of sensitized AISI 316L biomaterial to pitting under conditions simulating the internal environment of the human body (Hank's balanced salt solution, 37 ± 0.5 °C). The resistance to pitting corrosion is tested by the potentiodynamic polarization and by the 50-day exposure immersion test. Corrosion damage after the exposure immersion test is evaluated in the specimens' cross-sections by optical microscope and SEM. Despite passive behavior in potentiodynamic polarization and shallow, slight corrosion damage observed after exposure, the sensitized AISI 316L biomaterial could represent a risk, especially in long-term implantation even after the chemical removal of high-temperature oxides.

Biofilms are a significant concern in the food industry. The utilization of plant-derived compounds to inactivate biofilms on food contact surfaces has not been widely reported. Also, the increasing negative perception of consumers against synthetic sanitizers has encouraged the hunt for natural compounds as alternatives. Therefore, in this study we evaluated the antimicrobial activities of ethanol extracts, acetone extracts, and essential oils (EOs) of seven culinary herbs against Salmonella enterica serotype Typhimurium and Listeria innocua using the broth microdilution assay. Among all tested extracts and EOs, the ethanol extract of Piper betle L. exhibited the most efficient antimicrobial activities. To evaluate the biofilm inactivation effect, S. Typhimurium and L. innocua biofilms on pitted and smooth stainless steel (SS) coupons were exposed to P. betle ethanol extract (12.5 mg/ml), sodium hypochlorite (NaClO; 200 ppm), hydrogen peroxide (HP; 1100 ppm), and benzalkonium chloride (BKC; 400 ppm) for 15 min. Results showed that, for the untreated controls, higher sessile cell counts were observed on pitted SS versus smooth SS coupons. Overall, biofilm inactivation efficacies of the tested sanitizers followed the trend of P. betle extract ≥ BKC > NaClO > HP. The surface condition of SS did not affect the biofilm inactivation effect of each tested sanitizer. The contact angle results revealed P. betle ethanol extract could increase the surface wettability of SS coupons. This research suggests P. betle extract might be utilized as an alternative sanitizer in food processing facilities.

The third-generation alloy, AA2198-T8, is highly recommended for the aerospace industry. However, it has come under scrutiny due to its high cost. This study aims to decrease the cost of manufacturing through a hybrid design that uses AA2198-T8 alloys for the crucial parts and AA2024-T3 alloys for the remaining structure. The two main techniques for joining AA2024-T3 to AA2198-T8 are reversed double-sided friction stir welding (DS-FSW) and traditional single-sided friction welding (SS-FSW). They were carried out under unaltered tool rotation speed followed by five different welding speeds. The mechanical properties of the joints were explored, and the maximum joining efficiency of the welding process was 96% for reversed DS-FSW at 102 mm/min welding speed. The hybrid joint was tested for compliance with ASTM G34 standards to examine the welding joint's exfoliation corrosion (EXCO) for eight exposure times. The findings showed that joint efficiency decreased relative to as-welded joints, and mechanical property deterioration increased with EXCO exposure duration, reaching 40% for specimens exposed for 120 h to the corroding solution. It has been noted that morphology and grain size changes significantly impact EXCO., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2023 The Authors.)

Aluminum alloy workpieces are prone to black spots and other corrosion problems in the cutting process, which greatly puzzles the machining industry and brings serious losses. However, the cause and mechanism of workpiece corrosion are still unclear. In this study, the effect of P. xiamenensis breeding in the cutting fluid on the corrosion of aluminum alloy 2219 (AA 2219) was studied by corrosion product characterization, biofilm evaluation, corrosion profile, quantitative pit analysis, and electrochemical characterization. The results showed that P. xiamenensis adhered to the surface of AA 2219, forming uneven corrosion product film and biofilm. The state of the film on the surface of the aluminum alloy changed, and pitting corrosion intensified after being immersed in cutting fluid containing P. xiamenensis. The maximum corrosion depths of the coupons were found to be 2.7 μm and 15.8 μm in sterile and inoculated cutting fluids, respectively. The corrosion rate of the aluminum alloy was as high as 9.16 × 10 -3 mm/y, which was about 9 times higher than the corrosion rate in the microbial-free cutting fluid. The presence of a P. xiamenensis biofilm accelerated the formation of the water-soluble corrosion product Al(OH) 4 , which destroyed the passive film and accelerated pitting corrosion.- , which destroyed the passive film and accelerated pitting corrosion., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

(i) Objective: The present study aimed to compare the electrochemical corrosion resistance of six different types of fixed lingual retainer wires used as fixed retention appliances in an in vitro study. (ii) Methods: In the study, two different Ringer solutions, with pH 7 and pH 3.5, were used. Six groups were formed with five retainer wires in each group. In addition, 3-braided stainless steel, 6-braided stainless steel, Titanium Grade 1, Titanium Grade 5, Gold, and Dead Soft retainer wires were used. The corrosion current density ( i corr ), corrosion rate (CR), and polarization resistance ( R p ) were determined from the Tafel polarization curves. (iii) Results: The corrosion current density of the Gold retainer group was statistically higher than the other retainer groups in both solutions ( p < 0.05). The corrosion rate of the Dead Soft retainer group was statistically higher than the other retainer groups in both solutions ( p < 0.05). The polarization resistance of the Titanium Grade 5 retainer group was statistically higher than the other retainer groups in both solutions ( p < 0.05). As a result of Scanning Electron Microscope (SEM) images, pitting corrosion was not observed in the Titanium Grade 1, Titanium Grade 5 and Gold retainer groups, while pitting corrosion was observed in the other groups. (iv) Conclusion: From a corrosion perspective, although the study needs to be evaluated in vivo, the Titanium Grade 5 retainer group included is in this in vitro study may be more suitable for clinical use due to its high electrochemical corrosion resistance and the lack of pitting corrosion observed in the SEM images.

Oxide metallurgy technology can improve the microstructure of a coarse-grained heat-affected zone (CGHAZ) but introduces extra inclusions. Local corrosion behavior of the CGHAZ of a Zr-Ti-Al-RE deoxidized steel was investigated in this work using theoretical calculations and experimental verification. The modified inclusions have a (Zr-Mg-Al-Ca-RE)O x core claded by a CaS and TiN shell. CaS dissolves first, followed by the oxide core, leaving TiN parts. This confirms that the addition of rare earth can reduce lattice distortion and prevent a galvanic couple between the inclusions and the matrix, while the chemical dissolution of CaS causes localized acidification, resulting in the pitting corrosion initiation.

By means of a pipe's inner surface grinding, a single-phase nanostructured austenite was formed on the surface of an AISI 304 stainless steel. The electrochemical corrosion behavior was compared with a coarse-grained counterpart of identical surface roughness. Experimental results show that the nanostructured austenite shows a higher pitting potential and a wider passivation interval than those of its coarse-grained counterpart. The enhanced corrosion resistance was attributed to the fast diffusion of Cr within the nanostructure and, hence, the formation of a thicker passive film to efficiently protect the surface against the ion attack. This work provides insights into a simple processing method to improve the surface strength and pitting resistance of stainless steel.

Cables are the main load-bearing components of a cable bridge and typically composed of high strength steel wires with a galvanized coating or Galfan coating. Galfan steel wire has recently started to be widely used because of its better corrosion resistance than galvanized steel wire. The corrosion characteristics of the coating and the difference in the corrosion fatigue process of the two types of steel wire are unclear. To further improve the service performance and maintenance of cable bridges, this study investigated the corrosion characteristics of galvanized steel wire and Galfan steel wire through accelerated corrosion tests and established a time-varying model of uniform corrosion and pitting corrosion of high-strength steel wire. Then, a long-span suspension bridge was taken as the research object, and the corrosion fatigue degradation of the two kinds of steel wire under a traffic load was analyzed on the basis of traffic monitoring data. The results showed that the uniform corrosion of the two types of steel wire conformed to an exponential development trend, the corrosion coefficient of galvanized steel wire conformed to the normal distribution, and the corrosion coefficient of Galfan steel wire conformed to the Cauchy distribution. The maximum pitting coefficient distribution of the two kinds of steel wire conformed to the generalized extreme value distribution. The location parameters and scale parameters of the two distributions showed an exponential downward trend with the increase of corrosion duration. When the traffic intensity was low, the corrosion characteristics of the steel wire was the main factor affecting its service life, and the average service life of Galfan steel wire was significantly higher than that of galvanized steel wire. Under a dense traffic flow, the service life of the steel wire was mainly controlled by the traffic load, and the service life of Galfan steel wire was slightly improved. Effective anti-corrosion measures are a key factor for improving the service life of steel wire.

In this work, the synergistic inhibitions of tungstate (WO 4 2- ) anions, including role and mechanism, on the initiation of pitting corrosion (PC) for Q235 carbon steel in chloride (Cl 4 2- ) anions, including role and mechanism, on the initiation of pitting corrosion (PC) for Q235 carbon steel in chloride (Cl - ) solution were investigated with electrochemical and surface techniques. The pitting potential (E p ) of the Q235 carbon steel in WO 4 2- + MoO 4 2- + Cl - solution was more positive than that in WO 4 2- + Cl - or MoO 4 2- + Cl - solution; at each E p , both peak potential and affected region of active pitting sites in WO 4 2- + MoO 4 2- + Cl - solution were smaller than those in WO 4 2- + Cl - or MoO 4 2- + Cl - solution. WO 4 2- and MoO 4 2- showed a synergistic role to inhibit the PC initiation of the Q235 carbon steel in Cl - solution, whose mechanism was mainly attributed to the influences of two anions on passive film. Besides iron oxides and iron hydroxides, the passive film of the Q235 carbon steel formed in WO 4 2- + Cl - , MoO 4 2- + Cl - , or WO 4 2- + MoO 4 2- + Cl - solution was also composed of FeWO 4 plus Fe 2 (WO 4 ) 3 , Fe 2 (MoO 4 ) 3 , or Fe 2 (WO 4 ) 3 plus Fe 2 (MoO 4 ) 3 , respectively. The film resistance and the defect quantity for Fe 2 (WO 4 ) 3 plus Fe 2 (MoO 4 ) 3 film were larger and smaller than those for FeWO 4 plus Fe 2 (WO 4 ) 3 film and Fe 2 (MoO 4 ) 3 film, respectively; for the inhibition of PC initiation, Fe 2 (WO 4 ) 3 plus Fe 2 (MoO 4 ) 3 film provided better corrosion resistance to Q235 carbon steel than FeWO 4 plus Fe 2 (WO 4 ) 3 film and Fe 2 (MoO 4 ) 3 film did.

In this study, the corrosion behavior and mechanism of Ti-6Al-4V in artificial saliva with Candida albicans were investigated using electrochemical and surface analysis techniques. Fluorescence microscopy (FM) and confocal laser scanning microscopy (CLSM) showed that C. albicans could easily adsorb on the surface of Ti-6Al-4V alloy to form non-dense biofilm. The non-compact biofilm provided necessary conditions for pitting corrosion on Ti-6Al-4V alloys by scanning electron microscopy (SEM) observation. The potentiodynamic polarization (PDP) curves and electrochemical impedance spectroscopy (EIS) revealed that C. albicans significantly reduced the corrosion resistance of Ti-6Al-4V alloys. The cyclic voltammetry (CV) and differential pulse voltammetry (DPV) results indicated that C. albicans biofilm promoted electron transfer from the anodic sites to cathodic depolarizer during the corrosion process, showing that the role of oral fungi must be considered when evaluating the performance of oral materials. This study may provide a new clue for evaluating the corrosion resistance of dental implant materials in the oral environment., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Considerable fluctuations in the cathodic protection potential under the impact of stray currents lead to the occurrence of local corrosion on steel structures operated in soils and seawater. The potential fluctuations induced by both alternating and direct current sources can be simulated by cycling a square potential step. This paper covers the impact of sign-alternating cyclic polarization (SACP) on the general and local corrosion of carbon steel in 3.5% NaCl solution containing a borate buffer (pH 6.7) and without it. A decrease in the cathodic half-period potential ( E c ) of SACP inhibited the general corrosion and accelerates the local corrosion of steel in both solutions, which was associated with an increase in the amount of hydrogen in the metal. Increasing the duration of the SACP cathodic half-period increased the pit density and total area at less negative E c values. At more negative E c values, an increase in the duration of cathodic polarization reduced the intensity of steel local corrosion in the unbuffered chloride solution. This effect is explained by blocking of the pit nucleation centers on the metal surface by a layer of steel dissolution products formed in the near-electrode electrolyte layer with a high pH. The combined body of data shows that hydrogen absorption by the metal determines the corrosion behavior of carbon steel under the impact of SACP in chloride solutions, which should be taken into account in the development of models of the corrosion of steel structures under the action of stray currents.

The electrochemical breakdown of a metal oxide film can directly affect the performance of functional electrochemical devices. However, revealing the structural insight into the breakdown sites is challenging because of heterogeneity: different breakdown sites are spatially distributed over the surface. Herein, we combine scanning electrochemical cell microscopy with identical-location microscopies to reveal the heterogeneity in the breakdown of NiO film on Ni in a site-by-site manner. Local critical breakdown potential varies by ∼500 mV, corresponding to an excess energy of 0.02-0.12 J/m 2 . Correlative composition imaging using time-of-flight secondary ion mass spectrometry shows Ni crystal grains with thinner NiO films are more resistant to breakdown. This high resistance is explained using classical nucleation theory, where the electrical energy is affected by the film thickness through the local interfacial capacitance. The correlative imaging approach overcomes the issue of heterogeneity, providing conclusive insight into the stability of the electrochemical interfaces.

A new type of pitting corrosion in copper, namely "moundless" corrosion, has recently been reported in Japan. This type of pitting corrosion has some unique morphological features that differ from ordinary types of pitting corrosion, such as type I or type II. Firstly, this type of pitting corrosion has no mound of corrosion products that cover the mouth of the pit. In addition, a glassy verdigris exists around the pit. Furthermore, the pit measures <1 mm in diameter, but is extremely deep. In our study, we reproduced moundless pits by field testing in an area where moundless pits have often occurred. Moundless pits were also generated in synthetic freshwater through the dissolution of some selected components in a laboratory test. This synthetic freshwater contained 40 ppm SiO 2 , 50 ppm SO 4 2- , 10 ppm Cl - , and 10 ppm HCO 3 - . Surface analysis of the moundless pit revealed that the mouths of the pits were covered with thin films that were mainly composed of silica., Competing Interests: The authors declare no conflict of interest., (© 2022 The Author(s).)

The degradation of metal materials in a marine environment represents the consequence of the electrochemical corrosion of metals under the influence of the environment. The application of new materials in the maritime industry requires experimental, real-world research on the form of corrosive damage and the intensity of the corrosion. This paper analyses the pitting corrosion of a rod-shaped nickel-titanium (Ni-Ti) alloy that was produced by means of the continuous casting method. In total, three samples were posted in a real seawater environment and analysed after 6, 12, and 18 months. Pits were detected on the Ni-Ti alloy after 18 months of exposure to the marine environment. The database on pitting corrosion was created by measuring depth in mm, which was performed by means of a nonlinear method, and by the generation of an artificial database of a total of 120, gauged in critical pit areas. The data were obtained by the application of a nonlinear model, and under the assumption that corrosion starts after 12 months of exposure in the corrosive marine environment. The EDX analysis of the Ni-Ti alloy composition inside the pits and on the edges of the pits indicated that the corrosion process in the hole of the pit occurs due to the degradation of the Ni.

In this paper, we have investigated the corrosion mechanism of X80 carbon steel in the presence of nitrate reducing bacteria (NRB), sulfate reducing bacteria (SRB) or both in the Shenyang soil solution. The results show that both SRB and NRB increase the corrosion rate of steel specimens and cause pitting corrosion of steel. Electrochemical tests and weight-loss data show that the addition of NRB in the SRB-containing environment leads to the reduction of corrosion. The thermodynamic analyses confirm the competitive advantage of NRB for the nutrients (organic carbon sources and irons) and the chemical oxidation of ferrous sulfide by nitrite, which results in a mitigation in the microbiologically influence corrosion (MIC) of SRB., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Aluminum alloy is widely used in aerospace structures. However, it often suffers from a harsh corrosion environment, resulting in different damage such as pitting corrosion, which leads to a reduction in the service life of aerospace structures. In the present study, the pitting corrosion with a radius of 1 mm and a depth of 0.6 mm was manufactured using hydrofluoric (HF) acid on a 2024-T3 aluminum alloy plate (400 mm × 400 mm × 2 mm) to simulate the corrosion state of equipment. A signal acquisition system with a square sensor network of 12 piezoelectric transducers (PZTs) was established. The sensor path weighting reconstruction algorithm for the probabilistic inspection of defects (SPW-RAPID) is proposed based on corrosion damage characteristic parameters including signal correlation coefficient (SDC), root mean squared error (RMSE), and signal energy damage index ( E 1) to explore the monitoring efficacy of pitting corrosion. The sensor path weight w , which is the product of value coefficient a and impact factor l , is established to modify the corrosion damage characteristic parameters. The results indicate that the SPW-RAPID algorithm can improve the accuracy and clarity of image reconstruction results based on SDC, RMSE and E 1, which can locate the pitting corrosion with a radius of 1 mm and a depth of 0.6 mm, and the positioning error is controlled within 0.1 mm. The research work may provide an available way to monitor tiny corrosion damage on an aluminum alloy structure.

Controlling the corrosion rate of implants to maintain mechanical properties during tissue healing is significant in developing magnesium alloy implants. In addition to surface treatment and material properties, the study of geometric alteration and mechanical strength are also vital for implant development. In this study, we developed a three-dimensional model for semi-autonomous computational pitting corrosion. It is based on the Monte Carlo method, modeling magnesium alloy implants toward clinical application. The corrosion probability is based on the number of exposed surfaces to saline and the oxidation characteristics of the elements. The computational results are well compared with the experimental measurement using micro-computed tomography (micro-CT) in 500 h. Subsequently, the computational analysis is extended to 3,000 h of corrosion analysis. The 3D model appears promising to assist the development of biodegradable implants., Competing Interests: The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2022 Chang, Chang and Hung.)

This paper investigates the corrosion of shot peened AA7075 aluminium alloys aged at different temperatures. The surface integrity of the hardened layer was evaluated with SEM, EDS, differential scanning calorimetry, hardness, and roughness measurements, and in the end also with corrosion resistance tests. The research results indicated that there were significant differences in precipitates distribution between aluminium alloys artificially aged at different temperatures. As the ageing temperature increases, the microhardness decreases, which influences the final roughness condition of the surface layer after shot peening. The results of potentiodynamic polarisation tests indicate that shot peening enables shifting the pitting potential to positive values, which ensures slightly higher corrosion resistance. SEM images confirmed the dissolution of the aluminium matrix near the separated iron-rich phases of the Al x form (Fe, Mn) by the action of galvanic cells.

In this study, the cause of failure of a low-carbon steel pipe meeting standard KS D 3562 (ASTM A135), in a district heating system was investigated. After 6 years of operation, the pipe failed prematurely due to pitting corrosion, which occurred both inside and outside of the pipe. Pitting corrosion occurred more prominently outside the pipe than inside, where water quality is controlled. The analysis indicated that the pipe failure occurred due to aluminum inclusions and the presence of a pearlite inhomogeneous phase fraction. Crevice corrosion occurred in the vicinity around the aluminum inclusions, causing localized corrosion. In the large pearlite fraction region, cementite in the pearlite acted as a cathode to promote dissolution of surrounding ferrite. Therefore, in the groundwater environment outside of the pipe, localized corrosion occurred due to crevice corrosion by aluminum inclusions, and localized corrosion was accelerated by the large fraction of pearlite around the aluminum inclusions, leading to pipe failure.

Adjusting the microstructure through the deformation process is one of the ways to improve the properties of Mg alloys. Most studies have focused on the influence of the microstructure after deformation treatment on the mechanical properties of Mg alloys. In this paper, extruded and forged Mg-Gd-Y-Nd-Zr alloys were selected to investigate the corrosion performance of two deformed magnesium alloys immersed in 0.6 M NaCl solution using a hydrogen evolution test, a weight loss test, an immersion experiment, and an electrochemical test. The results showed that WE43 alloys undergoing different deformation treatments presented different microstructures, which led to different corrosion behaviors and corrosion resistance. The extruded WE43 alloy showed uniform corrosion, while the forged WE43 alloy suffered severe local galvanic corrosion. Meanwhile, the corrosion rate of the forged WE43 alloy was about four times faster than that of the extruded WE43 alloy.

The use of metal additive manufacturing (AM) has strongly increased in the industry during the last years. More specifically, selective laser melting (SLM) is one of the most used techniques due to its numerous advantages compared to conventional processing methods. The purpose of this study is to investigate the effects of process parameters on the microstructural and corrosion properties of the additively manufactured AISI 316L stainless steel. Porosity, surface roughness, hardness, and grain size were studied for specimens produced with energy densities ranging from 51.17 to 173.91 J/mm 3 that resulted from different combinations of processing parameters. Using experimental results and applying the Taguchi model, 99.38 J/mm 3 was determined as the optimal energy density needed to produce samples with almost no porosity. The following analysis of variance ANOVA confirmed the scanning speed as the most influential factor in reducing the porosity percentage, which had a 74.9% contribution, followed by the position along the building direction with 22.8%, and finally, the laser energy with 2.3%. The influence on corrosion resistance was obtained by performing cyclic potentiodynamic polarization tests (CPP) in a 3.5 wt % NaCl solution at room temperature for different energy densities and positions ( Z axis). The corrosion properties of the AM samples were studied and compared to those obtained from the traditionally manufactured samples. The corrosion resistance of the samples worsened with the increase in the percentage of porosity. The process parameters have consequently been optimized and the database has been extended to improve the quality of the AM-produced parts in which microstructural heterogeneities were observed along the building direction.

The influence of the nanocrystalline structure produced by severe plastic deformation (SPD) on the corrosion behavior of CoCrFeMnNi alloys with Cr contents ranging from 0 to 20 at.% was investigated in aqueous 0.5 M H 2 SO 4 and 3.5% NaCl solutions. The resistance to general corrosion and pitting became higher in both the solutions, with higher passivation capability observed with increasing Cr content, and it is believed that the high corrosion resistance of CoCrFeMnNi alloys can be attributed to the incorporation of the Cr element. However, the impact of the nanocrystalline structure produced by SPD on the corrosion behavior was negligibly small. This is inconsistent with reports on nanocrystalline binary Fe-Cr alloys and stainless steels processed by SPD, where grain refinement by SPD results in higher corrosion resistance. The small change in the corrosion behavior with respect to grain refinement is discussed, based on the passivation process of Fe-Cr alloys and on the influence of the core effects of HEAs on the passivation process.

The effect of aging on the resistance to pitting corrosion of ultrafine-grained 7475 aluminium (Al) alloy processed by hydrostatic extrusion (HE) is studied. Differences in the microstructure were investigated using secondary electron (SEM) and transmission electron microscopy (TEM). Corrosion tests were performed in 0.1 M NaCl, and characterization of corroded surface was performed. The results of this work show that the pitting susceptibility of ultra-fine grained 7475Al is related to the distribution of MgZn 2 precipitates. After HE, the formation of An ultrafine-grained microstructure at the grain boundaries of ultrafine grains is observed, while subsequent aging results in the formation of MgZn 2 precipitates in the grain interior. Grain refinement increases susceptibility to localized attack, while the subsequent aging improves the overall corrosion resistance and limits the propagation of corrosion attack.

Introduction: Primary Ewing Sarcoma of Bone is a malignancy whose treatment requires both systemic chemotherapy and local control through surgical resection and/or radiation. Ewing Sarcoma of the pelvis has been noted to confer a worse prognosis relative to other anatomic sites of Ewing Sarcoma. This study explores the presenting features, treatment modalities for local control, and overall survival of primary Ewing sarcoma of the pelvis in comparison to other commonly affected anatomic sites., Methods: The National Cancer Institute Surveillance, Epidemiology, and End-Results (SEER) database was used to identify cases of pelvic Ewing sarcoma diagnosed between years 2004 and 2015. Demographic variables including sex, race, and age at diagnosis were described for each case, as well as therapeutic modalities including surgery and radiation. Bone-specific Collaborative Staging variables, including tumor size, tumor extension, and metastasis at diagnosis, were described for the same cohort. Univariate and multivariate assessments were performed for statistical comparison between presenting factors, treatment modalities, and between anatomic locations of presentation., Results: Within the database, 296 patients with Ewing sarcoma of the pelvic bones were available for review, which represented 25.7% of the 1152 cases surveyed across all anatomic sites. In the subset of patients with Ewing Sarcoma of the pelvis, 63.5% were male; the median age of diagnosis was 17 years; extra-compartmental tumor extension was noted in 82.1%; average tumor size was 9.7 cm; and metastasis at diagnosis was noted in 46.1% of the cohort. Only 28.6% of the pelvis sarcoma patients received surgical resection as part or all of their local control treatment, while 67.6% received some form of radiation therapy. When compared to the presenting features of Ewing Sarcoma from other anatomic sites, patients with pelvic tumors had larger tumors at time of diagnosis, higher rates of metastatic disease, and were less likely to undergo surgical intervention. The 2-, 5-, and 10-year overall survival rates for the patients presenting with Ewing Sarcoma of the pelvis was 70.3%, 49.7%, and 41.9%, respectively, which were significantly lower across all time-points than any other anatomic site., Discussion and Conclusion: Ewing Sarcoma of the pelvis is an aggressive malignancy that presents with relatively large tumors and a high rate of metastatic dissemination. Surgical intervention is less frequent when Ewing Sarcoma presents in the pelvis than when it presents in other anatomic locations. These factors may contribute to the worse overall survival of Ewing Sarcoma when compared to the same diagnosis originating in other anatomic sites. Prospective, randomized study is required to determine the true causal effects of these factors on survival., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

Copper strips experience severe corrosion when rolled with an oil-in-water (O/W) emulsions lubricant. The effects of rolling reduction on the pitting corrosion behavior and surface microstructure of Cu strips were studied in detail using electrochemical measurements and electron back scattered diffraction (EBSD) analysis. It was found that the corrosion current densities of the rolled Cu strips increased with accumulated reduction, which also lowered the pitting potentials and weakened their corrosion resistances. Therefore, the corrosive tendency of Cu strips under different rolling reductions (ε) followed the order of ε 0% < ε 20.7% < ε 50.6% < ε 77.3% . The Cu surface easily reacted with chlorine, sulfur, and carbon components from O/W emulsions to generate pitting corrosion. Under the interactive effect of pitting corrosion and stress corrosion, pits expanded along the rolling direction. The aggregation of anions in surface defects, such as dislocations, metastable pits, and microcracks, further accelerated the pitting corrosion of the surface.

A high-velocity oxygen fuel (HVOF) system was employed to prepare a Fe 49.7 Cr 18 Mn 1.9 Mo 7.4 W 1.6 B 15.2 C 3.8 Si 2.4 amorphous coating on mild steel. The electrochemical behavior of the resultant coatings, namely as-sprayed coating and vacuum heat-treated coating (at 650 °C and 800 °C), were investigated in a 3.5% NaCl solution at variable temperatures using scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, optical microscopy (OM), and XRD diffraction. Moreover, COMSOL Multiphysics version 5.5 software were employed for predicting the galvanic corrosion of amorphous material immersed in an aqueous NaCl solution, using the software finite element kit. The experiments demonstrated that the coatings' pitting resistance was significantly affected by temperature. The results also showed that temperature affected the pitting corrosion rate and changed the shape of the pits. However, the changes were not as extreme as those observed in stainless steel. Furthermore, there was no significant difference between the as-sprayed coating and the vacuum-heat-treated coating at 650 °C. At low NaCl concentrations at and temperatures below the critical pitting temperature, the resulting pits were significantly small with a hemisphere-like. By contrast, at a higher NaCl concentration at 70 °C, particularly in the case of heating at 650 °C, the pits appearing on the Fe-based amorphous coating were vast and sometimes featured a lacy cover.

Fungi that degrade B20 biodiesel in storage tanks have also been linked to microbiologically influenced corrosion (MIC). A member of the filamentous fungal genus Paecilomyces and a yeast from the genus Wickerhamomyces were isolated from heavily contaminated B20 storage tanks from multiple Air Force bases. Although these taxa were linked to microbiologically influenced corrosion in situ , precise measurement of their corrosion rates and pitting severity on carbon steel was not available. In the experiments described here, we directly link fungal growth on B20 biodiesel to higher corrosion rates and pitting corrosion of carbon steel under controlled conditions. When these fungi were growing solely on B20 biodiesel for carbon and energy, consumption of FAME and n -alkanes was observed. The corrosion rates for both fungi were highest at the interface between the B20 biodiesel and the aqueous medium, where they acidified the medium and produced deeper pits than abiotic controls. Paecilomyces produced the most corrosion of carbon steel and produced the greatest pitting damage. This study characterizes and quantifies the corrosion of carbon steel by fungi that are common in fouled B20 biodiesel through their metabolism of the fuel, providing valuable insight for assessing MIC associated with storing and dispensing B20 biodiesel. IMPORTANCE Biodiesel is widely used across the United States and worldwide, blended with ultra-low-sulfur diesel in various concentrations. In this study, we were able to demonstrate that the filamentous fungus Paecilomyces AF001 and the yeast Wickerhamomyces SE3 were able to degrade fatty acid methyl esters and alkanes in biodiesel, causing increases in acidity. Both fungi also accelerated the corrosion of carbon steel, especially at the interface of the fuel and water, where their biofilms were located. This research provides controlled, quantified measurements and the localization of microbiologically influenced corrosion caused by common fungal contaminants in biodiesel fuels.

In the present study, a new SERS-active gold nanoparticle clusters having a flower-shape have been prepared easily on nano porous anodic aluminium oxide (AAO) by immersing it in auric chloride solution without any need for complex production steps. In this process, presented for the first time, the metallic aluminum which were released under the influence of chloride ions due to pitting corrosion act as a reducing agent, while gold ions were reduced onto the AAO layer based on the difference in standard reduction potentials between aluminum and gold. Gold nanoparticle clusters on AAO layer formed "hot spots" providing enhanced Raman signal. Optical microscope, SEM, EDX, AFM, and UV-vis spectrophotometer have been used to characterize the substrate. In order to demonstrate applicability of the method, label free SERS measurements of nitrate ion was performed on the proposed sensing platform. A high sensitivity with 1.03 ppm of limit of detection level and the enhancement factor of 2.9 × 10 5 were obtained for nitrate ion. In addition, remarkable recoveries ranging from 98.4% to 106.8% were obtained for nitrate spiked into drinking water samples. The inter-day and intra-day precisions of the method as relative standard deviation (RSD) were determined as 3.3% and 5.2%, respectively. The sensor platform, developed using a facile method and a low-cost base material (aluminum), can be a good alternative for SERS based sensing applications., (Copyright © 2021 Elsevier B.V. All rights reserved.)