1. Thermal Stability and Kinetics of Thermal Decomposition for Protionamide
- Author
-
Li Yan-Sheng, Zhao Zhe, Wang Shao-Xu, Li Ying, Tong Bo, Shi Quan, and Tan Zhi-Cheng
- Subjects
Entropy of fusion ,Thermogravimetry ,Chemistry ,Differential thermal analysis ,Thermal decomposition ,Enthalpy ,Kinetics ,Melting point ,Thermodynamics ,Thermal stability ,Physical and Theoretical Chemistry - Abstract
The thermal stability and the kinetics of thermal decomposition of protionamide were studied by thermogravimetry. activation energy e-a of thermal decomposition of this substance was obtained to be 54.65 kj center dot mol(-1) by kissinger method and ozawa-flynn-wall method. kinetics model function and frequency factor a of protionamide were predicted with the malek method, which were f(alpha)=alpha(0.391)(1-alpha)(0.145) and ina=13.12, respectively. moreover, melting point, molar enthalpy and entropy of fusion of this compound were determined to be 414.09 k, 23.21 kj center dot mol(-1), and 56.06 j center dot mol(-1) center dot k-1, respectively.
- Published
- 2007