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The transition of the current fossil based chemical industry to a carbon-neutral industry can be done by the substitution of fossil carbon for defossilized carbon in the production of base chemicals. Methanol is one of the seven base chemicals, which could be used to produce other base chemicals (light olefins and aromatics). In this research, we evaluated the synthesis of methanol based on defossilized carbon sources (maize, waste biomass, direct air capture of CO 2 (DAC), and CO 2 from the cement industry) by considering carbon source availability, energy, water, and land demand. This evaluation was based on a carbon balance for each of the carbon sources. Our results show that maize, waste biomass, and CO 2 cement could supply 0.7, 2, 15 times the carbon demand for methanol respectively. Regarding the energy demand maize, waste biomass, DAC, and CO 2 from cement demand 25, 21, 48, and 45GJton MeOH separately. The demand for water is 5300, 220, 8, and 8m 3 ton MeOH . And lastly, land demand was estimated to 1031, 36, 83, and 77m 2 ton MeOH per carbon source. The high-demanding-resource production of defossilized methanol is dependent on the availability of resources per location. Therefore, we analyzed the production of defossilized methanol in the Netherlands, Saudi Arabia, China, and the USA. China is the only country where CO 2 from the cement industry could provide all the demand of carbon. But as we envision society becoming carbon neutral, CO 2 from the cement industry would diminish in time, as a consequence, it would not be sufficient to supply the demand for carbon. DAC would be the only source able to provide the demand for defossilized carbon., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Water users can reduce their impact on scarce freshwater resources by using more abundant regional brackish or saline groundwater resources. Decentralized water supply networks (WSN) can connect these regional groundwater resources with water users. Here, we present WaterROUTE (Water Route Optimization Utility Tool & Evaluation), a model which optimizes water supply network configurations based on infrastructure investment costs while considering the water quality (salinity) requirements of the user. We present an example simulation in which we determine the optimal WSN for different values of the maximum allowed salinity at the demand location while supplying 2.5 million m 3 year -1 with regional groundwater. The example simulation is based on data from Zeeuws-Vlaanderen, the Netherlands. The optimal WSN configurations for the years 2030, 2045 and 2110 are generated based on the simulated salinity of the regional groundwater resources. The simulation results show that small changes in the maximum salinity at the demand location have significant effects on the WSN configuration and therefore on regional planning. For the example simulation, the WSN costs can differ by up to 68% based on the required salinity at the demand site. WaterROUTE can be used to design water supply networks which incorporate alternative water supply sources such as local brackish groundwater (this study), effluent, or rainwater., (Copyright © 2021. Published by Elsevier Ltd.)

Petroleum-industry wastewater (PI-WW) is a potential source of water that can be reused in areas suffering from water stress. This water contains various fractions that need to be removed before reuse, such as light hydrocarbons, heavy metals and conditioning chemicals. Constructed wetlands (CWs) can remove these fractions, but the range of PI-WW salinities that can be treated in CWs and the influence of an increasing salinity on the CW removal efficiency for abovementioned fractions is unknown. Therefore, the impact of an increasing salinity on the removal of conditioning chemicals benzotriazole, aromatic hydrocarbon benzoic acid, and heavy metal zinc in lab-scale unplanted and Phragmites australis and Typha latifolia planted vertical-flow CWs was tested in the present study. P. australis was less sensitive than T. latifolia to increasing salinities and survived with a NaCl concentration of 12 g/L. The decay of T. latifolia was accompanied by a decrease in the removal efficiency for benzotriazole and benzoic acid, indicating that living vegetation enhanced the removal of these chemicals. Increased salinities resulted in the leaching of zinc from the planted CWs, probably as a result of active plant defence mechanisms against salt shocks that solubilized zinc. Plant growth also resulted in substantial evapotranspiration, leading to an increased salinity of the CW treated effluent. A too high salinity limits the reuse of the CW treated water. Therefore, CW treatment should be followed by desalination technologies to obtain salinities suitable for reuse. In this technology train, CWs enhance the efficiency of physicochemical desalination technologies by removing organics that induce membrane fouling. Hence, P. australis planted CWs are a suitable option for the treatment of water with a salinity below 12 g/L before further treatment or direct reuse in water scarce areas worldwide, where CWs may also boost the local biodiversity. Graphical abstract.