Search

Recent advances in laboratory spectroscopy lead to the claim of ionized Buckminsterfullerene (C60(+)) as the carrier of two diffuse interstellar bands (DIBs) in the near-infrared. However, irrefutable identification of interstellar C60(+) requires a match between the wavelengths and the expected strengths of all absorption features detectable in the laboratory and in space. Here we present Hubble Space Telescope (HST) spectra of the region covering the C60(+) 9348, 9365, 9428, and 9577 Å absorption bands toward seven heavily reddened stars. We focus in particular on searching for the weaker laboratory C60(+) bands, the very presence of which has been a matter for recent debate. Using the novel STIS-scanning technique to obtain ultra-high signal-to-noise spectra without contamination from telluric absorption that afflicted previous ground-based observations, we obtained reliable detections of the (weak) 9365, 9428 Å and (strong) 9577 Å C60(+) bands. The band wavelengths and strength ratios are sufficiently similar to those determined in the latest laboratory experiments that we consider this the first robust identification of the 9428 Å band, and a conclusive confirmation of interstellar C60(+).

One of the major objectives of Laboratory Astrophysics is the optimization of data return from space missions by measuring spectra of atomic and molecular species in laboratory environments that mimic interstellar conditions (WhitePaper (2002, 2006)). Among interstellar species, PAHs are an important and ubiquitous component of carbon-bearing materials that represents a particularly difficult challenge for gas-phase laboratory studies. We present the absorption spectra of jet-cooled neutral and ionized PAHs and discuss the implications for astrophysics. The harsh physical conditions of the interstellar medium have been simulated in the laboratory. We are now, for the first time, in the position to directly compare laboratory spectra of PAHs and carbon nanoparticles with astronomical observations. This new phase offers tremendous opportunities for the data analysis of current and upcoming space missions geared toward the detection of large aromatic systems (HST/COS, FUSE, JWST, Spitzer).

We present the results of a dedicated search for the spectral signatures in the visible range of neutral polycyclic aromatic hydrocarbons (PAHs) in astronomical observations representing various astrophysical environments, probing a total column of line of sight material corresponding to Av=50. Laboratory measurements of PAHs in simulated astrophysical conditions are now available (see contribution of Salama et al.) which provide for the first time the exact wavelengths for the spectral features of these molecules, as well as detailed information on the intrinsic line profiles and oscillator strengths. These measurements therefore allow a direct comparison to astronomical observations and an estimate of, or upper limit to, the abundance of individual PAHs in space. As the column densities for individual PAHs in interstellar or circumstellar lines of sight are expected to be very low, such a comparison and analysis requires astronomical observations at very high signal to noise. We present such a data set here for lines of sight representing diffuse clouds and circumstellar environments of carbon stars, and their comparison with gas phase spectra of a representative set of free, cold PAHs.

We present the gas-phase spectroscopy of neutral and ionized polycyclic aromatic hydrocarbons (PAHs) measured in the W-Visible-NIR range in an astrophysically relevant environment. These measurements provide data on PAHs and nanometer sized particles that can now be directly compared to astronomical observations. The harsh physical conditions of the IS medium - characterized by a low temperature, an absence of collisions and strong VUV radiation fields - are simulated in the laborat'ory by associating a molecular beam with an ionizing discharge to generate a cold plasma expansion. PAH ions are formed from the neutral precursors in an isolated environment at low temperature ($\sim lOO$-K). The spectra of neutral and ionized PAHs are measured using the high sensitivity methods of cavity ring down spectroscopy (CRDS) and multiplex integrated cavity output spectroscopy (MICOS). These experiments provide unique information on the spectra of free, cold large carbon molecules and ions in the gas phase. The electronic bands measured for ionized PAH are found to be intrinsically broad ($\geq$20 cm$^{-l}$) while the bands associated with the neutral precursors are narrower (of the order of 2 - 10 cm$^{-l}$). The laboratory data are discussed and compared with recent astronomical spectra of large and narrow DIBs and with the spectra of circumstellar environments of selected carbon stars (see contribution of Cami et al.) and the implications for the interstellar PAH population are derived. Preliminary results also show that carbon nanoparticles are formed during the short residence time of the precursors in the plasma. This finding holds great potential for understanding the formation process of interstellar grains.

Analysis of high spectral resolution observations of the lambda6614 DIB line profile show systematic variations in the positions of the peaks in the substructure of the profile. These variations can only be understood in the framework of rotational contours of large molecules, where the variations are caused by changes in the rotational excitation temperature. We show that the rotational excitation temperature for the DIB carrier is of the order 10-40 K - much lower than the gas kinetic temperature - indicating that for this particular DIB carrier angular momentum buildup is not very efficient. The rotational constant indicates that the carrier of this DIB is smaller than previously assumed:7-22 C atoms, depending on the geometry.