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Disasters caused by the spontaneous combustion of coal have occurred in major coal-producing countries, resulting in the loss of resources and human life and severe environmental pollution. The development of an efficient model to calculate the shortest spontaneous combustion period (SSCP) has been a long-standing challenge. In this study, we propose a continuous model that calculates the SSCP by changing the traditional time summation form into a time integration form. The proposed model can reduce the calculation errors and determine the heating time to any temperature, which overcomes the limitations of the traditional model. The accuracy and convenience of the improved model were validated through a comparison with the results of the traditional model and a numerical model. The parameter sensitivities were analyzed in the improved model. The results showed that the SSCPs calculated using the improved continuous model are in good agreement with those of the traditional and numerical models. The results also indicated that the continuous model is more accurate and convenient than the traditional model. Parameters such as the heat release intensity, water content, specific heat capacity, and gas content influence the SSCP results in the sensitivity analysis. This model can potentially help prevent and control the risk of coal spontaneous combustion and should be further tested in practical mine management., Competing Interests: The authors declare no competing financial interest., (Copyright © 2020 American Chemical Society.)

Concerns over the negative impacts of microplastics on human health have led to growing attention on the occurrence of microplastics in aquatic environment. Recent studies have extended their focus from marine to inland waters, especially on the spatial-temporal distribution of the microplastics in urban rivers. In this study, Maozhou River, the largest river in Shenzhen, a tributary of the Pearl River, was selected as a representative inland waterway of Guangdong-Hong Kong-Macao Greater Bay Area. The spatial-temporal investigation was performed on microplastics in the surface water and sediments of 17 sites along the mainstream of the Maozhou River. Results show that microplastics were widely and unevenly distributed along the river and reached the high abundances on the site most intensively surrounded by industries as well as the sites downstream. The abundances in dry season ranged from 4.0 ± 1.0 to 25.5 ± 3.5 items·L -1 in water and 35 ± 15 to 560 ± 70 item·kg -1 in sediments, which were relatively higher than those observed in the wet season (water: 3.5 ± 1.0 to 10.5 ± 2.5 items·L -1 ; sediments: 25 ± 5 to 360 ± 90 item·kg -1 ; p value < 0.05). The dominant types of the microplastics were identified as: PE Polyethylene (PE, water: 45.0%, sediments: 42.0%), polypropylene (PP, water and sediments: 12.5%), polystyrene (PS, water: 34.5%; sediments 14.5%) and polyvinyl chloride (PVC, water: 2.0%; sediments: 15%). Moreover, metals like Al, Si, Ca were discovered on the rough surface of the microplastics, indicating the interactions between the microplastics and the aquatic environment. Through a comprehensive comparison with other major inland waters in China, this work provides valuable data on the microplastics pollution of a representative inland water in the Greater Bay Area, and will further contribute to a better understanding on the land-based input of microplastics from the intensively affected inland waters., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Numerical modeling of water movement in both unsaturated soils and saturated groundwater aquifers is important for water resource management simulations. The development of efficient numerical algorithms for coupling unsaturated and saturated flow has been a long-lasting challenge in hydrologic modeling, especially for regional-scale modeling. In this study, a new method coupling the Finite Element Method (FEM) and Finite Difference Method (FDM), FE-FDM, is developed to solve Richards equation for simulating unsaturated-saturated water flow. The FEM is adopted to discretize the governing equation in the horizontal direction, while the FDM is used in the vertical direction. This method combines the advantages of FEM in domain discretization, especially for complex computational domain, and the advantages of FDM in modeling simplicity and efficiency. The validity of the new method is demonstrated with three test cases that show that the FE-FDM solutions are accurate and are applicable for regional scale problems. In the test cases, the FE-FDM solutions are compared with experimental data and numerical results calculated with common software packages including FEFLOW and COMSOL. This study verified that the FE-FDM is applicable for simulating water flow in the unsaturated-saturated zone.

This paper presents a demonstration of an integrated risk assessment and site investigation for groundwater contamination through a case study, in which the geologic and hydrogeological feature of the site and the blueprint of the fossil power plant (FPP) were closely analyzed. Predictions for groundwater contamination in case of accidents were performed by groundwater modeling system (GMS) and modular three-dimensional multispecies transport model (MT3DMS). Results indicate that the studied site area presents a semi-isolated hydrogeological unit with multiplicity in stratum lithology, the main aquifers at the site are consisted of the filled karst development layer with a thickness between 6.0 and 40.0 m. The poor permeability of the vadose zone at the FPP significantly restricted the infiltration of contaminants through the vadose zone to the subsurface. The limited influence of rarely isotropic porous karstified carbonate rocks on the groundwater flow system premised the simulate scenarios of plume migration. Analysis of the present groundwater chemistry manifested that that the groundwater at the site and the local area are of the HCO 3 -Ca, HCO 3 , and SO 4 -Ca types. A few of the water samples were contaminated by coliform bacteria and ammonia nitrogen as a result of the local cultivation. Prediction results indicate that the impact of normal construction and operation processes on the groundwater environment is negligible. However, groundwater may be partly contaminated within a certain period in the area of leakage from the diesel tanks, the industrial wastewater pool, and the cooling tower water tank in case of accidents. On a positive note, none of the plumes would reach the local sensitive areas for groundwater using. Finally, an anti-seepage scheme and a monitoring program are proposed to safeguard the groundwater protection. The integrated method of the site investigation and risk assessment used in this case study can facilitate the protection of groundwater for the construction of large-scale industrial project.

In the advanced oxidation processes, using persulfate (PS) as a radical precursor for pollutant degradation in groundwater has received increasing attention. In this study, zeolite supported nZVI composites (Z/nZVI) were synthesized through an ion exchange and borohydride reduction method to investigate their ability to activate PS for the TCE degradation. Based on preliminary screening of the PS activation by the Z/nZVI (PS-Z/nZVI) system in terms of TCE degradation, Z/nZVI composite with a zeolite to nZVI mass ratio of 1:1 (Z/nZVI (1)) was optimized as the best composition and chosen for further characterization and examination. Especially, for this PS-Z/nZVI system, PS concentration, solution matrix effects (i.e., solution pH, coexisting anions and natural organic matter) were studied. Characterization results revealed that the aggregation of nZVI particles was alleviated and they were good dispersed on the zeolite sheet with a large SSA (159.49 m 2 /g) compared to the unsupported nZVI (8.77 m 2 /g). The synthesized Z/nZVI (1) composite exhibited excellent activated ability towards PS (1.5 mM) and effectively degraded 98.8% of TCE at pH 7 within 120 min. The PS-Z/nZVI system was observed to operate effectively over a wide range of pH (i.e., 4-7) for TCE degradation. Moreover, the presence of nitrates (1 mM) and bicarbonates (10 mM) decreased the TCE degradation efficiency to 91.5% and 59.6%, respectively. Scavenger tests demonstrated that both sulfate and hydroxyl radicals participated in the TCE degradation. The ion chromatography analysis suggested the formation of oxalic acid and formic acid as the reaction intermediates during the TCE degradation process in the PS-Z/nZVI system., (Copyright © 2019 Elsevier B.V. All rights reserved.)

Persulfate (PSF) is a strong oxidant that has been used extensively in the In-Situ Chemical Oxidation (ISCO) technology. The geoenvironmental impact of PSF treatment is barely investigated. This situation should be carefully considered as it may affect the reutilization of contaminated soil as engineering materials. This paper studied the removal of bisphenol A (BPA) by PSF with Nano Zero-Valent Iron (nZVI) and percarbonate (SPC) activated/enhanced and their subsequent impacts on the engineering properties of soil. The physicochemical and geotechnical properties of soils before and after treatment were evaluated using batch experiments. The results indicate that the introduced pristine PSF can be activated by some naturally occurring matters and subsequently lead to the mineralization of BPA. Both non-activated PSF and activated/enhanced PSF treatment led to the soil improvement in the undrained shear strength at different degrees. The primary mechanism of soil improvement is ascribed to the heterogeneous sulfate and/or carbonate precipitation. Meanwhile, Ca2+ in the pore fluid played a significant role in the enhancement of the soil strength. A conclusion was drawn that the treatment of both non-activated PSF, nZVI- and SPC-activated PSF treatment can achieve removal of BPA and soil improvement in the short-term simultaneously. This study can improve the PSF-involved remediation of brownfields and dredged sediments for a sustainable and low-carbon society., Competing Interests: The authors have declared that no competing interests exist.

This study demonstrates the feasibility of nanoscale Zero-Valent Iron (nZVI) for simultaneous stabilization of Pb and improvement of soil strength via batch experiments. The soil samples were prepared using slurry and pre-consolidation method at nZVI doses of 0.2%, 1%, 5%, and 10% (by dry weight). The physicochemical and geotechnical properties of Pb-contaminated soil treated by nZVI were analyzed. The results indicate that the contamination of Pb(II) resulted in a notable reduction in the undrained shear strength of soil from 16.85 kPa to 7.25 kPa. As expected, the Pb in exchangeable and carbonate-bound fractions decreased significantly with the increasing doses of nZVI. Meanwhile, the undrained shear strength of Pb-contaminated soil enhanced substantially as the increase of nZVI, from 25.83 kPa (0.2% nZVI treatment) to 69.33 kPa (10% nZVI treatment). An abundance of bubbles, generated from the oxidation of nZVI, was recorded. The mechanisms for simultaneous stabilization of Pb and soil improvement primarily include: 1) the precipitation and transformation of Pb-/Fe-hydrated oxides on the soil particles and their induced bounding effects; 2) the increased drainage capability of soil as the occupation of nZVI aggregates and bubbles in the macropores space and 3) the lower soil density derived from the increase in microbubbles retained in the soil. This study is provided to facilitate the application of nZVI in the redevelopment of contaminated soil., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Near surface disposal of low- and intermediate-level radioactive wastes (LILW) requires evaluating the field conditions of the candidate site. However, assessment of the site conditions may be challenging due to the limited prior knowledge of some remote sites, and various multi-disciplinary data requirements at any given site. These situations arise in China as in the rest of the industrialized world, particularly since a regional strategy for LILW disposal has been implemented to protect humans and the environment. This paper presents a demonstration of the site assessment process through a case study focusing mainly on the geologic, hydrogeologic and geochemical characteristics of the candidate site. A joint on-site and laboratory investigation, supplemented by numerical modeling, was implemented in this assessment. Results indicate that no fault is present in the site area, although there are some minor joints and fractures, primarily showing a north-south trend. Most of the joints are filled with quartz deposits and would thus function hydraulically as impervious barriers. Investigation of local hydrologic boundaries has shown that the candidate site represents an essentially isolated hydrogeologic unit, and that little or no groundwater flow occurs across its boundaries on the north or east, or across the hilly areas to the south. Groundwater in the site area is recharged by precipitation and discharges primarily by evapo-transpiration and surface flow through a narrow outlet to the west. Groundwater flows slowly from the hilly area to the foot of the hills and discharges mainly into the inner brooks and marshes. Some groundwater circulates in deeper granite in a slower manner. The vadose zone in the site was investigated specially for their significant capability for restraining the transport of radionuclides. Results indicate that the vadose zone is up to 38m in thickness and is made up of alluvial clay soils and very highly weathered granite. The vadose zone has low saturated hydraulic conductivities on the order of 10(-5)cm/s and in this respect is well-suited for the disposal of LILW. The saturated formations are primarily made up of silt and moderately-to-slightly weathered granite, which exhibit even lower hydraulic conductivities, on the order of 10(-6)cm/s, also favorable for restraining the transport of radionuclides. Chemical analyses indicate that the groundwaters at the site are of the HCO(3)-Na · Ca and HCO(3) · SO(4)-Na · Ca types and are weakly corrosive to concrete and steel. Geochemical analyses indicate that the rock and soil materials (particularly weathered granite) at the site contain very small fractions of colloidal particles and exhibit low Cation Exchange Capacities (CEC), and would therefore have limited capacity for sorption of radionuclides. Groundwater flow and solute transport models of the candidate site have been developed using MODFLOW and MT3DMS, incorporating the data obtained during the assessment program. Calibration was based on the available measured groundwater level fluctuations and tracer concentrations from in situ dispersion tests. The longitudinal dispersion coefficient as determined in calibration is equal to 5.0 × 10(-3) m(2)/d. Numerical sensitivity analyses indicate that the hydraulic conductivity and the longitudinal dispersion coefficient are the key parameters controlling the transport of radionuclides, while the numerical model is not sensitive to changes in the effective porosity and the specific yield. Preliminary predictions have been performed with the calibrated model both for the natural setting of the site and the graded site in which the valleys of the site are backfilled with low permeable materials. Results indicate that the proposed site grading increases the safety of the site for disposal of LILW by reducing both the groundwater level and the hydraulic gradient and that radionuclide transport would not likely be a problem or cause groundwater contamination. Although there are some problems remaining to be addressed in future work, the conclusion of the assessment is that the conditions at this site are appropriate for LILW disposal. This study provides an example of the procedures necessary in an assessment of site conditions relevant to the safe disposal of LILW. Such an assessment is crucial to the site selection process and to subsequent environmental impact assessment., (Copyright © 2011 Elsevier B.V. All rights reserved.)