1. Single-crystal LiNi0.5Co0.2Mn0.3O2: a high thermal and cycling stable cathodes for lithium-ion batteries
- Author
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Shang Weili, Lei Chen, Chen Lingzhen, Kong Lingyong, Huang Shaozhen, Ren Wangbao, Ming Sun, and Zhong Zeqin
- Subjects
Materials science ,020502 materials ,Mechanical Engineering ,Thermal decomposition ,chemistry.chemical_element ,02 engineering and technology ,Cathode ,Dielectric spectroscopy ,law.invention ,Differential scanning calorimetry ,0205 materials engineering ,chemistry ,Chemical engineering ,Mechanics of Materials ,law ,General Materials Science ,Lithium ,Thermal stability ,Crystallite ,Single crystal - Abstract
Single-crystalline LiNi0.5Co0.2Mn0.3O2 (denoted as SC-523) with micron size had been successfully synthesized through a facile method. Electrochemical impedance spectroscopy and differential scanning calorimetry were carried out to identify the improved electrochemical performance and desired thermal stability. Even after 100 cycles, SC-523 still delivered a discharge capacity of 151.1 mA h g−1 (capacity retention with 90.3%) at 1 C in voltage range from 3.0 to 4.5 V (vs. Li/Li+), while polycrystalline spherical LiNi0.5Co0.2Mn0.3O2 (denoted as PC-523) only exhibited 141.7 mA h g−1 (capacity retention with 78.4%). Besides, SC-523 shows a higher decomposition temperature of 332.13 °C, 14.61 °C higher than that of PC-523 during the thermal decomposition. Consequently, single-crystalline particles with robust morphological integrity ensure the enhanced cycling stability and thermal stability.
- Published
- 2019