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Highly flexible hydrogels are widely used in fields such as agriculture, drug delivery, and tissue engineering. However, the simultaneous integration of excellent mechanical properties, swelling properties, and high electrical conductivity into a hydrogel is still a great challenge. This work introduces 1D tubular multi-walled carbon nanotubes (MWCNTs) and 2D layered graphene oxide (GO) into polyacrylamide/poly-acrylic acid (PAM/PAA) hydrogels. The high specific surface area and oxygen-containing groups of GO contribute to excellent mechanical properties and water absorption of the PAM/PAA hydrogels, but the conductivity is poorly affected due to the presence of defects on GO surface. However, MWCNTs with large aspect ratios benefit to form continuous conductive paths in PAM/PAA hydrogels which further improves conductivity of the hydrogels. MWCNTs are entangled with PAM/PAA molecular chains to form a dense three-dimensional (3D) network structure, and this special structure improves the water absorption of PAM/PAA hydrogels by 3.7 g g -1 . What's more, the MWCNTs/PAM/PAA hydrogel not only provides excellent mechanical properties (compressive strength up to 2.7 MPa), but also has high conductivity (2.3 S m -1 ). In particular, a strain sensor based on MWCNTs/PAM/PAA hydrogel exhibits exceptional sensitivity (gauge factor = 3.9 at 230-300 % strain) with a rapid response (200 ms) over a wide strain range (50 ∼ 200 %) which enables the ability to precisely and reliably monitor human motion. Therefore, the work provides a new insight into the design of multifunctional hydrogels with application on anatomical water plugging, electronic skin, and biosensors., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Inc.)

Hydrogels present significant potential in flexible materials designed for electromagnetic interference (EMI) shielding, attributed to their soft, stretchable mechanical properties and water-rich porous structures. Unfortunately, EMI shielding hydrogels commonly suffer from low mechanical properties, deficient fracture energy, and low strength, which limit the serviceability of these materials in complex mechanical environments. In this study, the double network strategy is successfully utilized along with the Hofmeister effect to create MXene/PAA (polyacrylic acid)-CS (chitosan) hydrogels and further strengthen and toughen the gel with (NH 4 ) 2 SO 4 solution. The gel exhibits enhanced functionalities such as outstanding stretchability, excellent strain sensitivity (11.66), and super fracture energy (≥9 kJ m -2 ). Notably, it demonstrates outstanding shielding effectiveness of 73.8 dB in the terahertz (THz) range, and the shielding properties can be effectively tuned by varying the MXene content, the (NH 4 ) 2 SO 4 concentration, and the thickness of the hydrogel. Additionally, the gel shows robust and superior shielding effectiveness after repeated stretching and long-term dehydration. The MXene/PAA-CS double-network (DN) hydrogels would be an excellent candidate for EMI shielding materials in advanced flexible electronic equipment and soft robots., (© 2024 Wiley‐VCH GmbH.)

To advance the industrialization of flexible strain sensors, an innovative flexible sensing fiber was developed through a sophisticated wet spinning process. Silver trifluoroacetate and graphene oxide (GO) were combined with thermoplastic polyurethane (TPU) to prepare the fibers via wet spinning. Ascorbic acid was used to in situ reduce the silver trifluoroacetate and graphene oxide within the polyurethane, causing the growth of silver nanoparticles to bond with reduced graphene oxide, forming a dual conductive pathway. This resulted in the creation of silver nanoparticles/reduced graphene oxide/polyurethane fibers (AgNPs-rGO-TPU sensing fibers). The tensile and sensing properties of AgNPs-rGO-TPU sensing fibers under different parameters were investigated. The results showed that with 25 wt% TPU as the matrix, 30 wt% silver trifluoroacetate, and 1 wt% graphene oxide, the fibers achieved an optimal balance of mechanical and sensing properties. The tensile strength was 7.69 MPa, the elongation at break was 370.75%, and the toughness modulus was 18.45 MJ m -3 . The AgNPs-rGO-TPU sensing fibers effectively detect external stimuli, exhibiting high sensitivity over a wide strain range (gauge factor is 4.25 below 5% strain, 24.79 in the 5%-25% strain range, 23.06 in the 25%-80% strain range, and 21.32 in the 80%-110% strain range), with a conductivity of 163.17 ms·cm -1 . They can stably recognize movements and physiological signals from various parts of the human body, showing good application prospects., (© 2025 IOP Publishing Ltd. All rights, including for text and data mining, AI training, and similar technologies, are reserved.)

Strain sensors utilizing mechanoluminescent (ML) materials have garnered significant attention and application due to their advantages, such as self-powering, non-contact operation, and real-time response. However, ML-based strain sensing techniques typically rely on the establishing of a mathematical relationship between ML intensity and mechanical parameters. The absolute ML intensity is vulnerable to environmental factors, which can result in measurement errors. Herein, an color-resolved visualized dynamic ML and self-referencing strain sensing is investigated in Ca 9 Al(PO 4 ) 7 : Tb 3+ , Mn 2+ . By analyzing the ML performance under various mechanical stimulations and adjustable strain parameters, a relationship between strain and the ML intensity ratio of Tb 3+ /Mn 2+ is aimed to bed established. This will enable the development of a self-referencing and visualized strain sensing technology. Through a comparison of luminescence characteristics under continuous mechanical stimulation (stretching) and continuous X-ray irradiation, it is discovered that the ratiometric dynamic ML is primarily driven by the dynamic filling and continuous release of carriers form traps, which compensates for the ML of Mn 2+ . Leveraging the self-referencing and color-resolved (from green to red) visualized ML characteristics, an application scenario for monitoring human joint movement is developed. This approach offers new insights into the use of dynamic ML materials in strain sensing and human-machine interaction., (© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)

Achieving high shielding effectiveness in electromagnetic shielding materials relies heavily on high conductivity, yet simultaneously enhancing the absorption loss remains a persistent challenge. Consequently, the study successfully creates efficient electromagnetic shielding composite films with a unique grape-like bunch structure of hollow nanosilver (HCAF) through layer-by-layer assembly. The utilization of poly(dopamine) (PDA) to anchor nanosilver granules (AgNPs) onto cellulose nanofibers (CNF) results in the formation of CNF@PDA@AgNPs. Subsequently, a surface protection etching method is employed to etch the AgNPs, resulting in hollow nanosilver (H-AgNPs) and the generation of CNF@PDA@H-AgNPs. A composite film featuring a grape bunch structure is fabricated by interweaving high aspect ratio CNF with CNF@PDA@H-AgNPs. A substantial quantity of H-AgNPs creates an abundant interface, while the grape bunch structure establishes an efficient conductive network. That enables the composite film to exhibit excellent impedance matching, excellent conductivity loss, abundant polarization loss, and multiple reflection loss. Therefore, the conductivity of the composite film with a thickness of 148.8 μm reaches 212660 S/m, with SE T , SE A , and SE R 89.56, 79.03, and 10.53 dB in the X band, significantly better than the 76.9, 55.55, and 21.41 dB of the solid AgNPs composite film. The composite film also exhibits remarkable thermal conductivity (The coefficients of in-plane and out-plane thermal conductivity are 4.61 and 0.17 W/(m·K), respectively), mechanical properties, and strain sensing capabilities, making it significant potential for applications in flexible electronics and other related fields.

The ultrafast preparation of electrically conductive hydrogels to endow high sensing performance and temperature tolerance remains a critical challenge. Herein, lignosulfonate sodium-templated polypyrrole (LS-PPy) nanofillers were rapidly introduced into polyacrylic acid (PAA) hydrogel through ultrafast free radical polymerization in a glycerol/water binary solvent system. The resultant LS-PPy/PAA electrically conductive organohydrogel possesses satisfactory mechanical performance (strength of 56 kPa at a tensile strain of 800 %), strong adhesion, and a desirable low freezing point (-35 °C). Furthermore, this organohydrogel exhibits high strain sensitivity (gauge factor = 2.65), fast response time (∼160 ms), low signal hysteresis, and excellent cyclic stability (over 1200 cycles). And the wearable LS-PPy/PAA organohydrogel sensor could accurately and real-time monitor various intense or subtle human movements, such as joint bending, facial expression and hand writing. Besides, the developed LS-PPy/PAA temperature sensor can respond to environmental temperature variations over a wide range of -20-100 °C. High resolution of 0.5 °C with remarkable sensitivity (-0.80 %/°C and linearity of R 2  = 0.99) and repeatability were achieved within 36.5-40 °C, which makes it suitable for human body temperature monitoring. All these results demonstrate the substantial prospective value of the LS-PPy/PAA hydrogel in wearable sensors and other associated fields., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

This paper explores the development of 3D-printed self-sensing Ultra-High Performance Concrete (UHPC) by incorporating graphite (G) powder, milled carbon microfiber (MCMF), and chopped carbon microfiber (CCMF) as additives into the UHPC matrix to enhance piezoresistive properties while maintaining workability for 3D printing. Percolation curves were established to identify optimal filler inclusion levels, and a series of compressive tests, including quasi-static cyclic, dynamic cyclic, and monotonic compressive loading, were conducted to evaluate the piezoresistive and mechanical performance of 29 different mix designs. It was found that incorporating G powder improved the conductivity of the UHPC but decreased compressive strength for both mold-cast and 3D-printed specimens. However, incorporating either MCMF or CCMF into the UHPC resulted in the maximum 9.8% and 19.2% increase in compressive strength and Young's modulus, respectively, compared to the plain UHPC. The hybrid combination of MCMF and CCMF showed particularly effective in enhancing sensing performance, achieving strain linearity over 600 με. The best-preforming specimens (3G250M250CCMF) were fabricated using 3 wt% of G, 0.25 wt% of MCMF, and 0.25 wt% of CCMF, yielding a maximum strain gauge factor of 540, a resolution of 68 με, and an accuracy of 4.5 με under axial compression. The 3D-printed version of the best-performing specimens exhibited slightly diminished piezoresistive and mechanical behaviors compared to their mold-cast counterparts, yielding a maximum strain gauge factor of 410, a resolution of 99 με, and an accuracy of 8.6 με.

The formation of phase-separated structures in hydrogels plays a crucial role in determining their optical and mechanical properties. Traditionally, phase-separated hydrogels are prepared through a two-step process involving initial hydrogel synthesis followed by post-treatment. In this study, we present an approach for temperature-governed phase separation microstructure modulation in hydrogels, harnessing the cononsolvency effect. This method allows the phase-separated structure to develop during hydrogel synthesis, significantly simplifying the preparation process. Importantly, we found that the preparation temperature has a substantial effect on the internal structure of the phase-separated hydrogel. We systematically investigated how the temperature influences the phase structure, optical properties, and mechanical performance of these hydrogels. The resulting hydrogels demonstrate excellent moisturizing and antifreezing capabilities. Additionally, the incorporation of sodium chloride imparts remarkable electrical conductivity to the hydrogels, making them suitable for strain sensing applications across a wide temperature range.

Electrically conductive fiberfibre/fabric composites (ECFCs) are competitive candidates for use in wearable electronics. Therefore, it is essential to develop mechanically robust ECFC strain sensors with sensing performance. In this study, MXene assembly and hot-pressing were combined to prepare strong yet breathable ECFCs for strain and temperature sensing. Hydrogen bonding between MXene and polyurethane (PU) and ultrasonication-induced interfacial sintering were responsible for MXene nanosheets assembly on the PU nanofibers. MXene decoration made PU nanofibers electrically conductive, resulting in a conductive network. Hot-pressing improved interface adhesion among the conductive nanofibers. Thus, the mechanical properties of the nanofiber composites, including tensile strength, toughness and fracture energy, were enhanced. The nanofiber composites exhibited surface stability and durability. When the nanofiber composites were used as strain sensors, they showed breathability with a linear resistance response ranging from 1 % to 100 % and cycling stability. In addition, they produced stable sensing signals over 1000 cycles when a notch was present. They could also monitor temperature variations with a negative temperature coefficient (-0.146 %/°C). This study provides an interfacial regulation method for the preparation of multi-functional nanofiber composites with potential applications in flexible and wearable electronics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Inc.)

The rapid advancement in attractive platforms such as biomedicine and human-machine interaction has generated urgent demands for intelligent materials with high strength, flexibility, and self-healing capabilities. However, existing self-healing ability materials are challenged by a trade-off between high strength, low elastic modulus, and healing ability due to the inherent low strength of noncovalent bonding. Here, drawing inspiration from human fibroblasts, a monomer trapping synthesis strategy is presented based on the dissociation and reconfiguration in amphiphilic ionic restrictors (7000-times volume monomer trapping) to develop a eutectogel. Benefiting from the nanoconfinement and dynamic interfacial interactions, the molecular chain backbone of the formed confined domains is mechanically reinforced while preserving soft movement capabilities. The resulting eutectogels demonstrate superior mechanical properties (1799% and 2753% higher tensile strength and toughness than pure polymerized deep eutectic solvent), excellent self-healing efficiency (>90%), low tangential modulus (0.367 MPa during the working stage), and the ability to sensitively monitor human activities. This strategy is poised to offer a new perspective for developing high strength, low modulus, and self-healing wearable electronics tailored to human body motion., (© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)

Liquid crystalline elastomers (LCEs) are a class of shape-changing polymers with exceptional mechanical properties and potential as artificial muscles/polymer actuators. In this study, multifunctional LCE actuators with strain sensing and joule heating responsivity are developed. LCEs are successfully synthesized using the thiol-ene two-staged michael addition polymerization (TMAP) method. The LCE films are further functionalized via sequential polydopamine (PDA) and silver electroless coating. It is found that the PDA coating enabled the anchoring of the Ag particles to the LCE, thereby enabling the electrical conductivity of the Ag-LCEs (<0.1 Ω cm -1 ). The studies confirm that the Ag/PDA coated LCEs can sense up to ≈30% strain, sense their own actuation strokes, and actuate at a rate of 1.83% s -1 while lifting a weight ≈50 times its mass in response to a 12 V 2A DC current., (© 2024 The Author(s). Macromolecular Rapid Communications published by Wiley‐VCH GmbH.)

For the need of direct contact with the skin, electronic skins (E-skins) should not only fulfill electric functions, but also ensure comfort during wearing, including permeability, waterproofness, and easy removal. Herein, the study has developed a self-adhesive, detach-on-demand, breathable, and waterproof E-skin (PDSC) for motion sensing and wearable comfort by electrospinning styrene-isoprene block copolymer rubber with carbon black nanosheets as the sensing layer and liner copolymers of N, N-dimethylacrylamide, n-octadecyl acrylate and lauryl methacrylate as the adhesive layer. The high elasticity and microfiber network structure endow the PDSC with good sensitivity and high linearity for strain sensing. The hydrophobic and crystallizable adhesive layer ensures robust, waterproof, and detaching-on-demand skin adhesion. Meanwhile, the fiber structure enables the PDSC good air and water permeability. The integration of electric and wearable functions endows the PDSC with great potential for motion sensing during human activities as both the sensing and wearable performances., (© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)

Developing multifunctional flexible composites with high-performance electromagnetic interference (EMI) shielding, thermal management, and sensing capacity is urgently required but challenging for next-generation smart electronic devices. Herein, novel nacre-like aramid nanofibers (ANFs)-based composite films with an anisotropic layered microstructure were prepared via vacuum-assisted filtration and hot-pressing. The formed 3D conductive skeleton enabled fast electron and phonon transport pathways in the composite films. As a result, the composite films showed a high electrical conductivity of 71.53 S/cm and an outstanding thermal conductivity of 6.4 W/m·K when the mass ratio of ANFs to MXene/AgNWs was 10:8. The excellent electrical properties and multi-layered structure endowed the composite films with superior EMI shielding performance and remarkable Joule heating performance, with a surface temperature of 78.3 °C at a voltage of 2.5 V. Additionally, it was found that the composite films also exhibited excellent mechanical properties and outstanding flame resistance. Moreover, the composite films could be further designed as strain sensors, which show great promise in monitoring real-time signals for human motion. These satisfactory results may open up a new opportunity for EMI shielding, thermal management, and sensing applications in wearable electronic devices.

The development of easy and direct real-time monitoring of welded joint quality instead of surface damage analysis is crucial to improve the quality of industrial products. This work presents the results of high-density polyethylene (HDPE)-based composites with various carbon black (CB) content (from 20 to 30 vol.%) for use as a heating element and strain sensor in electrofusion-welded polymer joints. The pyroresistive heating process was used to determine the effect of generated Joule heat during welding on the structure and sensor properties of polymer-carbon composites. It is shown that the generation of Joule heat depends on the nanocarbon content and affects the crystallinity of the polymer matrix. The partial disruption of the conductive path of carbon black particles was observed and, as a result, a decrease in electrical conductivity for composites with lower CB content after welding was found. For the highest CB amount, conductivity increased, which is caused by smaller particle-to-particle distance for filler paths. Therefore, the best balance between pyroresistive and sensor properties was found.

The accurate perception of external environment information through the robot foot is crucial for the mobile robot to evaluate its ability to traverse terrain. Adequate foot-end contact signals can provide robust support for robot motion control and decision-making processes. The shape and uncertain rotation of the wheel-legged robot foot end represent a significant challenge to sensing the robot foot-end contact state, which current foot-end sensing schemes cannot solve. This paper presents a sensing method for the tire stress field of wheel-legged robots. A finite element analysis was conducted to study the deformation characteristics of the foot-end tire under force. Based on this analysis, a heuristic contact position estimator was designed that utilizes symmetrical deformation characteristics. Strain sensors, arranged in an array, extract the deformation information on the inner surface of the tire at a frequency of 200 Hz. The contact position estimator reduces the dimensionality of the data and fits the eigenvalues to the estimated contact position. Using support vector regression, the force estimator utilizes the estimated contact position and sensor signal to estimate the normal reaction force, designated as F Z . The sensing system is capable of detecting the contact position on the wheel circumference (with a root mean square error of 1.150°), as well as the normal force of 160 N on the Z axis (with a root mean square error of 6.04%). To validate the efficacy of the sensor detection method, a series of randomized and repeated experiments were conducted on a self-constructed test platform. This novel approach offers a promising avenue for perceiving contact states in wheel-legged robots.

The utilization of biomass-based conductive polymer hydrogels in wearable electronics holds great promise for advancing performance and sustainability. An interpenetrating network of polyacrylamide/2-hydroxypropyltrimethyl ammonium chloride chitosan (PAM/HACC) was firstly obtained through thermal-initiation polymerization of AM monomers in the presence of HACC. The positively charged groups on HACC provide strong electrostatic interactions and hydrogen bonding with the PAM polymer chains, leading to improved mechanical strength and stability of the hydrogel network. Subsequently, the PAM/HACC networks served as the skeletons for the in-situ polymerization of polypyrrole (PPy), and then the resulting conductive hydrogel demonstrated stable electromagnetic shielding performance (40 dB), high sensitivity for strain sensing (gauge factor = 2.56). Moreover, the incorporation of quaternary ammonium chitosan into PAM hydrogels enhances their antimicrobial activity, making them more suitable for applications in bacterial contamination or low-temperature environments. This conductive hydrogel, with its versatility and excellent mechanical properties, shows great potential in applications such as electronic skin and flexible/wearable electronics., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

Robust hand motion tracking holds promise for improved human-machine interaction in diverse fields, including virtual reality, and automated sign language translation. However, current wearable hand motion tracking approaches are typically limited in detection performance, wearability, and durability. This article presents a hand motion tracking system using multiple soft polymer acoustic waveguides (SPAWs). The innovative use of SPAWs as strain sensors offers several advantages that address the limitations. SPAWs are easily manufactured by casting a soft polymer shaped as a soft acoustic waveguide and containing a commercially available small ceramic piezoelectric transducer. When used as strain sensors, SPAWs demonstrate high stretchability (up to 100%), high linearity ( R 2  > 0.996 in all quasi-static, dynamic, and durability tensile tests), negligible hysteresis (<0.7410% under strain of up to 100%), excellent repeatability, and outstanding durability (up to 100,000 cycles). SPAWs also show high accuracy for continuous finger angle estimation (average root-mean-square errors [RMSE] <2.00°) at various flexion-extension speeds. Finally, a hand-tracking system is designed based on a SPAW array. An example application is developed to demonstrate the performance of SPAWs in real-time hand motion tracking in a three-dimensional (3D) virtual environment. To our knowledge, the system detailed in this article is the first to use soft acoustic waveguides to capture human motion. This work is part of an ongoing effort to develop soft sensors using both time and frequency domains, with the goal of extracting decoupled signals from simple sensing structures. As such, it represents a novel and promising path toward soft, simple, and wearable multimodal sensors.

Protein-based hydrogels with promising biocompatibility and biodegradability have attracted considerable interest in areas of epidermal sensing, whereas, which are still difficult to synchronously possess high mechanical strength, self-adhesion, and recoverability. Hence, the bio-polymer lignosulfonate-reinforced gluten organohydrogels (GOHL x ) are fabricated through green and simple food-making processes and the following solvent exchange with glycerol/water binary solution. Ascribing to the uniform distribution of lignosulfonate in gluten networks, as well as the noncovalent interactions (e.g., H-bond) between them, the resultant GOHL x exhibit favorable conductivity (∼14.3 × 10 -4  S m -1 ), toughness (∼711.0 kJ m -3 ), self-adhesion (a maximal lap-shear strength of ∼33.5 kPa), high sensitivity (GF up to ∼3.04), and durability (∼3000 cycles) toward shape deformation, which are suitable for the detection of both drastic (e.g., elbow and wrist bending) and subtle (e.g., swallowing and speaking) human movements even under -20 °C. Furthermore, the GOHL x is also biocompatible, degradable, and recoverable (by a simple kneading process). Thus, this work may pave a simple, green, and cheap way to prepare all-biomass-based, tough, sticky, and recoverable protein-based organohydrogels for epidermal strain sensing even in harsh environments., Competing Interests: Declaration of competing interest The authors declare no conflict of interest., (Copyright © 2024. Published by Elsevier B.V.)

Here, stretchable hierarchical porous polyurethane fibers were designed, fabricated, and employed as a three-dimensional hierarchical interconnected framework for conductive networks interwoven with silver nanoparticles and carbon nanotubes. The fiber possessed favorable thermal insulation, strain sensing, and electric heating properties. The core-shell layered porous structure of fiber made the fiber have high heat insulation performance (the difference value of temperature |Δ T | = 3.54, 8.9, and 12.7 °C at heating stage temperatures of 35, 50, and 65 °C) and ultrahigh elongation at break (813%). Importantly, after conductive filler decoration, the fiber could exhibit real-time strain-sensing capacities with a high gauge factor. In addition, the fibers could be heated at low voltage, like an electrical heater. The development of flexible, stretchable, and multifunctional porous fibers had great potential applications in intelligent wearable devices for integrated thermal management, strain sensing, and intrinsic self-warming capability.

Conductive polymer composites (CPCs), obtained by incorporating conductive fillers into a polymer matrix, are suitable for producing strain sensors for structural health monitoring (SHM) in infrastructure. Here, the effect of the addition of inorganic semiconductor nanoparticles (INPs) to a poly (vinylidene fluoride) (PVDF) composite filled with multi-walled carbon nanotubes (MWCNTs) on the piezoresistive behavior is investigated. INPs with different morphologies and sizes are synthesized by a hydrothermal method. The added inorganic oxide semiconductors showed two distinct morphologies, including different phases. While particles with flower-like plate morphology contain phases of orth-ZnSnO 3 and SnO, the cauliflower-like nanoparticles contain these metal oxides and ZnO. The nanoparticles are characterized by field-emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD), and the nanocomposites by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Cyclic tensile testing is applied to determine the strain-sensing behavior of PVDF/1 wt% MWCNT nanocomposites with 0-10 wt% inorganic nanoparticles. Compared to the PVDF/1 wt% MWCNT nanocomposite, the piezoresistive sensitivity is higher after the addition of both types of nanoparticles and increases with their amount. Thereby, nanoparticles with flower-like plate structures improve strain sensing behavior slightly more than nanoparticles with cauliflower-like structures. The thermogravimetric analysis results showed that the morphology of the semiconductor nanoparticles added to the PVDF/MWCNT matrix influences the changes in thermal properties.

The Structural Health Monitoring (SHM) capabilities of a well-studied self-healing epoxy resin based on disulfide bonds, through the addition of carbon nanotubes (CNTs), are studied. Since these materials demonstrated, in recent works, a high dependency of the dynamic hardener content on the repair performance, this study aimed to analyze the effect of the vitrimeric chemistry on the electromechanical properties by studying different 2-aminophenyl disulfide (2-AFD) hardener and CNT contents. The electrical conductivity increases with both the CNT and AFD contents, in general. Moreover, an excess of AFD close to the stoichiometric ratio with a low CNT content improved the tensile strength by 45%, while higher AFD contents promoted its detriment by 41% due to a reduced crosslinking density. However, no significant difference in the mechanical properties was observed at a higher CNT content, regardless of the AFD ratio. The developed materials demonstrate a robust electromechanical response at quasi-static conditions. The sensitivity significantly increases at higher AFD ratios, from 0.69 to 2.22 for the 0.2 wt.%. CNT system, which is advantageous due to the enhanced repair performance of these vitrimeric materials with a higher hardener content. These results reveal the potential use of self-healing vitrimers as integrated SHM systems capable of detecting damages and self-repairing autonomously.

The finite element method (FEM) was used to investigate the optical-mechanical behavior of a Fabry-Perot Interferometer (FPI) composed of a capillary segment spliced between two sections of standard optical fiber. The developed FEM model was validated by comparing it with theory and with previously published experimental data. The model was then used to show that the absolute strain on the host substrate is usually smaller than the strain measurement obtained with the sensor. Finally, the FEM model was used to propose a cavity geometry that can be produced with repeatability and that yields the correct absolute strain experienced by the host substrate, without requiring previous strain calibration.

Articular cartilages exhibit load-bearing capacity and durability due to their inhomogeneous structure. Inspired by this unique structure, a tough and inhomogeneous salt-hydrogel was developed by trapping sodium acetate (NaAc) crystals in polyacrylamide (PAM) polymer networks and then partially redissolving the NaAc crystals. The compressive and tensile stresses of the salt-hydrogel increase significantly by more than 20 times when oversaturated Ac - and Na + are introduced into the gel network. Such an enhancement in mechanical strength is primarily attributed to the formation of NaAc crystals within the gel network. Further investigations reveal that the mechanical strength of the salt-hydrogel is temperature-dependent as the NaAc crystals gradually redissolve in the gel network with increasing temperature. Furthermore, redissolving NaAc crystals in an aqueous solution can yield an inhomogeneous salt-hydrogel. The topmost soft surface of the salt-hydrogel offers hydration lubrication, while the inhomogeneous network confers load-bearing capacity and durability. Compared to regular hydrogels, the inhomogeneous salt-hydrogel surface can realize drag reduction and remain smooth without damage after the friction tests. Moreover, a salt-hydrogel coating is also fabricated to visually demonstrate its drag-reducing property. In addition, this salt-hydrogel possesses conductivity and can be utilized in the development of inhomogeneous salt-hydrogel fibers (diameter = 438 ± 7 μm) for strain detection. The produced salt-hydrogel fiber exhibits excellent durability and reproducibility as a strain sensor, capable of detecting both small strains (e.g., 1%) and large strains (e.g., 40%). This work provides fundamental insights into developing hydrogels with an inhomogeneous network and explores their potential applications (e.g., hydrated drag-reducing, strain sensing).

Chronic diabetic wound with persistent inflammatory responses is still a serious threat to human health and life. Ideal wound dressings can be applied not only for covering the injury area, but also for regulating the inflammation to accelerate the wound healing and long-term monitoring of wound condition. However, there remains a challenge to design a multifunctional wound dressing for simultaneous treatment and monitoring of wound. Herein, an ionic conductive hydrogel with intrinsic reactive oxygen species (ROS)-scavenging properties and good electroactivity was developed for achieving the synergetic treatment and monitoring of diabetic wounds. In this study, we modified dextran methacrylate with phenylboronic acid (PBA) to prepare a ROS-scavenging material (DMP). Then the hydrogel was constructed by phenylboronic ester bonds induced dynamic crosslinking network, photo-crosslinked DMP and choline-based ionic liquid as the second network, and the crystallized polyvinyl alcohol as the third network, realizing good ROS-scavenging performance, high electroactivity, durable mechanical properties, and favorable biocompatibility. In vivo results showed that the hydrogel combined with electrical stimulation (ES) demonstrated good performance in promoting re-epithelization, angiogenesis and collagen deposition in chronic diabetic wound treatment by alleviating inflammation. Notably, with desirable mechanical properties and conductivity, the hydrogel could also precisely monitor movements of human body and possible tensile and compressive stresses of the wound site, providing timely alerts of excessive mechanical stress applied to the wound tissue. Thus, this "all-in-one" hydrogel exhibits great potential in constructing the next generation flexible bioelectronics for wound treatment and monitoring. STATEMENT OF SIGNIFICANCE: Chronic diabetic wounds characterized by overexpressed reactive oxygen species (ROS) are still a serious threat to human health and life. However, there remains a challenge to design a multifunctional wound dressing for simultaneous wound treatment and monitoring. Herein, a flexible conductive hydrogel dressing with intrinsic ROS-scavenging properties and electroactivity was developed for the combined treatment and monitoring of the wound. The antioxidant hydrogel combined with electrical stimulation synergistically accelerated chronic diabetic wound healing by regulating oxidative stress, alleviating inflammation, promoting re-epithelization, angiogenesis and collagen deposition. Notably, with desirable mechanical properties and conductivity, the hydrogel also presented great potential in monitoring possible stresses of the wound site. The "all-in-one" bioelectronics integrating the treatment and monitoring functions present great application potential for accelerating chronic wound healing., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.)

Silicon nanoparticles (Si NPs) supporting Mie resonances exhibit vivid structural colors on the subwavelength scale. For future wearable devices, next generation Si-based optical units need to be dynamic and stretchable for display, sensing, or signal processing required by human-computer interaction. Here, by utilizing the distance-sensitive electromagnetic coupling of Mie resonances, we maximize the active tuning effect of Si NP-based structures including dimers, oligomers, and NPs on WS 2 , which we called Si nanopixels. Through the optical tweezers-assisted printing of Si nanopixels, patterns can be formed on arbitrary flexible substrates. The strain-sensitive tuning of scattering spectra indicates their promising application on strain sensing of various stretchable substrates via a simple "spray and test" process. In the case of Si nanopixels on polydimethylsiloxane (PDMS), local strains around 1% can be detected by a scattering measurement. Moreover, we demonstrate that the scattering intensity variation of Si nanopixels printed on wrinkled tungsten disulfide (WS 2 ) is pixel-dependent and wavelength-dependent. This property facilitates the application of information encryption, and we demonstrate that three barcodes can be independently encoded into the R, G, and B scattering channels through ternary logic represented by the strain-tuning effects of scattering.

Tactile sensors, or sensors that collect measurements through touch, have versatile applications in a wide range of fields including robotic gripping, intelligent manufacturing, and biomedical technology. Hoping to match the ability of human hands to sense physical changes in objects through touch, engineers have experimented with a variety of materials from soft polymers to hard ceramics, but so far, all have fallen short. A grand challenge for developers of "human-like" bionic tactile sensors is to be able to sense a wide range of strains while maintaining the low profile necessary for compact integration. Here, we developed a low-profile tactile sensor (∼300 μm in height) based on patterned, vertically aligned carbon nanotubes (PVACNT) that can repetitively sense compressive strains of up to 75%. Upon compression, reversible changes occur in the points of contact between CNTs, producing measurable changes in electrical admittance. By patterning VACNT pillars with different aspect ratios and pitch sizes, we engineered the range and resolution of strain sensing, suggesting that CNT-based tactile sensors can be integrated according to device specifications.

Strain-based condition evaluation has garnered as a crucial method for the structural health monitoring (SHM) of large-scale engineering structures. The use of traditional wired strain sensors becomes tedious and time-consuming due to their complex wiring operation, more workload, and instrumentation cost to collect sufficient data for condition state evaluation, especially for large-scale engineering structures. The advent of wireless and passive RFID technologies with high efficiency and inexpensive hardware equipment has brought a new era of next-generation intelligent strain monitoring systems for engineering structures. Thus, this study systematically summarizes the recent research progress of cutting-edge RFID strain sensing technologies. Firstly, this study introduces the importance of structural health monitoring and strain sensing. Then, RFID technology is demonstrated including RFID technology's basic working principle and system component composition. Further, the design and application of various kinds of RFID strain sensors in SHM are presented including passive RFID strain sensing technology, active RFID strain sensing technology, semi-passive RFID strain sensing technology, Ultra High-frequency RFID strain sensing technology, chipless RFID strain sensing technology, and wireless strain sensing based on multi-sensory RFID system, etc., expounding their advantages, disadvantages, and application status. To the authors' knowledge, the study initially provides a systematic comprehensive review of a suite of RFID strain sensing technology that has been developed in recent years within the context of structural health monitoring.

Carbon nanoparticle-reinforced adhesive films have been explored as surface sensors for the detection of small strains. It has been observed that graphene nanoplatelets, GNPs, promote a significant increase of the gauge factor when compared to carbon nanotubes, CNTs (5.6 to 0.6, respectively, at low strains), due to their intrinsic 2D nature. The application as surface sensors for the monitoring of the strain field in an aluminum plate has been proven to be successful, with a repeatable signal under consecutive cycles despite some irreversibility in the first one for GNPs. Furthermore, the electrical response given by the sensors under plastic deformation of the aluminum plate was in total agreement with the mechanical response validated by numerical analysis, proving the high potential of the proposed adhesive film for sensing purposes., (© 2023 IOP Publishing Ltd.)

The emerging intelligent piezoresistive yarn/textile-based sensors are of paramount importance for skin-interface electronics, owing to their unparalleled features including softness, breathability, and easy integration with functional devices. However, employing a facile way to fabricate 1D sensing yarns with mechanical robustness, multi-functional integration, and comfortability is still demanded for satisfying the practical applications. Herein, a facile one-step synchronous conjugated electrospinning and electrospraying technique is innovatively employed to continuously construct an Ag NW-embedded polyurethane (PU) nanofiber sensing yarn (AENSY) with hierarchical architecture. This 1D AENSY with weavability and stretchability can be woven into AENSY textile-based sensors integrated with functions of strain and pressure sensing. In this embedded multi-scale architecture, Ag NWs are evenly embedded and locked in the oriented and twisted PU nanofiber (PUNF) scaffold, forming the hierarchical mechanical sensing layer on the surface of the AENSY with favorable stability. Meanwhile, the presence of the elastic PUNFs enhances porosity, elasticity, and considerable deformation space, which in turn endow the AENSY textile-based sensor with a gauge factor (GF) up to 1010, a pressure sensitivity up to 16.7 N -1 , high stretchability up to 160%, and high stability under long-term cycles. In addition, the AENSY textile-based sensor exhibits light weight and the unique advantage of skin-friendliness with the human body, which can be directly and conformally attached to the curved human skin to monitor the various human movements. Furthermore, the weavable AENSYs can be integrated into smart textiles with sensing arrays, which are capable for spatial pressure and strain mapping. Thus, the continuous one-step developing process and the stable embedded-twisted fiber structure provide a promising strategy to develop innovative smart yarns and textiles for personalized healthcare and human-machine interfaces.

It is still a challenge for flexible electronic materials to realize integrated strain sensors with a large linear working range, high sensitivity, good response durability, good skin affinity and good air permeability. In this paper, we present a simple and scalable porous piezoresistive/capacitive dual-mode sensor with a porous structure in polydimethylsiloxane (PDMS) and with multi-walled carbon nanotubes (MWCNTs) embedded on its internal surface to form a three-dimensional spherical-shell-structured conductive network. Thanks to the unique spherical-shell conductive network of MWCNTs and the uniform elastic deformation of the cross-linked PDMS porous structure under compression, our sensor offers a dual piezoresistive/capacitive strain-sensing capability, a wide pressure response range (1-520 kPa), a very large linear response region (95%), excellent response stability and durability (98% of initial performance after 1000 compression cycles). Multi-walled carbon nanotubes were coated on the surface of refined sugar particles by continuous agitation. Ultrasonic PDMS solidified with crystals was attached to the multi-walled carbon nanotubes. After the crystals were dissolved, the multi-walled carbon nanotubes were attached to the porous surface of the PDMS, forming a three-dimensional spherical-shell-structure network. The porosity of the porous PDMS was 53.9%. The large linear induction range was mainly related to the good conductive network of the MWCNTs in the porous structure of the crosslinked PDMS and the elasticity of the material, which ensured the uniform deformation of the porous structure under compression. The porous conductive polymer flexible sensor prepared by us can be assembled into a wearable sensor with good human motion detection ability. For example, human movement can be detected by responding to stress in the joints of the fingers, elbows, knees, plantar, etc., during movement. Finally, our sensors can also be used for simple gesture and sign language recognition, as well as speech recognition by monitoring facial muscle activity. This can play a role in improving communication and the transfer of information between people, especially in facilitating the lives of people with disabilities.

Developing highly sensitive strain sensors requires conduction pathways capable of rapidly switching between disconnection and reconnection in response to strain. Ion channels in living organisms exactly control the channel switch through protein-composed gates, achieving changeable ion currents. Herein, inspired by the gating characteristics of the ion channels, a programmable fluidic strain sensor enhanced by gating ion pathways through heterogeneous strain distribution of discrete micropillars is proposed. During stretching, the contraction and closure of the widthwise gaps between discrete micropillars greatly weaken or even nearly cut off the conduction pathway, resulting in orders of magnitude increase in resistance and thus ultrahigh sensitivity. By adjusting the combination form and structural parameters of the discrete micropillars in the fluidic channel, the sensitivity and strain range can be customized. Thus, a gauge factor of up to 45 300 and a stretch range of 590% are obtained. Benefiting from the fluidic gating mechanism, no mechanical mismatch can be observed at the interface, breaking through the sensing stability issue of flexible sensors. The proposed sensor can be used to detect the full range of human motion, and integrated into a data glove to achieve human-machine interaction., (© 2022 Wiley-VCH GmbH.)

In the past, electromagnetic interference (EMI) shielding materials have achieved great breakthroughs, however, they still suffer from high reflectivity and poor environmental stability, resulting in detrimental secondary pollution and weak adaptability. Herein, an organohydrogel-based EMI shielding material was prepared through cellulose nanofibril-based Pickering emulsion, composed of an MXene network for electron conduction, encapsulated paraffin wax microspheres with MXene-Fe 3 O 4 shells for multiple scattering of the incident wave, and MXene-CNF-Fe 3 O 4 -polyacrylamide hybrid interfaces for dielectric polarization. The EMI shielding performance of our organohydrogel shows an absorption-dominated feature. It can effectively shield 99.625 % electromagnetic wave, satisfying the requirement of commercial EMI shielding materials. Moreover, the organohydrogel possesses excellent flame retardancy properties and long-time environment properties to improve safety and reliability; and it also demonstrates sensitive deformation responses as an on-skin sensor. Therefore, our organohydrogel can simultaneously detect human motion and protect human from EMI radiation and accidental burn., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Conductive polymers and their composites have been widely applied in different applications, including sensing applications. Herein, we constructed a conductive composite of polypropylene, carbon black, and multi-walled carbon nanotubes (PP/CB/MWCNTs) to experimentally study its sensing behaviors in a humid thermal environment. The as-synthesized PP/CB/MWCNT composite polymer was immersed in simulated sweat in deionized water at 67 °C. Regarding their electrical and mechanical properties, different experimental parameters, such as cyclic loading and hygrothermal aging, were investigated by recording the mass changes, carrying out strain sensing experiments, and performing dynamic mechanical analyses before and after the immersion test. The results reveal that the filler content improved the rate of water absorption but decreased at higher concentrations of the solution. The sensitivity of the material decreased by up to 53% after the hygrothermal ageing and cyclic loading. Moreover, the sensitivity under cyclic compression loading decreased with an increasing immersion time, qualitatively illustrated by an effective quantum tunneling effect and conducting path model. Finally, hygrothermal aging reduced the composite's glass transition temperature. This reduction was the most significant for specimens immersed in deionized water, ascribed to the moisture absorption, reducing the molecular chain activity.

With the advancement of material science and electronic technology, wearable devices have been integrated into daily lives, no longer just a stirring idea in science fiction. In the future, robust multifunctionalized wearable devices with low cost and long-term service life are urgently required. However, preparing multifunctional wearable devices robust enough to resist harsh conditions using a commercially available raw material through a simple process still remains challenging. In this work, reprocessable polyurea (HUBTPU) with a hard segment of hindered urea bonds (HUBs) and a soft segment of polyether is synthesized via a facile one-pot method. The robust dual functional wearable devices were obtained by simply spray-coating silver nanowires (AgNWs) on HUBTPU elastomer substrates. Due to the dynamic combination and decomposition of the HUBs and hydrogen bonds at 130 °C, the robust elastomer demonstrates favorable adhesion to various substrates. Especially, the partially embedded AgNW structure is also achieved by using ethanol as a spray solvent. The adhesion of HUBTPU substrates and embedded structure leads to stronger interfacial adhesion and stability compared to non-adhesive substrates. The as-obtained HUBTPU electrodes are able to be heated to 115 °C by applying a low voltage and sensing the strain deformation caused by human movement, which means that the electrodes are endowed with both electrical heating capability and strain sensing functionality. Therefore, this strategy reveals a potential way to prepare multifunctional wearable devices using other conductive particles and adhesive functional polymer substrates.

Presented here is the synthesis of a 3D printable nano-polysaccharide self-healing hydrogel for flexible strain sensors. Consisting of three distinct yet complementary dynamic bonds, the crosslinked network comprises imine, hydrogen, and catecholato-metal coordination bonds. Self-healing of the hydrogel is demonstrated by macroscopic observation, rheological recovery, and compression measurements. The hydrogel was produced via imine formation of carboxyl methyl chitosan, oxidized cellulose nanofibers, and chitin nanofibers followed by two subsequent crosslinking stages: immersion in tannic acid (TA) solution to create hydrogen bonds, followed by soaking in Fe III solution to form catecholato-metal coordination bonds between TA and Fe III . The metal coordination bonds were critical to imparting conductivity to the hydrogel, a requirement for flexible strain sensors. The hydrogel exhibits excellent shear-thinning and dynamic properties with high autonomous self-healing (up to 89%) and self-recovery (up to 100%) at room temperature without external stimuli. Furthermore, it shows good printability, biocompatibility, and strain sensing ability., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

To date, multifunctional sensors have aroused widespread concerns owing to their vital roles in the healthcare area. However, there are still significant challenges in the fabrication of functionalized integrated devices. In this work, hydrophobic-hydrophilic patterns are constructed on polyester-spandex-blended knitted fabric surface by the chemical click method, enabling accurate deposition of functionalized materials for sensitive and stable motion and humidity sensing. Representatively, a conductive silver nanowire (Ag NW) network was deliberately deposited on only the designated hydrophilic fabric surface to realize accurate, repeatable, and stable motion sensing. Such a Ag NWs sensor recorded a low electrical resistance (below 60 Ω), stable resistance cycling response (over 2000 cycles), and fast response time to humidity (0.46 s) during the sensing evaluation. In addition to experimental sensing, real human motions, such as mouth-opening and joint-flexing (wrist and neck), could also be detected using the same sensor. Similar promising outputs were also obtained over the humidity sensor fabricated over the same chemical click method, except the sensing material was replaced with polydopamine-modified carboxylated carbon nanotubes. The resultant sensor exhibits excellent sensitivity to not only experimentally adjusted environment humidity but also to the moisture content of breath and skin during daily activities. On top of all these, both sensors were fabricated over highly flexible fabric that offers high wearability, promising great application potential in the field of healthcare monitoring.

Multifunctional nanocomposites based on carbon nanotubes (CNT)-reinforced Surlyn, which is a commercial ionomeric polymer, are manufactured by micro-compounding and hot-press processes. Multifunctionality is studied in terms of electromechanical response and self-healing abilities. The strain sensing analysis under tensile conditions shows ultra-high gauge factor (GF) values from 10 to 20 at low strain levels up to 10 6 at high strain levels, and a decreasing sensitivity as CNT content increases because of the reduction in the tunneling distance between neighboring nanoparticles. The electromechanical response under consecutive tensile cycles demonstrated the robustness of the proposed materials due to the repeatability of both responses. With regard to mechanical properties, the addition of CNT induces a clear increase in Young's modulus because the nanoparticles enable uniform load distributions. Moreover, self-healing capabilities are improved when 4 and 5 wt.% CNT are introduced because of the synergistic effect of the high thermal conductivity of CNT and their homogeneous distribution, promoting an increase in the thermal conductivity of bulk nanocomposites. Thus, by comparing the measured functionalities, 4 and 5 wt.% CNT-reinforced Surlyn nanocomposites showed a high potential for various applications due to their high degree of multifunctionality.

In this work, a composite strain sensor is fabricated by synthesizing MXene and deposition of polypyrrole on top of the flexible electrospun PVDF nanofibers. The fabricated sensor exhibits a conductive network constructed with MXene and polypyrrole of microcracks network structure, demonstrating its strain sensing properties. The presence of these microcracks serves as mechanical weak points, which leads to sensitivity enhancement, while the electrospun fiber substrate act as a cushion for strain loading under large deformations. The as-prepared MXene@Polypyrrole PVDF sensor has a gauge factor range of 78-355 with a sensing range between 0-100%. Besides strain deformations, the sensor can operate in torsional deformation and human motion, indicating the sensor's potential as a wearable health monitoring device.

Hybrid nanomaterial film consisting of multi-walled carbon nanotubes (MWCNT) and graphene nanoplatelet (GNP) were deposited on a highly flexible polyimide (PI) substrate using spray gun. The hybridization between 2-D GNP and 1-D MWCNT reduces stacking among the nanomaterials and produces a thin film with a porous structure. Carbon-based nanomaterials of MWCNT and GNP with high electrical conductivity can be employed to detect the deformation and damage for structural health monitoring. The strain sensing capability of carbon-based hybrid nanomaterial film was evaluated by its piezoresistive behavior, which correlates the change of electrical resistance with the applied strain through a tensile test. The effects of weight ratio between MWCNT and GNP and the total amount of hybrid nanomaterials on the strain sensitivity of the nanomaterial thin film were investigated. Experimental results showed that both the electrical conductivity and strain sensitivity of the hybrid nanomaterial film increased with the increase of the GNP contents. The gauge factor used to characterize the strain sensitivity of the nanomaterial film increased from 7.75 to 24 as the GNP weight ratio increased from 0 wt.% to 100 wt.%. In this work, a simple, low cost, and easy to implement deposition process was proposed to prepare a highly flexible nanomaterial film. A high strain sensitivity with gauge factor of 24 was achieved for the nanomaterial thin film.

Flexible and stretchable strain sensors are an important development for measuring various movements and forces and are increasingly used in a wide range of smart textiles. For example, strain sensors can be used to measure the movements of arms, legs or individual joints. Thereby, most strain sensors are capable of detecting large movements with a high sensitivity. Very few are able to measure small movements, i.e., strains of less than 5%, with a high sensitivity, which is necessary to carry out important health measurements, such as breathing, bending, heartbeat, and vibrations. This research deals with the development of strain sensors capable of detecting strain of 1% with a high sensitivity. For this purpose, a total of six commercially available metallic yarns were coated with a carbon-containing silicone coating. The process is based on a vertical dip-coating technology with a self-printed 3D coating bath. Afterwards, the finished yarns were interlooped and stretched by 1% while electrical resistance measurements were carried out. It was shown that, although the coating reduced the overall conductivity of the yarns, it also improved their sensitivity to stress. Conclusively, highly sensitive strain sensors, designed specially for small loads, were produced by a simple coating set-up and interlooping structure of the sensory yarns, which could easily be embedded in greater textile structures for wearable electronics.

We proposed a novel temperature-compensated multi-point strain sensing system based on cascaded FBG and optical FMCW interferometry. The former is used for simultaneous sensing of temperature and strain, and the latter is used for position information reading and multiplexing. In the experiment, a narrow linewidth laser with continuous frequency-sweeping was used as the light source. After demodulating the beat-frequency signal, the link information of the 16 m fiber was obtained, and the measured result was identical to the actual position. The measurement accuracy reached 50.15 mm, and the dynamic range was up to 22.68 dB. Meanwhile, we completed the sensing experiments for temperature range from 20 °C to 90 °C and strain range from 0 με to 7000 με. The sensitivity of the sensing system to temperature was 10.21 pm/°C, the sensitivity and accuracy to strain were as high as 1.163 pm/με and 10 με, respectively. Finally, the measured strain and temperature values were obtained using the sensing matrix. The sensing system has important practical significance in the field of quasi-distributed strain measurement.

Respiration is a major vital sign, which can be used for early illness diagnosis and physiological monitoring. Wearable respiratory sensors present an exciting opportunity to monitor human respiratory behaviors in a real-time, noninvasive, and comfortable way. Among them, fiber-shaped triboelectric nanogenerators (FS-TENGs) are attractive for their comfort and high degree of freedom. However, the single-electrode FS-TENGs cannot respond to their own tensile strains, and the coaxial double-electrode FS-TENGs show low sensitivity to strain due to structural limitations. Here, a type of helical fiber strain sensor (HFSS) is developed, which can respond to tiny tensile strains. In addition, a smart wearable real-time respiratory monitoring system is developed based on the HFSSs, which can measure some key breathing parameters for disease prevention and medical diagnosis. An intelligent alarm can automatically call a preset mobile phone for help in response to respiratory behavior changes. This work provides an effective helical structure for fabricating highly sensitive strain sensors based on FS-TENGs and develops wearable self-powered real-time respiratory monitoring systems.

Conductive polymer nanofiber composites (CPNCs) based wearable sensing electronics have aroused great attention of scientists in recent years. However, it is still difficult to obtain CPNCs with good water proof, excellent durability, and multiple sensing performance. Herein, we develop a multifunctional CPNC with a wrinkled reduced graphene oxide (RGO) shell and polymer nanofiber core, which is prepared by ultrasonication induced decoration of RGO onto the pre-stretched polyurethane (PU) nanofibers, followed by the release of the strain. The RGO assembly with a wrinkled structure not only greatly increases the surface roughness and thus the hydrophobicity but also enhances the strain sensing sensitivity (with a gauge factor of 154.8 in the strain range of 85%-100%) of the nanofibrous membrane. The obtained CPNC strain sensor also shows excellent sensing durability (over 1000 cycles) and can be used for body motion monitoring. The CPNC shows a negative temperature coefficient effect, which holds promising applications in high performance temperature sensors., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier Inc. All rights reserved.)

3D printing of conductive polymers is an attractive technique for achieving high flexibility, wearability, and sensing characteristics without geometrical limitations. However, there is an urgent need to integrate printability, conductivity, and sensing capability. Herein, a conductive polymer ink for 3D printing that combines the desirable features of high electrical conductivity, flexible stretchability, and strain-sensing monitoring is prepared. The ink matrix is polydimethylsiloxane and synergistically enhanced by acetylene carbon black (ACB) and multi-walled carbon nanotubes (MWCNTs) (silane or un-silane-modified). The inks are screened step-by-step to explore their printability, rheology, mechanical properties, and electrical performance upon loading. The formation of an electrically conductive network, electrical properties upon tensile load, and strain sensing stability under cyclic stretching are investigated intensively. It is demonstrated that conductive polymers filled by ACB and silane-modified, MWCNTs (MWCNTs-MTES) possess superior printability, stretchability, conductivity, and strain sensing behaviors. Finally, a flexible wearable strain-sensing skin patch is printed, and it successfully records joint motion signals on human fingers, wrists, and elbows with good stability and repeatability. Those results show the extent of potential applications in healthcare and motion monitoring fields. This work provides an efficient and simple route to achieve comfortably wearable and high-performance strain sensors., (© 2021 Wiley-VCH GmbH.)

Electrically conductive composite materials are highlighted as a potential tech path toward future flexible devices for wearable health technologies. To be commercially viable, these materials must not only be mechanically soft, highly sensitive to deformation, and report a sustainable signal but also utilize manufacturing methods that facilitate large-scale production. An ideal candidate for these envisioned technologies is the viscous, electromechanically sensitive composite material g-putty. Inks based on g-putty here are shown to transform a commercial polymer foam into a sensitive strain sensing material through a simple, scalable soaking procedure. Foam composites reported here have sensitives as high as ∼20 in terms of compressive strain and ∼0.4 kPa -1 with respect to applied compressive stress; both values being comparable to the parent g-putty material. Through g-putty's self-adhering nature, the foams used acted as an elastic scaffolding that aided in overcoming many of the hysteresis effects associated with g-putty without the need for further encapsulation methods. From this, these composite foams were demonstrated to have a sustainable signal that allowed for effective impact and vital sign sensing.

Plants are primary resources for oxygen and foods whose production is fundamental for our life. However, diseases and pests may interfere with plant growth and cause a significant reduction of both the quality and quantity of agriculture products. Increasing agricultural productivity is crucial for poverty reduction and food security improvements. For this reason, the 2030 Agenda for Sustainable Development gives a central role to agriculture by promoting a strong technological innovation for advancing sustainable practices at the plant level. To accomplish this aim, recently, wearable sensors and flexible electronics have been extended from humans to plants for measuring elongation, microclimate, and stressing factors that may affect the plant's healthy growth. Unexpectedly, fiber Bragg gratings (FBGs), which are very popular in health monitoring applications ranging from civil infrastructures to the human body, are still overlooked for the agriculture sector. In this work, for the first time, plant wearables based on FBG technology are proposed for the continuous and simultaneous monitoring of plant growth and environmental parameters (i.e., temperature and humidity) in real settings. The promising results demonstrated the feasibility of FBG-based sensors to work in real situations by holding the promise to advance continuous and accurate plant health growth monitoring techniques.

Conductive polymer composites (CPCs) are suitable as piezoresistive-sensing materials. When using CPCs for strain sensing, it is still a big challenge to simultaneously improve the piezoresistive sensitivity and linearity along with the electrical conductivity and mechanical properties. Here, highly tunable piezoresistive behavior is reported for multiwalled carbon nanotube (CNT)-filled CPCs based on blends of two semicrystalline polymers poly(vinylidene fluoride) (PVDF) and poly(butylene succinate) (PBS), which are miscible in the melt. When cooling the homogeneous mixture of the blend components, successive crystallization of PVDF and PBS occurs, creating complex crystalline structures in a mixed amorphous phase. The morphology of the blend matrix, the crystallinity of the blend components, and the dispersion and location of the CNTs in the blend depend on the CNT content and the blend composition. Compared with PVDF/CNT composites, the substitution of 10 to 50 wt % PVDF by PBS in the composites shifts the electrical percolation concentration Φ c from 0.79 wt % to filler contents as low as 0.50 wt % while improving the stretchability. The piezoresistive behavior is highly tunable by changing the PVDF/PBS ratio. The ternary composites with matrix compositions of PVDF (90 wt %)/PBS (10 wt %) and PVDF (50 wt %)/PBS (50 wt %) show either higher piezoresistive sensitivity or linearity, respectively, caused by the differences in the microstructure of the CPCs. For example, the crystallinity of PBS in the ternary composites increased from 19.8% to 52.0% as the PBS content increased from 10 wt % to 50 wt %, which is connected with altered CNT distribution and conductive network structure and substantial improvement of the linearity of the electrical response to strains up to >20%. Our findings highly contribute to the understanding of the piezoresistive properties of CPCs based on two semicrystalline polymers and are important for future studies to tune the piezoresistive behavior to achieve simultaneously improved sensitivity and linearity.

Electrical and electromechanical properties of hybrid graphene nanoplatelet (GNP)/carbon nanotube (CNT)-reinforced composites were analyzed under two different sonication conditions. The electrical conductivity increases with increasing nanofiller content, while the optimum sonication time decreases in a low viscosity media. Therefore, for samples with a higher concentration of GNPs, an increase of sonication time of the hybrid GNP/CNT mixture generally leads to an enhancement of the electrical conductivity, up to values of 3 S/m. This means that the optimum sonication process to achieve the best performances is reached in the longest times. Strain sensing tests show a higher prevalence of GNPs at samples with a high GNP/CNT ratio, reaching gauge factors of around 10, with an exponential behavior of electrical resistance with applied strain, whereas samples with lower GNP/CNT ratio have a more linear response owing to a higher prevalence of CNT tunneling transport mechanisms, with gauge factors of around 3-4.

Self-powered elastic Conductors based on thermoelectric materials with the ability to harvest energy from the living environment are considered as important for electronic devices under off-grid, maintenance-free, or unfeasible battery replacement circumstances. Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is perhaps the most well-known organic conductor. However, the application of PEDOT:PSS in flexible devices is limited by its brittleness and various unrecoverable properties under strain. Various polymer blends based on water-soluble polymers and PEDOT:PSS have been prepared. Nevertheless, they fail to illustrate good balance between electrical conductivity and mechanical performance due to various issues, including the phase morphology with PEDOT:PSS as the dispersed phase; thus, the formation of a conductive network between PEDOT:PSS is prohibited. In this study, PEDOT:PSS is incorporated into natural rubber (NR), with NR as the dispersed phase. For 10 wt % PEDOT:PSS-NR composite films doped with dimethyl sulfoxide (DMSO), the conductivity was up to 87 S/cm and the elongation at break was maintained at 490%. More importantly, self-powered temperature- and tensile strain-sensing abilities were also realized. Furthermore, it is also demonstrated that most of the unrecoverable strain and conductivity under cyclic tensile strain could be healed by water and phosphate-buffered saline (PBS) post-treatment. This work provides interesting insights for preparing healed and stretchable self-powered electronic sensors.

The emerging personal healthcare has significantly propelled the development of advanced wearable electronics with novel functions of providing diagnostic information and point-of-care therapies for specific diseases. However, it is still challenging to simultaneously achieve high sensitivity for health biomonitoring and multifunction integration for point-of-care therapies in a one single flexible, lightweight yet robust fiber-based device. Here, a knittable and sewable spandex yarn with conductive nacre-mimetic composite coating has been developed through an alternant dip-coating method employing MXene nanosheets as the "brick" and polydopamine (PDA)/Ni 2+ as the "mortar". The resultant spandex yarn coating with MXene/PDA/Ni 2+ (MPNi@Spandex) can be assembled as a strain sensor with high sensitivity (up to 5.7 × 10 4 for the gauge factor), wide sensing range (∼61.2%), and low detection limit (0.11%) to monitor the biological activities of the human body. Furthermore, MPNi@Spandex displays great potential to give on-demand thermotherapy by virtue of the fast response to near-infrared irradiation, controllable surface temperature, and applicability even under sewing conditions. In addition, MPNi@Spandex knitted textiles demonstrate a strong antibacterial effect due to the sharp edges, anionic, and hydrophilic nature of MXene nanosheets. Remarkably, near-infrared irradiation further improves the bacteria-killing efficiency of an MPNi@Spandex knitted textile to more than 99.9%. This work paves the way for the design of multifunctional wearable electronics with an all-in-one theranostic platform for personal healthcare.