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Funder: German Research Foundation (DFG) SFB-TRR 170 "Late Accretion onto Terrestrial Planets" (subprojects C5, C6) and projects Ts 17/2-1 and NO 1324/2-1, Funder: Swiss National Foundation under grant PZ00P2 174028 and the National Center for Competence in Research PlanetS, Volcanic degassing of planetary interiors has important implications for their corresponding atmospheres. The oxidation state of rocky interiors affects the volatile partitioning during mantle melting and subsequent volatile speciation near the surface. Here we show that the mantle redox state is central to the chemical composition of atmospheres while factors such as planetary mass, thermal state, and age mainly affect the degassing rate. We further demonstrate that mantle oxygen fugacity has an effect on atmospheric thickness and that volcanic degassing is most efficient for planets between 2 and 4 Earth masses. We show that outgassing of reduced systems is dominated by strongly reduced gases such as [Formula: see text], with only smaller fractions of moderately reduced/oxidised gases ([Formula: see text], [Formula: see text]). Overall, a reducing scenario leads to a lower atmospheric pressure at the surface and to a larger atmospheric thickness compared to an oxidised system. Atmosphere predictions based on interior redox scenarios can be compared to observations of atmospheres of rocky exoplanets, potentially broadening our knowledge on the diversity of exoplanetary redox states.

Context. The first opportunity to detect indications for life outside of the Solar System may be provided already within the next decade with upcoming missions such as the James Webb Space Telescope (JWST), the European Extremely Large Telescope (E-ELT) and the Atmospheric Remote-sensing Infrared Exoplanet Large-survey (ARIEL) mission, searching for atmospheric biosignatures on planets in the habitable zone of cool K- and M-stars. Nevertheless, their harsh stellar radiation and particle environment could lead to photochemical loss of atmospheric biosignatures. Aims. We aim to study the influence of cosmic rays on exoplanetary atmospheric biosignatures and the radiation environment considering feedbacks between energetic particle precipitation, climate, atmospheric ionization, neutral and ion chemistry, and secondary particle generation. Methods. We describe newly combined state-of-the-art modeling tools to study the impact of the radiation and particle environment, in particular of cosmic rays, on atmospheric particle interaction, atmospheric chemistry, and the climate-chemistry coupling in a selfconsistent model suite. To this end, models like the Atmospheric Radiation Interaction Simulator (AtRIS), the Exoplanetary Terrestrial Ion Chemistry model (ExoTIC), and the updated coupled climate-chemistry model are combined. Results. In addition to comparing our results to Earth-bound measurements, we investigate the ozone production and -loss cycles as well as the atmospheric radiation dose profiles during quiescent solar periods and during the strong solar energetic particle event of February 23, 1956. Further, the scenario-dependent terrestrial transit spectra, as seen by the NIR-Spec infrared spectrometer onboard the JWST, are modeled. Amongst others, we find that the comparatively weak solar event drastically increases the spectral signal of HNO3, while significantly suppressing the spectral feature of ozone. Because of the slow recovery after such events, the latter indicates that ozone might not be a good biomarker for planets orbiting stars with high flaring rates.

Exoplanet science is one of the most thriving fields of modern astrophysics. A major goal is the atmospheric characterization of dozens of small, terrestrial exoplanets in order to search for signatures in their atmospheres that indicate biological activity, assess their ability to provide conditions for life as we know it, and investigate their expected atmospheric diversity. None of the currently adopted projects or missions, from ground or in space, can address these goals. In this White Paper we argue that a large space-based mission designed to detect and investigate thermal emission spectra of terrestrial exoplanets in the MIR wavelength range provides unique scientific potential to address these goals and surpasses the capabilities of other approaches. While NASA might be focusing on large missions that aim to detect terrestrial planets in reflected light, ESA has the opportunity to take leadership and spearhead the development of a large MIR exoplanet mission within the scope of the "Voyage 2050" long-term plan establishing Europe at the forefront of exoplanet science for decades to come. Given the ambitious science goals of such a mission, additional international partners might be interested in participating and contributing to a roadmap that, in the long run, leads to a successful implementation. A new, dedicated development program funded by ESA to help reduce development and implementation cost and further push some of the required key technologies would be a first important step in this direction. Ultimately, a large MIR exoplanet imaging mission will be needed to help answer one of mankind's most fundamental questions: "How unique is our Earth?"