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The Earth-abundant kesterite Cu2ZnSnS4 (CZTS) exhibits outstanding structural, optical, and electronic properties for a wide range of optoelectronic applications. However, the efficiency of CZTS thin-film solar cells is limited due to a range of factors, including electronic disorder, secondary phases, and the presence of anti-site defects, which is a key factor limiting the Voc. The complete substitution of Zn lattice sites in CZTS nanocrystals (NCs) with Cd atoms offers a promising approach to overcome several of these intrinsic limitations. Herein, we investigate the effects of substituting Cd2+ into Zn2+ lattice sites in CZTS NCs through a facile solution-based method. The structural, morphological, optoelectronic, and power conversion efficiencies (PCEs) of the NCs synthesized have been systematically characterized using various experimental techniques, and the results are corroborated by first-principles density functional theory (DFT) calculations. The successful substitution of Zn by Cd is demonstrated to induce a structural transformation from the kesterite phase to the stannite phase, which results in the bandgap reduction from 1.51 eV (kesterite) to 1.1 eV (stannite), which is closer to the optimum bandgap value for outdoor photovoltaic applications. Furthermore, the PCE of the novel Cd-substituted liquid junction solar cell underwent a four-fold increase, reaching 1.1%. These results highlight the importance of substitutional doping strategies in optimizing existing CZTS-based materials to achieve improved device characteristics.

There is a huge potential to deploy solar thermal energy in process heat applications in industrial sectors. Around 50 % of industrial heat demand is less than 250 °C which can be addressed through solar energy. The heat energy requirement of industries like automobile, auto ancillary, metal processing, food and beverages, textile, chemical, pharmaceuticals, paper and pulp, hospitality, and educational institutes etc. can be partially met with solar hybridization based solutions. The automobile industry is one of the large consumers of fossil fuel energy in the world. The automobile industry is major economic growth driver of India and has its 60 % fuel dependence on electricity and remaining on oil based products. With abundant area available on roof top, and need for medium temperature operation makes this sector most suitable for substitution of fossil fuel with renewable solar energy. Auto sector has requirement of heat in the temperature range of 80-140 oC or steam up to 2 bar pressure for various processes like component washing, degreasing, drying, boiler feed water preheating, LPG vaporization and cooling. This paper discusses use of solar energy through seamless integration with existing heat source for a few processes involved in automobile industries. Integration of the concentrated solar thermal technology (CST) with the existing heating system is discussed with a case study for commonly used processes in auto industry such as component washing, degreasing and phosphating. The present study is undertaken in a leading automobile plant in India. Component cleaning, degreasing and phosphating are important processes which are carried out in multiple water tanks of varying temperatures. Temperatures of tanks are maintained by electrical heaters which consumes substantial amount of electricity. Non-imaging solar collectors, also known as compound parabolic concentrators (CPC) are used for generation of hot water at required process temperature. The CPC are no